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    • 5. 发明申请
    • THIN FILM SOLID STATE LITHIUM ION SECONDARY BATTERY AND METHOD OF MANUFACTURING THE SAME
    • 薄膜固体锂离子二次电池及其制造方法
    • US20110281167A1
    • 2011-11-17
    • US13146138
    • 2010-01-28
    • Yuichi SabiKoichiro HinokumaKatsunori TakaharaHiroyuki MoriokaTatsuya Furuya
    • Yuichi SabiKoichiro HinokumaKatsunori TakaharaHiroyuki MoriokaTatsuya Furuya
    • H01M10/052H01M10/058H01M4/131
    • H01M2/0212H01M4/131H01M4/134H01M4/136H01M4/1391H01M4/1397H01M4/382H01M4/667H01M6/40H01M10/0525H01M10/0562H01M10/0585H01M2004/027
    • A high-performance and inexpensive thin film solid state lithium ion secondary battery that is able to be charged and discharged in the air and is able to be manufactured stably at a favorable yield, and a method of manufacturing the same are provided. The thin film solid state lithium ion secondary battery has an electric insulating substrate 10 formed from an organic resin, an inorganic insulating film provided on the substrate face, a cathode-side current collector film 30, a cathode active material film 40, a solid electrolyte film 50, an anode-side current collector protective film 68, and an anode-side current collector film 70. In the thin film solid state lithium ion secondary battery, the cathode-side current collector film and/or the anode-side current collector film is formed on the inorganic insulating film face. The anode-side current collector protective film is formed from a conductive oxide including at least any one of an oxide of Sn, In, and Zn, and holds the total amount of lithium associated with charge and discharge roughly constant. The thickness of the anode-side current collector protective film is 2 nm or more and 22 nm or less. The thickness of the inorganic insulating film is 5 nm or more and 500 nm or less. The inorganic insulating film contains at least any one of an oxide, a nitride, and a sulfide containing one of Si, Al, Cr, Zr, Ta, Ti, Mn, Mg, and Zn.
    • 提供能够在空气中充放电并且能够以良好的收率稳定地制造的高性能且廉价的薄膜固态锂离子二次电池及其制造方法。 薄膜固态锂离子二次电池具有由有机树脂形成的电绝缘基板10,设置在基板面上的无机绝缘膜,阴极侧集电体膜30,正极活性物质膜40,固体电解质 膜50,阳极侧集电体保护膜68和阳极侧集电体膜70.在薄膜固体锂离子二次电池中,阴极侧集电体膜和/或阳极侧集电体 在无机绝缘膜面上形成膜。 阳极侧集电体保护膜由包含Sn,In和Zn的氧化物中的至少任一种的导电氧化物形成,并且与充放电相关的总量保持大致恒定。 阳极侧集电体保护膜的厚度为2nm以上且22nm以下。 无机绝缘膜的厚度为5nm以上且500nm以下。 无机绝缘膜含有包含Si,Al,Cr,Zr,Ta,Ti,Mn,Mg和Zn中的一种的氧化物,氮化物和硫化物中的至少一种。