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1. 发明授权

US07989087B2 Brazing fin material for heat exchangers, heat exchanger, and method of manufacturing same 有权
标题翻译：用于热交换器的钎焊翅片材料，热交换器及其制造方法
公开(公告)号：US07989087B2
公开(公告)日：2011-08-02
申请号：US11764372
申请日：2007-06-18
申请人： Yuji Suzuki , Yuji Hisatomi , Yoshiharu Hasegawa , Taketoshi Toyama , Masahiro Shimoya
发明人： Yuji Suzuki , Yuji Hisatomi , Yoshiharu Hasegawa , Taketoshi Toyama , Masahiro Shimoya
IPC分类号： B32B15/20 , F28F21/08 , C22C21/04
CPC分类号： B23K35/0266 , B23K35/286 , Y10S165/905 , Y10S428/925 , Y10T428/12764
摘要： A brazing fin material for heat exchangers includes a core material and a filler metal clad on each side of the core material, wherein the core material is an aluminum alloy including manganese, the filler metal is an aluminum alloy including 6 to 9.5 mass % of silicon, silicon particles in the filler metal have an average circle equivalent diameter of 3 μm or less, and the brazing fin material has a thickness of 0.06 mm or less.
摘要翻译：用于热交换器的钎焊翅片材料包括在芯材的每一侧包覆的芯材和填充金属，其中芯材是包括锰的铝合金，该填充金属是含有6至9.5质量％的硅的铝合金填充金属中的硅颗粒的平均圆当量直径为3μm以下，钎焊翅片材料的厚度为0.06mm以下。

2. 发明授权

US07534309B2 Aqueous aluminum brazing composition, aluminum material coated with the brazing composition, brazing method using the aluminum material, and automotive heat exchanger manufactured by using the brazing method 有权
标题翻译：水硬铝钎焊组合物，用钎焊组合物涂覆的铝材料，使用铝材料的钎焊方法，以及使用钎焊方法制造的汽车热交换器
公开(公告)号：US07534309B2
公开(公告)日：2009-05-19
申请号：US10517291
申请日：2003-06-16
申请人： Taketoshi Toyama , Ryoichi Sanada , Takashi Hatori , Yoshiharu Hasegawa , Yuji Hisatomi , Ichiro Taninaka
发明人： Taketoshi Toyama , Ryoichi Sanada , Takashi Hatori , Yoshiharu Hasegawa , Yuji Hisatomi , Ichiro Taninaka
IPC分类号： B23K35/34 , C08L93/00 , B23K1/20 , B23K31/02
CPC分类号： F28F21/084 , B23K1/0012 , B23K35/288 , B23K35/3605 , B23K35/3612 , B23K35/3613 , B23K2101/006 , B23K2101/14 , B23K2103/10 , F28F1/126
摘要： An aqueous aluminum brazing composition containing an organic binder and a zinc-based flux which prevents the precipitation of the zinc-based flux having a large specific gravity while securing an excellent brazeability. The thixotropic index of the brazing composition is adjusted to 1.01-1.20 by adding a (meth)acrylic acid/(meth)acrylate copolymer emulsion to the brazing composition as a precipitation inhibitor in an amount of 0.03-1.50 wt % of 100 wt % of the brazing composition. Since the (meth)acrylic acid/(meth)acrylate copolymer emulsion is used as the precipitation inhibitor in a specific amount instead of other types of compounds used for a powder-containing paint, such as ultrafine particle silica, poly(meth)acrylate, or polyvinyl alcohol, the precipitation of the zinc-based flux can be prevented without impairing the brazeability.
摘要翻译：含有有机粘合剂的水性铝钎焊组合物和锌基助熔剂，其在确保优异的钎焊性的同时防止具有大比重的锌基焊剂的析出。通过向作为沉淀抑制剂的钎焊组合物中加入（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液的量为0.03〜1.50重量％的量为100重量％的（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液，将钎焊组合物的触变指数调整为1.01〜钎焊组成。由于使用（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液作为特定量的沉淀抑制剂而不是用于含粉末涂料的其它类型的化合物，例如超细颗粒二氧化硅，聚（甲基）丙烯酸酯，或聚乙烯醇，可以防止锌基焊剂的沉淀而不损害钎焊性。

3. 发明申请

US20060102691A1 Water-base aluminum-brazing composition and process of brazing 有权
标题翻译：水基铝钎焊组成及钎焊工艺
公开(公告)号：US20060102691A1
公开(公告)日：2006-05-18
申请号：US10517291
申请日：2003-06-16
申请人： Taketoshi Toyama , Ryoichi Sanada , Yoshiharu Hasegawa , Yuji Hisatomi , Ichiro Taninaka
发明人： Taketoshi Toyama , Ryoichi Sanada , Yoshiharu Hasegawa , Yuji Hisatomi , Ichiro Taninaka
IPC分类号： A47J36/02
CPC分类号： F28F21/084 , B23K1/0012 , B23K35/288 , B23K35/3605 , B23K35/3612 , B23K35/3613 , B23K2101/006 , B23K2101/14 , B23K2103/10 , F28F1/126
摘要： An aqueous aluminum brazing composition containing an organic binder and zinc-based flux which prevents precipitation of the zinc-based flux having a large specific gravity while securing excellent brazeability. The thixotropic index of the brazing composition is adjusted to 1.01-1.20 by adding (meth)acrylic acid/(meth)acrylate copolymer emulsion to the brazing composition as a precipitation inhibitor in an amount of 0.03-1.50 wt % of 100 wt % of the brazing composition. Since the (meth)acrylic acid/(meth)acrylate copolymer emulsion is used as the precipitation inhibitor in a specific amount instead of other types of compounds used for powder-containing paint such as ultrafine particle silica, poly(meth)acrylate, or polyvinyl alcohol, precipitation of the zinc-based flux can be prevented without impairing brazeability.
摘要翻译：一种含有有机粘合剂和锌基助熔剂的铝水硬铝合金组合物，其在确保优异的钎焊性的同时防止具有大比重的锌基焊剂沉淀。通过向作为沉淀抑制剂的钎焊组合物中加入（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液的量为0.03〜1.50重量％的100重量％的（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液，将钎焊组合物的触变指数调整为1.01〜钎焊组成。由于使用（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液作为特定量的沉淀抑制剂而不是其它类型的用于含粉末涂料的化合物，例如超细颗粒二氧化硅，聚（甲基）丙烯酸酯或聚酒精，可以防止锌基助熔剂的沉淀而不损害钎焊性。

4. 发明申请

US20060102328A1 Aluminum heat exchanger and manufacturing method thereof 审中-公开
标题翻译：铝热交换器及其制造方法
公开(公告)号：US20060102328A1
公开(公告)日：2006-05-18
申请号：US11280632
申请日：2005-11-16
申请人： Taketoshi Toyama , Yoshiharu Hasegawa , Naohiro Ohya , Yasunaga Itoh , Yuji Hisatomi , Hirokazu Tanaka
发明人： Taketoshi Toyama , Yoshiharu Hasegawa , Naohiro Ohya , Yasunaga Itoh , Yuji Hisatomi , Hirokazu Tanaka
IPC分类号： F28F13/18
CPC分类号： B23K1/0012 , B23K2101/14 , F28D1/0391 , F28D2021/0085 , F28F3/025 , F28F19/06 , F28F21/084 , F28F21/089
摘要： A sheet material for the tube 10 includes: a core material 10b; and a sacrifical corrosion material 10c clad on one face of the core material 10b which becomes an outside of the tube 10. A sheet material for the fin is a bare aluminum material on which a brazing filler metal is not clad. A mixture composition 10e, in which powder of a brazing filler metal and flux are mixed with each other, is coated on the outside of the tube 10. The tube 10 and the fin are brazed to each other with this mixture composition 10e. Even after the completion of brazing, the sacrifical corrosion material 10c remains on the outside of the tube 10.
摘要翻译：用于管10的片材包括：芯材料10b; 以及包围在成为管10外侧的芯材料10b的一个面上的牺牲腐蚀材料10c。用于翅片的片材是裸金属材料，钎焊金属不包覆在其上。将钎料和助熔剂的粉末彼此混合的混合物组合物10e涂覆在管10的外侧。管10和翅片用这种混合物组合物10e彼此钎焊。即使在钎焊完成之后，牺牲腐蚀材料10c保留在管10的外侧。

5. 发明授权

US07018722B2 Aluminum alloy fin material for heat exchangers and heat exchanger including the fin material 有权
标题翻译：用于热交换器的铝合金翅片材料和包括翅片材料的热交换器
公开(公告)号：US07018722B2
公开(公告)日：2006-03-28
申请号：US10601752
申请日：2003-06-23
申请人： Taketoshi Toyama , Koji Hirao , Takashi Hatori , Yuji Hisatomi , Yasunaga Itoh , Yoshifusa Shoji
发明人： Taketoshi Toyama , Koji Hirao , Takashi Hatori , Yuji Hisatomi , Yasunaga Itoh , Yoshifusa Shoji
IPC分类号： B32B15/20 , F28F21/08 , C22C21/04
CPC分类号： F28F21/084 , B23K35/286 , B32B15/016 , C22C21/00 , Y10S165/905 , Y10S428/925 , Y10T428/12764
摘要： The present invention provides an aluminum alloy fin material for heat exchangers which has a thickness of 80 μm (0.08 mm) or less and excels in joinability to a tube material and in intergranular corrosion resistance. The aluminum alloy fin material is an aluminum alloy bare fin material or a brazing fin material which has a thickness of 80 μm or less and is incorporated into a heat exchanger made of an aluminum alloy manufactured by brazing through an Al—Si alloy filler metal. The structure of the core material before brazing is a fiber structure, and the crystal grain diameter of the structure after brazing is 50–250 μm. The Si concentration in the Si dissolution area on the surface of the fin material and at the center of the thickness of the fin material after brazing is preferably 0.8% or more and 0.7% or less, respectively.
摘要翻译：本发明提供一种用于热交换器的铝合金翅片材料，其具有80μm（0.08mm）或更小的厚度，并且与管材的接合性和耐晶间腐蚀性优异。铝合金翅片材料是铝合金裸翅片材料或厚度为80μm以下的钎焊翅片材料，并且被并入由通过Al-Si合金填料金属钎焊制造的铝合金制成的热交换器中。钎焊前的芯材的结构是纤维结构，钎焊后的结构的晶粒直径为50〜250μm。翅片材料表面上的Si溶解区域中的Si浓度和钎焊后的翅片材料的厚度的中心分别优选为0.8％以上且0.7％以下。

6. 发明授权

US06403232B1 Aluminum brazing sheet 有权
标题翻译：铝钎焊板
公开(公告)号：US06403232B1
公开(公告)日：2002-06-11
申请号：US09911468
申请日：2001-07-25
申请人： Tadashi Okamoto , Osamu Takezoe , Takahiko Nagaya , Yasuaki Isobe , Taketoshi Toyama , Sunao Fukuda
发明人： Tadashi Okamoto , Osamu Takezoe , Takahiko Nagaya , Yasuaki Isobe , Taketoshi Toyama , Sunao Fukuda
IPC分类号： B32B1520
CPC分类号： C22C21/00 , B23K35/0238 , B23K35/286 , B32B15/016 , C22C21/08 , F28F21/084 , F28F21/089 , F28F2275/04 , Y10S428/933 , Y10T29/49108 , Y10T428/12764
摘要： A core material of an aluminum brazing sheet restricts Mg to less than 0.3 wt % and Fe to not more than 0.2 wt %, and contains more than 0.2 wt % and not more than 1.0 wt % of Cu, 0.3 to 1.3 wt % of Si, 0.3 to 1.5 wt % of Mn and the balance of Al and inevitable impurities. A brazing filler material is formed on one surface of the core material by Al—Si based aluminum alloy. Also, a cladding material is formed on the other surface of the core material, and contains less than 0.2 wt % of Si, 2.0 to 3.5 wt % of Mg, not less than 0.5 wt % and less than 2.0 wt % of Zn and the balance of Al and inevitable impurities. Further, the value (cladding material hardness)/(the core material hardness) that is a ratio of the hardness of the cladding material to the hardness of the core material is not more than 1.5.
摘要翻译：铝钎焊片的芯材将Mg抑制在0.3重量％以下，Fe：0.2重量％以下，含有0.2重量％以上且1.0重量％以下的Cu，0.3〜1.3重量％的Si ，Mn为0.3〜1.5重量％，余量由Al和不可避免的杂质构成。通过Al-Si基铝合金在芯材的一个表面上形成钎料。此外，在芯材的另一个表面上形成包覆材料，其含有少于0.2重量％的Si，2.0-3.5重量％的Mg，不小于0.5重量％且小于2.0重量％的Zn，平衡Al和不可避免的杂质。此外，包层材料的硬度与芯材的硬度的比值（包层材料硬度）/（芯材硬度）为1.5以下。

7. 发明授权

US06186222B1 Aluminum alloy tube and heat exchanger, and method of metal-spraying a filler alloy 失效
标题翻译：铝合金管和热交换器，以及金属喷涂填充合金的方法
公开(公告)号：US06186222B1
公开(公告)日：2001-02-13
申请号：US09116254
申请日：1998-07-16
申请人： Takeyoshi Doko , Hirokazu Yamaguchi , Osamu Kato , Taketoshi Toyama , Kouji Hirakami , Akira Uchikawa , Takaaki Sakane , Homare Koutate
发明人： Takeyoshi Doko , Hirokazu Yamaguchi , Osamu Kato , Taketoshi Toyama , Kouji Hirakami , Akira Uchikawa , Takaaki Sakane , Homare Koutate
IPC分类号： F28F1318
CPC分类号： F28F1/126 , B23K35/288 , C23C4/04 , C23C4/08 , F28F19/06 , Y10T29/49377 , Y10T428/12063
摘要： There is disclosed an aluminum alloy tube whose outer surface is covered with a filler alloy by metal-spraying, wherein the base material of the tube has an uneven rough surface with the depth of 10 &mgr;m or more, and the difference between the highest projection of the base material surface and the highest projection of the filler alloy layer covering it is 3 to 25 &mgr;m; a heat exchanger, which is assembled by using the tubes; and a method of metal-spraying, which comprises metal-spraying an aluminum alloy filler powder in a melted state, by the high-velocity flame metal-spraying process, in which the filler contains 15 to 50% Si by weight, and the powder is mainly made up of particles whose diameter is 10 &mgr;m to 70 &mgr;m. The aluminum alloy tube is excellent in brazability and corrosion resistance, and by using the tube, it is possible to assemble a heat exchanger without allowing locally filler-unbonded parts to be formed. Further, according to the method of metal-spraying, it is possible to form a excellent filler alloy layer, and obtain a tube high in brazability and corrosion resistance.
摘要翻译：公开了一种铝合金管，其外表面通过金属喷涂被填充合金覆盖，其中管的基材具有不均匀的粗糙表面，深度为10um或更大，并且最高投影之间的差异基材表面和覆盖其的填充合金层的最高突起为3〜25μm; 热交换器，其通过使用管组装; 以及一种金属喷涂方法，其中包括通过高速火焰金属喷涂工艺对熔融状态的铝合金填料粉末进行金属喷涂，其中填料含有15〜50重量％的Si，粉末主要由直径为10〜70um的颗粒组成。铝合金管的钎焊性和耐腐蚀性优异，并且通过使用管，可以组装热交换器而不允许形成局部填料 - 未结合部分。此外，根据金属喷涂的方法，可以形成优异的填充合金层，并获得高钎焊性和耐腐蚀性的管。

8. 发明授权

US06523605B2 Heat exchanger made of an aluminum alloy 有权
标题翻译：铝合金换热器
公开(公告)号：US06523605B2
公开(公告)日：2003-02-25
申请号：US09802907
申请日：2001-03-12
申请人： Takeyoshi Doko , Koji Okada , Takeshi Iguchi , Takaaki Sakane , Yoshihiro Kinoshita , Taketoshi Toyama , Akira Uchikawa , Satoshi Nohira , Homare Koutate
发明人： Takeyoshi Doko , Koji Okada , Takeshi Iguchi , Takaaki Sakane , Yoshihiro Kinoshita , Taketoshi Toyama , Akira Uchikawa , Satoshi Nohira , Homare Koutate
IPC分类号： F28F1318
CPC分类号： F28F21/084 , F28F9/0234 , Y10S165/916 , Y10T29/49393
摘要： There is disclosed a heat exchanger made of an aluminum alloy having a radiator part (10) and an oil cooler part (11) in combination and manufactured integrally by the brazing method, wherein a refrigerant tank (13) for covering and sealing the oil cooler part is made of an aluminum alloy, an aluminum alloy containing Si in an amount from more than 7.0 wt % to 12.0 wt %, Fe in an amount from more than 0.05 wt % to 0.5 wt %, Cu in an amount from more than 0.4 wt % to 8.0 wt %, Zn in an amount from more than 0.5 wt % to 10.0 wt %, and the balance of aluminum and inevitable impurities is used as a filler material of brazing sheets that are used for the oil cooler part and are brazed in the tank, and the refrigerant tank is assembled integrally with the radiator part and the oil cooler part by brazing with the brazing material. The heat exchanger made of an aluminum alloy by using an aluminum material instead of a resin tank, can be easily recycled, is excellent in corrosion resistance, and can be manufactured without requiring a step of caulking a tank.
摘要翻译：公开了一种由铝合金制成的热交换器，其具有散热器部分（10）和油冷却器部分（11），并通过钎焊方法整体制造，其中用于覆盖和密封油冷却器的制冷剂罐（13）部分由铝合金，含有大于7.0重量％至12.0重量％的Si的铝合金，大于0.05重量％至0.5重量％的Fe，大于0.4的Cu 重量％至8.0重量％，大于0.5重量％至10.0重量％的Zn，其余为铝和不可避免的杂质，用作用于油冷却器部分并钎焊的钎焊板的填料在储罐中，通过与钎焊材料钎焊，将制冷剂罐与散热器部件和油冷却器部件一体地组装。通过使用铝材代替树脂罐，由铝合金制成的热交换器可以容易地再循环，耐腐蚀性优异，并且可以制造而不需要对槽进行铆接的步骤。

9. 发明授权

US06261706B1 Aluminum alloy clad material for heat exchangers exhibiting high strength and excellent corrosion resistance 有权
标题翻译：用于热交换器的铝合金包覆材料具有高强度和优异的耐腐蚀性
公开(公告)号：US06261706B1
公开(公告)日：2001-07-17
申请号：US09413357
申请日：1999-10-06
申请人： Sunao Fukuda , Yoshihiko Kamiya , Taketoshi Toyama , Hirokazu Tanaka , Hiroshi Ikeda , Yoshifusa Shoji
发明人： Sunao Fukuda , Yoshihiko Kamiya , Taketoshi Toyama , Hirokazu Tanaka , Hiroshi Ikeda , Yoshifusa Shoji
IPC分类号： F28F2108
CPC分类号： F28F21/089 , B23K35/28 , B32B15/016 , C22C21/00 , F28F21/084 , Y10S165/905 , Y10S428/933 , Y10T428/12764
摘要： An aluminum alloy clad material for heat exchangers exhibiting superior strength after brazing and excellent corrosion resistance is provided. The aluminum alloy clad material comprises a sacrificial anode material which is clad on one side of a core material, wherein the core material comprises an aluminum alloy comprising 0.3-2.0% of Mn, 0.25-1.0% of Cu, 0.3-1.1% of Si, and 0.05-0.35% of Ti with the remaining portion consisting of aluminum and impurities, the sacrificial anode material comprises an aluminum alloy comprising 1.5-8% of Zn, 0.01-0.8% of Si, and 0.01-0.3% of Fe with the remaining portion consisting of aluminum and impurities, and the total number of particles of Si compounds and Fe compounds with a particle diameter (circle equivalent diameter) of 1 &mgr;m or more present in the sacrificial anode material matrix is 2×104 or less per 1 mm2. The clad material is suitably used as a tube material or header plate material for automotive heat exchangers such as a radiator or heater core.
摘要翻译：提供一种用于热交换器的铝合金包覆材料，其在钎焊之后表现出优异的强度和优异的耐腐蚀性。铝合金覆层材料包括牺牲阳极材料，该牺牲阳极材料包覆在芯材的一侧，其中芯材包括铝合金，其包含0.3-2.0％的Mn，0.25-1.0％的Cu，0.3-1.1％的Si ，和0.05-0.35％的Ti，其余部分由铝和杂质组成，牺牲阳极材料包括铝合金，其包含1.5-8％的Zn，0.01-0.8％的Si和0.01-0.3％的Fe，其中由铝和杂质组成的剩余部分，牺牲阳极材料基体中存在的Si化合物和粒子直径（圆当量直径）为1um以上的Fe化合物的总数为1×2mm以下。包层材料适合用作汽车热交换器如散热器或加热器芯的管材或集管板材料。

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