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    • 6. 发明授权
    • Lithium-containing transition metal oxide target, process for producing the same and lithium ion thin film secondary battery
    • 含锂过渡金属氧化物靶,其制造方法和锂离子薄膜二次电池
    • US08062486B2
    • 2011-11-22
    • US12297320
    • 2007-04-27
    • Ryuichi NagaseYoshio Kajiya
    • Ryuichi NagaseYoshio Kajiya
    • C23C14/00C25B11/00
    • C23C14/3414H01M4/0426H01M4/131H01M4/1391H01M4/485H01M4/505H01M4/525H01M10/0525
    • Proposed are a lithium-containing transition metal oxide target formed from a sintered compact of lithium-containing transition metal oxides showing a hexagonal crystalline system in which the sintered compact has a relative density of 90% or higher and an average grain size of 1 μm or greater and 50 μm or less, and a lithium-containing transition metal oxide target formed from a sintered compact of lithium-containing transition metal oxides showing a hexagonal crystalline system in which the intensity ratio of the (003) face, (101) face and (104) face based on X-ray diffraction using CuKα ray satisfies the following conditions: (1) Peak intensity ratio of the (101) face in relation to the (003) face is 0.4 or higher and 1.1 or lower; and (2) Peak ratio of the (101) face in relation to the (104) face is 1.0 or higher. In addition to this lithium-containing transition metal oxide target optimal for forming a thin film positive electrode for use in a thin film battery such as a three-dimensional battery and a solid state battery, also proposed are its production method and a lithium ion thin film secondary battery. In particular, the present invention aims to propose a positive electrode target capable of obtaining a thin film with superior homogeneity.
    • 提出了由含有过渡金属氧化物的烧结体形成的含锂过渡金属氧化物靶,其表现出六方晶系,其中烧结体的相对密度为90%以上,平均粒径为1μm, 大于或等于50μm的含锂过渡金属氧化物靶和由(003)面,(101)面和第(101)面的强度比的六方晶系的含锂过渡金属氧化物的烧结体形成的含锂过渡金属氧化物靶 (101)面相对于(003)面的峰强度比为0.4以上且1.1以下;(1)相对于(003)面的(101)面的峰强度比为 和(2)(101)面相对于(104)面的峰值比为1.0以上。 除了用于形成用于诸如三维电池和固态电池的薄膜电池中的薄膜正极的最佳的含锂过渡金属氧化物靶之外,还提出了其制造方法和锂离子薄膜 薄膜二次电池。 特别地,本发明的目的在于提出能够获得均匀性优异的薄膜的正极靶。
    • 7. 发明申请
    • Lithium-Containing Transition Metal Oxide Target, Process for Producing the same and Lithium Ion Thin Film Secondary Battery
    • 含锂过渡金属氧化物靶,其制造方法和锂离子薄膜二次电池
    • US20090166187A1
    • 2009-07-02
    • US12297320
    • 2007-04-27
    • Ryuichi NagaseYoshio Kajiya
    • Ryuichi NagaseYoshio Kajiya
    • C23C14/34
    • C23C14/3414H01M4/0426H01M4/131H01M4/1391H01M4/485H01M4/505H01M4/525H01M10/0525
    • Proposed are a lithium-containing transition metal oxide target formed from a sintered compact of lithium-containing transition metal oxides showing a hexagonal crystalline system in which the sintered compact has a relative density of 90% or higher and an average grain size of 1 μm or greater and 50 μm or less, and a lithium-containing transition metal oxide target formed from a sintered compact of lithium-containing transition metal oxides showing a hexagonal crystalline system in which the intensity ratio of the (003) face, (101) face and (104) face based on X-ray diffraction using CuKα ray satisfies the following conditions: (1) Peak intensity ratio of the (101) face in relation to the (003) face is 0.4 or higher and 1.1 or lower; and (2) Peak ratio of the (101) face in relation to the (104) face is 1.0 or higher. In addition to this lithium-containing transition metal oxide target optimal for forming a thin film positive electrode for use in a thin film battery such as a three-dimensional battery and a solid state battery, also proposed are its production method and a lithium ion thin film secondary battery. In particular, the present invention aims to propose a positive electrode target capable of obtaining a thin film with superior homogeneity.
    • 提出了由含锂过渡金属氧化物的烧结体形成的含锂过渡金属氧化物靶,其表现出六方晶系,其中烧结体的相对密度为90%以上,平均粒径为1μm, 大于或等于50um的含锂过渡金属氧化物靶,以及由(003)面,(101)面和第(101)面的强度比的六方晶系的含锂过渡金属氧化物的烧结体形成的含锂过渡金属氧化物靶 (101)面相对于(003)面的峰强度比为0.4以上且1.1以下;(1)相对于(003)面的(101)面的峰强度比为 和(2)(101)面相对于(104)面的峰值比为1.0以上。 除了用于形成用于诸如三维电池和固态电池的薄膜电池中的薄膜正极的最佳的含锂过渡金属氧化物靶之外,还提出了其制造方法和锂离子薄膜 薄膜二次电池。 特别地,本发明的目的在于提出一种能够获得均匀性优异的薄膜的正极靶。