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    • 8. 发明授权
    • Thermoplastic resin composition
    • 热塑性树脂组合物
    • US5206284A
    • 1993-04-27
    • US728285
    • 1991-07-11
    • Osamu FukuiKiyoshi TsutsuiTomohiko AkagawaIkunori SakaiTakao NomuraTakeyoshi NishioToshio YokoiNobuya Kawamura
    • Osamu FukuiKiyoshi TsutsuiTomohiko AkagawaIkunori SakaiTakao NomuraTakeyoshi NishioToshio YokoiNobuya Kawamura
    • C08K3/34C08L51/00C08L51/06C08L53/00C08L53/02C08L77/00
    • C08L51/006C08K3/346C08L51/06C08L53/005C08L53/025C08L77/00
    • A polypropylene thermoplastic resin composition comprising (a) a modified crystalline polypropylene of a crystalline polypropylene comprising said modified crystalline polypropylene and (b) a modified polyamide obtained by partially or wholly grafting a polyamide with a clay mineral. A polypropylene thermoplastic resin composition comprising, in addition to the above polypropylene thermoplastic resin composition comprising the components (a) and (b), one or any combination of the following components (c), (d) and (e): (c) an ethylene-.alpha.-olefin copolymer rubber or a modified ethylene-.alpha.-olefin copolymer rubber, (d) a block copolymer between a monovinyl-substituted aromatic hydrocarbon and a conjugated diene, a hydrogenation product of said block copolymer, or a modification product of said block copolymer, and (e) an inorganic filler. The modified polyamide as the component (b), obtained by modifying a polyamide with a clay mineral has good compatibility with or good dispersibility in the component (a), i.e. the modified crystalline polypropylene or the crystalline polypropylene comprising the modified crystalline polypropylene. Therefore, the polypropylene thermoplastic resin composition comprising these components (a) and (b) has excellent heat resistance and excellent impact resistance.
    • 一种聚丙烯热塑性树脂组合物,其包含(a)包含所述改性结晶聚丙烯的结晶聚丙烯的改性结晶聚丙烯和(b)通过部分或全部用粘土矿物接枝聚酰胺获得的改性聚酰胺。 一种聚丙烯热塑性树脂组合物,除了包含组分(a)和(b)的上述聚丙烯热塑性树脂组合物外,还包含以下组分(c),(d)和(e)中的一种或任意组合:(c) 乙烯-α-烯烃共聚物橡胶或改性乙烯-α-烯烃共聚物橡胶,(d)单乙烯基取代的芳烃和共轭二烯之间的嵌段共聚物,所述嵌段共聚物的氢化产物或 所述嵌段共聚物,和(e)无机填料。 通过用粘土矿物改性聚酰胺获得的作为组分(b)的改性聚酰胺与组分(a),即改性结晶聚丙烯或包含改性结晶聚丙烯的结晶聚丙烯具有良好的相容性或良好的分散性。 因此,包含这些组分(a)和(b)的聚丙烯热塑性树脂组合物具有优异的耐热性和优异的耐冲击性。
    • 10. 发明授权
    • Polypropylene resin composition
    • 聚丙烯树脂组合物
    • US5883174A
    • 1999-03-16
    • US680971
    • 1996-07-16
    • Tomohiko AkagawaIkunori SakaiSaburo HinenoyaYasuo KitaKaoru InoueTakeyoshi NishioTakao Nomura
    • Tomohiko AkagawaIkunori SakaiSaburo HinenoyaYasuo KitaKaoru InoueTakeyoshi NishioTakao Nomura
    • C08K3/34C08L23/16C08L53/00C08J5/10C08L23/12
    • C08L53/00
    • A polypropylene resin composition having excellent rigidity, impact resistance and formability (moldability) and thus useful for the interior parts of automobile, includes (A) a crystalline E/P block copolymer containing a fraction Ac soluble in p-xylene at room temperature and having an ethylene content of 18 to 22%; (B) a crystalline E/P block copolymer containing a fraction Bc soluble in p-xylene at room temperature and having an ethylene content of 27 to 40% and (C) talc particles having an average size of 3 to 5 .mu.m and largest size less than 20 .mu.m, in which composition, (a) the p-xylene-soluble fractions Ac and Bc are in contents As and Bs based on the total weight of the copolymers (A) and (B) and satisfying As+Bs=7 to 17% by weight and As/(A +Bs)=0.1 to 0.6; (b) an isotactic pentad fraction of propylene in each of copolymers (A) and (B) is 96% or more, and the mixture of the copolymers (A) and (B) has a MFR of 20 to 35 g/10 min at 230.degree. C. under 2160 g load; and (c) the copolymers (A) and (B) are in a total weight content of 50 to 95% and talc (C) is in a weight content of 5 to 50%.
    • 具有优异的刚性,耐冲击性和成型性(成型性),因此可用于汽车内部的聚丙烯树脂组合物包括(A)在室温下含有可溶于对二甲苯的馏分Ac的结晶E / P嵌段共聚物,并具有 乙烯含量为18〜22%; (B)在室温下含有可溶于对二甲苯的馏分Bc,乙烯含量为27〜40%的结晶性E / P嵌段共聚物,(C)平均粒径为3〜5μm的滑石粉末和最大 (a)对二甲苯可溶级分Ac和Bc的含量为A,Bs为基于共聚物(A)和(B)的总重量,满足As + Bs = 7〜17重量%,As /(A + Bs)= 0.1〜0.6; (b)共聚物(A)和(B)中的丙烯的全同立构五单元组分率为96%以上,共聚物(A)和(B)的混合物的MFR为20〜35g / 10分钟 在230℃,2160g负荷下; 和(c)共聚物(A)和(B)的总重量含量为50-95%,滑石(C)的重量含量为5-50%。