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    • 3. 发明申请
    • PRESSURE-SENSITIVE ADHESIVE AND RETARDATION LAYER-ATTACHED POLARIZING PLATE, METHOD FOR MANUFACTURING THEREOF, OPTICAL FILM, AND IMAGE DISPLAY
    • 压敏粘合剂和延缓层附着的极化板,其制造方法,光学膜和图像显示
    • US20100039590A1
    • 2010-02-18
    • US12066462
    • 2006-09-28
    • Minoru MiyatakeHiroaki MizushimaYuusuke ToyamaYuuji SaikiNaoyuki Nitta
    • Minoru MiyatakeHiroaki MizushimaYuusuke ToyamaYuuji SaikiNaoyuki Nitta
    • G02F1/1335G02B1/08B32B37/00
    • C09J133/02C08K5/0025C09J129/04C09J133/06C09J133/08C09J2201/606G02B5/305Y10T156/10Y10T428/1059
    • A pressure-sensitive adhesive and retardation layer-attached polarizing plate (4) of the invention comprises a retardation layer-attached polarizing plate (3) comprising a polarizing plate (2) that comprises an iodine-based polarizer (1) and a transparent protective film laminated on both sides of the polarizer (1); and a retardation layer provided on at least one of the transparent protective films; and an acrylic pressure-sensitive adhesive layer laminated on the retardation layer side of the retardation layer-attached polarizing plate (3), wherein the iodine-based polarizer (1) has a ratio (K/I), which is the content (% by weight) of potassium (K) to the content (% by weight) of iodine (I) in the polarizer, of 0.200 to 0.235, the polarizing plate (2) comprises the iodine-based polarizer (1) and the transparent protective film laminated with an adhesive layer formed from a water-soluble adhesive containing an acetoacetyl group-containing polyvinyl alcohol resin and a crosslinking agent, the retardation layer-attached polarizing plate (3) has a measured dimensional shrinkage of 0.5% or less in the direction of its absorption axis after it is allowed to stand at 80° C. for 24 hours, the pressure-sensitive adhesive and retardation layer-attached polarizing plate (4) has a single-piece transmittance of 41.0% to 43.2%. The pressure-sensitive adhesive and retardation layer-attached polarizing plate can resist a change in optical properties and keep visibility high, even under heated or humidified conditions.
    • 本发明的压敏粘合剂和相位差层附着的偏光板(4)包括具有偏振板(2)的延迟层附着的偏光板(3),该偏光板包括碘系偏振片(1)和透明保护膜 薄膜层压在偏振器(1)的两侧; 以及设置在所述透明保护膜中的至少一个上的延迟层; 以及层叠在相位差层附着的偏光板(3)的相位差层侧的丙烯酸系压敏粘合剂层,其中,所述碘系偏振片(1)的比例(K / I)为所述含量(% (K)相对于偏振片中碘(I)的含量(重量%)为0.200〜0.235,偏振片(2)包含碘系偏振片(1)和透明保护膜 层压有由含有含乙酰乙酰基的聚乙烯醇树脂和交联剂的水溶性粘合剂形成的粘合剂层,所述延迟层附着的偏光板(3)的测定尺寸收缩率为0.5%以下, 其吸收轴在80℃静置24小时后,粘合剂和延迟层附着的偏光板(4)的单片透射率为41.0%〜43.2%。 压敏粘合剂和延迟层附着的偏光板即使在加热或加湿的条件下也能抵抗光学性能的变化并保持可见性。