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    • 1. 发明授权
    • Thin-film electroluminescence display device
    • 薄膜电致发光显示装置
    • US5539424A
    • 1996-07-23
    • US197492
    • 1994-02-16
    • Yutaka HattoriAtsushi MizutaniNobuei ItoTadashi Hattori
    • Yutaka HattoriAtsushi MizutaniNobuei ItoTadashi Hattori
    • H05B33/12H05B33/22G09G3/30
    • H05B33/12H05B33/22
    • A thin-film EL display device of red luminescent color having high luminous intensity and high reliability is disclosed. The thin-film EL display device has a first transparent electrode, a first transparent insulating layer, a light-emitting layer of zinc sulfide (ZnS) with the addition of manganese (Mn), a red-light transmitting filter of amorphous silicon (a-Si), a second transparent insulating layer, and a second transparent electrode (second electrode), which are successively deposited one on top of another on a glass substrate. The EL display device produces red light from orange light emission from the light-emitting layer. High temperature resistance of the filter permits the insertion of the filter to a desired position during the fabrication process for the thin-film EL display device. Furthermore, since the filter characteristics of the thin-film EL display do not suffer degradation by the heat generated during the light emitting operation thereof, there is no concern for luminescent color deterioration with time.
    • 公开了一种具有高发光强度和高可靠性的红色发光颜色的薄膜EL显示装置。 薄膜EL显示装置具有第一透明电极,第一透明绝缘层,添加有锰(Mn)的硫化锌(ZnS)发光层,非晶硅的红光透射滤光片(a -Si),第二透明绝缘层和第二透明电极(第二电极),其在玻璃基板上依次彼此沉积。 EL显示装置产生来自发光层的橙色发光的红光。 过滤器的耐高温性允许在薄膜EL显示装置的制造过程中将滤光片插入所需位置。 此外,由于薄膜EL显示器的滤光器特性不会因其在发光操作期间产生的热而劣化,所以不关心发光颜色随时间劣化。
    • 3. 发明授权
    • Thin-film EL display panel having uniform display characteristics
    • 具有均匀显示特性的薄膜EL显示面板
    • US5883465A
    • 1999-03-16
    • US414093
    • 1995-03-31
    • Kazuhiro InoguchiNobuei ItoTadashi HattoriYutaka HattoriMasahiko Osada
    • Kazuhiro InoguchiNobuei ItoTadashi HattoriYutaka HattoriMasahiko Osada
    • H05B33/04H05B33/06H05B33/12H05B33/26
    • H05B33/06H05B33/04H05B33/12H05B33/26
    • A thin-film EL display panel which has excellent packageability, high reliability and stable performance characteristics, and which can prevent nonuniformity of brightness and color from occurring and a fabrication method thereof are provided. In the above thin-film EL display panel, two thin-film EL elements 1 and 2 formed by sequentially laminating first electrodes 12 and 22, first insulating layers, luminescent layers, second insulating layers and second electrodes 16 and 26 respectively on glass substrates 11 and 21 are laminated into position and connecting terminal portions 12a, 22a, 16a and 26a for connecting the first electrodes 12 and 22 and second electrodes 16 and 26 are formed on the edge portions of the substrates 11 and 21 of the thin-film EL elements 1 and 2. Connecting pad portions 17 and 18 which correspond respectively to the connecting terminal portions 22a and 26a of the thin-film EL element 2 are provided on the edge portions on the substrate of the thin-film EL element 1, the connecting pad portions are connected to the connecting terminal portions of the other thin-film EL element via conductive coupling sections 19 and the connecting pad portions and the connecting terminal portions to which lead wires are connected are provided on the edge portion of one substrate at a position where both substrates will not be laminated.
    • 提供了具有优异的可封装性,高可靠性和稳定的性能特性的薄膜EL显示面板,并且可以防止发生亮度和颜色的不均匀性及其制造方法。 在上述薄膜EL显示面板中,通过将玻璃基板11上的第一电极12和22,第一绝缘层,发光层,第二绝缘层和第二电极16和26依次层叠而形成的两个薄膜EL元件1和2 和21层压到位置,并且用于连接第一电极12和22的连接端子部分12a,22a,16a和26a和第二电极16和26形成在薄膜EL元件的基板11和21的边缘部分上 在薄膜EL元件1的基板上的边缘部分上设置有与薄膜EL元件2的连接端子部分22a和26a相对应的连接焊盘部分17和18,连接焊盘 部分经由导电耦合部分19和连接焊盘部分和连接端子部分连接到另一薄膜EL元件的连接端子部分,引线 连接在一个基板的边缘部分上,两个基板将不被层压的位置。
    • 4. 发明授权
    • Process for the production of electroluminescence element,
electroluminescence element
    • 电致发光元件,电致发光元件的制造方法
    • US5853552A
    • 1998-12-29
    • US300552
    • 1994-09-07
    • Hajime IshiharaYutaka HattoriMasayuki KatayamaNobuei ItoTadashi Hattori
    • Hajime IshiharaYutaka HattoriMasayuki KatayamaNobuei ItoTadashi Hattori
    • C09K11/61C09K11/77C23C14/00C23C14/06H05B33/10H05B33/14H05B33/18C23C14/34
    • C23C14/0057C09K11/612C09K11/7745C09K11/776C23C14/0629H05B33/10H05B33/14H05B33/18
    • A process for producing an electroluminescence element provided with a luminescent layer sandwiched between two electrodes on an insulating substrate, the luminescent layer being composed of a host material with a luminescent center element added. The process comprises a step of forming the aforesaid luminescent layer as a film onto the insulating substrate by either sputtering or evaporation, by use of a source material composed of a compound of an element of Group II and an element of Group VI, to which a halide of a rare earth element is added as the luminescent center element. The atmosphere at the time of the film formation contains either a halogen gas or halide gas. The aforesaid luminescent layer is formed as a film onto the insulating substrate by either sputtering or evaporation, by use of a source material composed of the aforesaid compound of an element of Group II and an element of Group VI, to which a fluoride or fluorine compound of the luminescent center element and a halide other than fluoride of the element of Group II are added. The film formation atmosphere may be pretreated with a chlorine-containing gas prior to a film formation step of forming the luminescent layer as a film onto the insulating substrate by a sputtering method by use of a source material composed of the host material with the luminescent center element. An electro-luminescence element is further disclosed, wherein the X-ray diffraction spectrum thereof has only a single peak at an X-ray diffraction angle from the luminescent layer, ranging from 25.degree. to 30.degree. according to a thin film X-ray diffraction measuring method using Cu-Kd radiation, and no other peaks of the X-ray diffraction spectrum exist at an X-ray diffraction angle of approximately 27.degree..
    • 一种制造电致发光元件的方法,所述电致发光元件在绝缘基板上具有夹在两个电极之间的发光层,所述发光层由添加有发光中心元件的主体材料构成。 该方法包括通过溅射或蒸发,通过使用由II族元素和VI族元素的化合物组成的源材料,通过溅射或蒸发将上述发光层作为膜形成在绝缘基板上的步骤,其中 加入稀土元素的卤化物作为发光中心元件。 成膜时的气氛中含有卤素气体或卤化物气体。 上述发光层通过溅射或蒸镀通过使用由上述化合物II族元素和VI族元素组成的源材料形成为绝缘基板,氟化物或氟化合物 的发光中心元素和除了II族元素的氟化物之外的卤化物。 成膜气氛可以在通过使用由主体材料与发光中心构成的源材料通过溅射法将形成发光层作为膜的成膜步骤之前用含氯气体预处理 元件。 进一步公开了一种电致发光元件,其中,根据薄膜X射线衍射,其X射线衍射光谱在距发光层的X射线衍射角仅为单峰,为25〜30° 使用Cu-Kd辐射的测量方法,并且在大约27°的X射线衍射角处不存在X射线衍射光谱的其它峰。
    • 10. 发明授权
    • Thin-film El display panel having uniform display characteristics
    • 具有均匀显示特性的薄膜El显示面板
    • US06262531B1
    • 2001-07-17
    • US09187454
    • 1998-11-05
    • Kazuhiro InoguchiNobuei ItoTadashi HattoriYutaka HattoriMasahiko Osada
    • Kazuhiro InoguchiNobuei ItoTadashi HattoriYutaka HattoriMasahiko Osada
    • H01J162
    • H05B33/06H05B33/04H05B33/12H05B33/26
    • A thin-film EL display panel which has excellent packageability, high reliability and stable performance characteristics, and which can prevent nonuniformity of brightness and color from occurring and a fabrication method thereof are provided. In the above thin-film EL display panel, two thin-film EL elements 1 and 2 formed by sequentially laminating first electrodes 12 and 22, first insulating layers, luminescent layers, second insulating layers and second electrodes 16 and 26 respectively on glass substrates 11 and 21 are laminated into position and connecting terminal portions 12a, 22a, 16a and 26a for connecting the first electrodes 12 and 22 and second electrodes 16 and 26 are formed on the edge portions of the substrates 11 and 21 of the thin-film EL elements 1 and 2. connecting pad portions 17 and 18 which correspond respectively to the connecting terminal portions 22a and 26a of the thin-film EL element 2 are provided on the edge portions on the substrate of the thin-film EL element 1, the connecting pad portions are connected to the connecting terminal portions of the other thin-film EL element via conductive coupling sections 19 and the connecting pad portions and the connecting terminal portions to which lead wires are connected are provided on the edge portion of one substrate at a position where both substrates will not be laminated.
    • 提供了具有优异的可封装性,高可靠性和稳定的性能特性的薄膜EL显示面板,并且可以防止发生亮度和颜色的不均匀性及其制造方法。 在上述薄膜EL显示面板中,通过将玻璃基板11上的第一电极12和22,第一绝缘层,发光层,第二绝缘层和第二电极16和26依次层叠而形成的两个薄膜EL元件1和2 和21层压到位置,并且用于连接第一电极12和22的连接端子部分12a,22a,16a和26a和第二电极16和26形成在薄膜EL元件的基板11和21的边缘部分上 在薄膜EL元件1的基板上的边缘部分设置有与薄膜EL元件2的连接端子部分22a和26a相对应的连接焊盘部分17和18,连接焊盘 部分经由导电耦合部分19和连接焊盘部分和连接端子部分连接到另一薄膜EL元件的连接端子部分,引线 连接在一个基板的边缘部分上,两个基板将不被层压的位置。