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1. 发明申请

US20120053352A1 BRANCHED COMPOUND, AND ORGANIC THIN FILM AND ORGANIC THIN FILM ELEMENT EACH COMPRISING SAME 审中-公开
标题翻译：分支化合物，有机薄膜和有机薄膜元件
公开(公告)号：US20120053352A1
公开(公告)日：2012-03-01
申请号：US13255211
申请日：2010-03-10
申请人： Yutaka Ie , Makoto Okabe , Yoshio Aso , Masato Ueda
发明人： Yutaka Ie , Makoto Okabe , Yoshio Aso , Masato Ueda
IPC分类号： C07D409/14
CPC分类号： H01L51/0068 , C07D333/78 , C07D409/14 , H01L51/0072 , H01L51/0558 , H01L51/42 , Y02E10/549
摘要： A branched compound having a construction with a core portion, at least 3 side chain portions bonded to the core portion, and end portions bonded to each of the side chain portions, wherein the side chain portions arc groups in which a plurality of conjugated units are linked, at least one of the conjugated units being a divalent heterocyclic group, at least one of the end portions is a group represented by formula (1), and the side chain portions and the end portions are conjugated with the core portion. [In the formula, Ar represents a trivalent aromatic hydrocarbon or a trivalent heterocyclic group, and X represents oxygen, sulfur, or a group represented by formula (a).] [In the formula, A represents hydrogen, a halogen or a monovalent group, and at least one A group is an electron-withdrawing group.]
摘要翻译：具有芯部结构的分支化合物，与芯部接合的至少3个侧链部分和与每个侧链部分接合的端部，其中多个共轭单元为侧链基团至少一个共轭单元为二价杂环基，至少一个端部为式（1）所示的基团，侧链部分和端部与芯部共轭。 [式中，Ar表示三价芳香族烃或三价杂环基，X表示氧，硫或式（a）表示的基团。] [式中，A表示氢，卤素或一价基团，并且至少一个A基团是吸电子基团。]

2. 发明申请

US20080302419A1 Polymer Comprising Unit Comprising Fluorocyclopentane Ring Fused With Aromatic Ring and Organic Thin Film and Organic Thin Film Element Both Comprising the Same 失效
标题翻译：包含芳环的氟环戊烷环和有机薄膜的聚合物组合单元和包含它们的有机薄膜元件
公开(公告)号：US20080302419A1
公开(公告)日：2008-12-11
申请号：US12066006
申请日：2006-08-28
申请人： Yutaka Ie , Yoshio Aso , Yoshikazu Umemoto , Masato Ueda
发明人： Yutaka Ie , Yoshio Aso , Yoshikazu Umemoto , Masato Ueda
IPC分类号： H01L31/0256 , C08G75/00 , H01L51/05 , B32B27/00
CPC分类号： H01L51/0036 , C07D333/78 , C08G61/12 , C08G61/126 , C08G2261/146 , C08G2261/3223 , C08G2261/414 , H01L51/0035 , H01L51/0039 , H01L51/0043 , H01L51/0068 , H01L51/0541 , H01L51/0545 , H01L51/4206 , Y02E10/549
摘要： A polymer comprising a repeating unit represented by the following general formula (I). (In the formula, Ar1 represents a divalent aromatic hydrocarbon or divalent heterocyclic group, X1, Y1, X2 and Y2 each independently represent a fluorine atom or alkylthio group, and X1 and Y1 and X2 and Y2 may together form a carbonyl or thiocarbonyl group with their bonding carbon atom.)
摘要翻译：一种包含由以下通式（I）表示的重复单元的聚合物。（式中，Ar 1表示二价芳香族烃或二价杂环基，X 1，Y 1，X 2，Y 2各自独立地表示氟原子或烷硫基，X 1，Y 1，X 2和Y 2可以一起形成羰基或硫代羰基，它们的键合碳原子）

3. 发明授权

US08841410B2 Nitrogen-containing condensed ring compound, nitrogen-containing condensed ring polymer, organic thin film, and organic thin film element 有权
标题翻译：含氮缩合环化合物，含氮缩合环聚合物，有机薄膜和有机薄膜元件
公开(公告)号：US08841410B2
公开(公告)日：2014-09-23
申请号：US13982410
申请日：2012-01-30
申请人： Yoshio Aso , Yutaka Ie , Masashi Ueta , Masato Ueda
发明人： Yoshio Aso , Yutaka Ie , Masashi Ueta , Masato Ueda
IPC分类号： C08G75/00 , C07D513/14 , C07D513/04 , H01L51/00 , C08G61/12 , H01L51/05
CPC分类号： H01L51/0071 , C07D513/04 , C07D513/14 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/3142 , C08G2261/3223 , C08G2261/3243 , C08G2261/3246 , C08G2261/3327 , C08G2261/3328 , C08G2261/414 , C08G2261/514 , H01L51/0036 , H01L51/0043 , H01L51/0541 , H01L51/0545 , Y02E10/549
摘要： It is an object of the present invention to provide a nitrogen-containing condensed ring compound, which can be used as an organic n-type semiconductor having an excellent electron transport property and which is also excellent in terms of solubility in an organic solvent. The nitrogen-containing condensed ring compound of the present invention has a structural unit represented by the following formula (1-1) or formula (1-2): wherein Ar1 represents an aromatic ring; one of Y1 and Y2 represents a single bond, and the other represents —C(R11)(R12)— or —C(═X1)—; one of Y3 and Y4 represents a single bond, and) the other represents —C(R21)(R22)— or —C(═X2)—, and one of Y1 to Y4 represents —C(R11)(R12)— or —C(R21)(R22)—; at least one of W1 and W2 represents —N═; and Z1 and Z2 each represent any one of the groups represented by the formula (i) to the formula (ix).
摘要翻译：本发明的目的是提供一种含氮稠环化合物，其可以用作具有优异的电子传输性的有机n型半导体，并且在有机溶剂中的溶解性也优异。本发明的含氮缩环化合物具有由下式（1-1）或式（1-2）表示的结构单元：其中Ar 1表示芳环; Y1和Y2之一表示单键，另一个表示-C（R 11）（R 12） - 或-C（= X 1） - ; Y 3和Y 4中的一个表示单键，另一个表示-C（R 21）（R 22） - 或-C（= X 2） - ，Y 1至Y 4中的一个表示-C（R 11）（R 12） - 或 -C（R 21）（R 22） - ; W1和W2中的至少一个表示-N =; 并且Z 1和Z 2各自表示由式（i）至式（ix）表示的基团中的任何一个。

4. 发明申请

US20110046341A1 BRANCHED COMPOUNDS, ORGANIC THIN FILMS MADE BY USING THE SAME, AND ORGANIC FILM DEVICES 审中-公开
标题翻译：分批化合物，使用该化合物的有机薄膜和有机薄膜器件
公开(公告)号：US20110046341A1
公开(公告)日：2011-02-24
申请号：US12867238
申请日：2009-01-07
申请人： Yutaka Ie , Toshihiko Uto , Yoshio Aso , Masato Ueda
发明人： Yutaka Ie , Toshihiko Uto , Yoshio Aso , Masato Ueda
IPC分类号： C08G75/06
CPC分类号： C07D333/08 , B82Y10/00 , C07D333/12 , C07D333/16 , C07D409/14 , C07D471/04 , H01L51/0047 , H01L51/0053 , H01L51/0068 , H01L51/0095 , H01L51/0512 , H01L51/0558 , Y02E10/549
摘要： A branched compound including a core part, at least one side chain part bonded to the core part, and an end, wherein one repeating unit or two or more repeating units expressed by the following formula (1) repeat in the or each side chain part, with the proviso that in a repeating unit bonded to the core part, T is bonded to the core part, and in two or more contiguous repeating units, each L is bonded to the T, each L is formed of a plurality of conjugation-forming units linked together; each L includes at least one thienylene unit as the conjugation-forming unit; and at least two of the groups existing at the ends of Ls (the ends of the L in sides which are not bonded to T) are acceptor groups. (In the formula, each L represents a divalent organic group which may have a substituent and the T represents a trivalent organic group which may have a substituent.)
摘要翻译：一种支链化合物，其包含核心部分，至少一个侧链部分与核心部分结合，以及末端，其中一个重复单元或两个或更多个由下式（1）表示的重复单元在该侧链或各侧链部分中重复条件是在与核心部分接合的重复单元中，T结合到核心部分，并且在两个或更多个连续的重复单元中，每个L结合到T，每个L由多个共轭 - 形成单元连接在一起; 每个L包括至少一个噻吩基单元作为共轭形成单元; 并且存在于Ls的末端的两个组中的至少两个（L侧不与T结合的端部）是受体组。（式中，L表示可以具有取代基的二价有机基团，T表示可具有取代基的三价有机基团。）

5. 发明申请

US20100171102A1 FLUORINE-CONTAINING POLYCYCLIC AROMATIC COMPOUND, FLUORINE-CONTAINING POLYMER, ORGANIC THIN FILM AND ORGANIC THIN FILM DEVICE 审中-公开
标题翻译：含氟聚合物的芳族化合物，含氟聚合物，有机薄膜和有机薄膜装置
公开(公告)号：US20100171102A1
公开(公告)日：2010-07-08
申请号：US12530435
申请日：2008-03-05
申请人： Yutaka Ie , Yoshio Aso , Masashi Nitani , Masato Ueda
发明人： Yutaka Ie , Yoshio Aso , Masashi Nitani , Masato Ueda
IPC分类号： H01L51/30 , C07C23/18 , C07C69/76 , C08G61/00 , C08G10/00
CPC分类号： C07C25/22 , C07C49/813 , C07D333/18 , C07D495/04 , C07D495/10 , C08G61/02 , C08G61/12 , C08G2261/146 , C08G2261/222 , C08G2261/3142 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0055 , H01L51/0068 , H01L51/0074 , H01L51/0541 , H01L51/0545 , H01L51/5048 , Y02E10/549
摘要： A fluorine-containing polycyclic aromatic compound represented by the following formula (I) is provided. According to present invention, a novel compound capable of being utilized as an organic n-type semiconductor having an excellent electron transport property is provided, wherein in formula (I), Ar1 and Ar2 each independently represent an aromatic hydrocarbon group having at least six carbon atoms or a heterocyclic group having at least four carbon atoms; R1, R2, R3 and R4 each independently represent a hydrogen atom, a halogen atom, or a monovalent group; R5 and R6 each independently represent a hydrogen atom or a monovalent organic group that may be substituted with a substituent; s1 and t1 each independently represent an integer of at least 2; with the proviso that at least one of R5 and R6 is the abovementioned monovalent organic group where at least one of all the hydrogen atoms of the monovalent organic group including the substituent is substituted with a fluorine atom.
摘要翻译：提供由下式（I）表示的含氟多环芳香族化合物。根据本发明，提供了能够用作具有优异的电子传输性质的有机n型半导体的新化合物，其中在式（I）中，Ar 1和Ar 2各自独立地表示具有至少6个碳原子的芳族烃基原子或具有至少四个碳原子的杂环基; R1，R2，R3和R4各自独立地表示氢原子，卤素原子或一价基团; R5和R6各自独立地表示氢原子或可以被取代基取代的一价有机基团; s1和t1各自独立地表示至少2的整数; 条件是R 5和R 6中的至少一个是上述一价有机基团，其中包含取代基的一价有机基团的全部氢原子中的至少一个被氟原子取代。

6. 发明申请

US20080293909A1 Covered Heteroaromatic Ring Compound 审中-公开
标题翻译：覆盖杂芳环化合物
公开(公告)号：US20080293909A1
公开(公告)日：2008-11-27
申请号：US11885878
申请日：2006-03-02
申请人： Yoshio Aso , Yutaka Ie , Aihong Han
发明人： Yoshio Aso , Yutaka Ie , Aihong Han
IPC分类号： C07F7/18 , C08G61/12
CPC分类号： H05B33/14 , C07F7/1804 , C08G61/123 , C08G61/124 , C08G61/125 , C08G61/126 , C09D165/00 , C09K11/06 , C09K2211/1458 , H01L51/0036 , H01L51/0068 , H01L51/0094
摘要： The present invention provide a covered heteroaromatic ring compound whose hetero ring effectively is covered and that is suitable for electronic materials and the like. For example, following Scheme 1 below, first, a thiophene monomer unit (1T) is synthesized, and then oligomers (2T) to (16T) are synthesized by repeating oxidative polymerization. The hetero ring is not limited to thiophene, and may be furan or pyrrole, for example. Also, substituents on silicon are not limited to those in Scheme 1, and any substituents may be used. The degree of polymerization and the synthesis method are not limited to those in Scheme 1. In the compound of the present invention, π electronic conjugation effectively is kept as shown in the ultraviolet and visible absorption spectrum in FIG. 1, for example. Accordingly, the compound is useful, for example, as a research tool for clarifying electrical properties according to the degree of polymerization of oligoheterocyclic compounds, and as molecular wires that are important in molecular electronics devices.
摘要翻译：本发明提供了一种被覆盖的杂环芳族化合物，其杂环被有效地覆盖并且适用于电子材料等。例如，按照下述方案1，首先合成噻吩单体单元（1T），然后通过重复氧化聚合合成低聚物（2T）至（16T）。杂环不限于噻吩，例如可以是呋喃或吡咯。此外，硅上的取代基不限于方案1中的取代基，并且可以使用任何取代基。聚合度和合成方法不限于方案1中的那些。在本发明的化合物中，如图1中的紫外和可见吸收光谱所示，有效地保持了π电子共轭。 1，例如。因此，该化合物可用作例如根据低聚杂环化合物的聚合度来澄清电性能的研究工具，以及作为在分子电子器件中重要的分子线。

7. 发明授权

US08207184B2 Condensation compound between fluorinated cyclopentane ring and aromatic ring, and process for producing the same 失效
公开(公告)号：US08207184B2
公开(公告)日：2012-06-26
申请号：US13106586
申请日：2011-05-12
申请人： Yutaka Ie , Yoshio Aso
发明人： Yutaka Ie , Yoshio Aso
IPC分类号： A61K31/435 , C07D221/02
CPC分类号： C07D495/20 , C07D333/78 , H01L51/0036
摘要： A condensation compound of a fluorinated cyclopentane ring and an aromatic ring, which is useful, for example, for electronic materials, and a process for producing the same are provided. For instance, according to Scheme 1 below, a compound (68) containing a condensed structure formed of a hexafluorocyclopentane ring and an aromatic ring is synthesized. The aromatic ring is not limited to a thiophene ring but can be any ring and any substituent can be used. Thus a compound containing a condensed ring structure formed of a hexafluorocyclopentane ring and an aromatic ring, particularly, for instance, a thiophene ring, which was impossible to produce conventionally, can be produced easily with high yield. The compound of the present invention is particularly suitable to be applied to, for example, electronic materials or semiconductors. When it is polymerized and thereby the π-electronic conjugation is extended, it also is expected to be applied to, for example, n-type organic semiconductors and molecular wires that are indispensable for developing molecular electronics elements.

8. 发明授权

US08129400B2 Condensation compound between fluorinated cyclopentane ring and aromatic ring, and process for producing the same 失效
标题翻译：氟化环戊烷环和芳环之间的缩合化合物及其制备方法
公开(公告)号：US08129400B2
公开(公告)日：2012-03-06
申请号：US13106620
申请日：2011-05-12
申请人： Yutaka Ie , Yoshio Aso
发明人： Yutaka Ie , Yoshio Aso
IPC分类号： A61K31/435 , C07D221/02
CPC分类号： C07D495/20 , C07D333/78 , H01L51/0036
摘要： A condensation compound of a fluorinated cyclopentane ring and an aromatic ring, which is useful, for example, for electronic materials, and a process for producing the same are provided. For instance, according to Scheme 1 below, a compound (68) containing a condensed structure formed of a hexafluorocyclopentane ring and an aromatic ring is synthesized. The aromatic ring is not limited to a thiophene ring but can be any ring and any substituent can be used. Thus a compound containing a condensed ring structure formed of a hexafluorocyclopentane ring and an aromatic ring, particularly, for instance, a thiophene ring, which was impossible to produce conventionally, can be produced easily with high yield. The compound of the present invention is particularly suitable to be applied to, for example, electronic materials or semiconductors. When it is polymerized and thereby the π-electronic conjugation is extended, it also is expected to be applied to, for example, n-type organic semiconductors and molecular wires that are indispensable for developing molecular electronics elements.
摘要翻译：提供氟化环戊烷环和芳环的缩合化合物，其可用于例如电子材料，以及其制备方法。例如，根据下述方案1，合成含有由六氟环戊烷环和芳香环形成的稠合结构的化合物（68）。芳环不限于噻吩环，而是可以是任何环，并且可以使用任何取代基。因此，可以容易地以高产率制备含有由六氟环戊烷环和芳环形成的稠环结构的化合物，特别是例如噻吩环，这是不可能制备的。本发明的化合物特别适用于例如电子材料或半导体。当其被聚合并由此延长了电子共轭时，也可以应用于例如用于开发分子电子元件不可或缺的n型有机半导体和分子线。

9. 发明申请

US20100084640A1 POLYMER HAVING UNIT OBTAINED BY CONDENSATION OF DIFLUOROCYCLOPENTANEDIONE RING AND AROMATIC RING, ORGANIC THIN FILM USING THE SAME, AND ORGANIC THIN FILM DEVICE 失效
标题翻译：聚合物具有通过使用它们的有机薄膜和有机薄膜装置获得的二元环戊二烯环和芳环的有机薄膜
公开(公告)号：US20100084640A1
公开(公告)日：2010-04-08
申请号：US12529878
申请日：2008-03-05
申请人： Yutaka Ie , Yoshio Aso , Yoshikazu Umemoto , Masato Ueda
发明人： Yutaka Ie , Yoshio Aso , Yoshikazu Umemoto , Masato Ueda
IPC分类号： H01L51/00 , C08F114/18 , B32B5/00 , H01L51/10
CPC分类号： H01L51/0043 , C07D333/78 , C08G61/126 , C08G2261/142 , C08G2261/146 , C08G2261/3142 , C08G2261/3223 , C08G2261/354 , C08G2261/92 , H01L51/0036 , H01L51/0039 , H01L51/0541 , H01L51/0545 , H01L51/5048 , H01L51/5052 , Y02E10/549 , Y02P70/521
摘要： A polymer having a repeating unit represented by the following general formula (I) and a ferrocene-based reduction potential of −1.5 to −0.5 V as measured by a cyclic voltammetry method wherein Ar1 represents a divalent aromatic hydrocarbon group or a divalent heterocyclic group, and these groups may be substituted by a substituent.
摘要翻译：具有下述通式（I）表示的重复单元和通过循环伏安法测定的二茂铁系还原电位为-1.5〜-0.5V的聚合物，其中Ar1表示二价芳族烃基或二价杂环基，并且这些基团可以被取代基取代。

10. 发明授权

US08859717B2 Nitrogen-containing fused ring compound, nitrogen-containing fused ring polymer, organic thin film, and organic thin film element 有权
标题翻译：含氮稠环化合物，含氮稠环聚合物，有机薄膜和有机薄膜元素
公开(公告)号：US08859717B2
公开(公告)日：2014-10-14
申请号：US13582246
申请日：2011-03-03
申请人： Yutaka Ie , Masashi Ueta , Yoshio Aso , Masato Ueda
发明人： Yutaka Ie , Masashi Ueta , Yoshio Aso , Masato Ueda
IPC分类号： C08G75/00 , C07D513/14 , C07D513/04 , H01L51/00 , H01L51/05
CPC分类号： H01L51/0036 , C07D513/04 , C07D513/14 , H01L51/0541 , H01L51/0545 , Y02E10/549
摘要： Nitrogen-containing fused ring compound having at least one structural unit selected from the group consisting of a structural unit represented by the formula (1-1) and a structural unit represented by the formula (1-2).
摘要翻译：具有选自由式（1-1）表示的结构单元和式（1-2）表示的结构单元的至少一种结构单元的含氮稠环化合物。

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