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1. 发明授权

US4911899A Zeolite particles having bacteriocidal properties 失效
标题翻译：沸石颗粒具有杀菌特性
公开(公告)号：US4911899A
公开(公告)日：1990-03-27
申请号：US296299
申请日：1988-12-28
申请人： Zenji Hagiwara , Shigetaka Hoshino , Hiroo Ishino , Saburo Nohara , Kenichi Tagawa , Keio Yamanaka
发明人： Zenji Hagiwara , Shigetaka Hoshino , Hiroo Ishino , Saburo Nohara , Kenichi Tagawa , Keio Yamanaka
IPC分类号： C08K9/00 , A01N25/34 , A01N59/00 , A01N59/16 , A01N59/20 , A46D1/00 , A61K33/30 , A61K33/34 , A61K33/38 , A61L2/16 , B32B27/18 , C08J3/20 , C08J5/00 , C08J5/18 , C08K3/34 , C08K9/02 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09D5/14 , D01F1/02 , D01F1/10 , D01F6/54 , D01F6/90 , D01F6/92 , C01B33/28
CPC分类号： C08K3/34 , A01N25/34 , A01N59/16 , A01N59/20 , A46D1/00 , A46D1/023 , Y10S264/25 , Y10S423/21 , Y10S423/24 , Y10S423/25 , Y10T428/25 , Y10T428/256 , Y10T428/2991
摘要： Zeolite particles retaining at least one metal ion having bacteriostatic properties on their ion-exchangeable sites in an amount up to 41% of the zeolite's ion exchange capacity are described.
摘要翻译：含有其上具有杀菌性的金属离子的沸石颗粒的聚合物制品，例如，通过离子交换反应提供的Ag，Cu或Zn表现出优异的杀菌效果和效果的耐久性，但不会降低聚合物的物理性能。聚合物制品通过将先前提供有金属离子的沸石颗粒与聚合物混合或通过将含沸石的聚合物模塑成制品然后用金属离子溶液处理制品来制备。

2. 发明授权

US4775585A Polymer article having an antibacterial property containing zeolite particles therein and the processes for producing same 失效
标题翻译：具有含有沸石颗粒的抗菌性的聚合物制品及其制造方法
公开(公告)号：US4775585A
公开(公告)日：1988-10-04
申请号：US8250
申请日：1987-01-29
申请人： Zenji Hagiwara , Shigetaka Hoshino , Hiroo Ishino , Saburo Nohara , Kenichi Tagawa , Keio Yamanaka
发明人： Zenji Hagiwara , Shigetaka Hoshino , Hiroo Ishino , Saburo Nohara , Kenichi Tagawa , Keio Yamanaka
IPC分类号： C08K9/00 , A01N25/34 , A01N59/00 , A01N59/16 , A01N59/20 , A46D1/00 , A61K33/30 , A61K33/34 , A61K33/38 , A61L2/16 , B32B27/18 , C08J3/20 , C08J5/00 , C08J5/18 , C08K3/34 , C08K9/02 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09D5/14 , D01F1/02 , D01F1/10 , D01F6/54 , D01F6/90 , D01F6/92 , B01D39/08
CPC分类号： C08K3/34 , A01N25/34 , A01N59/16 , A01N59/20 , A46D1/00 , A46D1/023 , Y10S264/25 , Y10S423/21 , Y10S423/24 , Y10S423/25 , Y10T428/25 , Y10T428/256 , Y10T428/2991
摘要： A polymer article containing zeolite particles on which metal ion having a bactericidal property, e.g. Ag, Cu or Zn, is provided by an ion exchange reaction shows an excellent bactericidal effect and durability of the effect, but no deterioration of physical properties of the polymer.The polymer article is produced by admixing zeolite particles previously provided with the metal ion with a polymer or by moulding a zeolite-containing polymer into an article and then treating the article with a metal ion solution.
摘要翻译：含有其上具有杀菌性的金属离子的沸石颗粒的聚合物制品，例如，通过离子交换反应提供的Ag，Cu或Zn表现出优异的杀菌效果和效果的耐久性，但不会降低聚合物的物理性能。聚合物制品通过将先前提供有金属离子的沸石颗粒与聚合物混合或通过将含沸石的聚合物模塑成制品然后用金属离子溶液处理制品来制备。

3. 发明授权

US4911898A Zeolite particles retaining silver ions having antibacterial properties 失效
标题翻译：保留银离子的沸石颗粒具有抗菌性能
公开(公告)号：US4911898A
公开(公告)日：1990-03-27
申请号：US301909
申请日：1988-12-28
申请人： Zenji Hagiwara , Shigetaka Hoshino , Hiroo Ishino , Saburo Nohara , Kenichi Tagawa , Keio Yamanaka
发明人： Zenji Hagiwara , Shigetaka Hoshino , Hiroo Ishino , Saburo Nohara , Kenichi Tagawa , Keio Yamanaka
IPC分类号： C08K9/00 , A01N25/34 , A01N59/00 , A01N59/16 , A01N59/20 , A46D1/00 , A61K33/30 , A61K33/34 , A61K33/38 , A61L2/16 , B32B27/18 , C08J3/20 , C08J5/00 , C08J5/18 , C08K3/34 , C08K9/02 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09D5/14 , D01F1/02 , D01F1/10 , D01F6/54 , D01F6/90 , D01F6/92 , C01B33/28
CPC分类号： C08K3/34 , A01N25/34 , A01N59/16 , A01N59/20 , A46D1/00 , A46D1/023 , Y10S264/25 , Y10S423/21 , Y10S423/24 , Y10S423/25 , Y10T428/25 , Y10T428/256 , Y10T428/2991
摘要： Zeolite particles retaining silver ions having bacteriostatic properties on their ion-exchangeable sites in an amount up to 41% of the zeolite's exchange capacity are described.
摘要翻译：含有其上具有杀菌性的金属离子的沸石颗粒的聚合物制品，例如，通过离子交换反应提供的Ag，Cu或Zn表现出优异的杀菌效果和效果的耐久性，但不会降低聚合物的物理性能。聚合物制品通过将先前提供有金属离子的沸石颗粒与聚合物混合或通过将含沸石的聚合物模塑成制品然后用金属离子溶液处理制品来制备。

4. 发明授权

US4525410A Particle-packed fiber article having antibacterial property 失效
标题翻译：具有抗菌性的颗粒填充纤维制品
公开(公告)号：US4525410A
公开(公告)日：1985-06-25
申请号：US525980
申请日：1983-08-24
申请人： Zenji Hagiwara , Hideo Ohki , Shigetaka Hoshino , Saburo Nohara , Shunya Ida , Kenichi Tagawa
发明人： Zenji Hagiwara , Hideo Ohki , Shigetaka Hoshino , Saburo Nohara , Shunya Ida , Kenichi Tagawa
IPC分类号： A01N25/34 , A01N59/16 , A01N59/20 , A61L2/16 , A61L15/18 , D06M16/00 , A61K9/70 , A61K33/34 , A61K33/38 , D06M11/04
CPC分类号： D06M16/00 , A01N25/34 , A01N59/16 , A01N59/20 , A61L15/18 , A61L2/16 , Y10T428/24826 , Y10T442/642
摘要： Specific zeolite particles retaining therein a metal ion having a bactericidal activity are packed and retained in a mixed fiber assembly composed of low-melting thermoplastic synthetic fibers and ordinary fibers. The zeolite particles are retained by welding of the low-temperature thermoplastic synthetic fibers but in a state of allowing the contact thereof with an external fluid. The particle-packed fiber article has an excellent and durable antibacterial activity and can be used in various fields.
摘要翻译：保留有具有杀菌活性的金属离子的特定沸石颗粒被填充并保留在由低熔点热塑性合成纤维和普通纤维构成的混合纤维组合物中。沸石颗粒通过低温热塑性合成纤维的焊接保持，但是在允许其与外部流体接触的状态下。颗粒填充纤维制品具有优异且耐久的抗菌活性，可用于各种领域。

5. 发明授权

US4929431A Process for producing amorphous aluminosilicates 失效
标题翻译：无定形硅铝酸盐的制备方法
公开(公告)号：US4929431A
公开(公告)日：1990-05-29
申请号：US83710
申请日：1987-08-10
申请人： Zenji Hagiwara , Satoshi Ando , Saburo Nohara
发明人： Zenji Hagiwara , Satoshi Ando , Saburo Nohara
IPC分类号： C01B33/26 , A01N25/08 , A01N59/06 , A01N59/16 , A01N59/18 , A01N59/20 , B01J39/14 , C01B33/46 , C01B39/46 , C08K3/34 , C09C1/40
CPC分类号： B82Y30/00 , A01N59/16 , A01N59/18 , A01N59/20 , C01B33/28 , C08K3/34 , C09C1/405 , C01P2002/02 , C01P2002/72 , C01P2004/03 , C01P2004/50 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/32
摘要： There is disclosed a process for producing an amorphous aluminosilicate having the formula:2Na.sub.x O.Al.sub.2 O.sub.3.ySiO.sub.2(wherein x is a number between 0.6 and 1.8 inclusive; and y is a number between 1.3 and 7 inclusive); which comprises:a step of maintaining an alkali solution (Solution-C), the alkalinity of which is within the range of 1.2-3.5N under stirring;a step of adding a sodium aluminate solution (Solution-A) containing free alkali and sodium silicate solution or colloidal silica solution (Solution-B) containing free alkali to the Solution-C, separately to prepare a slurry which contains an amorphous sodium aluminosilicate in the form of finely divided particles which are only slightly soluble in water; anda step of aging the slurry, characterized in that the addition of Solution-A and Solution-B into Solution-C is carried out so that the Si/Al ratio in the resultant mixture is kept within the range of 0.7 to 7.6 during and after the addition, and mixing effected at 55.degree. C. or lower, and Solution-A and Solution-B are prepared so that both the alkalinity of the aqueous solution phase during the formation of the slurry and during the maturing is kept within .+-.0.30N of the alkalinity of Solution-C.
摘要翻译：公开了一种用于制备具有下式的无定形硅铝酸盐的方法：其中x是包括0.6和1.8之间的数字; y是包括1.3和7之间的数字）; 其包括：在搅拌下将其碱度处于1.2-3.5N范围内的碱溶液（溶液C）的保持步骤; 将含有游离碱和硅酸钠溶液的铝酸钠溶液（溶液A）或含有游离碱的胶体二氧化硅溶液（溶液B）分别加入到溶液C中以制备含有无定形硅铝酸钠的浆料的步骤仅微溶于水的微细颗粒的形式; 以及使浆料老化的步骤，其特征在于将溶液-A和溶液-B加入到溶液C中，使得所得混合物中的Si / Al比保持在0.7至7.6的范围内，加入后，在55℃以下进行混合，制备溶液A和溶液-B，使浆料形成期间和成熟期间的水溶液相的碱度保持在+ -0.30N的溶液C的碱度。

6. 发明授权

US5827524A Antimicrobial polymer composition 失效
标题翻译：抗微生物聚合物组成
公开(公告)号：US5827524A
公开(公告)日：1998-10-27
申请号：US584001
申请日：1996-01-11
申请人： Zenji Hagiwara , Kazuo Kishimoto , Hiroshi Yamazaki
发明人： Zenji Hagiwara , Kazuo Kishimoto , Hiroshi Yamazaki
IPC分类号： A01N25/10 , A01N25/08 , A01N59/16 , A01N59/20 , C08K3/00 , C08K3/34 , C08K3/36 , C08K9/02 , C08L101/00 , A61K9/10
CPC分类号： C08K9/02 , A01N59/16 , C08K3/36
摘要： The present invention relates to a novel antimicrobial polymer composition comprising a novel crystalline antimicrobial composition. More particularly, the present invention relates to an antimicrobial polymer composition comprising a crystalline antimicrobial composition and a polymer, wherein said crystalline antimicrobial composition comprises a crystalline silicon dioxide containing silver ions and one or two optional metal ions selected from the group consisting of zinc and copper.
摘要翻译：本发明涉及包含新型结晶抗微生物组合物的新型抗微生物聚合物组合物。更具体地，本发明涉及包含结晶抗微生物组合物和聚合物的抗微生物聚合物组合物，其中所述结晶抗微生物组合物包含含有银离子的结晶二氧化硅和选自锌和铜的一种或两种任选的金属离子。

7. 发明授权

US5298252A Antimicrobial composition having resistance to heat and weathers 失效
标题翻译：具有耐热性和耐候性的抗微生物组合物
公开(公告)号：US5298252A
公开(公告)日：1994-03-29
申请号：US751969
申请日：1991-08-29
申请人： Zenji Hagiwara , Masao Okubo
发明人： Zenji Hagiwara , Masao Okubo
IPC分类号： A01N25/08 , A01N59/16 , A01N59/20 , A01N61/00 , C08K3/34 , C08K9/02 , C08K9/12 , C08L101/00 , B32B5/16
CPC分类号： C08K9/12 , A01N59/16 , A01N59/20 , Y10T428/24826 , Y10T428/2991
摘要： A silica gel based heat-resistant and weatherproof antimicrobial composition having an aluminosilicate layer on the surfaces of pores in the silica gel as substituted by silver and an optional antimicrobial metal, said composition containing ion-exchangeable metals that are chiefly an alkali metal and that are present in an amount of up to 2.57 mmol per gram of said composition on an anhydrous basis.
摘要翻译：一种基于硅胶的耐热和耐候性的抗微生物组合物，其在硅胶作为银取代的孔表面上具有铝硅酸盐层和任选的抗微生物金属，所述组合物含有主要为碱金属的可离子交换的金属，以每克所述组合物的无水量存在高达2.57mmol的量。

8. 发明授权

US5698212A Antimicrobial polymer composition 失效
标题翻译：抗微生物聚合物组成
公开(公告)号：US5698212A
公开(公告)日：1997-12-16
申请号：US614251
申请日：1996-03-12
申请人： Zenji Hagiwara
发明人： Zenji Hagiwara
IPC分类号： A01N25/10 , A01N43/78 , A01N59/16 , C08K3/34 , C08K3/36 , C08K5/00 , C08K5/45 , C08K5/47 , C08K7/02 , C08K13/02 , C08L101/00 , A01N25/26 , A01N25/08
CPC分类号： C08K7/02 , A01N59/16 , C08K5/0058
摘要： The present invention provides a novel antimicrobial polymer composition having superior weatherability and discoloration resistance to those of the prior art. The present invention provides an antimicrobial polymer composition comprising a polymer and an antimicrobial composition having an antimicrobial coat of an aluminosilicate on the surface of silica gel, wherein said aluminosilicate containing antimicrobial metal ions, characterized in that said antimicrobial polymer composition further comprises thiabendazole.
摘要翻译：本发明提供了一种具有优于现有技术的耐候性和耐变色性的新型抗微生物聚合物组合物。本发明提供一种抗微生物聚合物组合物，其包含聚合物和在硅胶表面上具有硅铝酸盐的抗微生物涂层的抗微生物组合物，其中所述含硅酸铝的抗微生物金属离子的特征在于所述抗微生物聚合物组合物还包含噻苯达唑。

9. 发明授权

US5413789A Antimicrobial composition of aluminosilicate coated silica gel 失效
标题翻译：硅铝酸盐涂层硅胶的抗微生物组成
公开(公告)号：US5413789A
公开(公告)日：1995-05-09
申请号：US61685
申请日：1993-05-17
申请人： Zenji Hagiwara , Masao Okubo
发明人： Zenji Hagiwara , Masao Okubo
IPC分类号： A61L2/16 , A01N25/10 , A01N25/26 , A01N59/16 , A01N59/20 , A01N61/00 , C01B33/159 , C02F1/50 , C08K9/02 , D01F1/10 , D01F6/04
CPC分类号： D01F6/04 , A01N25/10 , A01N25/26 , A01N59/16 , A01N59/20 , C02F1/505 , C08K9/02 , D01F1/103
摘要： The invention provides a novel antibacterial compound and a process for producing it. Futhermore, the invention provides a novel antibacterial polymer composite comprising a polymer and the antimicrobial compositon.
摘要翻译：本发明提供了一种新型的抗菌化合物及其生产方法。此外，本发明提供了包含聚合物和抗微生物组合物的新型抗菌聚合物复合物。

10. 发明授权

US5064599A Process for producing an antibacterial fiber article 失效
标题翻译：生产防霉纤维制品的方法
公开(公告)号：US5064599A
公开(公告)日：1991-11-12
申请号：US512566
申请日：1990-04-24
申请人： Satoshi Ando , Akira Dohno , Zenji Hagiwara
发明人： Satoshi Ando , Akira Dohno , Zenji Hagiwara
IPC分类号： C08K3/34 , A01N25/34 , A01N59/16 , A01N59/20 , C08K7/16 , C08K7/18 , C08K9/08 , C08K9/12 , C08L101/00 , D01D5/30 , D01F1/10 , D01F8/04 , D01F8/06 , D01F8/14
CPC分类号： D04H1/54 , A01N25/34 , A01N59/16 , A01N59/20
摘要： Zeolite particles retaining antibacterial metal ion, such as Ag, Cu or Zn ion, at ion-exchangeable sites of the zeolite are included in a low-melting component of conjugated fibers which comprise a low-melting component and a high-melting component. Upon heating, the low-melting component spreads to cause more zeolite particles to be exposed, which yields higher antibacterial activity in a fiber article produced from the conjugated fibers.

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