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1. 发明授权

US4463113A Bis-phenol phosphates as clarifiers for polyolefin resins 失效
标题翻译：双酚磷酸酯作为聚烯烃树脂的澄清剂
公开(公告)号：US4463113A
公开(公告)日：1984-07-31
申请号：US379821
申请日：1982-05-20
申请人： Yutaka Nakahara , Mitsuo Akutsu , Tohru Haruna , Masayuki Takahashi
发明人： Yutaka Nakahara , Mitsuo Akutsu , Tohru Haruna , Masayuki Takahashi
IPC分类号： C08L23/00 , C07F9/6571 , C07F9/6574 , C07F9/6578 , C08K5/52 , C08K5/527 , C08K5/53 , C08K5/5357 , C08L7/00 , C08L21/00 , C08L23/02 , C08L101/00 , C07F9/21
CPC分类号： C08K5/527 , C07F9/657181 , C07F9/65744 , C07F9/6578 , C08K5/5357
摘要： Bis-phenol phosphates, are provided, represented by the formula: ##STR1## wherein: R is selected from the group consisting of a carbon-to-carbon bond; thio sulfur --S--; and alkylidene ##STR2## in which R.sub.3 and R.sub.4 are selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms, and cycloalkyl, including cycloalkylidene in which R.sub.3 and R.sub.4 are taken together as part of a cycloalkylene ring, having from three to about twelve carbon atoms;R.sub.1 and R.sub.2 are each selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms; and cycloalkyl having from three to about twelve carbon atoms;m is 0 or 1;M is a metal atom which can be monovalent or polyvalent; and n is the valence of the metal atom M, ranging from one to about four;useful to improve clarity of polyolefin resin compositions in an amount within the range from 0.005 to 5 parts by weight per 100 parts of resin.
摘要翻译：双酚磷酸酯，由下式表示：其中：R选自碳 - 碳键; 硫硫-S-; 和亚烷基“IMAGE”，其中R 3和R 4选自氢，具有1至约18个碳原子的烷基和环烷基，包括环烷叉基，其中R 3和R 4一起作为亚环烷基环的一部分，其具有三至十二个碳原子; R1和R2各自选自氢，具有1至约18个碳原子的烷基; 和具有3至约12个碳原子的环烷基; m为0或1; M是可以是一价或多价的金属原子; n为金属原子M的化合价，为1〜4; 可用于提高聚烯烃树脂组合物的澄清度，其量为每100份树脂0.005-5份重量。

2. 发明授权

US4239803A Ethylene polymer composition 失效
标题翻译：乙烯聚合物组合物
公开(公告)号：US4239803A
公开(公告)日：1980-12-16
申请号：US806511
申请日：1977-06-14
申请人： Toshio Ohzeki , Mitsuo Akutsu , Yutaka Nakahara , Tohru Haruna , Motonobu Minagawa , Masahiro Nonoyama
发明人： Toshio Ohzeki , Mitsuo Akutsu , Yutaka Nakahara , Tohru Haruna , Motonobu Minagawa , Masahiro Nonoyama
IPC分类号： C08L23/00 , C08J3/24 , C08K5/36 , C08K5/37 , C08K5/375 , C08L7/00 , C08L21/00 , C08L23/04 , C08L31/04 , C08L33/00 , C08L33/02 , C08L101/00 , H01B3/44 , C07C153/09
CPC分类号： C07C323/00 , C08K5/14 , C08K5/37 , C08K5/375 , Y10T428/294
摘要： A composition for enhancing and maintaining mechanical properties such as tensile strength of an ethylene polymer on heating at elevated temperature comprises (A) an initiator of cross-linking having a half-life measured at 110.degree. C. of 0.1 to 50 hours and (B) an alkylthioalkylenecarboxylic acid ester of a polycarbocyclic polyhydric phenol.
摘要翻译：用于提高和保持机械性能如乙烯聚合物在升高温度下加热时的拉伸强度的组合物包括（A）在110℃下测量的半衰期为0.1至50小时的交联引发剂（B））多环多元酚的烷基硫代亚烷基羧酸酯。

3. 发明授权

US4309335A Polyphenylene oxide resin composition stabilizer 失效
标题翻译：聚苯醚树脂组合物稳定剂
公开(公告)号：US4309335A
公开(公告)日：1982-01-05
申请号：US76300
申请日：1979-09-17
申请人： Mitsuo Akutsu , Yutaka Nakahara , Kazumi Kitsukawa
发明人： Mitsuo Akutsu , Yutaka Nakahara , Kazumi Kitsukawa
IPC分类号： C08L71/00 , C08K5/52 , C08K5/526 , C08L71/12
CPC分类号： C08K5/526
摘要： Ortho-substituted phenyl acid phosphite stabilizers for polyphenylene oxide resin compositions have the formula ##STR1## in which R.sub.1 is a t-butyl, t-amyl, cyclohexyl or phenyl group; R.sub.2 is a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, a cyclohexyl group, or a phenyl group; R.sub.3 is a hydrogen atom or a methyl group; and R.sub.4 is a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an ether-alkyl group having 3 to about 70 carbon atoms and 1 to 30 ether groups, an aryl group having 6 to 18 carbon atoms, a cycloalkyl group having 5 to 14 carbon atoms, an aralkyl, alkaryl, or alkoxyaryl group having 7 to 19 carbon atoms, an ethoxylated aryl or alkaryl group having 8 to 78 carbon atoms and 1 to 30 ether groups, or a cycloalkylaryl group having 11 to 19 carbon atoms.
摘要翻译：聚苯醚树脂组合物的正取代苯基酸亚磷酸酯稳定剂具有式“IMAGE”，其中R 1是叔丁基，叔戊基，环己基或苯基; R2是氢原子，碳原子数1〜5的烷基，环己基或苯基; R3是氢原子或甲基; R4为氢原子，碳原子数1〜20的烷基，碳原子数3〜70的醚 - 烷基，碳原子数1〜30的芳基，碳原子数6〜18的芳基，碳原子数为5〜14的芳烷基，烷芳基或碳原子数为7〜19的烷氧基芳基，碳原子数为8〜78的乙氧基化芳基或烷芳基，碳原子数为11〜19的环烷基芳基。

4. 发明授权

US4707507A 2,2,6,6-tetramethyl quaternary ammonium halides and synthetic resin and stabilizer compositions 失效
标题翻译： 2,2,6,6-四甲基季铵卤化物和合成树脂和稳定剂组合物
公开(公告)号：US4707507A
公开(公告)日：1987-11-17
申请号：US904130
申请日：1986-09-04
申请人： Mitsuo Akutsu , Mitsuharu Kanai
发明人： Mitsuo Akutsu , Mitsuharu Kanai
IPC分类号： C07D211/58 , B01F17/18 , C07D211/52 , C08K5/3435 , C09D7/00 , C09D7/12 , C11D1/62 , C08K5/34
CPC分类号： C08K5/3435 , C07D211/52
摘要： Water-soluble or dispersible 2,2,6,6-tetramethylquaternary ammonium halides are provided, effective as stabilizers to increase the resistance to deterioration when exposed to light of synthetic resins, and having the formula: ##STR1## wherein: R.sub.1, R.sub.3 and R.sub.4 are alkyl having from one to about twelve carbon atoms;n is 1 or 2;when n is 1, R.sub.2 is alkyl having from one to about twelve carbon atoms; andwhen n is 2, R.sub.2 is alkylene having from one to about twelve carbon atoms; andX is halogen as well as stabilizer compositions and synthetic resin compositions containing the same.
摘要翻译：提供了水溶性或分散性的2,2,6,6-四甲基季铵卤化物，作为稳定剂有效，以增加当暴露于合成树脂的光时耐劣化性，并具有下式：其中：R1 R 3和R 4为具有1至约12个碳原子的烷基; n为1或2; 当n为1时，R 2为具有1至约12个碳原子的烷基; 当n为2时，R 2为具有1至约12个碳原子的亚烷基; X是卤素，以及稳定剂组合物和含有它们的合成树脂组合物。

5. 发明授权

US4258142A Clarified olefin polymer composition 失效
标题翻译：澄清的烯烃聚合物组合物
公开(公告)号：US4258142A
公开(公告)日：1981-03-24
申请号：US937961
申请日：1978-08-30
申请人： Toshio Ohzeki , Mitsuo Akutsu , Junji Kawai
发明人： Toshio Ohzeki , Mitsuo Akutsu , Junji Kawai
IPC分类号： C08K5/098 , C08K5/523 , C09K3/00
CPC分类号： C08K5/098 , C08K5/523 , Y10T428/269
摘要： The clarity of molded olefin polymer specimens is augmented by incorporating 0.005 to 5% by weight of the olefin polymer of a phenyl phosphate compound having the formula ##STR1## in which R.sub.1 and R.sub.2 are independently selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkoxy group having 1 to 18 carbon atoms, a cycloalkyl group having 5 to 12 carbon atoms, a phenyl group, a phenoxy group, and a group ##STR2## in which R.sub.5 is a hydrogen atom or an alkyl group having 1 to 18 carbon atoms; R.sub.3 is selected from the group consisting of an alkyl group having 1 to 18 carbon atoms, ##STR3## , and R.sub.4 ; and R.sub.4 is a hydrogen atom or a metal atom equivalent M.sub.1/a where a is the valence of the metal atom M.In the presence of such a phenyl phosphate, further improvements in clarity are obtained by also incorporating certain metal compounds.
摘要翻译：通过加入0.005至5重量％的具有式“IMAGE”的苯基磷酸酯化合物的烯烃聚合物，其中R 1和R 2独立地选自氢原子，具有1至18个碳原子的烷基，具有1至18个碳原子的烷氧基，具有5至12个碳原子的环烷基，苯基，苯氧基和其中R 5是氢原子的基团或具有1至18个碳原子的烷基; R3选自具有1至18个碳原子的烷基，＆lt; IMAGE＆gt;和R4; R4是氢原子或金属原子当量M1 / a，其中a是金属原子M的化合价。在这种磷酸苯酯的存在下，通过还掺入某些金属化合物可以进一步提高透明度。

6. 发明授权

US06319652B1 Energy beam curable epoxy resin composition 有权
标题翻译：能量束固化环氧树脂组合物
公开(公告)号：US06319652B1
公开(公告)日：2001-11-20
申请号：US09396800
申请日：1999-09-15
申请人： Mitsuo Akutsu , Tetsuyuki Nakayashiki , Hiroyuki Tachikawa , Kazuo Ohkawa , Satoyuki Chikaoka
发明人： Mitsuo Akutsu , Tetsuyuki Nakayashiki , Hiroyuki Tachikawa , Kazuo Ohkawa , Satoyuki Chikaoka
IPC分类号： G03F7038
CPC分类号： G03F7/038 , B29C64/106 , B29K2063/00 , B33Y10/00 , B33Y70/00 , C08G59/24 , C08G59/30 , C08G59/68 , G03F7/0037
摘要： The energy beam curable epoxy resin composition comprising as essential components, (1) specific cationically polymerizing organic substance,(2) energybeam sensitive cation polymerization initiator, (3) cationically polymerizing organic substance except for the specific cationically polymerizing organic substance, described above, (4) radically polymerizing organic compound, and (5) energy beam sensitive radical polymerization initiator. The cured articles resulted from said resin composition, have superior properties and particularlly superior dimensional stability on humidity absorption. Therefore, a stereolithographic resin composition and a stereolithographic method are also provided.
摘要翻译：作为必要成分的能量束固化性环氧树脂组合物，（1）特定的阳离子聚合性有机物，（2）能量敏感性阳离子聚合引发剂，（3）上述特定的阳离子聚合性有机物以外的阳离子聚合性有机物（ 4）自由基聚合有机化合物，和（5）能量束敏感自由基聚合引发剂。由所述树脂组合物产生的固化制品具有优异的性能和特别优异的湿度吸收尺寸稳定性。因此，还提供了立体光刻树脂组合物和立体光刻方法。

7. 发明授权

US5081099A Heat-sensitive recording material 失效
标题翻译：热敏记录材料
公开(公告)号：US5081099A
公开(公告)日：1992-01-14
申请号：US554408
申请日：1990-07-19
申请人： Mitsuo Akutsu , Syuji Iwakura , Keiji Oya
发明人： Mitsuo Akutsu , Syuji Iwakura , Keiji Oya
IPC分类号： B41M5/337
CPC分类号： B41M5/3375
摘要： A heat-sensitive recording material wherein a color-forming layer comprising a coupling substance which is usually colorless or light-colored and a developer which gives rise to color in the coupling substance upon heating further contains, as a sensitizer, a tetrahydronaphthalene compound of the following general formula (I): ##STR1## wherein X represents an alkylene group, --O--CO--O--, --O--CO-- or --O--R'.sub.n Y--, n represents 1 or 2, Y represents --O-- or --S--, R' represents an alkylene group, and R represents a phenyl, alkylphenyl or tetrahydronaphthyl group.
摘要翻译：一种热敏记录材料，其中包含通常无色或浅色的偶联物质的成色层和加热时在偶联物质中引起颜色的显色剂进一步含有作为敏化剂的四氢化萘化合物通式（I）：其中X表示亚烷基，-O-CO-O-，-O-CO-或-O-R'nY-，n表示1或2，Y表示 -O-或-S-，R'表示亚烷基，R表示苯基，烷基苯基或四氢萘基。

8. 发明授权

US07696257B2 Oxime ester compound and photopolymerization initiator containing such compound 有权
标题翻译：含有这种化合物的肟酯化合物和光聚合引发剂
公开(公告)号：US07696257B2
公开(公告)日：2010-04-13
申请号：US11659979
申请日：2005-08-03
申请人： Mitsuo Akutsu , Daisuke Sawamoto , Yasunori Kozaki , Toshihiko Murai
发明人： Mitsuo Akutsu , Daisuke Sawamoto , Yasunori Kozaki , Toshihiko Murai
IPC分类号： C08F2/50 , C07C251/00 , C07D405/12 , C07D409/12 , C07D421/12
CPC分类号： C08F2/50 , C07D405/10 , C07D405/12 , C07D409/12 , C07D421/12
摘要： An oxime ester compound represented below is useful as a photopolymerization initiator. A photopolymerization initiator including this as an active constituent has high sensitivity and causes no concern about coloration or contamination. (X represents a halogen atom or alkyl group. R1, R2, and R3 each independently represent R, OR, COR, SR, CONRR′, or CN, wherein R and R′ each represent an alkyl group, an aryl group, an aralkyl group, or a heterocyclic group; these groups may be substituted with (a) halogen atom(s) and/or (a) heterocyclic group(s); the alkylene moiety in the alkyl or aralkyl group may be interrupted by (an) unsaturated bond(s), (an) ether bond(s), (a) thioether bond(s), or (an) ester bond(s); and R and R′ may form a ring. Y1 represents an oxygen, sulfur, or selenium atom; A represents a heterocyclic group; m represents an integer 0-4; p represents an integer 0-5; and q represents 0 or 1.)
摘要翻译：下述的肟酯化合物可用作光聚合引发剂。包含其作为活性成分的光聚合引发剂具有高灵敏度，并且不会引起着色或污染。（X表示卤素原子或烷基，R 1，R 2和R 3各自独立地表示R，OR，COR，SR，CONRR'或CN，其中R和R'各自表示烷基，芳基，芳烷基基团或杂环基团;这些基团可以被（a）卤素原子和/或（a）杂环基团取代;烷基或芳烷基中的亚烷基部分可以被（a）不饱和的键，（a）醚键，（a）硫醚键或（an）酯键; R和R'可以形成环，Y1表示氧，硫，或硒原子; A表示杂环基; m表示0-4的整数; p表示0-5的整数，q表示0或1.）

9. 发明申请

US20070270522A1 Oxime Ester Compound and Photopolymerization Initiator Containing Such Compound 有权
标题翻译：含有这种化合物的肟酯化合物和光聚合引发剂
公开(公告)号：US20070270522A1
公开(公告)日：2007-11-22
申请号：US11659979
申请日：2005-08-03
申请人： Mitsuo Akutsu , Daisuke Sawamoto , Yasunori Kozaki , Toshihiko Murai
发明人： Mitsuo Akutsu , Daisuke Sawamoto , Yasunori Kozaki , Toshihiko Murai
IPC分类号： C07C251/34 , C08F2/46
CPC分类号： C08F2/50 , C07D405/10 , C07D405/12 , C07D409/12 , C07D421/12
摘要： An oxime ester compound represented below is useful as a photopolymerization initiator. A photopolymerization initiator including this as an active constituent has high sensitivity and causes no concern about coloration or contamination. (X represents a halogen atom or alkyl group. R1, R2, and R3 each independently represent R, OR, COR, SR, CONRR′, or CN, wherein R and R′ each represent an alkyl group, an aryl group, an aralkyl group, or a heterocyclic group; these groups may be substituted with (a) halogen atom(s) and/or (a) heterocyclic group(s); the alkylene moiety in the alkyl or aralkyl group may be interrupted by (an) unsaturated bond(s), (an) ether bond(s), (a) thioether bond(s), or (an) ester bond(s); and R and R′ may form a ring. Y1 represents an oxygen, sulfur, or selenium atom; A represents a heterocyclic group; m represents an integer 0-4; p represents an integer 0-5; and q represents 0 or 1.)
摘要翻译：下述的肟酯化合物可用作光聚合引发剂。包含其作为活性成分的光聚合引发剂具有高灵敏度，并且不会引起着色或污染。（X表示卤素原子或烷基，R 1，R 2，R 3和R 3各自独立地表示R，OR，COR，SR ，CONRR'或CN，其中R和R'各自表示烷基，芳基，芳烷基或杂环基;这些基团可以被（a）卤素原子和/或（a ）杂环基团;烷基或芳烷基中的亚烷基部分可以被（a）不饱和键，（a）醚键，（a）硫醚键或（一个或多个））酯键; R和R'可以形成环，Y 1表示氧，硫或硒原子; A表示杂环基; m表示0-4的整数; p表示0-5的整数，q表示0或1.）

10. 发明授权

US6117487A Process for forming metal oxide film by means of CVD system 失效
标题翻译：通过CVD系统形成金属氧化物膜的工艺
公开(公告)号：US6117487A
公开(公告)日：2000-09-12
申请号：US275408
申请日：1999-03-24
申请人： Mitsuo Akutsu , Naohiro Kubota , Akifumi Masuko , Naoki Yamada
发明人： Mitsuo Akutsu , Naohiro Kubota , Akifumi Masuko , Naoki Yamada
IPC分类号： C23C16/40 , C23C16/00 , C07F7/28 , H05H1/24
CPC分类号： C23C16/405
摘要： A process for forming a metal oxide film by means of a chemical vapor deposition system, which comprises using a complex of a .beta.-diketone compound and a group IV metal glycolate, the complex being represented by formula (I): ##STR1## wherein M represents a metal atom of the group IV; R.sup.1 and R.sup.2 each represent a branched alkyl or cycloalkyl group having 4 to 8 carbon atoms; and R.sup.3 represents a straight-chain or branched alkylene group having 2 to 18 carbon atoms.
摘要翻译：一种通过化学气相沉积系统形成金属氧化物膜的方法，该方法包括使用β-二酮化合物和IV族金属乙醇酸的络合物，该络合物由式（I）表示：其中M表示金属 IV组原子; R1和R2各自表示具有4-8个碳原子的支链烷基或环烷基; R 3表示碳原子数为2〜18的直链或支链亚烷基。

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