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    • 1. 发明授权
    • Imaging element comprising a hydrophobic photopolymerizable composition
and method for producing lithographic plates therewith
    • 包含疏水性光聚合组合物的成像元件及其制造平版印刷版的方法
    • US5922506A
    • 1999-07-13
    • US539960
    • 1995-10-06
    • Yvan HoogmartensMarc Van DammeJoan VermeerschYves Verburgh
    • Yvan HoogmartensMarc Van DammeJoan VermeerschYves Verburgh
    • G03F7/004G03F7/00G03F7/027G03F7/028G03F7/033G03F7/038G03F7/039G03F7/09G03F7/095G03F7/34G03C1/76G03F7/26
    • G03F7/0955G03F7/34
    • The present invention provides a negative-working photosensitive imaging element comprising on a hydrophilic surface of a support in the order given (i) a hydrophobic photopolymerizable composition capable of being irradiated with actinic light through the support and/or through the front and containing at least one unsaturated compound with at least one polymerizable ethylenically unsaturated group, at least one hydrophobic thermoplastic polymer and at least one photoinitiator, and (ii) optionally a receptor layer, characterized in that said hydrophobic photopolymerizable composition comprises in the order given (i) a polymerizable layer contiguous to said hydrophilic surface and comprising at least part of said at least one unsaturated compound and (ii) a hydrophobic photosensitive layer contiguous to said polymerizable layer comprising at least part of said at least one hydrophobic thermoplastic polymer and of said at least one photoinitiator.The present invention also provides a method for obtaining a lithographic plate of high quality with said imaging element.
    • 本发明提供一种负性光敏成像元件,其按照以下顺序包含在载体的亲水性表面上:(i)疏水性光聚合性组合物,其能够通过载体和/或通过前面并通过前部照射光化学光,并且至少含有 一种具有至少一个可聚合烯键式不饱和基团的不饱和化合物,至少一种疏水性热塑性聚合物和至少一种光引发剂,和(ii)任选的受体层,其特征在于所述疏水性可光聚合组合物按照下列顺序包含:(i) 所述至少一部分所述至少一种不饱和化合物和(ii)与所述可聚合层邻接的疏水光敏层,其包含至少部分所述至少一种疏水性热塑性聚合物和所述至少一种光引发剂 。 本发明还提供了一种利用所述成像元件获得高质量的平版印刷版的方法。
    • 4. 发明授权
    • Recording material with improved image tone and or stability upon
thermal development
    • 记录材料具有改善的图像色调和热稳定性
    • US6114100A
    • 2000-09-05
    • US323861
    • 1999-06-01
    • Ingrid GeuensYvan GilliamsDirk BollenYvan HoogmartensAndre Bellens
    • Ingrid GeuensYvan GilliamsDirk BollenYvan HoogmartensAndre Bellens
    • G03C1/498G03C1/490
    • G03C1/49809G03C1/4989
    • A recording material comprising a support and a thermosensitive element comprising silver palmitate, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the silver palmitate is not associated with mercury and/or lead ions and when the recording material is irradiated with a copper K.alpha..sub.1 X-ray source the ratio of the sum of the peak heights of the X-ray diffraction lines attributable to silver palmitate at Bragg angles, 2.THETA., of 4.01.degree., 6.049.degree., 8.031.degree., 10.06.degree., 12.08.degree. and 14.09.degree. to the sum of the peak heights of the X-ray diffraction lines at Bragg angles, 2.THETA., of 25.60.degree., 35.16.degree. and 43.40.degree. of NIST standard 1976, rhombohedral Al.sub.2 O.sub.3, determined with the same X-ray diffractometer in the same state of adjustment on a sample of the recording material and a sample of the NIST standard 1976 cut to fit a sample holder of the X-ray diffractometer, divided by the square root of the quantity of silver in the recording material, expressed in g per m.sup.2, is greater than 3.09 m/g.sup.0.5 ; and a process for producing particles of substantially light-insensitive organic silver salt comprising silver palmitate with these X-ray characteristics in the substantial absence of organic solvent.
    • 一种记录材料,包括支持体和包含棕榈酸棕榈酯的热敏元件,与其热加工关系的有机还原剂和粘合剂,其中棕榈酸银与汞和/或铅离子不相关,并且当记录材料被照射时 铜Kα1 X射线源是归因于布拉格角棕榈酸酯的X射线衍射线的峰高之和的比值为4.01°,6.049°,8.031°,10.06°,12.08° DEG和14.09°与布拉格角的X射线衍射线的峰高和2 THETA的峰值高度之和为25.60°,35.16°和43.40°的NIST标准1976,菱形Al2O3,用相同的X射线衍射仪测定 在与记录材料的样品相同的调整状态下,将NIST标准1976的样品切割成适合X射线衍射仪的样品架,除以银的量的平方根 以g / m2表示的记录材料大于3.09m / g0.5; 以及在基本上不存在有机溶剂的情况下,生产具有这些X射线特性的棕榈酸棕榈酯的基本上不透光的有机银盐颗粒的方法。
    • 6. 发明授权
    • Recording material with improved shelf-line producing prints upon
thermal development with improved archivability
    • 具有改进的架线生产印刷品的记录材料在热显影时具有改进的可归档性
    • US6127102A
    • 2000-10-03
    • US323860
    • 1999-06-01
    • Ingrid GeuensYvan GilliamsDirk BollenYvan HoogmartensAndre Bellens
    • Ingrid GeuensYvan GilliamsDirk BollenYvan HoogmartensAndre Bellens
    • G03C1/498
    • G03C1/49809G03C1/4989
    • A recording material comprising a support and a thermosensitive element containing silver stearate, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the silver stearate is not associated with mercury and/or lead ions and when the recording material is irradiated with a copper K.alpha..sub.1 X-ray source the ratio of the sum of the peak heights of the X-ray diffraction lines attributable to silver stearate at Bragg angles, 2.THETA., of 2.THETA., of 3.62.degree., 5.45.degree., 7.30.degree., 9.04.degree., 10.97.degree. and 12.71.degree. to the sum of the peak heights of the X-ray diffraction lines at Bragg angles, 2.THETA., of 25.60.degree., 35.16.degree. and 43.40.degree. of NIST standard 1976, rhombohedral Al.sub.2 O.sub.3, determined with the same X-ray diffractometer in the same state of adjustment on a sample of the recording material and a sample of the NIST standard 1976 cut to fit a sample holder of the X-ray diffractometer, divided by the square root of the quantity of silver in the recording material, expressed in g per m.sup.2, is greater than 2.2 m/g.sup.0.5 ; and a process for producing particles of substantially light-insensitive organic silver salt comprising silver stearate with these X-ray characteristics in the substantial absence of organic solvent.
    • 一种记录材料,包括载体和含有硬脂酸银的热敏元件,与其热加工关系的有机还原剂和粘合剂,其中所述硬脂酸银与汞和/或铅离子不相关,并且当记录材料被照射时 铜Kα1 X射线源是归因于布拉格角度的硬脂酸银的X射线衍射线的峰高之和的比例,2TETA的2 THETA为3.62°,5.45°,7.30°, 9.04°,10.97°和12.71°,相对于布拉格角X射线衍射线的峰高,2 THETA,相同的NIST标准1976的25.6°F,35.16°和43.40°的峰高度之和 在对记录材料的样品进行相同调整状态的X射线衍射仪和NIST标准1976的样品切割以适合X射线衍射仪的样品架,除以银量的平方根 在记录材料中,以g / m2表示,大于2.2m / g0.5; 以及在基本上不存在有机溶剂的情况下,制造具有这些X射线特性的基本上不含光敏性的有机银盐的颗粒的方法。