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    • 6. 发明授权
    • Method of producing an acylated cellulose film
    • 酰化纤维素膜的制造方法
    • US5695694A
    • 1997-12-09
    • US468982
    • 1995-06-06
    • Kaoru IwataMasanori AbeUtami YonemuraTakeshi Sasaki
    • Kaoru IwataMasanori AbeUtami YonemuraTakeshi Sasaki
    • C08J5/18B29D11/00
    • C08J5/18C08J2301/10Y10T428/1036Y10T428/1086
    • An acylated cellulose film having a high optical isotropy and uniformity is produced by dissolving an acylated cellulose in a solvent substantially free from water and including, as a principal component, 1,3-dioxolane in a ratio in weight of the acylated cellulose to the solvent of 10/250 to 10/15; spreading the acylated cellulose solution on a film-forming surface of a support; and drying, for example, initially drying the spread solution layer on film-forming surface so as to reduce the content of the residual solvent in the resultant film to 5 to 30% by weight; removing the resultant residual solvent-containing film from the film-forming surface; and finally drying the removed film, while allowing the film to shrink in the transversal direction thereof, at a drying temperature controlled continuously or intermittently to a level satisfying the relationship (I): (Tg'-50.degree. C.).ltoreq.T.ltoreq.(Tg'+20.degree. C.) (I), wherein T is the drying temperature (.degree.C.) and Tg' is a glass transition temperature (.degree.C.) of the solvent-containing film, the temperature Tg' varying in response to the solvent content in the film.
    • 通过将酰化纤维素溶解在基本上不含水的溶剂中,以酰化纤维素与溶剂的重量比为主要成分的1,3-二氧戊环作为主要成分,制得具有高光学各向同性和均匀性的酰化纤维素膜 10/50〜10/15; 将酰化纤维素溶液铺展在载体的成膜表面上; 并干燥,例如,最初在成膜表面上干燥铺展的溶液层,以便将所得膜中残留溶剂的含量降低至5至30重量%; 从所述成膜表面除去所得残留的含溶剂的膜; 最后在连续或间歇地控制的干燥温度下使薄膜在其横向上收缩,同时使除去的膜干燥至满足关系式(I):(Tg'-50℃)T = (℃)(I)其中T是干燥温度(℃),Tg'是含溶剂膜的玻璃化转变温度(℃),温度Tg “响应于膜中的溶剂含量而变化。