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    • 5. 发明授权
    • Indolins styryl-like compounds
    • 吲哚啉类似苯乙烯基化合物
    • US4314058A
    • 1982-02-02
    • US119147
    • 1980-02-06
    • Masaaki HayamiSeiko Torikoshi
    • Masaaki HayamiSeiko Torikoshi
    • C09K9/00B41M5/28C09B23/00C09B23/10C09B23/14C09B57/00G03C1/24G03C1/29G03C1/685G03C8/02C07D498/04
    • B41M5/286C09B23/105C09B23/143G03C1/24G03C1/29G03C1/685G03C8/02
    • This invention relates to color-changing stryl-like compounds and the preparing of the same. A compound according to the present invention has, as its principal ring, an indoline ring of 2nd position, and has, at stimulation reversible or irreversible change(s) between a closed ring structre of a non-plane molecular structure indicated by the following chemical formula(1) showing white or pale color, and an open ring structure of a plane molecular structure indicated by the following chemical formula(2) showing vivid visible color: ##STR1## Wherein Q represents benzene ring with or without substituted radicals and/or condensed ring(s); R.sub.1 and R.sub.2 represent lower alkyl radicals hydroxyalkyl radicals or alkoxyalkyl radicals of the same or different kinds,; R.sub.3 represents hydrogen, alkyl radical, alkoxy radical, halogen, nitrile radical, aromatic radical or phenoxy radical; Y represents oxygen (O) or sulfer (S); Z represents alkylene radical of carbon number of 2 to 4 with or without alkyl substitution radical(s) necessary to form a ring structure together with ##STR2## A represents a condensation reaction residue of an aromatic aldehyde, heterocyclic aldehyde, aromatic nitroso compound, or heterocyclic nitroso compound. And X represents an anion.
    • 本发明涉及变色层状化合物及其制备。 根据本发明的化合物作为其主环具有第二位的二氢吲哚环,并且在刺激下面由以下化学物质表示的非平面分子结构的闭环结构之间可逆或不可逆地改变 显示白色或浅色的式(1)和由以下化学式(2)表示的具有生动可见颜色的平面分子结构的开环结构:其中Q表示苯 具有或不具有取代基和/或稠环的环; R1和R2代表相同或不同种类的低级烷基羟基烷基或烷氧基烷基; R3表示氢,烷基,烷氧基,卤素,腈基,芳族基或苯氧基; Y表示氧(O)或磺(S); Z表示碳数为2至4的亚烷基,具有或不具有形成环结构所必需的烷基取代基,而A表示芳族醛,杂环醛,芳族亚硝基化合物的缩合反应残基,或 杂环亚硝基化合物。 X表示阴离子。
    • 6. 发明授权
    • Apparatus for changing color
    • 改变颜色的设备
    • US4139274A
    • 1979-02-13
    • US734627
    • 1976-11-08
    • Akio YamashitaMasaaki Hayami
    • Akio YamashitaMasaaki Hayami
    • C09B23/10C09B23/14C09K9/02G02F1/17G02F1/23
    • G02F1/17C09B23/105C09B23/143C09K9/02
    • This invention relates to an apparatus for changing color utilizing new materials, the color of which changes, disappears or appears at the stimulation by, for example, light, heat, ions, electricity, pressure or radioactive rays. The materials are new styryl-like compounds having the below mentioned chemical formula: ##STR1## Wherein Q represents a benzene ring with or without substituted radicals and/or condensed ring(s); R.sub.1 and R.sub.2 represent lower alkyl radicals, hydroxyalkyl radicals or alkoxyalkyl radicals of the same or different kinds,; R.sub.3 represents hydrogen, an alkyl radical, alkoxy radical, halogen, nitrile radical, aromatic radical or phenoxy radical; Y represents oxygen (O) or sulphur (S); Z represents an alkylene radical of 2 to 4 carbon atoms with or without alkyl substitution radical(s) necessary to form a ring structure together with ##STR2## A represents a condensation reaction residue of an aromatic aldehyde, heterocyclic aldehyde, aromatic nitroso compound, or heterocyclic nitroso compound.
    • 本发明涉及利用新材料改变颜色的装置,其颜色在例如光,热,离子,电,压力或放射线的刺激下变化,消失或出现。 该材料是具有下述化学式的新的苯乙烯基类化合物:其中Q表示具有或不具有取代基和/或稠环的苯环; R1和R2表示相同或不同种类的低级烷基,羟基烷基或烷氧基烷基; R 3表示氢,烷基,烷氧基,卤素,腈基,芳族基或苯氧基; Y表示氧(O)或硫(S); Z表示具有或不具有形成环结构所必需的烷基取代基的2至4个碳原子的亚烷基,A表示芳族醛,杂环醛,芳族亚硝基化合物的缩合反应残基,或 杂环亚硝基化合物。