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1. 发明授权

US5283286A Impact-resistant thermoplastic resin composition containing a grafted butadiene rubber 失效
标题翻译：含有接枝丁二烯橡胶的耐冲击热塑性树脂组合物
公开(公告)号：US5283286A
公开(公告)日：1994-02-01
申请号：US879999
申请日：1992-05-08
申请人： Yosuke Takahashi , Yasumasa Komatsu , Hiroshi Hagiwara , Takayuki Katto
发明人： Yosuke Takahashi , Yasumasa Komatsu , Hiroshi Hagiwara , Takayuki Katto
IPC分类号： C08F279/02 , C08L21/00 , C08L25/16 , C08L33/04 , C08L33/12 , C08L33/18 , C08L33/20 , C08L51/00 , C08L51/04 , C08L35/06
CPC分类号： C08L25/16 , C08L33/12 , C08L51/04
摘要： A thermoplastic resin composition is prepared by blending 50-95 wt. % of a copolymer (A) of 10-75 wt. % of .alpha.-methyl styrene, 10-60 wt. % of methyl methacrylate, 5-35 wt. % of acrylonitrile and 0-20 wt. % of a monomer copolymerizable therewith; and 5-50 wt. % of a graft copolymer (B) comprising 50-85 wt. parts of a butadiene-based rubber polymer and 15-50 wt. parts of a vinyl monomer graft-polymerized onto the rubber polymer. The butadiene-based rubber polymer includes 50-98 wt. % of butadiene, 2-50 wt. % of an aromatic polycyclic vinyl monomer represented by a formula (I) below and 0-20 wt. % of a monomer copolymerizable therewith: ##STR1## wherein R denotes an optionally substituted biphenylyl or naphthyl group, and R.sub.1 denotes a hydrogen atom or a methyl group. The thermoplastic resin composition is provided with a good balance among heat-resistance, impact resistance, transparency and processability because the graft copolymer (B) using an aromatic polycyclic vinyl monomer shows a good impact resistance-modifying effect while retaining a relatively high refractive index and the copolymer (A) shows a good heat resistance and a relatively low refractive index.
摘要翻译：热塑性树脂组合物通过混合50-95wt。％的共聚物（A）为10-75wt。％的（α） - 甲基苯乙烯，10-60wt。％的甲基丙烯酸甲酯，5-35wt。丙烯腈的百分比和0-20重量％可与其共聚的单体的％。和5-50wt。％的接枝共聚物（B）包含50-85wt。部分丁二烯类橡胶聚合物和15-50wt。部分接枝聚合到橡胶聚合物上的乙烯基单体。丁二烯类橡胶聚合物包含50-98wt。丁二烯的％，2-50wt。％的由下式（I）表示的芳族多环乙烯基单体和0-20重量％可与其共聚的单体的％：（*化学结构*）（I）其中R表示任选取代的联苯基或萘基，R 1表示氢原子或甲基。由于使用芳族多环乙烯基单体的接枝共聚物（B）在保持相对高的折射率的同时表现出良好的耐冲击性改性效果，所以热塑性树脂组合物在耐热性，耐冲击性，透明性和加工性方面具有良好的平衡，共聚物（A）显示良好的耐热性和较低的折射率。

2. 发明授权

US4701495A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US4701495A
公开(公告)日：1987-10-20
申请号：US834122
申请日：1986-02-26
申请人： Takayuki Katto , Yasumasa Komatsu , Zenya Shiiki
发明人： Takayuki Katto , Yasumasa Komatsu , Zenya Shiiki
IPC分类号： C08L51/00 , C08L7/00 , C08L21/00 , C08L25/00 , C08L25/02 , C08L25/16 , C08L25/18 , C08L33/00 , C08L33/02 , C08L33/04 , C08L33/20 , C08L51/02 , C08L51/04 , C08L51/06 , C08L55/00 , C08L55/02
CPC分类号： C08L25/16 , C08L25/02 , C08L55/02
摘要： A thermoplastic resin composition of high heat resistance and high impact resistance is described, comprising: (A) 50 to 90% by weight of a copolymer prepared by copolymerization of 10 to 35% by weight of acrylonitrile, 60 to 85% by weight of a monomer mixture of 2-isopropenylnaphthalene (2-IPN) and .alpha.-methylstyrene (.alpha.-MeSt), the proportion of 2-IPN being 5 to 70% by weight based on the total weight of 2-IPN and .alpha.-MeSt, and 0 to less than 10% by weight of a vinyl monomer copolymerizable with the foregoing monomers; and (B) 10 to 50% by weight of a graft copolymer prepared by polymerizing 15 to 50 parts by weight of at least one monomer selected from the group consisting of aromatic vinyl compounds, vinyl cyanides, methacrylic acid alkyl esters, and acrylic acid alkyl esters in the presence of 50 to 85 parts by weight of a butadiene- or alkyl acrylate-based rubber, the sum of the graft and rubber components being 100 parts by weight.
摘要翻译：描述了具有高耐热性和高耐冲击性的热塑性树脂组合物，其包含：（A）通过共聚合10至35重量％的丙烯腈，60至85重量％的丙烯腈制备的共聚物，50至90重量％ 2-异丙烯基萘（2-IPN）和α-甲基苯乙烯（α-MeSt）的单体混合物，2-IPN的比例为5至70重量％，基于2-IPN和α-MeSt的总重量，0 至少于10重量％的可与上述单体共聚的乙烯基单体; 和（B）10至50重量％的通过聚合15至50重量份的至少一种选自芳族乙烯基化合物，乙烯基氰化物，甲基丙烯酸烷基酯和丙烯酸烷基酯的单体制备的接枝共聚物在50至85重量份的基于丙烯酸丁酯或丙烯酸酯的橡胶存在下，所述接枝和橡胶组分的总和为100重量份。

3. 发明授权

US4732935A Thermoplastic resin composition 失效
公开(公告)号：US4732935A
公开(公告)日：1988-03-22
申请号：US901644
申请日：1986-08-29
申请人： Takayuki Katto , Yasumasa Komatsu , Zenya Shiiki
发明人： Takayuki Katto , Yasumasa Komatsu , Zenya Shiiki
IPC分类号： C08F12/00 , C08F212/32 , C08L7/00 , C08L21/00 , C08L25/00 , C08L25/02 , C08L25/16 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L69/00 , C08L51/06
CPC分类号： C08L69/00 , C08L25/02 , C08L25/16 , C08L51/04
摘要： A thermoplastic resin composition of high heat resistance and high impact resistance in described, comprising: (A) 5 to 85% by weight of a copolymer prepared from 40 to 85% by weight of a monomer mixture of 2-isopropenylnaphthalene (2-IPN) and .alpha.-methylstyrene (.alpha.-MeSt), the proportion of 2-IPN being 5 to 70% by weight based on the total weight of 2-IPN and .alpha.-MeSt, 7.5 to 35% by weight of acrylonitrile, and 0 to 40% by weight of a vinyl monomer copolymerizable with the foregoing monomers; (B) 1 to 40% by weight of a graft copolymer prepared by graft polymerization of 15 to 50 parts by weight of at least one monomer as the graft component selected from the group consisting of methacrylic acid alkyl esters, acrylic acid alkyl esters, aromatic vinyl compounds, and vinyl cyan compounds onto 50 to 85 parts by weight of a butadiene-based rubber or alkyl acrylate-based rubber as the rubber component, provided that the sum of the graft and rubber components is 100 parts by weight; and (C) 10 to 90% by weight of a polycarbonate.

4. 发明授权

US4447578A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US4447578A
公开(公告)日：1984-05-08
申请号：US451325
申请日：1982-12-20
申请人： Takayuki Katto , Yasumasa Komatsu , Zenya Shiiki
发明人： Takayuki Katto , Yasumasa Komatsu , Zenya Shiiki
IPC分类号： C08L33/00 , C08L7/00 , C08L21/00 , C08L25/00 , C08L25/02 , C08L33/02 , C08L33/04 , C08L33/12 , C08L51/00 , C08L51/02 , C08L51/04
CPC分类号： C08L25/02 , C08L51/04
摘要： A thermoplastic resin composition having high heat resistance coupled with high impact resistance is obtained by combining a predominant amount of (A) a copolymer of methyl methacrylate, acrylonitrile, 2-isopropenylnaphthalene and .alpha.-methylstyrene, and (B) a graft copolymer of methyl methacrylate, optionally with styrene and acrylonitrile, on a butadiene rubber.
摘要翻译：通过组合主要量的（A）甲基丙烯酸甲酯，丙烯腈，2-异丙烯基萘和α-甲基苯乙烯的共聚物和（B）甲基丙烯酸甲酯的接枝共聚物，得到具有高耐热性和高耐冲击性的热塑性树脂组合物，任选地含有苯乙烯和丙烯腈，在丁二烯橡胶上。

5. 发明授权

US4748205A Thermoplastic resin composition 失效
公开(公告)号：US4748205A
公开(公告)日：1988-05-31
申请号：US62694
申请日：1987-06-16
申请人： Takayuki Katto , Yasumasa Komatsu , Zenya Shiiki
发明人： Takayuki Katto , Yasumasa Komatsu , Zenya Shiiki
IPC分类号： C08L51/00 , C08L7/00 , C08L21/00 , C08L25/00 , C08L25/02 , C08L25/16 , C08L25/18 , C08L33/00 , C08L33/02 , C08L33/04 , C08L33/20 , C08L51/02 , C08L51/04 , C08L51/06 , C08L55/00 , C08L55/02
CPC分类号： C08L25/16 , C08L25/02 , C08L55/02
摘要： A thermoplastic resin composition of high heat resistance and high impact resistance is described, comprising: (A) 50 to 90% by weight of a copolymer prepared by copolymerization of 10 to 35% by weight of acrylonitrile, 60 to 85% by weight of a monomer mixture of 2-isopropenylnaphthalene (2-IPN) and .alpha.-methylstyrene (.alpha.-MeSt), the proportion of 2-IPN being 5 to 70% by weight based on the total weight of 2-IPN and .alpha.-MeSt, and 0 to less than 10% by weight of a vinyl monomer copolymerizable with the foregoing monomers; and (B) 10 to 50% by weight of a graft copolymer prepared by polymerizing 15 to 50 parts by weight of at least one monomer selected from the group consisting of aromatic vinyl compounds, vinyl cyanides, methacrylic acid alkyl esters, and acrylic acid alkyl esters in the presence of 50 to 85 parts by weight of a butadiene- or alkyl acrylate-based rubber, the sum of the graft and rubber components being 100 parts by weight.

6. 发明授权

US4636553A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US4636553A
公开(公告)日：1987-01-13
申请号：US618662
申请日：1984-06-08
申请人： Takayuki Katto , Yasumasa Komatsu , Zenya Shiiki
发明人： Takayuki Katto , Yasumasa Komatsu , Zenya Shiiki
IPC分类号： C08F12/00 , C08F212/32 , C08L7/00 , C08L21/00 , C08L25/00 , C08L25/02 , C08L25/16 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L69/00 , C08L51/06 , C08L55/02
CPC分类号： C08L69/00 , C08L25/02 , C08L25/16 , C08L51/04
摘要： A thermoplastic resin composition of high heat resistance and high impact resistance is described, comprising: (A) 5 to 85% by weight of a copolymer prepared from 40 to 85% by weight of a monomer mixture of 2-isopropenylnaphthalene (2-IPN) and .alpha.-methylstyrene (.alpha.-MeSt), the proportion of 2-IPN being 5 to 70% by weight based on the total weight of 2-IPN and .alpha.-MeSt, 7.5 to 35% by weight of acrylonitrile, and 0 to 40% by weight of a vinyl monomer copolymerizable with the foregoing monomers; (B) 1 to 40% by weight of a graft copolymer prepared by graft polymerization of 15 to 50 parts by weight of at least one monomer as the graft component selected from the group consisting of methacrylic acid alkyl esters, acrylic acid alkyl esters, aromatic vinyl compounds, and vinyl cyan compounds onto 50 to 85 parts by weight of a butadiene-based rubber or alkyl acrylate-based rubber as the rubber component, provided that the sum of the graft and rubber components is 100 parts by weight; and (C) 10 to 90% by weight of a polycarbonate.
摘要翻译：描述了一种具有高耐热性和高耐冲击性的热塑性树脂组合物，其包含：（A）5-85重量％的由40至85重量％的2-异丙烯基萘（2-IPN）单体混合物制备的共聚物，和α-甲基苯乙烯（α-MeSt），2-IPN的比例为5至70重量％，基于2-IPN和α-MeSt的总重量，7.5至35重量％的丙烯腈和0至40 可与上述单体共聚的乙烯基单体的重量％（B）1〜40重量％的接枝共聚物，其通过接枝聚合15〜50重量份的至少一种单体作为接枝成分，所述接枝成分选自甲基丙烯酸烷基酯，丙烯酸烷基酯，芳香族乙烯基化合物和乙烯基青色化合物作为橡胶组分的50至85重量份的丁二烯基橡胶或丙烯酸烷基酯橡胶，条件是接枝橡胶组分的总和为100重量份; 和（C）10〜90重量％的聚碳酸酯。

7. 发明授权

US4390382A Tone arm manufacturing method 失效
标题翻译：音臂制作方法
公开(公告)号：US4390382A
公开(公告)日：1983-06-28
申请号：US281509
申请日：1981-07-08
申请人： Shunsuke Matsuda , Yasumasa Komatsu
发明人： Shunsuke Matsuda , Yasumasa Komatsu
IPC分类号： B21C37/06 , B32B5/16 , G11B3/10 , G11B3/31 , B65H81/00 , G01B3/10
CPC分类号： B32B5/16 , G11B3/31 , Y10T428/1372 , Y10T428/30
摘要： Method of manufacturing a tone arm by superposing a sheet of graphite flakes bound with resin, on a carbon fiber prepreg, winding the resultant double layer product around a core, heat-hardening the resultant assembly, and removing the core to form a pipe-shaped tone arm.
摘要翻译：通过将与树脂结合的石墨薄片叠层在碳纤维预浸料上，将所得双层产品卷绕在芯周围，对所得组件进行加热硬化，并除去芯以形成管状的方式制造色调臂的方法音臂。

8. 发明授权

US4578526A Solar module 失效
标题翻译：太阳能组件
公开(公告)号：US4578526A
公开(公告)日：1986-03-25
申请号：US636245
申请日：1984-07-31
申请人： Akihiko Nakano , Hitoshi Matsumoto , Hiroshi Uda , Yasumasa Komatsu , Kiyoshi Kuribayashi , Seiji Ikegami
发明人： Akihiko Nakano , Hitoshi Matsumoto , Hiroshi Uda , Yasumasa Komatsu , Kiyoshi Kuribayashi , Seiji Ikegami
IPC分类号： H01L31/042 , H01L31/048 , H01L27/14
CPC分类号： B32B17/10761 , B32B17/10018 , B32B17/10788 , H01L31/0445 , H01L31/048 , H01L31/073 , Y02E10/543
摘要： A reliable and inexpensive solar module is disclosed. The solar module comprises a thin-film type photovoltaic cell array formed on a glass superstrate, leaving a margin of an appropriate width along the periphery of the glass superstrate, and a resin layer coated on the photovoltaic cell array and the peripheral margin of the glass superstrate. The solar module further comprises a backcover adhered by the resin layer to cover the photovoltaic cell array and the peripheral margin of the glass superstrate. The resin layer is preferably made of a fluoropolymer derived from a compound containing a perfluoroalkylene and active hydrogen atoms.
摘要翻译：公开了可靠且廉价的太阳能模块。太阳能组件包括形成在玻璃顶板上的薄膜型光伏电池阵列，沿着玻璃顶板的周边留下适当宽度的边缘，以及涂覆在光伏电池阵列上的树脂层和玻璃的周边边缘上层太阳能模块还包括由树脂层粘附以覆盖光伏电池阵列和玻璃盖的周边边缘的后盖。树脂层优选由含有全氟亚烷基和活性氢原子的化合物衍生的含氟聚合物制成。

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