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    • 8. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US4634633A
    • 1987-01-06
    • US678814
    • 1984-12-06
    • Yoshinobu NinomiyaMasashi SomezawaKiyokazu Oiyama
    • Yoshinobu NinomiyaMasashi SomezawaKiyokazu Oiyama
    • C08G18/08C08G18/67C08G18/81G11B5/702G11B5/72
    • G11B5/7021C08G18/0819C08G18/671C08G18/675C08G18/8158Y10S428/90Y10T428/31609
    • A magnetic recording medium has a magnetic layer consisting essentially of a binder and magnetic particles on one surface of a non-magnetic substrate. The thermoplastic polyurethane-urea resin in which unsaturated bonds sensitive to radiation are introduced is used as the binder.The thermoplastic polyurethane-urea resin in which the radiation-sensitive unsaturated bonds are introduced has both urethane and urea bonds in the molecular structure thereof. It is synthesized from long chain diol with a molecular weight of approximately 500 to 5000, a short chain diol with a molecular weight of approximately 50 to 500, an organic diisocyanate, an organic diamine, and a compound containing radiation-sensitive unsaturated double bonds, and cured by radiation.The thermoplastic polyurethane-urea resin in which not only the radiation-sensitive double bonds but also hydrophilic polar groups are introduced may also be used as the binder. These hydrophilic polar groups may for example include --SO.sub.3 M, --OSO.sub.3 M, --COOM, and ##STR1##
    • 磁记录介质具有基本由粘合剂组成的磁性层和在非磁性基底的一个表面上的磁性颗粒。 引入对辐射敏感的不饱和键的热塑性聚氨酯 - 脲树脂用作粘合剂。 其中引入辐射敏感性不饱和键的热塑性聚氨酯 - 脲树脂在其分子结构中具有氨基甲酸酯和脲键。 分子量约为500〜5000的长链二醇,分子量约为50〜500的短链二醇,有机二异氰酸酯,有机二胺,含有辐射敏感性不饱和双键的化合物, 并通过辐射治愈。 也可以使用其中不仅引入了辐射敏感双键,而且还引入亲水极性基团的热塑性聚氨酯 - 脲树脂作为粘合剂。 这些亲水极性基团可以例如包括-SO 3 M,-OSO 3 M,-COOM和