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1. 发明授权

US07745652B2 Integrated chemical processes for industrial utilization of seed oils 有权
标题翻译：种子油工业利用综合化学工艺
公开(公告)号：US07745652B2
公开(公告)日：2010-06-29
申请号：US12328868
申请日：2008-12-05
申请人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
发明人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
IPC分类号： C07C51/43
CPC分类号： C07D303/42 , C07C67/31 , C07C67/333 , C07C67/347 , C07C67/56 , C07C69/533 , C07C227/08 , C07C227/18 , C07C229/08 , Y02P20/125 , C07C69/716 , C07C69/675
摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ω-polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.
摘要翻译：从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸或酯。还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

2. 发明申请

US20090143544A1 INTEGRATED CHEMICAL PROCESSES FOR INDUSTRIAL UTILIZATION OF SEED OILS 有权
标题翻译：种子油的工业化利用综合化学工艺
公开(公告)号：US20090143544A1
公开(公告)日：2009-06-04
申请号：US12328868
申请日：2008-12-05
申请人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
发明人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
IPC分类号： C08L63/08 , C07C51/43 , C07C59/42 , C07C31/18 , C07C215/00 , C08L79/02 , C08L67/04 , C07C229/00 , C07C69/732 , C07C1/00
CPC分类号： C07D303/42 , C07C67/31 , C07C67/333 , C07C67/347 , C07C67/56 , C07C69/533 , C07C227/08 , C07C227/18 , C07C229/08 , Y02P20/125 , C07C69/716 , C07C69/675
摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.
摘要翻译：从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链的α-烯烃和还原链不饱和酸或酯，优选还原链的α，ω-不饱和酸或酯。还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

3. 发明授权

US07176336B2 Process for the synthesis of unsaturated alcohols 有权
标题翻译：合成不饱和醇的方法
公开(公告)号：US07176336B2
公开(公告)日：2007-02-13
申请号：US10940403
申请日：2004-09-14
申请人： Bob R. Maughon , Kenneth A. Burdett , Zenon Lysenko
发明人： Bob R. Maughon , Kenneth A. Burdett , Zenon Lysenko
IPC分类号： C07C29/00 , C07C33/025 , C07C33/03
CPC分类号： C07C29/095 , C07C67/293 , C07C67/333 , C07C67/475 , C07C69/007 , C07C69/533 , C07C69/593 , C07C69/145 , C07C33/03 , C07C33/035
摘要： A process of preparing an unsaturated alcohol (olefin alcohol), such as, a homo-allylic mono-alcohol or homo-allylic polyol, involving protecting a hydroxy-substituted unsaturated fatty acid or fatty acid ester, such as methyl ricinoleate, derived from a seed oil, to form a hydroxy-protected unsaturated fatty acid or fatty acid ester; homo-metathesizing or cross-metathesizing the hydroxy-protected unsaturated fatty acid or fatty acid ester to produce a product mixture containing a hydroxy-protected unsaturated metathesis product; and deprotecting the hydroxy-protected unsaturated metathesis product under conditions sufficient to prepare the unsaturated alcohol. Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.
摘要翻译：一种制备不饱和醇（烯烃）的方法，例如均聚单醇或均烯基多元醇，包括保护羟基取代的不饱和脂肪酸或脂肪酸酯如蓖麻油酸甲酯，其衍生自种子油，形成羟基保护的不饱和脂肪酸或脂肪酸酯; 羟基保护的不饱和脂肪酸或脂肪酸酯的均匀化或交叉变性以产生含有羟基保护的非饱和复分解产物的产物混合物; 并在足以制备不饱和醇的条件下脱保护羟基保护的不饱和复分解产物。优选地，蓖麻油酸甲酯通过交叉复分解或均一复分解转化成均相烯醇1-癸烯-4-醇或均烯基多元醇9-十八碳烯-7,12-二醇。

4. 发明授权

US07119216B2 Metathesis of unsaturated fatty acid esters or unsaturated fatty acids with lower olefins 有权
标题翻译：不饱和脂肪酸酯或不饱和脂肪酸与低级烯烃的复分解
公开(公告)号：US07119216B2
公开(公告)日：2006-10-10
申请号：US10469321
申请日：2002-02-27
申请人： Thomas H. Newman , Cynthia L. Rand , Kenneth A. Burdett , Bob R. Maughon , Donald L. Morrison , Eric P. Wasserman
发明人： Thomas H. Newman , Cynthia L. Rand , Kenneth A. Burdett , Bob R. Maughon , Donald L. Morrison , Eric P. Wasserman
IPC分类号： C11C3/00
CPC分类号： C07C51/353 , B01J31/1658 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/24 , B01J31/2404 , B01J31/28 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C7/04 , C07C7/12 , C07C67/333 , Y02P20/127 , C07C11/02 , C07C57/03 , C07C69/533
摘要： An olefin metathesis process involving contacting an unsaturated fatty acid ester or unsaturated fatty acid, such as methyloleate or oleic acid, with a lower olefin, preferably ethylene, in the presence of a metathesis catalyst so as to prepare a first product olefin, preferably, a reduced chain α-olefin, such as methyl-9-decenoate or 9-decenoic acid, respectively. The metathesis catalyst contains ruthenium or osmium and a chelating ligand, preferably, a chelating ligand containing a carbene moiety and a second donor moiety of a Group 15 or 16 element Optionally, the catalyst can be supported on a catalyst support, such as, a cross-linked polymeric resin.
摘要翻译：一种烯烃复分解方法，包括使不饱和脂肪酸酯或不饱和脂肪酸如羟甲基或油酸与复分解催化剂存在下使低级烯烃（优选乙烯）接触，以制备第一产物烯烃，优选为还原链α-烯烃，如9-癸烯酸甲酯或9-癸烯酸。复分解催化剂含有钌或锇和螯合配体，优选含有卡宾部分和第15或16族元素的第二供体部分的螯合配体任选地，催化剂可负载在催化剂载体上，例如十字连接的聚合物树脂。

5. 发明申请

US20080103346A1 Membrane Separation Of A Metathesis Reaction Mixture 审中-公开
标题翻译：复分解反应混合物的膜分离
公开(公告)号：US20080103346A1
公开(公告)日：2008-05-01
申请号：US11665723
申请日：2005-10-14
申请人： Kenneth A. Burdett , Baymond M. Collins , Bob R. Maughon , Michael L. Tulchinsky
发明人： Kenneth A. Burdett , Baymond M. Collins , Bob R. Maughon , Michael L. Tulchinsky
IPC分类号： C07C7/144
CPC分类号： C07C7/144 , B01D61/027 , C07C6/04 , C07C2531/24
摘要： A process for separating a homogeneous metathesis catalyst and, optionally, one or more homogeneous metathesis catalyst degradation products from a metathesis reaction mixture containing in addition to said metathesis catalyst and said metathesis catalyst degradation product(s), one or more olefin metathesis products, one or more unconverted reactant olefins, and optionally, a solvent. The process involves contacting the metathesis reaction mixture with a nanofiltration membrane, such as a polyimide nanofiltration membrane, so as to recover a permeate containing a substantial portion of the olefin reaction products, the unconverted reactant olefins, and optional solvent, and a retentate containing the metathesis catalyst, and optionally, metathesis catalyst degradation product(s). In another aspect, this invention pertains to a continuous metathesis reaction-catalyst separation process, preferably, conducted in a nanofiltration membrane reactor.
摘要翻译：一种用于从包含所述复分解催化剂和所述复分解催化剂分解产物的复分解反应混合物中分离均相复分解催化剂和任选的一种或多种均化复分解催化剂降解产物的方法，一种或多种烯烃复分解产物，一种或更多未转化的反应物烯烃，以及任选的溶剂。该方法包括使复分解反应混合物与纳滤膜如聚酰亚胺纳滤膜接触，以回收含有大部分烯烃反应产物，未转化反应物烯烃和任选溶剂的渗透物，以及含有复分解催化剂和任选的复分解催化剂降解产物。另一方面，本发明涉及连续复分解反应 - 催化剂分离方法，优选在纳滤膜反应器中进行。

6. 发明授权

US06313252B1 Functionalized ethylene/vinyl or vinylidene aromatic interpolymers 失效
标题翻译：官能化乙烯/乙烯基或亚乙烯基芳族互聚物
公开(公告)号：US06313252B1
公开(公告)日：2001-11-06
申请号：US09244921
申请日：1999-02-04
申请人： Ray E. Drumright , Robert H. Terbrueggen , Kenneth A. Burdett , Francis J. Timmers , Stephen F. Hahn
发明人： Ray E. Drumright , Robert H. Terbrueggen , Kenneth A. Burdett , Francis J. Timmers , Stephen F. Hahn
IPC分类号： C08F21208
CPC分类号： C08F8/24 , C08F8/30 , C08F2800/10 , C08F2800/20 , C08F2810/30 , C08F2810/50 , C08F210/02 , C08F8/44 , C08F8/32 , C08F8/40 , C08F8/00 , C08F8/10 , C08F8/06 , C08F8/04 , C08F8/34 , C08F8/42 , C08F8/22
摘要： Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.
摘要翻译：公开了新的基本上随机的官能化互聚物及其制备方法。新型互聚物包括由乙烯和乙烯基芳族单体如乙烯 - 苯乙烯互聚物制备的那些，然后用各种亲电子和亲核试剂进行官能化。

7. 发明授权

US4287323A Addition polymerizable polyethers having pendant ethylenically unsaturated urethane groups 失效
标题翻译：具有侧链烯属不饱和氨基甲酸酯基团的加成聚合聚醚
公开(公告)号：US4287323A
公开(公告)日：1981-09-01
申请号：US1125
申请日：1979-01-05
申请人： Nancy B. Tefertiller , Kenneth A. Burdett , Robert F. Harris
发明人： Nancy B. Tefertiller , Kenneth A. Burdett , Robert F. Harris
IPC分类号： C08F299/02 , C08G18/63 , C08G18/81 , C08G65/333 , C09D171/02 , C08L75/08
CPC分类号： C08F299/024 , C08G18/635 , C08G18/81 , C08G18/8116 , C08G65/33396 , C09D171/02 , Y10S525/912 , Y10S525/925
摘要： Addition polymerizable polyethers having pendant ethylenically unsaturated urethane groups are usefully employed as flooring materials and in other applications utilizing radiation curable or chemically curable materials. Such urethane polyethers are advantageously prepared by reacting a polyether polyol such as a hydroxy terminated polypropylene glycol with an isocyanatoalkyl ester of an ethylenically unsaturated acid such as 2-isocyanatoethyl methacrylate.

8. 发明授权

US5488020A Copper-impregnated zeolite composition 失效
标题翻译：铜浸渍沸石组合物
公开(公告)号：US5488020A
公开(公告)日：1996-01-30
申请号：US200258
申请日：1994-02-23
申请人： Ronald W. Diesen , Kenneth A. Burdett , Ravi S. Dixit , Stanley S. T. King
发明人： Ronald W. Diesen , Kenneth A. Burdett , Ravi S. Dixit , Stanley S. T. King
IPC分类号： B01J29/072 , B01J29/06 , C07B61/00 , C07C2/52 , C07C13/20 , C07C2/50
CPC分类号： C07C2/52 , C07C2101/16 , C07C2529/08 , C07C2529/18 , C07C2529/60 , C07C2529/70
摘要： A composition comprising a copper(I) impregnated aluminosilicate zeolite wherein the zeolite is selected from faujasites, L and .OMEGA., and wherein the zeolite has a silica to bulk alumina molar ratio between about 12 and about 50 and a silica to framework alumina molar ratio of at least about 15. The catalyst preparation involves in the following order: drying the selected zeolite, impregnating the dried zeolite with a copper(II) salt, calcining the copper(II)-impregnated zeolite, and reducing the copper(II) to copper(I). The composition is useful as a catalyst for the cyclodimerization of 1,3-butadiene to 4-vinylcyclohexene.
摘要翻译：一种包含铜（I）浸渍的硅铝酸盐沸石的组合物，其中所述沸石选自八面沸石，L和OMEGA，并且其中所述沸石的二氧化硅与本体氧化铝摩尔比为约12至约50，二氧化硅与骨架氧化铝的摩尔比为催化剂制备按以下顺序包括：干燥所选择的沸石，用铜（II）盐浸渍干燥的沸石，煅烧铜（II）浸渍的沸石，并将铜（II）还原成铜（一世）。该组合物可用作1,3-丁二烯环化为4-乙烯基环己烯的催化剂。

9. 发明授权

US5196621A Process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes 失效
标题翻译：将1,3-丁二烯环化为4-乙烯基环己烯的方法
公开(公告)号：US5196621A
公开(公告)日：1993-03-23
申请号：US688808
申请日：1991-04-19
申请人： Ronald W. Diesen , Kenneth A. Burdett , Ravi S. Dixit , Stanley S. T. King , Michael M. Olken
发明人： Ronald W. Diesen , Kenneth A. Burdett , Ravi S. Dixit , Stanley S. T. King , Michael M. Olken
IPC分类号： C07C2/52
CPC分类号： C07C2/52 , C07C2101/16 , C07C2529/08 , C07C2529/18 , C07C2529/60 , C07C2529/70
摘要： A process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes comprising contacting a butadiene in the presence of a promoting amount of a hydroxylic solvent with a catalyst containing copper(I) ions supported on a carrier. A second process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes comprising contacting a butadiene with a catalytic amount of a copper(I)-impregnated aluminosilicate zeolite characterized by a bulk SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio in the range from about 5 to about 50 and a framework SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least about 15. A catalyst composition comprising a copper(I)-impregnated zeolite of specified bulk and framework silica to alumina molar ratios and specified water content. The catalyst exhibits high activity and long lifetime in the aforementioned dimerization processes and is easily regenerated.
摘要翻译：将1,3-丁二烯环化为4-乙烯基环己烯的方法包括在促进量的羟基溶剂存在下使丁二烯与负载在载体上的含有（I）的离子的催化剂接触。 1,3-丁二烯环化为4-乙烯基环己烯的第二种方法，包括将丁二烯与催化量的浸渍硅酸铜（I）的硅酸铝沸石接触，其特征在于本体SiO 2 / Al 2 O 3摩尔比在约5- 约50，骨架SiO 2 / Al 2 O 3摩尔比为至少约15.一种催化剂组合物，其包含具有规定体积和骨架二氧化硅与氧化铝摩尔比的特定水含量的铜（I）浸渍沸石。该催化剂在上述二聚过程中表现出高的活性和长的使用寿命，并且易于再生。

10. 发明授权

US4278809A Process for preparing 2-isocyanatoalkyl esters of organic carboxylic acids 失效
标题翻译：制备有机羧酸的2-异氰酸根合烷基酯的方法
公开(公告)号：US4278809A
公开(公告)日：1981-07-14
申请号：US806805
申请日：1977-06-15
申请人： Kenneth A. Burdett
发明人： Kenneth A. Burdett
IPC分类号： C07C265/04 , C07C67/00 , C07C67/18 , C07C241/00 , C07C263/10 , C07D263/12 , C07D263/14
CPC分类号： C07C263/08 , C07D263/12 , C07D263/14
摘要： 2-Isocyanatoalkyl esters of organic carboxylic acids are prepared by reacting (a) an aqueous solution of a 2-oxazoline with (b) an organic solution of phosgene dissolved in a water-immiscible organic solvent in the presence of (c) a hydrochloric acid acceptor. As an example, 2-isocyanatoethyl methacrylate was prepared by concurrently blending an aqueous stream of 2-isopropenyl-2-oxazoline, a methylene chloride stream of phosgene and an aqueous stream of sodium hydroxide at a temperature of from about 0.degree. C. to about 10.degree. C. The reaction rate is very high and the reaction is essentially complete upon blending the reactants.
摘要翻译：有机羧酸的2-异氰酸烷基酯通过在（c）盐酸存在下，使（a）2-恶唑啉的水溶液与（b）溶解在与水不混溶的有机溶剂中的光气的有机溶液反应受体。作为实例，通过在约0℃至约约0℃的温度下同时混合2-异丙烯基-2-恶唑啉的水流，光气的二氯甲烷流和氢氧化钠的水流，制备甲基丙烯酸2-异氰酸基乙酯 10℃。反应速率非常高，并且在混合反应物时反应基本上完成。

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