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    • 1. 发明授权
    • Method for manufacturing slurry and mold for precision casting
    • 制造精密铸造用浆料和模具的方法
    • US07892343B2
    • 2011-02-22
    • US11922777
    • 2006-06-21
    • Kiyomi EmaYutaka OhmoriHirokazu KatoKenji Yamaguchi
    • Kiyomi EmaYutaka OhmoriHirokazu KatoKenji Yamaguchi
    • C23C16/40
    • B22C1/08B82Y30/00C04B35/481C04B35/486C04B35/624C04B35/6263C04B35/6303C04B35/634C04B2235/3208C04B2235/3217C04B2235/3244C04B2235/3246C04B2235/3248C04B2235/3463C04B2235/442C04B2235/5427C04B2235/5454C04B2235/6028C04B2235/606C04B2235/6567
    • A manufacturing method for a slurry for the production of a precision casting mold that includes a zirconia sol and a refractory powder, and a manufacturing method for a precision casting mold that uses the slurry is provided. The present invention relates to a manufacturing method for a slurry for the production of a precision casting mold for a metal that includes a step in which an alkaline zirconia sol (A1) and a refractory powder (D) are mixed, the alkaline zirconia sol (A1) being obtained by a manufacturing method that includes a step (i), in which a zirconium salt (B1) is heated at 60 to 110° C. in an aqueous medium that includes a carbonate of quaternary ammonium, and a step (ii), in which a hydrothermal treatment is carried out at 100 to 250° C. In addition, the present invention relates to a manufacturing method for a slurry for the production of a precision casting mold for a metal that includes a step in which an acidic zirconia sol (C3) and a refractory powder (D) are mixed, the acidic zirconia sol (C3) being obtained by a manufacturing method that includes a step (I), in which an alkaline zirconia sol (A3) and a zirconium salt (B3) are mixed, and a step II, in which the obtained liquid mixture is caused to react at 80 to 250° C.
    • 提供了一种用于生产包括氧化锆溶胶和耐火材料粉末的精密铸造模具的浆料的制造方法,以及使用该浆料的精密铸造模具的制造方法。 本发明涉及一种用于生产金属精密铸造模具的浆料的制造方法,其包括将碱性氧化锆溶胶(A1)和耐火材料粉末(D)混合的步骤,所述碱性氧化锆溶胶( A1)通过包括步骤(i)的制备方法获得,其中锆盐(B1)在包含季铵盐的碳酸盐的水性介质中在60至110℃下加热,和步骤(ii) ),其中在100〜250℃下进行水热处理。此外,本发明涉及一种用于制造金属精密铸造模具的浆料的制造方法,其包括以下步骤:将酸性 氧化锆溶胶(C3)和耐火粉末(D)混合,所述酸性氧化锆溶胶(C3)通过包括步骤(I)的制备方法获得,其中碱性氧化锆溶胶(A3)和锆盐( B3)混合,和步骤II,其中所获得的液体混合 e在80〜250℃下反应
    • 5. 发明申请
    • Acidic Zirconia Sol and Production Method of the Same
    • 酸性氧化锆溶胶及其制备方法
    • US20090036556A1
    • 2009-02-05
    • US11918134
    • 2006-04-11
    • Yutaka OhmoriHirokazu KatoKenji Yamaguchi
    • Yutaka OhmoriHirokazu KatoKenji Yamaguchi
    • B01F3/12
    • C01G25/02B82Y30/00C01P2004/64
    • There is provided an acidic zirconia sol having compatibility of particle properties and binding properties, and a production method of the same.The present invention relates to a production method of an acidic zirconia sol containing zirconia particles having a particle diameter of less than 20 nm in a content of 10 to 50% by mass, based on the mass of all zirconia particles including: a first process in which an alkaline zirconia sol (A) and a zirconium salt (B) are mixed in a mass ratio (Bs/As) ranging from 0.2 to 5.0 of a mass of a solid content (Bs) which is converted into an amount of ZrO2 in the zirconium salt (B) to a mass of a solid content (As) which is converted into an amount of ZrO2 in the alkaline zirconia sol (A); and a second process in which the resultant mixture is reacted at 80 to 250°C. to produce an acidic zirconia sol.
    • 提供了具有颗粒性质和结合性质的相容性的酸性氧化锆溶胶及其制备方法。 本发明涉及以氧化锆粒子的质量计,含有10〜50质量%的粒径小于20nm的氧化锆粒子的酸性氧化锆溶胶的制造方法,其特征在于,包括: 将碱土金属氧化锆溶胶(A)和锆盐(B)以质量比(Bs / As)为0.2〜5.0,以固体成分(Bs)的质量比转化成ZrO 2的量 在碱性氧化锆溶胶(A)中将锆盐(B)转化为一定量的ZrO 2的固体成分(As)的质量; 和其中所得混合物在80-250℃下反应的第二种方法。 以产生酸性氧化锆溶胶。
    • 6. 发明申请
    • Method for Manufacturing Slurry and Mold for Precision Casting
    • 制造精密铸造用浆料和模具的方法
    • US20090032994A1
    • 2009-02-05
    • US11922777
    • 2006-06-21
    • Kiyomi EmaYutaka OhmoriHirokazu KatoKenji Yamaguchi
    • Kiyomi EmaYutaka OhmoriHirokazu KatoKenji Yamaguchi
    • B29C33/38C04B35/48
    • B22C1/08B82Y30/00C04B35/481C04B35/486C04B35/624C04B35/6263C04B35/6303C04B35/634C04B2235/3208C04B2235/3217C04B2235/3244C04B2235/3246C04B2235/3248C04B2235/3463C04B2235/442C04B2235/5427C04B2235/5454C04B2235/6028C04B2235/606C04B2235/6567
    • A manufacturing method for a slurry for the production of a precision casting mold that includes a zirconia sol and a refractory powder, and a manufacturing method for a precision casting mold that uses the slurry is provided. The present invention relates to a manufacturing method for a slurry for the production of a precision casting mold for a metal that includes a step in which an alkaline zirconia sol (A1) and a refractory powder (D) are mixed, the alkaline zirconia sol (A1) being obtained by a manufacturing method that includes a step (i), in which a zirconium salt (B1) is heated at 60 to 110° C. in an aqueous medium that includes a carbonate of quaternary ammonium, and a step (ii), in which a hydrothermal treatment is carried out at 100 to 250° C. In addition, the present invention relates to a manufacturing method for a slurry for the production of a precision casting mold for a metal that includes a step in which an acidic zirconia sol (C3) and a refractory powder (D) are mixed, the acidic zirconia sol (C3) being obtained by a manufacturing method that includes a step (I), in which an alkaline zirconia sol (A3) and a zirconium salt (B3) are mixed, and a step II, in which the obtained liquid mixture is caused to react at 80 to 250° C.
    • 提供了一种用于生产包括氧化锆溶胶和耐火材料粉末的精密铸造模具的浆料的制造方法,以及使用该浆料的精密铸造模具的制造方法。 本发明涉及一种用于生产金属精密铸造模具的浆料的制造方法,其包括将碱性氧化锆溶胶(A1)和耐火材料粉末(D)混合的步骤,所述碱性氧化锆溶胶( A1)通过包括步骤(i)的制备方法获得,其中锆盐(B1)在包含季铵盐的碳酸盐的水性介质中在60至110℃下加热,和步骤(ii) ),其中在100〜250℃下进行水热处理。此外,本发明涉及一种用于制造金属精密铸造模具的浆料的制造方法,其包括以下步骤:将酸性 氧化锆溶胶(C3)和耐火粉末(D)混合,所述酸性氧化锆溶胶(C3)通过包括步骤(I)的制备方法获得,其中碱性氧化锆溶胶(A3)和锆盐( B3)混合,和步骤II,其中所获得的液体混合 e在80〜250℃下反应
    • 7. 发明授权
    • Acidic zirconia sol and production method of the same
    • 酸性氧化锆溶胶及其制备方法相同
    • US07691910B2
    • 2010-04-06
    • US11918134
    • 2006-04-11
    • Yutaka OhmoriHirokazu KatoKenji Yamaguchi
    • Yutaka OhmoriHirokazu KatoKenji Yamaguchi
    • C09K3/00
    • C01G25/02B82Y30/00C01P2004/64
    • There is provided an acidic zirconia sol having compatibility of particle properties and binding properties, and a production method of the same.The present invention relates to a production method of an acidic zirconia sol containing zirconia particles having a particle diameter of less than 20 nm in a content of 10 to 50% by mass, based on the mass of all zirconia particles including: a first process in which an alkaline zirconia sol (A) and a zirconium salt (B) are mixed in a mass ratio (Bs/As) ranging from 0.2 to 5.0 of a mass of a solid content (Bs) which is converted into an amount of ZrO2 in the zirconium salt (B) to a mass of a solid content (As) which is converted into an amount of ZrO2 in the alkaline zirconia sol (A); and a second process in which the resultant mixture is reacted at 80 to 250° C. to produce an acidic zirconia sol.
    • 提供了具有颗粒性质和结合性质的相容性的酸性氧化锆溶胶及其制备方法。 本发明涉及以氧化锆粒子的质量计,含有10〜50质量%的粒径小于20nm的氧化锆粒子的酸性氧化锆溶胶的制造方法,其特征在于,包括: 将碱土金属氧化锆溶胶(A)和锆盐(B)以质量比(Bs / As)为0.2〜5.0,以固体成分(Bs)的质量比转化成ZrO 2的量 在碱性氧化锆溶胶(A)中将锆盐(B)转化为一定量的ZrO 2的固体成分(As)的质量; 和第二种方法,其中所得混合物在80-250℃反应生成酸性氧化锆溶胶。
    • 10. 发明申请
    • Method for Producing Metal Oxide Particle
    • 金属氧化物颗粒的生产方法
    • US20090148380A1
    • 2009-06-11
    • US12227950
    • 2007-05-31
    • Yutaka OhmoriHirokazu KatoKenji Yamaguchi
    • Yutaka OhmoriHirokazu KatoKenji Yamaguchi
    • C01G25/02
    • C01G25/00C01G1/02C01G25/02C01P2006/12C01P2006/40H01M8/124Y02P70/56
    • There is provided a method for stably producing metal oxide solid solution particle at low temperature, wherein an alkaline zirconia sol is used as a raw material which is mixed with a metal compound, and then dried and fired. Specifically, there is disclosed a method for producing metal oxide particle (A3) such as zirconia particle in which metal oxides are solid-solubilized, comprising: a step (I) for obtaining metal oxide (A2) sol such as zirconia sol containing a precursor of a metal oxide by mixing an alkaline zirconia (A1) sol which is obtained by a method including a step (i) for heating a zirconium salt (B2) at 60-110° C. in an aqueous medium containing a carbonate of quaternary ammonium and a step (ii) for performing a hydrothermal treatment at 110-250° C., with a compound (B1) containing an element selected from a group consisting of the group II and group III elements of the periodic table; and a step (II) for drying the thus-obtained sol and then firing a resultant substance at a temperature of 500-1200° C.
    • 提供了一种在低温下稳定生产金属氧化物固溶体颗粒的方法,其中使用碱性氧化锆溶胶作为与金属化合物混合的原料,然后干燥和烧制。 具体地说,公开了一种金属氧化物(A3)的制造方法,其中金属氧化物是固溶的氧化锆颗粒,包括:用于获得金属氧化物(A2)溶胶的步骤(I),例如含有前体的氧化锆溶胶 通过混合通过包括步骤(i)的方法获得的碱性氧化锆(A1)溶胶,所述方法包括在60-110℃下加热锆盐(B2)在含有季铵盐的碳酸盐的水性介质中 和用于在110-250℃进行水热处理的步骤(ⅱ)与含有选自周期表第II族和第III族元素的元素的化合物(B1)进行水热处理; 和干燥所得溶胶的步骤(II),然后在500-1200℃的温度下焙烧所得物质。