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1. 发明授权

US5306738A Process for producing flexible polyurethane foam having high air flow property 失效
标题翻译：具有高空气流动性的柔性聚氨酯泡沫塑料的制造方法
公开(公告)号：US5306738A
公开(公告)日：1994-04-26
申请号：US17437
申请日：1993-02-12
申请人： Hiroyuki Yoshimura , Yutaka Tamano , Shoji Arai
发明人： Hiroyuki Yoshimura , Yutaka Tamano , Shoji Arai
IPC分类号： C08G18/18 , C08G18/20 , C08G101/00 , C08J9/02
CPC分类号： C08G18/2027 , C08G2101/0008 , C08G2101/0083
摘要： Process for producing a flexible polyurethane foam through reaction of a polyol with a polyisocyanate in the presence of an amine catalyst, a blowing agent, and a foam stabilizer, the amine catalyst comprising at least one of the imidazoles represented by the general formula below: ##STR1## wherein R.sup.1 is alkyl of 1 to 4 carbons, dimethylaminopropyl, benzyl, vinyl, or hydroxyalkyl of 1 to 3 carbons; R.sup.2 is hydrogen, alkyl of 1 to 4 carbons, allyl, benzyl, or phenyl; and R.sup.3 and R.sup.4 are respectively hydrogen, alkyl of 1 to 4 carbons, or hydroxymethyl.
摘要翻译：在胺催化剂，发泡剂和泡沫稳定剂的存在下通过多元醇与多异氰酸酯的反应制备软质聚氨酯泡沫的方法，所述胺催化剂包含由以下通式表示的至少一种咪唑：（ *化学结构*）其中R 1为1至4个碳的烷基，二甲基氨基丙基，苄基，乙烯基或1至3个碳的羟烷基; R2是氢，1至4个碳的烷基，烯丙基，苄基或苯基; R3和R4分别为氢，1〜4个碳的烷基或羟甲基。

2. 发明授权

US4910230A Preparation of fine-cell rigid polyurethane foam using amine catalyst 失效
标题翻译：使用胺催化剂制备细胞硬质聚氨酯泡沫
公开(公告)号：US4910230A
公开(公告)日：1990-03-20
申请号：US288238
申请日：1988-12-22
申请人： Yutaka Tamano , Shoji Arai
发明人： Yutaka Tamano , Shoji Arai
IPC分类号： C08G18/18
CPC分类号： C08G18/1875 , C08G2101/0025 , C08G2101/005
摘要： A fine-cell rigid polyurethane foam is prepared by reacting a polyol having a blowing agent such as water incorporated therein with a polyisocyanate in the presence of an amine catalyst having a retarding effect. The amine catalyst is comprised of (a) 30 to 50 parts by weight of triethylene diamine, (b) 30 to 50 parts by weight of bis(dimethylaminoethyl)ether and/or N,N',N",N"-pentamethyldiethylene triamine, (c) up to 40 parts by weight of tetramethylhexamethylene diamine and/or trimethylaminoethylpiperazine, and (d) formic acid in an amount of 0.2 to 1.5 moles per mole of triethylene diamine.

3. 发明授权

US5006501A Amine catalyst for forming fine-cell rigid polyurethane foam 失效
标题翻译：用于形成细胞硬质聚氨酯泡沫的胺催化剂
公开(公告)号：US5006501A
公开(公告)日：1991-04-09
申请号：US458504
申请日：1989-12-28
申请人： Yutaka Tamano , Shoji Arai
发明人： Yutaka Tamano , Shoji Arai
IPC分类号： C08G18/18
CPC分类号： C08G18/1875 , C08G2101/0025 , C08G2101/005
摘要： A fine-cell rigid polyurethane foam is prepared by reacting a polyol having a blowing agent such as water incorporated therein with a polyisocyanate in the presence of an amine catalyst having a retarding effect. The amine catalyst is comprised of (a) 30 to 50 parts by weight of triethylene diamine, (b) 30 to 50 parts by weight of bis(dimethylaminoethyl)ether and/or N,N',N",N"-pentamethyldiethylene triamine, (c) up to 40 parts by weight of tetramethylhexamethylene diamine and/or trimethylaminoethylpiperazine, and (d) formic acid in an amount of 0.2 to 1.5 moles per mole of triethylene diamine.

4. 发明授权

US5100927A Process for producing rigid polyurethane foam 失效
标题翻译：生产刚性聚氨酯泡沫的方法
公开(公告)号：US5100927A
公开(公告)日：1992-03-31
申请号：US533753
申请日：1990-06-06
申请人： Yutaka Tamano , Shuichi Okuzono , Masaki Ishida , Shoji Arai , Hiroyuki Yoshimura
发明人： Yutaka Tamano , Shuichi Okuzono , Masaki Ishida , Shoji Arai , Hiroyuki Yoshimura
IPC分类号： C08G18/20
CPC分类号： C08G18/2027 , C08G2101/0025 , C08G2101/005 , C08G2101/0058
摘要： A process for producing a rigid polyurethane foam by use of a decreased amount of a CFC blowing agent and an increased amount of water used as a blowing agent, maintaining a high degree of heat insulation and improving the deterioration in friability of the product. The catalyst is one of the imidazoles represented by the formula (I): ##STR1## where R.sup.1 is alkyl having 1 to 4 carbons, benzyl, dimethylaminopropyl, or hydroxyalkyl having 1 to 3 carbons; R.sup.2 is hydrogen, alkyl having 1 to 4 carbons, allyl, or benzyl; and R.sup.3 and R.sup.4 are independently hydrogen, methyl, or hydroxymethyl.

5. 发明授权

US4638016A Process for producing high density elastic polyurethane using a combination of 4-methyl-1-(2-dimethylaminoethyl) piperazine together with another tertiary amine catalyst 失效
标题翻译：使用4-甲基-1-（2-二甲基氨基乙基）哌嗪与另一种叔胺催化剂的组合制备高密度弹性聚氨酯的方法
公开(公告)号：US4638016A
公开(公告)日：1987-01-20
申请号：US767870
申请日：1985-08-21
申请人： Shoji Arai , Yutaka Tamano , Masazumi Hasegawa
发明人： Shoji Arai , Yutaka Tamano , Masazumi Hasegawa
IPC分类号： C08G18/00 , C08G18/18 , C08G18/20
CPC分类号： C08G18/2027
摘要： Process for producing a high density elastic polyurethane of reduced weight having excellent resistance to bending, which employs as catalyst 4-methyl-1-(2-dimethylaminoethyl)piperazine or a mixture of 4-methyl-1-(2-dimethylaminoethyl)piperazine and another tertiary amine compound as co-catalyst.
摘要翻译：制备具有优异耐弯曲性的具有优异耐弯曲性的高密度弹性聚氨酯的方法，其使用4-甲基-1-（2-二甲基氨基乙基）哌嗪或4-甲基-1-（2-二甲基氨基乙基）哌嗪和4-甲基-1-（2-二甲基氨基乙基）哌嗪的混合物另一种叔胺化合物作为助催化剂。

6. 发明授权

US4617286A Catalyst for polyurethane having delay property 失效
标题翻译：具有延迟性能的聚氨酯催化剂
公开(公告)号：US4617286A
公开(公告)日：1986-10-14
申请号：US647399
申请日：1984-09-05
申请人： Shoji Arai , Yutaka Tamano , Yukihiro Tsutsumi
发明人： Shoji Arai , Yutaka Tamano , Yukihiro Tsutsumi
IPC分类号： C08G18/00 , C08G18/18 , C08G18/20 , C08G18/14 , B01J31/04
CPC分类号： C08G18/1875 , C08G18/2027
摘要： The disclosed catalyst for polyurethane comprises an organic carboxylic acid salt of a tertiary amine compound and 1-methyl-4-(2-dimethylaminoethyl)piperazine. The tertiary amine compound is selected from the group of triethylenediamine, bis(2-dimethylaminoethyl)ether and N,N,N',N",N"-pentamethyldiethylenetriamine and the organic carboxylic acid is selected from the organic carboxylic acids having 1-20 carbon atoms.
摘要翻译：所公开的聚氨酯催化剂包括叔胺化合物和1-甲基-4-（2-二甲基氨基乙基）哌嗪的有机羧酸盐。叔胺化合物选自三亚乙基二胺，双（2-二甲基氨基乙基）醚和N，N，N'，N“，N” - 五甲基二亚乙基三胺，有机羧酸选自具有1 -20个碳原子。

7. 发明申请

US20110077376A1 PROCESS FOR PRODUCING HYDROXYALKYLTRIETHYLENEDIAMINE, AND CATALYST COMPOSITION FOR THE PRODUCTION OF POLYURETHANE RESIN USING IT 审中-公开
标题翻译：用于生产羟基甲基氯乙烯的方法，以及使用它生产聚氨酯树脂的催化剂组合物
公开(公告)号：US20110077376A1
公开(公告)日：2011-03-31
申请号：US12995332
申请日：2009-05-29
申请人： Katsumi Tokumoto , Takao Suzuki , Hiroyuki Kiso , Yoshihiro Takahashi , Yutaka Tamano
发明人： Katsumi Tokumoto , Takao Suzuki , Hiroyuki Kiso , Yoshihiro Takahashi , Yutaka Tamano
IPC分类号： C08G18/20 , B01J31/18
CPC分类号： C08G18/6688 , B01J25/02 , B01J27/16 , B01J31/0258 , B01J31/0259 , B01J31/0261 , B01J2231/40 , C08G18/1825 , C08G18/2027 , C08G18/4816 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： To provide a process for producing a hydroxyalkyltriethylenediamine or hydroxytriethylenediamine simply and in a small number of steps without requiring multi-stage reaction steps; a novel catalyst composition whereby a polyurethane product can be obtained with good productivity and good moldability without bringing about odor problems or environmental problems; and a process for producing a polyurethane resin using the catalyst composition.For example, a hydroxyalkyltriethylenediamine or hydroxytriethylenediamine is produced by subjecting a mono-substituted dihydroxyalkylpiperazine and/or a di-substituted hydroxyalkylpiperazine to an intramolecular dehydration condensation reaction in the presence of an acid catalyst.Further, for example, a polyurethane resin is produced by using a catalyst composition which comprises a hydroxyalkyltriethylenediamine or hydroxytriethylenediamine (A), and an amine compound (B) having, in its molecule, one or more substituents selected from the group consisting of a hydroxy group, a primary amino group and a secondary amino group, or a tertiary amine compound (C) having a value of [blowing reaction rate constant/gelling reaction rate constant] of at least 0.5.
摘要翻译：提供一种简单且少量步骤生产羟基烷基三亚乙基二胺或羟基三亚乙基二胺的方法，而不需要多级反应步骤; 可以以高生产率和良好的成型性获得聚氨酯产品而不引起气味问题或环境问题的新型催化剂组合物; 以及使用该催化剂组合物制造聚氨酯树脂的方法。例如，羟基烷基三亚乙基二胺或羟基三亚乙基二胺通过在酸催化剂的存在下使单取代的二羟基烷基哌嗪和/或二取代的羟烷基哌嗪进行分子内脱水缩合反应来制备。此外，例如，通过使用包含羟烷基三亚乙基二胺或羟基三亚乙基二胺（A）的催化剂组合物和在其分子中具有一个或多个选自羟基或叔氨基和仲氨基，或具有至少为0.5的[发泡反应速度常数/凝胶化反应速率常数]值的叔胺化合物（C）。

8. 发明授权

US5304578A Process for producing urethane foam having a high density skin layer 失效
标题翻译：具有高密度表层的聚氨酯泡沫的制造方法
公开(公告)号：US5304578A
公开(公告)日：1994-04-19
申请号：US027691
申请日：1993-03-08
申请人： Yutaka Tamano , Shuichi Okuzono
发明人： Yutaka Tamano , Shuichi Okuzono
IPC分类号： C08G18/18 , C08J9/34
CPC分类号： C08G18/1875 , C08G18/1858 , C08G2101/0008 , C08G2101/0016 , C08G2101/0025 , C08G2101/0033 , C08G2101/0083
摘要： A process is provided for producing a polyurethane foam having a high-density skin layer by reacting a polyol with a polyisocyanate in a short time. The reaction is allowed to proceed in the presence of a blowing agent, a catalyst, and optionally an additive, the blowing agent being composed only of water, and the catalyst being an amine represented by formula (I) below and/or an organic acid salt thereof: ##STR1## where R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are, independently, an alkyl group of 1 to 12 carbons, or R.sub.1 and R.sub.2, and/or R.sub.3 and R.sub.4 may be linked to form a cycloalkyl or heterocyclic ring together with the adjacent nitrogen atom; and R.sub.5 is hydrogen, an alkyl group of 1 to 12 carbons, a phenyl group, or a cycloalkyl group. This process does not use halogenated hydrocarbons which cause ozone layer destruction.
摘要翻译：提供了一种通过在短时间内使多元醇与多异氰酸酯反应来制备具有高密度表层的聚氨酯泡沫体的方法。使反应在发泡剂，催化剂和任选的添加剂的存在下进行，发泡剂仅由水组成，催化剂是由下式（I）表示的胺和/或有机酸其盐：（*化学结构*）（I）其中R 1，R 2，R 3和R 4独立地为1至12个碳的烷基，或R 1和R 2，和/或R 3和R 4可以连接形成环烷基或杂环与相邻的氮原子一起; R 5为氢，碳数1〜12的烷基，苯基或环烷基。该方法不使用引起臭氧层破坏的卤代烃。

9. 发明授权

US5229430A Amine catalyst for producing polyurethane and process for producing polyurethane 失效
标题翻译：用于生产聚氨酯的胺催化剂和生产聚氨酯的方法
公开(公告)号：US5229430A
公开(公告)日：1993-07-20
申请号：US979262
申请日：1992-11-20
申请人： Yutaka Tamano , Masaki Ishida , Shuichi Okuzono
发明人： Yutaka Tamano , Masaki Ishida , Shuichi Okuzono
IPC分类号： C08G18/18
CPC分类号： C08G18/1825 , C08G2101/0008 , C08G2101/0016 , C08G2101/0025 , C08G2101/0041
摘要： An amine catalyst for producing polyurethane comprising a compound of formula (I): ##STR1## wherein n is an integer from 0 to 3, and R.sub.1, R.sub.2, and R.sub.3 are each independently a C.sub.1-3 alkyl group. The amine catalyst has a secondary hydroxyl group in the molecule and is non-bleeding in the polyurethane resin and excellent in moldability. A process for producing a polyurethane foam by reacting a polyol with a polyisocyanate in the presence of the amine catalyst defined above and a foaming agent are also disclosed.
摘要翻译：一种用于生产聚氨酯的胺催化剂，其包含式（I）化合物：其中n为0-3的整数，并且R 1，R 2和R 3各自独立地为C 1-3烷基。胺催化剂在分子中具有仲羟基并且在聚氨酯树脂中不渗色，并且成型性优异。还公开了在上述胺催化剂和发泡剂的存在下使多元醇与多异氰酸酯反应制备聚氨酯泡沫的方法。

10. 发明申请

US20100130629A1 CATALYST COMPOSITION FOR PRODUCTION OF POLYURETHANE RESIN AND METHOD FOR PRODUCING POLYURETHANE RESIN (AS AMENDED) 有权
标题翻译：用于生产聚氨酯树脂的催化剂组合物和生产聚氨酯树脂的方法（如修饰）
公开(公告)号：US20100130629A1
公开(公告)日：2010-05-27
申请号：US12377004
申请日：2007-08-10
申请人： Hiroyuki Kometani , Yutaka Tamano
发明人： Hiroyuki Kometani , Yutaka Tamano
IPC分类号： C08J9/04 , C08G18/32 , B01J31/18 , B01J31/04
CPC分类号： C08G18/1875 , A43B13/04 , C08G18/092 , C08G18/1808 , C08G18/1825 , C08G18/2036 , C08G18/2063 , C08G18/2072 , C08G18/225 , C08G18/4816 , C08G2101/0008 , C08G2101/0066 , C08G2101/0083 , C08G2105/02 , C08G2410/00
摘要： Disclosed is a catalyst composition for polyurethane resin production which contains (A) triethylenediamine, (B) a specific polyisocyanurating catalyst and/or (C) a specific highly temperature-sensitive catalyst. By using this catalyst composition, a polyurethane resin can be molded with good curability, while suppressing initial reactivity. Consequently, a polyurethane resin having excellent moldability and fluidity can be produced with high productivity by using the catalyst composition. The thus-obtained polyurethane resin is suitably applicable to shoe soles. The component (B) is selected from the group consisting of alkali metal salts of carboxylic acids, quaternary ammonium compounds expressed as R1R2R3R4N+,X−, N,N,N′-trimethylaminoethylethanolamine, and 2,4,6-tris(dimethylaminomethyl)phenol, while the component (C) is selected from the group consisting of triazole salts and benzotriazole salts of 1,8-diazabicyclo[5.4.0]undecene-7 or 1,5-diazabicyclo[4.3.0]nonene-5. The mixing ratio of the component (B) and/or the component (C) to the component (A) is from 2% by weight to 60% by weight.
摘要翻译：公开了含有（A）三亚乙基二胺，（B）特定聚异氰脲酸酯化催化剂和/或（C）特定的高温度敏感催化剂的聚氨酯树脂生产用催化剂组合物。通过使用该催化剂组合物，可以在抑制初始反应性的同时，以良好的固化性成型聚氨酯树脂。因此，可以通过使用催化剂组合物以高生产率制造具有优异成型性和流动性的聚氨酯树脂。这样得到的聚氨酯树脂适用于鞋底。组分（B）选自羧酸的碱金属盐，表示为R1R2R3R4N +，X，N，N，N'-三甲基氨基乙基乙醇胺和2,4,6-三（二甲基氨基甲基）苯酚的季铵化合物而组分（C）选自1,8-二氮杂双环[5.4.0]十一碳烯-7或1,5-二氮杂双环[4.3.0]壬烯-5的三唑盐和苯并三唑盐。组分（B）和/或组分（C）与组分（A）的混合比例为2重量％至60重量％。

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