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    • 4. 发明申请
    • Antistatic molded article and antistatic coating
    • 防静电成型品和抗静电涂层
    • US20050230666A1
    • 2005-10-20
    • US10521462
    • 2003-06-27
    • Toshiharu OtsukaMasahisa SonkuMasayuki Mizukami
    • Toshiharu OtsukaMasahisa SonkuMasayuki Mizukami
    • B05D5/12B05D7/02C09D5/24H01B1/00
    • C09D5/24C08K3/22C08L2201/04C09D7/61C09D7/67C09D7/68
    • An antistatic molded article obtained only by coating a substrate with an antistatic paint, which antistatic molded article has smooth surface, does not deteriorate the transparency and coloration of substrate and excels in antistatic properties. In particular, an antistatic molded article comprising a substrate of complex configuration such as three-dimensional configuration having irregularity and, superimposed thereon, an antistatic layer. There is also provided an antistatic paint whose application is easy, which antistatic paint does not need any after treatment and excels in transparency, surface smoothness and antistatic properties. More specifically, there are provided an antistatic molded article comprising a substrate and, superimposed on a surface thereof, an antistatic layer from an antistatic paint containing a conductive metal oxide, which antistatic molded article exhibits a surface resistivity of 1×104 to 1×109 Ω/□ and a surface roughness (Ra) of 5 to 50 nm; and an antistatic paint for use therein.
    • 通过使抗静电成型体具有光滑表面的抗静电涂料对基材进行涂布而得到的抗静电成型体不会降低基材的透明性和着色性,抗静电性优异。 特别是一种抗静电成型体,其特征在于,具有复合构造的基板,例如具有不规则性的三维结构,并且叠加在其上的抗静电层。 还提供了一种抗静电涂料,其应用容易,抗静电涂料不需要任何后处理,并且透明度,表面光滑度和抗静电性能优异。 更具体地,提供了一种抗静电成型制品,其包括基材,并且在其表面上叠加来自含有导电金属氧化物的抗静电涂料的抗静电层,该抗静电模塑制品的表面电阻率为1×10 4 / SUP至1×10 9Ω/□,表面粗糙度(Ra)为5〜50nm; 和用于其中的抗静电涂料。
    • 7. 发明授权
    • Solid oxide fuel cell system
    • 固体氧化物燃料电池系统
    • US09385386B2
    • 2016-07-05
    • US13876934
    • 2011-09-28
    • Toshiharu OtsukaKatsuhisa TsuchiyaTsukasa ShigezumiToshiharu OoeKiyotaka NakanoTakuya Matsuo
    • Toshiharu OtsukaKatsuhisa TsuchiyaTsukasa ShigezumiToshiharu OoeKiyotaka NakanoTakuya Matsuo
    • H01M8/06H01M8/04H01M8/12
    • H01M8/0606H01M8/04022H01M8/04268H01M8/04373H01M8/04776H01M8/0618H01M2008/1293Y02E60/50Y02E60/525
    • A solid oxide fuel cell system is disclosed. The solid oxide fuel cell system includes a cell stack having multiple adjacent fuel cells; a reformer that reforms raw gas and produces fuel gas supplied to the fuel cells; a combustion section that causes combustion of the fuel gas discharged from the fuel cells and heats the reformer with combustion heat of the fuel gas; an ignition device that ignites the combustion section; a combustion state confirmation device that senses that heating of the entire reformer has started using the advancement of flame transfer between fuel cells in the combustion section; and a controller programmed to start an operation of the system heating the reformer by using combustion heat from the combustion section and reaction heat from the partial oxidation reforming reaction (POX) in the reformer. During the period until the combustion state confirmation device senses that the heating of the entire reformer has started after the ignition device ignited the combustion section, the controller suppresses the amount of heat emitted by the partial oxidation reforming reaction in the reformer more than the amount of heat emitted after heating of the entire reformer has started.
    • 公开了一种固体氧化物燃料电池系统。 固体氧化物燃料电池系统包括具有多个相邻燃料电池的电池堆; 改革原燃料和生产向燃料电池供应的燃料气体的改革者; 燃烧部,其使从燃料电池排出的燃料气体燃烧,并利用燃料气体的燃烧热加热重整器; 点燃燃烧部分的点火装置; 检测整个重整器的加热开始使用燃烧部中的燃料电池之间的火焰传递的燃烧状态确认装置; 以及控制器,被编程为开始通过使用来自燃烧部分的燃烧热量和重整器中部分氧化重整反应(POX)的反应热来加热重整器的系统的操作。 在燃烧状态确认装置感测到在点火装置点燃燃烧部分之后开始整个重整器的加热的时间段期间,控制器抑制重整器中的部分氧化重整反应发出的热量大于 加热整个重整器后发出的热量已经开始。
    • 9. 发明申请
    • SOLID OXIDE FUEL CELL SYSTEM
    • 固体氧化物燃料电池系统
    • US20130216926A1
    • 2013-08-22
    • US13876934
    • 2011-09-28
    • Toshiharu OtsukaKatsuhisa TsuchiyaTsukasa ShigezumiToshiharu OoeKiyotaka NakanoTakuya Matsuo
    • Toshiharu OtsukaKatsuhisa TsuchiyaTsukasa ShigezumiToshiharu OoeKiyotaka NakanoTakuya Matsuo
    • H01M8/06
    • H01M8/0606H01M8/04022H01M8/04268H01M8/04373H01M8/04776H01M8/0618H01M2008/1293Y02E60/50Y02E60/525
    • A solid oxide fuel cell system is disclosed. The solid oxide fuel cell system includes a cell stack having multiple adjacent fuel cells; a reformer that reforms raw gas and produces fuel gas supplied to the fuel cells; a combustion section that causes combustion of the fuel gas discharged from the fuel cells and heats the reformer with combustion heat of the fuel gas; an ignition device that ignites the combustion section; a combustion state confirmation device that senses that heating of the entire reformer has started using the advancement of flame transfer between fuel cells in the combustion section; and a controller programmed to start an operation of the system heating the reformer by using combustion heat from the combustion section and reaction heat from the partial oxidation reforming reaction (POX) in the reformer. During the period until the combustion state confirmation device senses that the heating of the entire reformer has started after the ignition device ignited the combustion section, the controller suppresses the amount of heat emitted by the partial oxidation reforming reaction in the reformer more than the amount of heat emitted after heating of the entire reformer has started.
    • 公开了一种固体氧化物燃料电池系统。 固体氧化物燃料电池系统包括具有多个相邻燃料电池的电池堆; 改革原燃料和生产向燃料电池供应的燃料气体的改革者; 燃烧部,其使从燃料电池排出的燃料气体燃烧,并利用燃料气体的燃烧热加热重整器; 点燃燃烧部分的点火装置; 检测整个重整器的加热开始使用燃烧部中的燃料电池之间的火焰传递的燃烧状态确认装置; 以及控制器,被编程为开始通过使用来自燃烧部分的燃烧热量和重整器中部分氧化重整反应(POX)的反应热来加热重整器的系统的操作。 在燃烧状态确认装置感测到在点火装置点燃燃烧部分之后开始整个重整器的加热的时间段期间,控制器抑制重整器中的部分氧化重整反应发出的热量大于 加热整个重整器后发出的热量已经开始。
    • 10. 发明授权
    • Solid oxide fuel cell device
    • 固体氧化物燃料电池装置
    • US08497044B2
    • 2013-07-30
    • US12788923
    • 2010-05-27
    • Katsuhisa TsuchiyaToshiharu OtsukaTsukasa ShigezumiToshiharu OoeKiyotaka NakanoYoshiyuki Kawamura
    • Katsuhisa TsuchiyaToshiharu OtsukaTsukasa ShigezumiToshiharu OoeKiyotaka NakanoYoshiyuki Kawamura
    • H01M8/04H01M8/06
    • H01M8/0612H01M8/0271H01M8/04223H01M8/04225H01M8/04753H01M8/2428H01M8/243H01M8/2484H01M2008/1293
    • To provide a solid oxide fuel cell device capable of stably increasing the temperature of a fuel cell units and smoothly starting electrical generation. The present invention is a solid oxide fuel cell device (1), having a fuel cell module (2); a reformer (20); a fuel supply means (38); a reforming oxidant gas supply means (44); a water supply means (28); a generating oxidant gas supply means (45); and a control section (110) for causing reforming reactions to occur in the reformer at the temperature at which electricity can be generated, prior to the start of electrical generation, in the sequence: POX, in which only the partial oxidation reaction occurs, ATR, in which the partial oxidation reaction and the steam reforming reactions occur, and SR, in which only steam reforming reaction occurs; whereby the control section controls the fuel supply means so that the rate of change in the fuel supply flow rate versus time at the time of transition from the ATR to the SR is the smallest of the rates of change when the fuel supply flow rate is changed at the temperature at which electricity can be generated.
    • 提供能够稳定地提高燃料电池单元的温度并平稳地开始发电的固体氧化物型燃料电池装置。 本发明是一种具有燃料电池模块(2)的固体氧化物燃料电池装置(1)。 改革者(20); 燃料供给装置(38); 重整氧化剂气体供给装置(44); 供水装置(28); 产生氧化剂气体供给装置(45); 以及控制部(110),其在仅在发生部分氧化反应的POX(其中仅发生部分氧化反应)的情况下,在发电开始之前,在重整器中发生重整反应的重整反应 ,其中发生部分氧化反应和蒸汽重整反应,以及仅发生蒸汽重整反应的SR; 由此控制部分控制燃料供给装置,使得当燃料供给流量变化时,从ATR到SR的转变时的燃料供给流量与时间的变化率是最小的变化率 在能够产生电力的温度下。