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    • 1. 发明授权
    • Process for producing polymer
    • 生产聚合物的方法
    • US06646107B2
    • 2003-11-11
    • US09799500
    • 2001-03-07
    • Yutaka MoroishiMichiharu YamamotoTetsuo InoueTomoko DoiMasakazu SugimotoFumiko Nakano
    • Yutaka MoroishiMichiharu YamamotoTetsuo InoueTomoko DoiMasakazu SugimotoFumiko Nakano
    • C08F600
    • C09D153/02C08F6/02C08F293/00C08F293/005C08F2438/01C08L53/02C08L2666/02C09J153/00C09J153/02C08L53/00
    • The object of the present invention is to produce a polymer, which is free from the troubles of the coloration and the decrease in the mechanical properties of molded articles (films, etc.), crosslinkage failure, migration (stain) or the like, by the living radical polymerization method wherein the content of impurities consisting of a transition metal and its ligand employed as a polymerization activator is reduced. A process for producing a polymer is described, comprising: a) the step of performing a polymerization reaction by using a monomer, a transition metal and its ligand and a polymerization initiator to form a polymer; and b) the step of eliminating the transition metal and its ligand contained in the polymer under the condition of a viscosity of 100 Pa·s or below, wherein the step b comprises: b1) the former step of eliminating the transition metal and its ligand insoluble in the polymer; and b2) the latter step of eliminating the transition metal and its ligand dissolved in the polymer.
    • 本发明的目的是制备聚合物,其不会由于成型品(膜等)的机械性能的着色和机械性能的降低,交联失效,迁移(污渍)等的不利影响而被 其中由过渡金属及其配体用作聚合活化剂的杂质含量降低的活性自由基聚合方法。 描述了一种制备聚合物的方法,包括:a)通过使用单体,过渡金属及其配体和聚合引发剂进行聚合反应以形成聚合物的步骤; 和b)在粘度为100Pa·s或更低的条件下消除聚合物中所含的过渡金属及其配体的步骤,其中步骤b包括:b1)除去过渡金属及其配体的前一步骤 不溶于聚合物; 和b2)消除过渡金属及其配体溶解在聚合物中的后一步骤。