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    • 3. 发明授权
    • Process for preparing polymer
    • 制备聚合物的方法
    • US5439980A
    • 1995-08-08
    • US169753
    • 1993-12-20
    • Yuji YutaniMasayoshi Tatemoto
    • Yuji YutaniMasayoshi Tatemoto
    • C08F2/00C08F20/12C08F293/00C08F259/08
    • C08F20/12C08F2/00C08F293/005
    • A polymer comprising at least one polymer chain is produced by polymerizing, in the presence of a radical generating source and an iodide compound, at least one monomer M.sub.1 having a radically polymerizable unsaturated bond between a carbon atom and an iodine atom constituting a carbon-iodine bond of the iodide compound to form at least one polymer chain between the carbon atom and the iodine atom, wherein the polymerization reaction is carried out in the presence of a monomer M.sub.2 which is different from the monomer M.sub.1 and has a larger addition reactivity with a carbon radical which is generated by cleavage of the carbon-iodine bond of the iodine compound than that of the monomer M.sub.1.
    • 包含至少一个聚合物链的聚合物通过在自由基产生源和碘化合物的存在下聚合至少一种在碳原子和构成碳 - 碘的碘原子之间具有自由基聚合性不饱和键的单体M1 碘化合物键在碳原子和碘原子之间形成至少一个聚合物链,其中聚合反应在不同于单体M1的单体M2存在下进行,并且与 通过裂解碘化合物的碳 - 碘键而产生的碳自由基比单体M1的碳自由基。
    • 5. 发明申请
    • Liquid fluoropolymer composition and process for producing crosslinked fluorochemical
    • US20070141425A1
    • 2007-06-21
    • US10580964
    • 2004-12-01
    • Takuya AraseMasayoshi Tatemoto
    • Takuya AraseMasayoshi Tatemoto
    • H01M8/10B05D5/12
    • H01M8/106C08K5/18C09D127/12H01M8/0289H01M8/1023H01M8/1039H01M8/1081H01M8/1088Y02P70/56C08L27/12
    • It is an object of the present invention to provide a liquid composition which comprises an acid/acid salt group-containing polymer and from which cured articles excellent in mechanical characteristics and undergoing only slight dimensional changes depending on the moisture content can be produced by application thereof to a substrate or impregnation of a porous material therewith. The present invention relates to a fluoropolymer liquid composition comprising a fluoropolymer liquid (A) which comprises a liquid medium and a crosslinkable functional group-containing crosslinkable fluoropolymer, wherein said fluoropolymer liquid (A) is a fluoropolymer liquid dispersion (AD) having, dispersed in a liquid dispersion medium, particles of a crosslinkable fluoropolymer (PD) containing acid/acid salt groups or organic groups capable of undergoing hydrolysis and thus being converted to carboxyl groups, or a fluoropolymer solution (AS) having, dissolved in a fluorosolvent or an alcohol/water mixed solvent, a crosslinkable fluoropolymer (PS) containing acid/acid salt groups or acid/acid salt groups precursors; said acid/acid salt groups are sulfonic acid groups, carboxyl groups or groups of the formula —SO2NR2R3, —SO3NR4R5R6R7, —SO3M11/L, —COONR8R9R10R11 or —COOM21/L, wherein R2 represents a hydrogen atom or M51/L, R3 represents an alkyl group or an sulfonyl-containing group, R4, R5, R6, R7, R8, R9, R10 and R11 are the same or different and each represents a hydrogen atom or an alkyl group, and M1, M2 and M5 each represents a metal having a valence of L, said metal having a valence of L being a metal belonging to the group 1, 2, 4, 8, 11, 12 or 13 of the periodic table; and said acid/acid salt groups precursors are —SO2F, —SO2NR22R23 (wherein R22 and R23 are the same or different and each represents an alkyl group) or organic groups capable of undergoing hydrolysis and thus being converted to carboxyl groups.