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1. 发明申请

US20070298248A1 Coating Composition, Hard Coat Film, and Optical Recording Medium 审中-公开
标题翻译：涂料组合物，硬涂层和光记录介质
公开(公告)号：US20070298248A1
公开(公告)日：2007-12-27
申请号：US11794358
申请日：2005-11-22
申请人： Yuki Hongo , Kenta Tomioka , Satoru Shoshi
发明人： Yuki Hongo , Kenta Tomioka , Satoru Shoshi
IPC分类号： C09D171/02 , C08J7/06 , C09D183/04 , C09D4/00 , G02B1/10 , G11B7/24 , G11B7/257
CPC分类号： C08J7/16 , C08J7/047 , C08J2369/00 , C08J2483/00 , C08K3/22 , C08K9/04 , C09D4/00 , C09D5/24 , C09D7/65 , C09D183/10 , G11B7/2545 , G11B7/256 , Y10T428/261 , Y10T428/265 , C08L2666/54
摘要： A coating composition containing reactive particles (A) in which an organic compound having at least one polymerizable unsaturated group in a molecule thereof is chemically bonded to inorganic oxide particles, an organic compound monomer or oligomer (B) having a polyethylene oxide chain (content in molecule: not less than 50% and less than 100%) and at least two polymerizable unsaturated groups in a molecule thereof and not having an aromatic ring and an alkyl chain having seven or more carbon atoms, an organic compound monomer or oligomer (C) having at least two polymerizable unsaturated groups in a molecule thereof, being an organic compound monomer or oligomer other than the organic compound monomer or oligomer (B), and a siloxane compound (D) having a dialkyl siloxane backbone is applied onto one surface of a base material film 11, and cured by irradiating with ionizing radiation, so as to form a hard coat layer 12 of thickness from 0.1 to 20 μm. This hard coat layer 12 has both excellent fingerprint wipability and excellent antistatic performance.
摘要翻译：含有反应性粒子（A）的涂料组合物，其中分子中具有至少一个可聚合不饱和基团的有机化合物与无机氧化物颗粒化学键合，具有聚环氧乙烷链的有机化合物单体或低聚物（B）（含量分子：不小于50％且小于100％）和分子中至少两个不具有芳环和具有7个或更多个碳原子的烷基链的可聚合不饱和基团，有机化合物单体或低聚物（C）在其分子中具有至少两个可聚合的不饱和基团，作为除了有机化合物单体或低聚物（B）之外的有机化合物单体或低聚物，并且具有二烷基硅氧烷骨架的硅氧烷化合物（D）被施加到基材膜11，通过照射电离辐射使其固化，形成厚度为0.1〜20μm的硬涂层12。该硬涂层12具有优异的指纹擦拭性和优异的抗静电性能。

2. 发明授权

US07589130B2 Coating composition, coating film, method of manufacturing coating film, and optical recording medium 失效
标题翻译：涂料组合物，涂膜，涂膜方法和光记录介质
公开(公告)号：US07589130B2
公开(公告)日：2009-09-15
申请号：US11194756
申请日：2005-08-02
申请人： Yuki Hongo , Satoru Shoshi , Hideo Senoo , Takeshi Yamasaki , Tomomi Yukumoto
发明人： Yuki Hongo , Satoru Shoshi , Hideo Senoo , Takeshi Yamasaki , Tomomi Yukumoto
IPC分类号： B29C71/04
CPC分类号： G11B7/26 , G11B7/24056 , G11B7/252 , G11B7/2542 , G11B7/256
摘要： A coating composition containing a solvent and a coating agent having an ionizing radiation-curable compound as a principal component thereof, wherein under the following condition for the concentration a (wt %) of the coating agent in the coating composition 0
摘要翻译：一种涂料组合物，其含有溶剂和具有电离辐射固化性化合物作为其主要成分的涂布剂，其中在以下条件下，将涂料组合物中的涂布剂a（wt％）< 公式description =“In-line Formulas”end =“lead”？> 0 涂层组合物的表面张力b（达因/厘米）满足以下关系式<？in-line-formula description =“In-line Formulas”end =“lead”？> b <=（ - a / 15 ）+26，<？in-line-formula description =“在线公式”end =“tail”？>被施加到保护膜11的表面上，并进行固化以形成硬涂层12.甚至在保护膜11的表面上存在突起或异物的情况下，硬涂层12可以隐藏这些，因此可以具有高的表面光滑度。

3. 发明申请

US20050238879A1 Film for optical applications 有权
标题翻译：光学应用薄膜
公开(公告)号：US20050238879A1
公开(公告)日：2005-10-27
申请号：US10977605
申请日：2004-10-28
申请人： Satoru Shoshi , Yuki Hongo , Hideo Seno
发明人： Satoru Shoshi , Yuki Hongo , Hideo Seno
IPC分类号： B32B27/30 , B32B7/02 , B32B27/08 , C08J7/04 , G02F1/135 , B32B27/36 , G02F1/136
CPC分类号： B32B27/08 , B32B7/12 , B32B23/08 , B32B27/308 , B32B27/32 , B32B27/36 , B32B27/365 , B32B2367/00 , B32B2369/00 , C08J7/04 , C08J2369/00 , Y10T428/31507 , Y10T428/31551 , Y10T428/31565 , Y10T428/31583 , Y10T428/31587 , Y10T428/31591
摘要： A hard coat film for optical applications which suppresses formation of defects on the surface derived from roughness of the surface of the substrate film, exhibits excellent scratch resistance and crack resistance and suppresses curling of the substrate film is provided. The film for optical applications comprises (A) a layer of a cured resin 2 which comprises 70% by weight or more of a cured resin derived from a difunctional urethane acrylate-based oligomer having a weight-average molecular weight of 3,000 or greater and has a thickness of 5 to 25 μm and (B) a hard coat layer 3 which comprises a resin cured by irradiation with an ionizing radiation and has a thickness of 1 to 15 μm, layers (A) and (B) being successively laminated on one face of a substrate film 1.
摘要翻译：用于光学应用的硬涂膜，其抑制由基材膜的表面的粗糙度导致的表面上的缺陷的形成，表现出优异的耐划伤性和抗裂纹性，并且抑制基材膜的卷曲。用于光学应用的膜包括（A）固化树脂2的层，其包含70重量％以上的衍生自重均分子量为3,000以上的双官能氨基甲酸酯丙烯酸酯类低聚物的固化树脂，并且具有厚度为5〜25μm，（B）硬涂层3，其包含用电离辐射照射固化的树脂，其厚度为1〜15μm，层（A）和（B）依次层压在一个衬底膜1的表面。

4. 发明授权

US07141298B2 Hard coat film 有权
标题翻译：硬涂膜
公开(公告)号：US07141298B2
公开(公告)日：2006-11-28
申请号：US10681069
申请日：2003-10-08
申请人： Satoru Shoshi , Yuki Hongo , Yoshitaka Takesako
发明人： Satoru Shoshi , Yuki Hongo , Yoshitaka Takesako
IPC分类号： B32B27/08
CPC分类号： G02B1/14 , C08J7/047 , C08J2369/00 , C08J2433/00 , G02B1/105 , G11B7/2534 , G11B7/2542 , G11B7/2545 , G11B7/256 , Y10T428/259 , Y10T428/31507 , Y10T428/31547 , Y10T428/31667 , Y10T428/31786 , Y10T428/31797
摘要： A hard coat film comprises a hard coat layer formed by coating at least one face of a substrate with a coating fluid and curing the obtained coating layer by irradiation with an ionizing radiation. The coating fluid comprises a component for forming a hard coat layer comprising (A) a compound which is formed by bonding an organic compound having a polymerizable unsaturated group to fine particles of silica, (B) an ester of (meth)acrylic acid having an alicyclic structure and (C) a compound having at least two polymerizable unsaturated groups and at least one aryl group in a molecule. The hard coat layer comprises 20 to 60% by weight of silica and has a refractive index of 1.53 or greater. The hard coat film exhibits excellent scratch resistance, little shrinking by curing and little shrinking and curling under high temperature and humidity and forms no optical interference fringes.
摘要翻译：硬涂膜包括通过用涂布液涂布基材的至少一个表面而形成的硬涂层，并且通过用电离辐射照射固化所获得的涂层。涂布流体包括用于形成硬涂层的组分，其包含（A）通过将具有可聚合不饱和基团的有机化合物与二氧化硅细颗粒结合而形成的化合物，（B）具有（甲基）丙烯酸的脂环结构和（C）分子中具有至少两个可聚合不饱和基团和至少一个芳基的化合物。硬涂层包含20至60重量％的二氧化硅，折射率为1.53或更大。硬涂膜具有优异的耐擦伤性，通过固化几乎不收缩，并且在高温和高湿下几乎不收缩和卷曲，并且不形成光学干涉条纹。

5. 发明授权

US07655308B2 Film for optical applications 有权
标题翻译：光学应用薄膜
公开(公告)号：US07655308B2
公开(公告)日：2010-02-02
申请号：US10977605
申请日：2004-10-28
申请人： Satoru Shoshi , Yuki Hongo , Hideo Seno
发明人： Satoru Shoshi , Yuki Hongo , Hideo Seno
IPC分类号： B32B27/40 , B32B27/32 , B32B27/36
CPC分类号： B32B27/08 , B32B7/12 , B32B23/08 , B32B27/308 , B32B27/32 , B32B27/36 , B32B27/365 , B32B2367/00 , B32B2369/00 , C08J7/04 , C08J2369/00 , Y10T428/31507 , Y10T428/31551 , Y10T428/31565 , Y10T428/31583 , Y10T428/31587 , Y10T428/31591
摘要： A hard coat film for optical applications which suppresses formation of defects on the surface derived from roughness of the surface of the substrate film, exhibits excellent scratch resistance and crack resistance and suppresses curling of the substrate film is provided. The film for optical applications comprises (A) a layer of a cured resin 2 which comprises 70% by weight or more of a cured resin derived from a difunctional urethane acrylate-based oligomer having a weight-average molecular weight of 3,000 or greater and has a thickness of 5 to 25 μm and (B) a hard coat layer 3 which comprises a resin cured by irradiation with an ionizing radiation and has a thickness of 1 to 15 μm, layers (A) and (B) being successively laminated on one face of a substrate film 1.
摘要翻译：用于光学应用的硬涂膜，其抑制由基材膜的表面的粗糙度导致的表面上的缺陷的形成，表现出优异的耐划伤性和抗裂纹性，并且抑制基材膜的卷曲。用于光学应用的膜包括（A）固化树脂2的层，其包含70重量％以上的衍生自重均分子量为3,000以上的双官能氨基甲酸酯丙烯酸酯类低聚物的固化树脂，并且具有厚度为5〜25μm，（B）硬涂层3，其包含用电离辐射照射固化的树脂，其厚度为1〜15μm，层（A）和（B）依次层叠在一个上衬底膜1的表面。

6. 发明申请

US20090291248A1 Coating composition, coating film, method of manufacturing coating film, and optical recording medium 审中-公开
标题翻译：涂料组合物，涂膜，涂膜方法和光记录介质
公开(公告)号：US20090291248A1
公开(公告)日：2009-11-26
申请号：US12461033
申请日：2009-07-30
申请人： Yuki Hongo , Satoru Shoshi , Hideo Senoo , Takeshi Yamasaki , Tomomi Yukumoto
发明人： Yuki Hongo , Satoru Shoshi , Hideo Senoo , Takeshi Yamasaki , Tomomi Yukumoto
IPC分类号： B32B3/02 , B32B3/30
CPC分类号： G11B7/26 , G11B7/24056 , G11B7/252 , G11B7/2542 , G11B7/256
摘要： A coating composition containing a solvent and a coating agent having an ionizing radiation-curable compound as a principal component thereof, wherein under the following condition for the concentration a (wt %) of the coating agent in the coating composition 0
摘要翻译：含有溶剂的涂料组合物和具有电离辐射固化性化合物作为其主要成分的涂布剂，其中在以下条件下，为了使涂料组合物0中涂布剂的浓度a（wt％）为浓度a，涂布剂和涂层组合物的表面张力b（达因/厘米）满足以下关系b被施加到保护膜11的表面上，并进行固化以形成硬涂层12.即使在突起或异物存在于保护膜11的表面上时，硬涂层12可以隐藏这些，因此可以具有高的表面光滑度。

7. 发明授权

US07211317B2 Light transmitting hard coat film for use in touch panels 有权
标题翻译：透光硬涂膜用于触摸屏
公开(公告)号：US07211317B2
公开(公告)日：2007-05-01
申请号：US10713209
申请日：2003-11-17
申请人： Yuki Hongo , Satoru Shoshi , Yoshitaka Takesako
发明人： Yuki Hongo , Satoru Shoshi , Yoshitaka Takesako
IPC分类号： B32B7/02 , B32B27/00
CPC分类号： G02B1/14 , G02B1/105 , G02F1/13338 , G02F2201/38 , G02F2201/50 , Y10T428/24967 , Y10T428/24975 , Y10T428/256 , Y10T428/259 , Y10T428/31663 , Y10T428/31667
摘要： The present invention provides a light transmitting hard coat film for use in touch panels, which comprises: (A) a light transmitting hard coat layer composed of a cured product of an ionizing-radiation-curable compound; (B) a high refractive index layer composed of a cured product of an ionizing-radiation-curable compound and containing antimony-doped tin oxide plus zirconium oxide and/or titanium oxide, as metal oxides, which has a refractive index in the range of 1.65 to 1.90 and a thickness of 30 to 160 nm; and (C) a low refractive index layer composed of a cured product of a siloxane-based curable compound which has a refractive index in the range of 1.40 to 1.55 and a thickness of 10 to 50 nm, all the layers being laminated on one side of a light transmitting base film in this order. The light transmitting hard coat film for use in touch panels has a high light transmittance and can produce transmitted light of blue color.
摘要翻译：本发明提供一种用于触摸面板的透光性硬涂膜，其包括：（A）由电离辐射固化性化合物的固化物构成的透光性硬涂层; （B）由电离辐射固化性化合物的固化物构成的含有掺锑氧化锡和氧化锆和/或氧化钛的高折射率层作为金属氧化物，其折射率在 1.65〜1.90，厚度30〜160nm; 和（C）由折射率为1.40〜1.55，厚度为10〜50nm的硅氧烷类固化性化合物的固化物构成的低折射率层，全部层叠在一侧的透光基膜。用于触摸屏的透光硬涂膜具有高透光率并且可以产生蓝色的透射光。

8. 发明申请

US20060044993A1 Coating composition, coating film, method of manufacturing coating film, and optical recording medium 失效
标题翻译：涂料组合物，涂膜，涂膜方法和光记录介质
公开(公告)号：US20060044993A1
公开(公告)日：2006-03-02
申请号：US11194756
申请日：2005-08-02
申请人： Yuki Hongo , Satoru Shoshi , Hideo Senoo , Takeshi Yamasaki , Tomomi Yukumoto
发明人： Yuki Hongo , Satoru Shoshi , Hideo Senoo , Takeshi Yamasaki , Tomomi Yukumoto
IPC分类号： G11B3/70 , G11B7/24
CPC分类号： G11B7/26 , G11B7/24056 , G11B7/252 , G11B7/2542 , G11B7/256
摘要： A coating composition containing a solvent and a coating agent having an ionizing radiation-curable compound as a principal component thereof, wherein under the following condition for the concentration a (wt %) of the coating agent in the coating composition 0
摘要翻译：一种涂料组合物，其含有溶剂和具有电离辐射固化性化合物作为其主要成分的涂布剂，其中在以下条件下，将涂料组合物中的涂布剂a（wt％）< 公式description =“In-line Formulas”end =“lead”？> 0 涂层组合物的表面张力b（达因/厘米）满足以下关系式<？in-line-formula description =“In-line Formulas”end =“lead”？> b <=（ - a / 15 ）+26，<？in-line-formula description =“在线公式”end =“tail”？>施加到保护膜11的表面上，并进行固化以形成硬涂层12。即使在保护膜11的表面上存在突起或异物的情况下，硬涂层12也可以隐藏这些，因此可以具有高的表面平滑度。

9. 发明申请

US20050147809A1 Coating composition, hard coat film, and optical disk 有权
标题翻译：涂料组合物，硬涂膜和光盘
公开(公告)号：US20050147809A1
公开(公告)日：2005-07-07
申请号：US10969329
申请日：2004-10-21
申请人： Yuki Hongo , Satoru Shoshi , Kazuya Katoh , Hideo Senoo
发明人： Yuki Hongo , Satoru Shoshi , Kazuya Katoh , Hideo Senoo
IPC分类号： G02B1/10 , B32B27/30 , C08F292/00 , C09D4/00 , C09D4/06 , C09D7/12 , C09D133/08 , C09D133/10 , C09D183/00 , C09D183/04 , C09D201/02 , G11B7/24 , G11B7/254 , G11B7/257 , B32B27/32 , B32B27/36 , C08F261/00
CPC分类号： G11B7/2542 , C08F292/00 , C09D4/00 , G11B7/2533 , G11B7/2534 , G11B7/2538 , G11B7/2545 , G11B7/256 , Y10T428/21 , Y10T428/265 , Y10T428/2993 , Y10T428/31507 , Y10T428/31935 , Y10T428/31938 , C08F220/10
摘要： One side of a substrate film 11 is coated with a coating composition containing (A) a reactive particle produced by chemically bonding an organic compound having at least one polymerizable unsaturated group in its molecule to an inorganic oxide particle, (B) a monomer or oligomer of an organic compound having at least two polymerizable unsaturated groups in its molecule, (C) an organic compound with a weight average molecular weight of at least 1500 and having at least one polymerizable unsaturated group in its molecule, and, if desired, (D) a siloxane compound having a dimethylsiloxane skeleton, and the coating composition is cured by irradiation with ionizing radiation to form a hard coat layer 12 with a thickness of 2 to 20 μm. This provides a hard coat film having adequate surface hardness and suppressed warpage.
摘要翻译：基材膜11的一面涂布有涂料组合物，该涂料组合物含有（A）通过将其分子中具有至少一个可聚合不饱和基团的有机化合物化学键合到无机氧化物颗粒而制备的反应性颗粒，（B）单体或低聚物的分子中具有至少两个可聚合不饱和基团的有机化合物，（C）重均分子量为至少1500的有机化合物，并且在其分子中具有至少一个可聚合不饱和基团，如果需要，（D））具有二甲基硅氧烷骨架的硅氧烷化合物，通过用电离辐射照射使涂料组合物固化，形成厚度为2〜20μm的硬涂层12。这提供了具有足够的表面硬度和抑制翘曲的硬涂层膜。

10. 发明授权

US07384676B2 Coating composition, hard coat film, and optical disk 有权
标题翻译：涂料组合物，硬涂膜和光盘
公开(公告)号：US07384676B2
公开(公告)日：2008-06-10
申请号：US10969329
申请日：2004-10-21
申请人： Yuki Hongo , Satoru Shoshi , Kazuya Katoh , Hideo Senoo
发明人： Yuki Hongo , Satoru Shoshi , Kazuya Katoh , Hideo Senoo
IPC分类号： B32B3/02
CPC分类号： G11B7/2542 , C08F292/00 , C09D4/00 , G11B7/2533 , G11B7/2534 , G11B7/2538 , G11B7/2545 , G11B7/256 , Y10T428/21 , Y10T428/265 , Y10T428/2993 , Y10T428/31507 , Y10T428/31935 , Y10T428/31938 , C08F220/10
摘要： One side of a substrate film 11 is coated with a coating composition containing (A) a reactive particle produced by chemically bonding an organic compound having at least one polymerizable unsaturated group in its molecule to an inorganic oxide particle, (B) a monomer or oligomer of an organic compound having at least two polymerizable unsaturated groups in its molecule, (C) an organic compound with a weight average molecular weight of at least 1500 and having at least one polymerizable unsaturated group in its molecule, and, if desired, (D) a siloxane compound having a dimethylsiloxane skeleton, and the coating composition is cured by irradiation with ionizing radiation to form a hard coat layer 12 with a thickness of 2 to 20 μm. This provides a hard coat film having adequate surface hardness and suppressed warpage.
摘要翻译：基材膜11的一面涂布有涂料组合物，该涂料组合物含有（A）通过将其分子中具有至少一个可聚合不饱和基团的有机化合物化学键合到无机氧化物颗粒而制备的反应性颗粒，（B）单体或低聚物的分子中具有至少两个可聚合不饱和基团的有机化合物，（C）重均分子量为至少1500的有机化合物，并且在其分子中具有至少一个可聚合不饱和基团，如果需要，（D））具有二甲基硅氧烷骨架的硅氧烷化合物，通过用电离辐射照射使涂料组合物固化，形成厚度为2〜20μm的硬涂层12。这提供了具有足够的表面硬度和抑制翘曲的硬涂层膜。

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