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1. 发明授权

US07544748B2 Components and catalysis for the polymerization of olefins 有权
标题翻译：烯烃聚合的组分和催化剂
公开(公告)号：US07544748B2
公开(公告)日：2009-06-09
申请号：US11547111
申请日：2005-03-08
申请人： Yuri Gulevich , Giulio Balbontin , Giampiero Morini , Ilya Nifant'ev
发明人： Yuri Gulevich , Giulio Balbontin , Giampiero Morini , Ilya Nifant'ev
IPC分类号： C08F4/642
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651
摘要： The present invention relates to a solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from β-keto-ester derivatives of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.
摘要翻译：本发明涉及一种用于烯烃CH2-CHR聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和选自β-酮酯的电子给体具体公式的衍生物。当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够以高产率和高二甲苯不溶性表现的高全同立构指数得到聚合物。

2. 发明申请

US20070208150A1 Components and Catalysis for the Polymerization of Olefins 有权
标题翻译：烯烃聚合的组分和催化
公开(公告)号：US20070208150A1
公开(公告)日：2007-09-06
申请号：US11547111
申请日：2005-03-08
申请人： Yuri Gulevich , Giulio Balbontin , Giampiero Morini , Ilya Nifant'Ev
发明人： Yuri Gulevich , Giulio Balbontin , Giampiero Morini , Ilya Nifant'Ev
IPC分类号： C08F2/00
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651
摘要： The present invention relates to a solid catalyst component for the polymerization of olefins CH2=CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from β-keto-ester derivatives of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.
摘要翻译：本发明涉及用于烯烃CH 2 = CHR的聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和电子供体选自特定式的β-酮酯衍生物。当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够以高产率和高二甲苯不溶性表现的高全同立构指数得到聚合物。

3. 发明授权

US07674741B2 Components and catalysts for the polymerization of olefins 有权
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US07674741B2
公开(公告)日：2010-03-09
申请号：US11629240
申请日：2005-05-27
申请人： Yuri Gulevich , Giulio Balbontin , Remco Kelder , Giampiero Morini , Jan Dirk Van Loon
发明人： Yuri Gulevich , Giulio Balbontin , Remco Kelder , Giampiero Morini , Jan Dirk Van Loon
IPC分类号： C08F4/64 , C08F10/00
CPC分类号： B01J31/0204 , B01J31/0208 , B01J31/0212 , B01J31/128 , B01J31/143 , B01J31/38 , C08F110/06 , C08F4/651 , C08F2500/17
摘要： The present invention relates to a solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from y-butyrolactone derivatives of a particular formula. Said catalyst components, when used in the polymerization of olefins and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.
摘要翻译：本发明涉及用于烯烃CH 2 = CHR聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和选自Y-丁内酯衍生物的电子给体一个特定的公式。当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够以高产率和高二甲苯不溶性表现的高全同立构指数得到聚合物。

4. 发明申请

US20090118446A1 Components and catalysts for the polymerization of olefins 有权
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US20090118446A1
公开(公告)日：2009-05-07
申请号：US11629240
申请日：2005-05-27
申请人： Yuri Gulevich , Giulio Balbontin , Remco Kelder , Giampiero Morini , Jan Dirk Van Loon
发明人： Yuri Gulevich , Giulio Balbontin , Remco Kelder , Giampiero Morini , Jan Dirk Van Loon
IPC分类号： C08F4/50 , B01J31/04
CPC分类号： B01J31/0204 , B01J31/0208 , B01J31/0212 , B01J31/128 , B01J31/143 , B01J31/38 , C08F110/06 , C08F4/651 , C08F2500/17
摘要： The present invention relates to a solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from γ-butyrolactone derivatives of a particular formula. Said catalyst components, when used in the polymerization of olefins and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.
摘要翻译：本发明涉及用于烯烃CH 2 -CHR的聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，其包含Mg，Ti，卤素和选自以下的γ-丁内酯衍生物一个特定的公式。当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够以高产率和高二甲苯不溶性表现的高全同立构指数得到聚合物。

5. 发明授权

US07482413B2 Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom 有权
标题翻译：二氯化镁 - 醇加合物和由其获得的催化剂组分
公开(公告)号：US07482413B2
公开(公告)日：2009-01-27
申请号：US10550986
申请日：2004-03-09
申请人： Giampiero Morini , Giulio Balbontin , Fabrizio Piemontesi , Maria Fusto , Gianni Vitale , Giansiro Prini
发明人： Giampiero Morini , Giulio Balbontin , Fabrizio Piemontesi , Maria Fusto , Gianni Vitale , Giansiro Prini
IPC分类号： C08F4/42
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F4/6543 , C08F4/651 , C08F2500/12 , C08F4/65
摘要： The present invention relates to MgCl2.(EtOH),m(ROH)n(H2O)p adduct in which R is a C1-C15 hydrocarbon group different from ethyl, n and m are indexes, higher than 0, satisfying the equations (n+m)≧0.7 and 0.05≦n/(n+m)≦0.95 and p is a number ranging from 0 to 0.7 with the proviso that when R is methyl and (n+m) is in the range of 0.7 to 1, the value of n/(n+m) ranges from 0.05 to 0.45. The catalyst components obtained from the adducts of the present invention are capable to give catalysts for the polymerization of olefins characterized by enhanced activity with respect to the catalysts prepared from the adducts of the prior art.
摘要翻译：本发明涉及MgCl 2（EtOH），m（ROH）n（H 2 O）p加合物，其中R是不同于乙基的C 1 -C 15烃基，n和m是指数，高于0，满足等式（n + m）> = 0.7和0.05 <= n /（n + m）<= 0.95，p为0至0.7的数，条件是当R为甲基且（n + m）为0.7 为1，n /（n + m）的值为0.05〜0.45。从本发明的加合物得到的催化剂组分能够产生用于烯烃聚合的催化剂，其特征在于相对于由现有技术的加合物制备的催化剂具有增强的活性。

6. 发明申请

US20060105906A1 Components and catalysts for the polymerization of olefins 有权
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US20060105906A1
公开(公告)日：2006-05-18
申请号：US10527298
申请日：2003-08-01
申请人： Giampiero Morini , Giulio Balbontin , Gianni Vitale
发明人： Giampiero Morini , Giulio Balbontin , Gianni Vitale
IPC分类号： B01J31/00 , C08F4/44
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F4/6543 , C08F2500/08
摘要： The present invention relates to a solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from succinates, said catalyst component being obtainable by a process comprising the following steps: (a) dissolving a halide of magnesium in a solvent system comprising an organic epoxy compound or an organic phosphorus compound and optionally an inert diluent to form a solution; (b) mixing the obtained solution with a titanium compound to form a mixture; (c) precipitating a solid from the mixture obtained in step (b) in the presence of a succinate and/or an auxiliary precipitant; (d) if a succinate is not used in step (c), contacting the solid obtained in (c) with a succinate, and (e) treating the solid obtained in (c) or (d) with a titanium compound optionally in the presence of an inert diluent.
摘要翻译：本发明涉及用于烯烃CH 2 -CHR的聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和电子所述催化剂组分可通过包括以下步骤的方法获得：（a）将镁的卤化物溶解在包含有机环氧化合物或有机磷化合物和任选的惰性稀释剂的溶剂体系中以形成溶液; （b）将所得溶液与钛化合物混合以形成混合物; （c）在琥珀酸盐和/或辅助沉淀剂存在下从步骤（b）中获得的混合物中沉淀出固体; （d）如果在步骤（c）中不使用琥珀酸酯，则将（c）中得到的固体与琥珀酸酯接触，和（e）用钛化合物处理在（c）或（d）中获得的固体，存在惰性稀释剂。

7. 发明申请

US20050131172A1 Propylene polymers 有权
标题翻译：丙烯聚合物
公开(公告)号：US20050131172A1
公开(公告)日：2005-06-16
申请号：US10965543
申请日：2004-10-14
申请人： Giampiero Morini , Giulio Balbontin
发明人： Giampiero Morini , Giulio Balbontin
IPC分类号： C08F4/651 , C08F4/654 , C08F10/00 , C08F4/44
CPC分类号： C08F10/00 , C08F4/651 , C08F4/6545
摘要： The present invention relates to catalyst components for the polymerization of olefins comprising Mg, Ti, halogen and at least two electron donor compounds, said catalyst component being characterized by the fact that at least one of the electron donor compounds, present in an amount from 20 to 50% by mol with respect to the total amount of donors, is selected from esters of succinic acids which are not extractable, for more than 25% by mol and at least another electron donor compound which is extractable, for more than 35%. The said catalyst component-are capable to give polymers with high xylene insolubility, high stereoblock content and broad MWD suitable for making the polymers usable in the BOPP sector.
摘要翻译：本发明涉及包含Mg，Ti，卤素和至少两种电子给体化合物的烯烃聚合的催化剂组分，所述催化剂组分的特征在于至少一种电子给体化合物的存在量为20 相对于供体总量为50摩尔％，选自不可提取的琥珀酸的酯，超过25摩尔％的至少另一种可提取的电子给体化合物，超过35％。所述催化剂组分 - 能够产生具有高二甲苯不溶性，高立体嵌段含量和宽MWD的聚合物，其适合于使聚合物可用于BOPP部分。

8. 发明授权

US06825309B2 Catalyst components for the polymerization of olefins 有权
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US06825309B2
公开(公告)日：2004-11-30
申请号：US10149306
申请日：2002-06-10
申请人： Giampiero Morini , Giulio Balbontin
发明人： Giampiero Morini , Giulio Balbontin
IPC分类号： C08F11006
CPC分类号： C08F10/00 , C08F4/651 , C08F4/6545
摘要： The present invention relates to catalyst components for the polymerization of olefins comprising Mg, Ti, halogen and at least two electron donor compounds, said catalyst component being characterized by the fact that at least one of the electron donor compounds, present in an amount from 20 to 50% by mol with respect to the total amount of donors, is selected from esters of succinic acids which are not extractable, for more than 25% by mol and at least another electron donor compound which is extractable, for more than 35%. The said catalyst component are capable to give polymers with high xylene insolubility, high stereoblock content and broad MWD suitable for making the polymers usable in the BOPP sector.
摘要翻译：本发明涉及包含Mg，Ti，卤素和至少两种电子给体化合物的烯烃聚合的催化剂组分，所述催化剂组分的特征在于至少一种电子给体化合物的存在量为20 相对于供体总量为50摩尔％，选自不可提取的琥珀酸的酯，超过25摩尔％的至少另一种可提取的电子给体化合物，超过35％。所述催化剂组分能够产生具有高二甲苯不溶性，高立体嵌段含量和宽MWD的聚合物，其适用于使聚合物可用于BOPP部分。

9. 发明授权

US06699814B2 Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US06699814B2
公开(公告)日：2004-03-02
申请号：US10455898
申请日：2003-06-06
申请人： Giampiero Morini , Giulio Balbontin , Yuri V. Gulevich
发明人： Giampiero Morini , Giulio Balbontin , Yuri V. Gulevich
IPC分类号： C08F4649
CPC分类号： C08F10/06 , C07C69/63 , C08F4/6365 , C08F4/651
摘要： The present invention relates to catalysts particularly suitable for the sterospecific polymermerization of olefins, comprising Ti, Mg, halogen and an electron donor compound selected from heteroatoms containing esters of malonic acids. Polymers produced by the catalysts have high isotactic index expressed in terms of high xylene insolubility.
摘要翻译：本发明涉及特别适用于包含Ti，Mg，卤素和选自含有丙二酸酯的杂原子的电子给体化合物的烯烃的固相特异性聚酯化的催化剂。由催化剂生产的聚合物具有高的二甲苯不溶性高的全同立构指数。

10. 发明授权

US6143684A Components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US6143684A
公开(公告)日：2000-11-07
申请号：US146368
申请日：1998-09-03
申请人： Giampiero Morini , Yuri V. Gulevich , Giulio Balbontin
发明人： Giampiero Morini , Yuri V. Gulevich , Giulio Balbontin
IPC分类号： C08F4/654 , C08F4/02 , C08F4/64 , C08F4/651 , C08F4/658 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/60
CPC分类号： C08F10/00
摘要： The invention relates to solid catalyst components for the polymerization of olefins CH.sub.2 .dbd.CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Ti, Mg, halogen and an electron donor compound selected from cyanoesters of formula (1): ##STR1## wherein R.sub.1 is a C.sub.1 -C.sub.20 linear or branched alkyl, alkenyl, cycloalkyl, cycloalkylalkyl, alkylcycloalkyl, aryl, arylalkyl or alkylaryl group; n is 0, 1, 2 or 3; R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are independently selected from hydrogen or C.sub.1 -C.sub.20 linear or branched alkyl, alkenyl, cycloalkyl, cycloalkylalkyl, alkylcycloalkyl, aryl, arylalkyl or alkylaryl groups; two or more of R.sub.2 and R.sub.3, and R.sub.4 and R.sub.5, can be joined to form a cycle. Said catalyst components when used in the polymerization of olefins are characterized by an excellent response to hydrogen and capability to produce polymers with broad Molecular Weight Distribution.
摘要翻译：本发明涉及用于烯烃CH2 = CHR聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，其包含Ti，Mg，卤素和选自式（1）的氰酯的电子给体化合物）：其中R1是C1-C20直链或支链烷基，烯基，环烷基，环烷基烷基，烷基环烷基，芳基，芳基烷基或烷基芳基; n为0,1,2或3; R 2，R 3，R 4和R 5独立地选自氢或C 1 -C 20直链或支链烷基，烯基，环烷基，环烷基烷基，烷基环烷基，芳基，芳基烷基或烷基芳基; R2和R3中的两个或更多个，以及R4和R5可以连接形成一个循环。当用于烯烃聚合时，所述催化剂组分的特征在于对氢的优异响应和产生具有宽分子量分布的聚合物的能力。

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