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1. 发明授权

US06706249B1 Composite polybasic salt, process for producing the same, and use 失效
标题翻译：复合多元盐，生产方法及用途
公开(公告)号：US06706249B1
公开(公告)日：2004-03-16
申请号：US09786423
申请日：2001-03-06
申请人： Yoshinobu Komatsu , Hitoshi Ishida , Hiroshi Igarashi , Masami Kondo , Madoka Minagawa , Tetsu Sato , Teiji Sato
发明人： Yoshinobu Komatsu , Hitoshi Ishida , Hiroshi Igarashi , Masami Kondo , Madoka Minagawa , Tetsu Sato , Teiji Sato
IPC分类号： C01F776
CPC分类号： C09K21/02 , B01J41/10 , C01B13/363 , C01F7/005 , C01G1/00 , C01P2002/01 , C01P2002/22 , C01P2002/72 , C01P2002/80 , C01P2002/82 , C01P2002/88 , C01P2004/03 , C08K3/22
摘要： A composite metal polybasic salt containing a trivalent metal and magnesium as metal components and having a novel crystal structure, and a method of preparing the same. The invention further deals with a composite metal polybasic salt which has anion-exchanging property, which by itself is useful as an anion-exchanger, capable of introducing anions suited for the use upon anion-exchange, and finds a wide range of applications, and a method of preparing the same. The composite metal polybasic salt has a particular chemical composition and X-ray diffraction peaks, and further has a degree of orientation (Io) of not smaller than 1.5.
摘要翻译：含有三价金属和镁作为金属成分并具有新的晶体结构的复合金属多元盐及其制备方法。本发明还涉及具有阴离子交换性质的复合金属多元盐，其本身可用作阴离子交换剂，能够引入适用于阴离子交换的阴离子，并且可广泛应用，并且其制备方法。复合金属多元盐具有特定的化学组成和X射线衍射峰，并且还具有不小于1.5的取向度（Io）。

2. 发明授权

US06835320B1 Zinc-modified composite polybasic salt, process for producing the same, and use 失效
标题翻译：锌改性复合多碱盐，其制备方法及用途
公开(公告)号：US06835320B1
公开(公告)日：2004-12-28
申请号：US09786427
申请日：2001-03-06
申请人： Yoshinobu Komatsu , Hitoshi Ishida , Hiroshi Igarashi , Masami Kondo , Madoka Minagawa , Tetsu Sato , Teiji Sato
发明人： Yoshinobu Komatsu , Hitoshi Ishida , Hiroshi Igarashi , Masami Kondo , Madoka Minagawa , Tetsu Sato , Teiji Sato
IPC分类号： C01F776
CPC分类号： B01J41/10 , C01G9/00 , C01G9/006 , C01P2002/22 , C07F5/069
摘要： A composite metal polybasic salt containing a trivalent metal, zinc metal and a divalent metal as metal components and having a novel crystal structure, and a method of preparing the same. The invention further deals with a composite metal polybasic salt which has anion-exchanging property, which by itself is useful as an anion-exchanger, capable of introducing anions suited for the use upon anion-exchange, and finds a wide range of applications, and a method of preparing the same. The composite metal polybasic salt has a particular chemical composition and X-ray diffraction peaks, exhibiting peaks at 2&thgr;=2 to 15°, 2&thgr;=19.5 to 24° and 2&thgr;=33 to 50°, and a single peak at 2&thgr;=60 to 64° in the X-ray diffraction (Cu-&agr;).
摘要翻译：含有三价金属，锌金属和二价金属作为金属成分并具有新颖晶体结构的复合金属多元盐及其制备方法。本发明还涉及具有阴离子交换性质的复合金属多元盐，其本身可用作阴离子交换剂，能够引入适用于阴离子交换的阴离子，并且可广泛应用，并且其制备方法。复合金属多元盐具有特定的化学组成和X射线衍射峰，在2θ= 2°至15°，2θ= 19.5°至24°和2θ= 33°至50°处具有峰值，在2θ= 60°至60° 在X射线衍射（Cu-α）中为64°。

3. 发明授权

US06683117B2 Oiliness agent and water-in-oil emulsion containing same 失效
标题翻译：含油剂和含有其的油包水乳液
公开(公告)号：US06683117B2
公开(公告)日：2004-01-27
申请号：US10056016
申请日：2002-01-28
申请人： Yoshinobu Komatsu , Hitoshi Ishida , Kouji Inoue , Hiroshi Igarashi , Masami Kondou , Madoka Minagawa , Tetsu Sato , Hiroshi Ogawa
发明人： Yoshinobu Komatsu , Hitoshi Ishida , Kouji Inoue , Hiroshi Igarashi , Masami Kondou , Madoka Minagawa , Tetsu Sato , Hiroshi Ogawa
IPC分类号： B01F1700
CPC分类号： A61K8/361 , A61K8/06 , A61K8/26 , A61Q19/00 , B01F17/0078 , B01F17/0085 , C07F5/069 , Y10S514/937
摘要： An oiliness agent comprising a carboxylate of a composite metal hydroxide having a chemical composition represented by the following general formula (1), M2aM3x(OH)y(A)z.nH2O (1) wherein, M2 indicates a divalent metal, M3 indicates a trivalent metal, A indicates an anion of an aliphatic carboxylic acid, a, x, y, and z are numbers satisfying the following formulas: a>0, 3x+2a−y−mz=0 (wherein m is a valency of anion A), 0.3≦a/x≦2.5 1.5≦y/(a+x)≦3.0 1.0≦(a+x)/z≦20.0, and n is a number not larger than 7. The oiliness agent exhibits excellent emulsifying properties such as dispersion stability and moisture retaining property without emitting odor and without a tendency of being colored, and is very useful for forming a water-in-oil emulsion which can be effectively used as a base material for cosmetics.
摘要翻译： 1.一种油性剂，其含有具有下述通式（1）表示的化学组成的复合金属氢氧化物的羧酸盐，其中，M 2表示二价金属，M 3表示三价金属，A表示脂族羧酸，a，x，y和z是满足下式的数字：n是不大于7的数。油性剂显示出优异的乳化性能，如分散稳定性和保湿性，而不发出气味，并且没有着色的倾向，并且对于形成可有效用作化妆品的基础材料的油包水乳液是非常有用的。

4. 发明授权

US5997836A Alkali aluminum complex hydroxide carbonate salt, and a process for producing said salt and its uses 失效
标题翻译：碱金属铝复合氢氧化物碳酸盐，以及所述盐的制造方法及其用途
公开(公告)号：US5997836A
公开(公告)日：1999-12-07
申请号：US817879
申请日：1997-05-01
申请人： Teiji Sato , Yoshinobu Komatsu , Katsumi Higuchi , Masami Kondo , Akira Tatebe
发明人： Teiji Sato , Yoshinobu Komatsu , Katsumi Higuchi , Masami Kondo , Akira Tatebe
IPC分类号： C01F7/00 , C08K3/26 , C08K9/04 , C01B31/30
CPC分类号： C01F7/004 , C01F7/005 , C08K3/26 , C08K9/04 , C01P2002/22 , C01P2002/72 , C01P2002/74 , C01P2002/77 , C01P2002/78 , C01P2002/80 , C01P2002/82 , C01P2002/88 , C01P2004/03 , C01P2004/10 , C01P2004/61 , C01P2004/62 , C01P2006/10 , C01P2006/12 , C01P2006/19 , C01P2006/40 , C01P2006/60 , C01P2006/90
摘要： According to this invention, an amorphous or pseudo-boehmite-type hydrated alumina gel and an alkali metal carbonate or bicarbonate as starting materials are reacted in an aqueous medium to give a method of producing a process for producing an alkali aluminum complex hydroxide carbonate salt which is industrially low-cost and has high productivity. Furthermore, by using a gibbsite-type hydrated alumina, a lithium aluminum complex hydroxide carbonate salt can be synthesized by a migration method.The lithium aluminum complex hydroxide carbonate salt and the sodium aluminum complex hydroxide carbonate salt obtained by the processes of the present invention have excellent compoundability in pigments and resins.In addition, these complex salts have no foaming hazards at the time of processing the resins and are useful as resin fillers for halogen capturing property, infrared ray absorbing property and excellent transparency. They are especially useful as a stabilizer (halogen capturing agent) for resin films, a warmth-keeping agent (infrared absorbing agent) and an anti-blocking agent.
摘要翻译： PCT No.PCT / JP96 / 02470 Sec。 371日期1997年5月1日 102（e）日期1997年5月1日PCT PCT 1996年9月2日PCT公布。出版物WO97 / 09274 日期1997年3月13日根据本发明，将无定形或假勃姆石型水合氧化铝凝胶和作为起始原料的碱金属碳酸盐或碳酸氢盐在水性介质中反应，得到制备碱铝的方法复合氢氧化物碳酸盐，工业上成本低，生产率高。此外，通过使用三水铝矿型水合氧化铝，可以通过迁移法合成锂铝复合氢氧化物碳酸盐。通过本发明的方法得到的锂铝复合氢氧化物碳酸盐和钠铝复合氢氧化物碳酸盐在颜料和树脂中具有优异的复合性。此外，这些复盐在加工树脂时没有起泡危害，并且可用作卤素捕获性，红外线吸收特性和优异透明性的树脂填料。它们作为用于树脂膜的稳定剂（卤素捕获剂），保温剂（红外线吸收剂）和防粘连剂特别有用。

5. 发明授权

US07041265B2 Alkaline earth metal-basic silicate particle 失效
标题翻译：碱土金属 - 碱性硅酸盐颗粒
公开(公告)号：US07041265B2
公开(公告)日：2006-05-09
申请号：US10484384
申请日：2002-07-24
申请人： Hitoshi Ishida , Yoshinobu Komatsu , Hiroshi Enoki , Kazunori Sakao , Katsumi Higuchi , Kouji Inoue , Junichi Nakajima
发明人： Hitoshi Ishida , Yoshinobu Komatsu , Hiroshi Enoki , Kazunori Sakao , Katsumi Higuchi , Kouji Inoue , Junichi Nakajima
IPC分类号： C01B33/24 , C01B33/22
CPC分类号： C09C1/02 , C01B33/24 , C01P2002/72 , C01P2002/88 , C01P2002/89 , C01P2004/03 , C01P2004/61 , C01P2004/62 , C01P2006/12 , C01P2006/19 , C08K3/34 , C08L101/04
摘要： Alkaline earth metal basic silicate particles having a silicate of an alkaline earth metal on the surfaces of the alkaline earth metal hydroxide particles, and having an SiO2/MO (M is an alkaline earth metal) molar ratio as a whole in a range of from 0.01 to 0.90. The particles are useful as a stabilizer for the chlorine-containing polymers.
摘要翻译：在碱土金属氢氧化物颗粒的表面上具有碱土金属的硅酸盐并且SiO 2 / MO（M是碱土金属）摩尔比的碱土金属碱性硅酸盐颗粒的摩尔比为整体在0.01〜0.90的范围内。该颗粒可用作含氯聚合物的稳定剂。

6. 发明授权

US5424351A Antistatic agent for polyacetal resins 失效
公开(公告)号：US5424351A
公开(公告)日：1995-06-13
申请号：US214500
申请日：1994-03-18
申请人： Yoshinobu Komatsu , Hiroshi Igarashi , Takahisa Erami
发明人： Yoshinobu Komatsu , Hiroshi Igarashi , Takahisa Erami
IPC分类号： C08K9/08 , C08L59/00 , C08L71/02 , C09K3/16 , C08K3/26 , C01D15/00 , C22B26/12
CPC分类号： C08K9/08 , C08L59/00 , C08L71/02
摘要： An antistatic agent imparting excellent antistatic property to the polyacetal resins and the polyacetal resins using this antistatic agent. The antistatic agent for polyacetal resins is obtained by including polyalkylene polyols or metal salt-dissolved polyalkylene polyols in a basic carbonate of metals consisting chiefly of alkali metals and aluminum having a porous volume of 0.5 cc/g or larger over a region of meso pores to quasi-macro pores of porous radii of from 200 to 1000 angstroms or in an anion exchanger thereof, said porous volume being greater than 30% of the whole porous volume, and a polyacetal resin composition in which said antistatic agent is blended. The antistatic agent of the invention imparts stable antistatic properties to the above resins and is little dependent upon the environment, and further does not lose thermal property or mechanical strength that occurred with the conventional antistatic agents. Therefore, the resin composition can be extensively used in the field of engineering plastics.

7. 发明授权

US5478877A Antistatic agent for polyacetal resins 失效
标题翻译：聚缩醛树脂的抗静电剂
公开(公告)号：US5478877A
公开(公告)日：1995-12-26
申请号：US391189
申请日：1995-02-21
申请人： Yoshinobu Komatsu , Hiroshi Igarashi , Takahisa Erami
发明人： Yoshinobu Komatsu , Hiroshi Igarashi , Takahisa Erami
IPC分类号： C08K9/08 , C08L59/00 , C08L71/02 , C09K3/16 , C08K3/10
CPC分类号： C08K9/08 , C08L59/00 , C08L71/02
摘要： An antistatic agent imparting excellent antistatic property to the polyacetal resins and the polyacetal resins using this antistatic agent. The antistatic agent for polyacetal resins is obtained by including polyalkylene polyols or metal salt-dissolved polyalkylene polyols in a basic carbonate of metals consisting chiefly of alkali metals and aluminum having a porous volume of 0.5 cc/g or larger over a region of meso pores to quasi-macro pores of porous radii of from 200 to 1000 angstroms or in an anion exchanger thereof, said porous volume being greater than 30% of the whole porous volume, and a polyacetal resin composition in which said antistatic agent is blended. The antistatic agent of the invention imparts stable antistatic properties to the above resins and is little dependent upon the environment, and further does not lose thermal property or mechanical strength that occurred with the conventional antistatic agents. Therefore, the resin composition can be extensively used in the field of engineering plastics.
摘要翻译：使用该抗静电剂赋予聚缩醛树脂和聚缩醛树脂优异的抗静电性的抗静电剂。聚缩醛树脂的抗静电剂通过在主要由碱金属和铝组成的金属的碱性碳酸盐中，在介孔的区域内包含多孔体积为0.5cc / g以上的金属的碱性碳酸盐包括聚亚烷基多元醇或金属盐溶解的聚亚烷基多元醇， 200〜1000埃的多孔半径的准宏观孔或其阴离子交换体，所述多孔体积大于整个多孔体积的30％，和其中混合有所述抗静电剂的聚缩醛树脂组合物。本发明的抗静电剂对上述树脂具有稳定的抗静电性能，并且几乎不依赖于环境，并且不会失去与常规抗静电剂发生的热性能或机械强度。因此，树脂组合物可广泛用于工程塑料领域。

8. 发明授权

US5419883A Lithium aluminum complex hydroxide salt and process for preparation thereof 失效
标题翻译：锂铝复合氢氧化物盐及其制备方法
公开(公告)号：US5419883A
公开(公告)日：1995-05-30
申请号：US213037
申请日：1994-03-15
申请人： Masahide Ogawa , Kunio Goto , Shoji Shoji , Yoshinobu Komatsu , Akira Tatebe
发明人： Masahide Ogawa , Kunio Goto , Shoji Shoji , Yoshinobu Komatsu , Akira Tatebe
IPC分类号： C01F7/04 , C01F7/00 , C08K3/00 , C08K3/22 , C08K3/26 , C08K3/30 , C08K5/00 , C08K9/04 , C08L101/00 , C09K3/00 , C01F1/00 , C01D15/00
CPC分类号： B82Y30/00 , C01F7/002 , C01F7/004 , C08K3/0041 , C08K3/22 , C08K3/26 , C08K3/30 , C08K5/005 , C08K9/04 , C01P2002/00 , C01P2002/72 , C01P2002/74 , C01P2002/78 , C01P2002/82 , C01P2002/88 , C01P2004/03 , C01P2004/20 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/10 , C01P2006/12 , C01P2006/22 , C01P2006/60
摘要： An lithium aluminum complex hydroxide salt (LAHS) and a process for preparation thereof is provided. The LAHS is represented by the formula;(Al.sub.2 Li(OH).sub.6).sub.n X, mH.sub.2 Owherein X is an inorganic or organic anion, n is a value number of X, and m is a number of not more than 3, and having an orientation degree (OD) of not less than 10, OD being defined by the formula;OD=I.sub.(002) /I.sub.(110)wherein I.sub.(002) is a relative intensity of a peak in X-ray diffraction pattern with an index of a plane (002) appearing at a spacing (d) of 7.67 .ANG. to 7.84 .ANG. and I.sub.(110) is a relative intensity of a peak in X-ray pattern with an index of a plane (110) appearing at a spacing (d) of 4.41 .ANG. to 4.45 .ANG.. This LAHS is useful for a stabilizer for chlorine-containing polymers or olefin-type resins containing halogen-containing catalyst residues.
摘要翻译：提供了一种锂铝复合氢氧化物盐（LAHS）及其制备方法。 LAHS由公式表示; （Al 2 Li（OH）6）nX，mH 2 O其中X是无机或有机阴离子，n是数值X，m是不大于3的数，并且取向度（OD）不小于 10，OD由公式定义; OD = I（002）/ I（110）其中I（002）是X射线衍射图中的峰的相对强度，其间距（d）的平面（002）的指数为7.67 ANGSTROM至7.84 ANGSTROM和I（110）是X射线图案中的峰值的相对强度，其间距（d）的平面（110）的索引为4.41 ANGSTROM至4.45 ANGSTROM。该LAHS可用于含氯聚合物或含有卤素的催化剂残余物的烯烃型树脂的稳定剂。

9. 发明授权

US5360859A Lithium aluminum complex hydroxide salt stabilizer for resins 失效
标题翻译：用于树脂的锂铝复合氢氧化物盐稳定剂
公开(公告)号：US5360859A
公开(公告)日：1994-11-01
申请号：US186913
申请日：1994-01-27
申请人： Masahide Ogawa , Kunio Goto , Shoji Shoji , Yoshinobu Komatsu , Akira Tatebe
发明人： Masahide Ogawa , Kunio Goto , Shoji Shoji , Yoshinobu Komatsu , Akira Tatebe
IPC分类号： C08K3/20 , C01F7/00 , C08K3/00 , C08K3/16 , C08K3/18 , C08K3/22 , C08K3/26 , C08K3/30 , C08K5/00 , C08K9/04 , C08L23/00 , C08L27/00 , C08L101/00 , C08K3/10 , C08K5/09
CPC分类号： B82Y30/00 , C08K3/0041 , C08K3/26 , C08K3/30 , C08K5/005 , C08K9/04 , C01P2002/72 , C01P2002/74 , C01P2002/78 , C01P2002/82 , C01P2002/88 , C01P2004/03 , C01P2004/20 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/10 , C01P2006/12 , C01P2006/22 , C01P2006/60
摘要： A stabilizer for resin, which is composed of a lithium aluminum complex hydroxide salt represented by the following formula[Al.sub.2 Li(OH).sub.6 ].sub.n X.mH.sub.2 O (1)wherein X is an inorganic or organic anion, n is a valence number of anion X, and m is a number of not more than 3.A chlorine-containing polymer composition comprising a chlorine-containing polymer and 0.01 to 10 parts by weight, per 100 parts by weight of the chlorine-containing polymer, of the above stabilizer. There is also provided an olefin-type resin composition comprising an olefin-type resin containing halogen-containing catalyst residues and 0.01 to 10 parts by weight, per 100 parts by weight of the olefin-type resin, of the above stabilizer. The stabilizer has excellent heat stabilizing action.
摘要翻译：由下式[Al 2 Li（OH）6] n X.mH 2 O（1）表示的锂铝复合氢氧化物盐组成的树脂稳定剂，其中X是无机或有机阴离子，n是阴离子X的价数，m为3以下的数。含有上述稳定剂的含氯聚合物的含氯聚合物组合物，相对于100重量份含氯聚合物，为0.01〜10重量份。还提供了一种烯烃型树脂组合物，其包含含有含卤素的催化剂残余物的烯烃型树脂和每100重量份的上述稳定剂的烯烃型树脂为0.01至10重量份。稳定剂具有优异的热稳定作用。

10. 发明授权

US5961943A Regularly-shaped aluminosilicate and its use 失效
标题翻译：定型铝硅酸盐及其用途
公开(公告)号：US5961943A
公开(公告)日：1999-10-05
申请号：US903767
申请日：1997-07-31
申请人： Yoshinobu Komatsu , Hiroshi Ogawa , Kazuyoshi Sugano , Hideyuki Nakagawa
发明人： Yoshinobu Komatsu , Hiroshi Ogawa , Kazuyoshi Sugano , Hideyuki Nakagawa
IPC分类号： C01B33/26 , C01B39/46 , C08K3/34 , C08L101/00 , C09C1/28 , C09C1/40 , C09D7/12
CPC分类号： C09D7/1275 , C01B39/46 , C09C1/405 , C09D7/1216 , C09D7/1283 , C01P2002/72 , C01P2004/03 , C01P2004/32 , C01P2004/38 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2004/80 , C01P2004/84 , C01P2006/10 , C01P2006/12 , C01P2006/19 , C01P2006/60 , C01P2006/90 , C08K3/34
摘要： A regularly-shaped aluminosilicate useful as a blending agent for resins and coating materials, featuring low hygroscopic property, excellent pigment property, being capable of being easily dispersed in resins, and making it easy to carry out the blending operation. The regularly-shaped aluminosilicate comprises regularly-shaped sodium aluminosilicate particles obtained by firing a synthetic A or Pc zeolite, and has a nepheline or carnegieite crystalline structure, and further has an average particle diameter of from 0.5 to 30 .mu.m, an apparent specific gravity of from 0.3 to 0.8 g/cm.sup.3, an amount of oil absorption of not larger than 50 ml/100 g, a refractive index of from 1.46 to 1.56, and an amount of moisture absorption of smaller than 1% at a relative humidity of 90%.
摘要翻译：可用作树脂和涂料的混合剂的规则形状的硅铝酸盐，具有低吸湿性，优异的颜料性能，能够容易地分散在树脂中，并且使得容易进行混合操作。规则形状的硅铝酸盐包括通过焙烧合成的A或Pc沸石获得的规则形状的硅铝酸钠颗粒，并且具有霞石或卡底基石结晶结构，并且还具有0.5至30μm的平均粒径，表观比重为0.3〜0.8g / cm 3，在相对湿度90°下吸油量不大于50ml / 100g，折射率为1.46〜1.56，吸湿量小于1％％。

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