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    • 5. 发明申请
    • REMOVABLE ADHESIVE COMPOSITION, REMOVABLE ADHESIVE LAYER, ADHESIVE SHEET, AND SURFACE PROTECTIVE MATERIAL
    • 可拆卸胶粘组合物,可拆卸粘合剂层,粘合片和表面保护材料
    • US20090022925A1
    • 2009-01-22
    • US11816900
    • 2006-02-06
    • Takeshi YamanakaKooki Ooyama
    • Takeshi YamanakaKooki Ooyama
    • B32B33/00C08L33/02
    • C09J133/04B32B7/12C08K5/0025C08K5/521C08L71/00C08L2666/22C09J4/06C09J7/385Y10T428/1452Y10T428/2891
    • Provided is a re-peeling pressure-sensitive adhesive composition for a surface protecting material for an adherend having a photocatalytic layer, comprising: a (meth)acryl-based polymer including, as monomer units, 50 to 99.9% by weight of (A) at least one acrylate-based monomer represented by the general formula (1): CH2═CR1COOR2 wherein R1 represents a hydrogen atom or a methyl group, and R2 represents an alkyl group having 2 to 14 carbon atoms, 0.1 to 10% by weight of (B) a functional-group-containing vinyl-based monomer, and 0 to 49.9% by weight of (C) a vinyl-based monomer copolymerizable with the component (A) and/or the component (B); and (D) a surfactant having a molecular weight of 150 to 5000, the amount of the component (D) being from 0.01 to 30 parts by weight with respect to 100 parts by weight of the (meth)acryl-based polymer. The re-peeling pressure-sensitive adhesive composition is excellent in re-peeling property, contact-angle-recoverability, and weather resistance.
    • 本发明提供一种用于具有光催化层的被粘物的表面保护材料的再剥离用压敏粘合剂组合物,其包含:(甲基)丙烯酸类聚合物,其包含作为单体单元的(A)50-99.9重量% 至少一种由通式(1)表示的丙烯酸酯类单体:CH2-CR1COOR2,其中R1表示氢原子或甲基,R2表示碳原子数2〜14的烷基,0.1〜10重量% (B)含官能团的乙烯基类单体和0〜49.9重量%的(C)可与组分(A)和/或组分(B)共聚的乙烯基类单体; 和(D)分子量为150〜5000的表面活性剂,相对于(甲基)丙烯酸系聚合物100重量份,成分(D)的含量为0.01〜30重量份。 再剥离压敏粘合剂组合物的再剥离性,接触角恢复性和耐候性优异。
    • 6. 发明申请
    • LAMINATED FILM AND PRESSURE-SENSITIVE ADHESIVE TAPE
    • US20110033662A1
    • 2011-02-10
    • US12836347
    • 2010-07-14
    • Shinsuke IKISHIMANaoto HayashiKooki OoyamaKeiji HayashiShou UchidaKouhei TakedaIkkou Hanaki
    • Shinsuke IKISHIMANaoto HayashiKooki OoyamaKeiji HayashiShou UchidaKouhei TakedaIkkou Hanaki
    • B32B3/10
    • B32B27/32B32B25/042B32B25/08B32B27/08B32B27/20B32B27/304B32B27/306B32B27/308B32B27/36B32B27/365B32B27/40B32B2250/24B32B2270/00B32B2274/00B32B2307/40B32B2307/412B32B2307/538B32B2307/748B32B2405/00C09J7/29C09J2201/162C09J2423/006Y10T428/24355
    • Provided are a laminated film and a pressure-sensitive adhesive tape each of which is adjusted so as to be capable of achieving compatibility between low haze property excellent in transparency and such large surface roughness that foreign matter such as a fish eye is hardly observed without fluctuations in mechanical properties of the entire laminated film or pressure-sensitive adhesive tape. Also provided is such a pressure-sensitive adhesive tape as described below capable of protecting the uneven surface of a member having unevenness on its surface. The pressure-sensitive adhesive tape brings together sufficient pressure-sensitive adhesiveness for, and sufficient releasability from, the member. In addition, even upon deformation of the member protected with the pressure-sensitive adhesive tape by, for example, lamination or continuous winding, the uneven shape does not deform and a base material layer in the pressure-sensitive adhesive tape is not damaged, and further, the pressure-sensitive adhesive tape is adjusted so as to be capable of achieving compatibility between low haze property excellent in transparency and such large surface roughness that foreign matter such as a fish eye is hardly observed without fluctuations in mechanical properties of the entire pressure-sensitive adhesive tape. Also provided is such a pressure-sensitive adhesive tape as described below. When a prism sheet having multiple triangle pole-shaped prisms fixed on its surface is used as the above-mentioned member having unevenness on its surface, the pressure-sensitive adhesive tape functions as a surface protective film capable of effectively protecting a lens surface, and brings together sufficient pressure-sensitive adhesiveness for, and sufficient releasability from, the prism sheet. In addition, when the prism sheet protected with the pressure-sensitive adhesive tape is brought into a state such as a laminated state or a continuously wound state, the emergence of irregularity (indentation) in the external appearance of the prism sheet to which the pressure-sensitive adhesive tape is attached can be suppressed. A laminated film of the present invention is a laminated film including a base material layer, a roughness-expressing layer, and a fine unevenness-erasing layer in the stated order, in which: the base material layer contains a thermoplastic resin; the roughness-expressing layer contains at least one kind of a resin component (A) selected from polyethylenes, ethylene-vinyl acetate copolymers, propylene-based polymers, and olefin-based thermoplastic elastomers; the fine unevenness-erasing layer contains a thermoplastic resin (B); an arithmetic average surface roughness Ra on the surface on the side of the fine unevenness-erasing layer is 1.0 μm to 3.0 μm; and the haze value of the laminated film is 30% or less.
    • 7. 发明授权
    • Apparatus and method for inflation extrusion molding of pressure-sensitive adhesive sheet
    • 用于压敏粘合片的吹塑挤出成型的装置和方法
    • US08226398B2
    • 2012-07-24
    • US13296591
    • 2011-11-15
    • Kooki OoyamaShinsuke IkishimaNaoto HayashiTadao ToriiToshihisa YamaneYuuki Katou
    • Kooki OoyamaShinsuke IkishimaNaoto HayashiTadao ToriiToshihisa YamaneYuuki Katou
    • A01J21/00
    • B29C47/0066B29C47/0026B29C49/04B29C2793/0063
    • The present invention provides an apparatus for inflation extrusion molding of pressure-sensitive adhesive sheet, including: one or a plurality of extruders; a die into which one or a plurality of resin materials are respectively introduced and which extrudes from an ejection opening the resin materials into an inflated cylindrical shape having a predetermined diameter in accordance with an inflation method; and two stabilizers facing each other at a predetermined angle so as to upwardly approach each other, and defining a space therebetween through which the cylindrically-shaped resin materials extruded from the die are passed to be deformed into a pressure-sensitive adhesive sheet in a flattened elliptical shape having a predetermined width, in which the stabilizers each have a plurality of air floating portions each of which blows air toward the resin materials; and the stabilizers rotate in one direction around the central axis of the cylindrically-shaped resin materials.
    • 本发明提供一种用于压敏粘合片的吹塑挤出成型的装置,包括:一个或多个挤出机; 分别引入一个或多个树脂材料的模具,并且根据膨胀方法将树脂材料从喷射口挤出成具有预定直径的膨胀圆筒形状的模具; 两个稳定器以预定的角度彼此面对,以便彼此向上接近,并且在其间限定了从模具挤出的圆柱形树脂材料通过的空间,以变形成压平粘合片 具有预定宽度的椭圆形状,其中稳定器具有多个空气浮动部分,每个空气浮动部分朝向树脂材料吹送空气; 并且稳定剂围绕圆柱形树脂材料的中心轴线在一个方向上旋转。
    • 8. 发明授权
    • Removable adhesive composition, removable adhesive layer, adhesive sheet, and surface protective material
    • 可拆卸的粘合剂组合物,可去除的粘合剂层,粘合片和表面保护材料
    • US07968189B2
    • 2011-06-28
    • US11816900
    • 2006-02-06
    • Takeshi YamanakaKooki Ooyama
    • Takeshi YamanakaKooki Ooyama
    • B32B27/30B32B33/00C08L33/02
    • C09J133/04B32B7/12C08K5/0025C08K5/521C08L71/00C08L2666/22C09J4/06C09J7/385Y10T428/1452Y10T428/2891
    • Provided is a re-peeling pressure-sensitive adhesive composition for a surface protecting material for an adherend having a photocatalytic layer, comprising: a (meth)acryl-based polymer including, as monomer units, 50 to 99.9% by weight of (A) at least one acrylate-based monomer represented by the general formula (1): CH2═CR1COOR2 wherein R1 represents a hydrogen atom or a methyl group, and R2 represents an alkyl group having 2 to 14 carbon atoms, 0.1 to 10% by weight of (B) a functional-group-containing vinyl-based monomer, and 0 to 49.9% by weight of (C) a vinyl-based monomer copolymerizable with the component (A) and/or the component (B); and (D) a surfactant having a molecular weight of 150 to 5000, the amount of the component (D) being from 0.01 to 30 parts by weight with respect to 100 parts by weight of the (meth)acryl-based polymer. The re-peeling pressure-sensitive adhesive composition is excellent in re-peeling property, contact-angle-recoverability, and weather resistance.
    • 本发明提供一种用于具有光催化层的被粘物的表面保护材料的再剥离用压敏粘合剂组合物,其包含:(甲基)丙烯酸类聚合物,其包含作为单体单元的(A)50-99.9重量% 至少一种由通式(1)表示的丙烯酸酯类单体:CH2 = CR1COOR2,其中R1表示氢原子或甲基,R2表示碳原子数2〜14的烷基,0.1〜10重量% (B)含官能团的乙烯基类单体和0〜49.9重量%的(C)可与组分(A)和/或组分(B)共聚的乙烯基类单体; 和(D)分子量为150〜5000的表面活性剂,相对于(甲基)丙烯酸系聚合物100重量份,成分(D)的含量为0.01〜30重量份。 再剥离压敏粘合剂组合物的再剥离性,接触角恢复性和耐候性优异。