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    • 2. 发明授权
    • Cross-linked optical siloxane polymer
    • 交联光硅氧烷聚合物
    • US4780510A
    • 1988-10-25
    • US860178
    • 1986-05-06
    • Takafumi UemiyaYoshitaka OsawaShin-ichiro NiwaAkira NishimuraYutaka Shibata
    • Takafumi UemiyaYoshitaka OsawaShin-ichiro NiwaAkira NishimuraYutaka Shibata
    • C08G77/38C08G77/50C08L83/04C08L83/05G02B1/04C08F130/08C08F283/12
    • G02B1/04C08G77/38C08G77/50C08L83/04C08G77/20C08G77/24C08G77/70
    • A cross-linked optical siloxane polymer having a group for modifying a refractive index of the polymer which is introduced in a side chain of the polymer by a hydrosilyl reaction of one of the following systems:(1) a compound (A) having a carbon-carbon unsaturated bond and a group for modifying a refractive index, and a siloxane polymer (B) having a silicon hydride group wherein the molar ratio of the silicon hydride group to the carbon-carbon unsaturated bond is more than 1, and(2) a compound (A') having a silicon hydride group and a group for modifying a refractive index, and a siloxane polymer (B') having a carbon-carbon unsaturated bond wherein the molar ratio of the carbon-carbon unsaturated bond to the silicon hydride group is more than 1,the polymer being cross-linked by a hydrosilyl reaction of the unreacted silicon hydride groups of the silixane polymer (B) with a compound (C) having at least two carbon-carbon unsaturated bonds when the system (1) is used, or by a hydrosilyl reaction of the unreacted carbon-carbon unsaturated bonds of the siloxane polymer (B') with a compound (C') having at least two silicon hydride groups when the system (2) is used, the refractive index of which is easily and precisely modified.
    • 一种交联光学硅氧烷聚合物,其具有用于通过以下系统之一的氢化硅烷基反应引入聚合物的侧链中的聚合物的折射率的基团:(1)具有碳的化合物(A) - 碳不饱和键和用于改性折射率的基团,以及具有硅氢化物基团的硅氧烷聚合物(B),其中硅氢化物基团与碳 - 碳不饱和键的摩尔比大于1,和(2) 具有氢化硅基的化合物(A')和用于改性折射率的基团和具有碳 - 碳不饱和键的硅氧烷聚合物(B'),其中碳 - 碳不饱和键与氢化硅的摩尔比 当系统(1)为1时,聚合物通过硅烷聚合物(B)的未反应的硅氢化物基团与具有至少两个碳 - 碳不饱和键的化合物(C)的氢化硅烷基反应而交联, 被使用,或由水溶液 当使用系统(2)时,硅氧烷聚合物(B')的未反应的碳 - 碳不饱和键与具有至少两个氢化硅基团的化合物(C')的反应,其折射率容易且精确 改性。