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1. 发明授权

US07122253B2 Curable resin composition, cured film, and composite product 有权
标题翻译：可固化树脂组合物，固化膜和复合产品
公开(公告)号：US07122253B2
公开(公告)日：2006-10-17
申请号：US10257762
申请日：2001-04-17
申请人： Yoshikazu Yamaguchi , Isao Nishiwaki , Yuichi Eriyama , Takashi Ukachi , Takao Yashiro , Michiko Takahashi
发明人： Yoshikazu Yamaguchi , Isao Nishiwaki , Yuichi Eriyama , Takashi Ukachi , Takao Yashiro , Michiko Takahashi
IPC分类号： C08F30/08
CPC分类号： C08G18/289 , C08F283/12 , C08F290/06 , C08G18/3893 , C08G18/673 , C08L51/085 , C08L51/10 , C09D151/085 , C09D151/10 , Y10T428/1476 , Y10T428/2985 , Y10T428/2991 , Y10T428/2995 , Y10T428/31663 , C08L2666/02
摘要： A curable resin composition comprising (A) reactive particles prepared by bonding (A1) at least one of oxide particles of an element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, ruthenium, rhenium, silver, nickel, cupper and cerium, and (A2) an organic compound which comprises a polymerizable unsaturated group, (B) a compound having two or more polymerizable unsaturated groups in the molecule, and optionally (C) a terminal reactive polysiloxane compound having at least one polymerizable group, other than organic compound (A2).
摘要翻译：一种可固化树脂组合物，其包含（A）通过将（A1）选自硅，铝，锆，钛，锌，锗，铟，锡，锑，钌中的至少一种元素的氧化物颗粒键合而制备的反应性颗粒铼，银，镍，铜和铈，和（A2）包含可聚合不饱和基团的有机化合物，（B）分子中具有两个或更多个可聚合不饱和基团的化合物，和任选地（C）末端反应性聚硅氧烷除了有机化合物（A2）以外，具有至少一个聚合性基团的化合物。

2. 发明授权

US06727334B2 Resin composition and cured product 失效
标题翻译：树脂组合物和固化产物
公开(公告)号：US06727334B2
公开(公告)日：2004-04-27
申请号：US09929290
申请日：2001-08-15
申请人： Isao Nishiwaki , Yoshikazu Yamaguchi , Yuichi Eriyama , Takashi Ukachi
发明人： Isao Nishiwaki , Yoshikazu Yamaguchi , Yuichi Eriyama , Takashi Ukachi
IPC分类号： C08F23008
CPC分类号： C08K9/06 , C09D4/00 , C08F222/1006
摘要： The invention relates to a resin composition exhibiting excellent coatability and capable of forming coatings with high hardness, superior scratch resistance, low curling properties, superb adhesion, excellent transparency, and superior coating surface appearance without a wavy striation, streaks, unevenness of coatings, cissing, and the like, as well as cured products made from the resin composition.
摘要翻译：本发明涉及一种树脂组合物，具有优异的涂布性能，能够形成具有高硬度，优异的耐擦伤性，低卷曲性，极好的粘附性，优异的透明性和优异的涂层表面外观，而无波浪条纹，条纹，涂层不均匀性，等，以及由树脂组合物制成的固化物。

3. 发明授权

US06846572B2 Curable composition, cured product, and laminate 失效
标题翻译：可固化组合物，固化产物和层压材料
公开(公告)号：US06846572B2
公开(公告)日：2005-01-25
申请号：US10195325
申请日：2002-07-16
申请人： Yoshikazu Yamaguchi , Takao Yashiro , Isao Nishiwaki , Takashi Ukachi
发明人： Yoshikazu Yamaguchi , Takao Yashiro , Isao Nishiwaki , Takashi Ukachi
IPC分类号： B32B27/42 , B32B7/10 , C08F2/44 , C08F290/00 , C08F290/14 , C08F292/00 , C09D4/00 , C09D4/06 , G03F7/027 , G03F7/038 , C08F30/04
CPC分类号： B32B7/10 , B32B27/06 , B32B27/302 , B32B27/308 , B32B27/32 , B32B27/365 , B32B27/38 , B32B27/42 , B32B2307/584 , B32B2323/00 , B32B2333/08 , B32B2355/02 , B32B2363/00 , B32B2367/00 , B32B2369/00 , C08F2/44 , C08F290/14 , C08F292/00 , C09D4/00 , C09D4/06 , G03F7/027 , G03F7/038 , Y10T428/31931 , Y10T428/31935 , Y10T428/31942 , C08F222/1006
摘要： The invention relates to a curable composition comprising (A) particles prepared by bonding at least one oxide of an element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium, and an organic compound which comprises a polymerizable group, (B) a compound having a melamine group and one or more polymerizable groups and (C) a compound having at least two polymerizable groups in the molecule other than the component (B); and to cured products and laminates with a with low reflectance and superior chemical resistance.
摘要翻译：本发明涉及一种可固化组合物，其包含（A）通过键合选自硅，铝，锆，钛，锌，锗，铟，锡，锑和铈中的至少一种元素的氧化物而制备的颗粒，以及包含可聚合基团的有机化合物，（B）具有三聚氰胺基团和一个或多个可聚合基团的化合物和（C）在分子中除了组分（B）之外具有至少两个可聚合基团的化合物; 并且具有低反射率和优异的耐化学性的固化产品和层压材料。

4. 发明授权

US06686047B2 Reactive particles, curable composition comprising the same and cured products 失效
标题翻译：反应性颗粒，包含其的可固化组合物和固化产物
公开(公告)号：US06686047B2
公开(公告)日：2004-02-03
申请号：US10183028
申请日：2002-06-27
申请人： Yoshikazu Yamaguchi , Takao Yashiro , Isao Nishiwaki , Takashi Ukachi
发明人： Yoshikazu Yamaguchi , Takao Yashiro , Isao Nishiwaki , Takashi Ukachi
IPC分类号： B32B516
CPC分类号： C08F292/00 , C08K9/04 , C08K2201/014 , Y10T428/254 , Y10T428/256 , Y10T428/259 , Y10T428/2998
摘要： Reactive particles have been invented that may be used for a curable composition exhibiting excellent cured product productivity and capable of forming coatings with high hardness, superior scratch resistance, excellent abrasion resistance, low curling properties, superb adhesion, and chemicals resistance, particularly high chemicals resistance, on the surface of various substrates; a curable composition containing the reactive particles; and cured products made from the curable composition.
摘要翻译：已经发明了可用于具有优异的固化产物生产率并且能够形成具有高硬度，优异的耐刮擦性，优异的耐磨性，低卷曲性，极好的粘附性和耐化学性，特别是高耐化学性的涂层的固化组合物的反应性颗粒，在各种基材的表面上; 含有反应性颗粒的可固化组合物; 和由可固化组合物制成的固化产物。

5. 发明授权

US06818678B2 Resin composition comprising particles 失效
标题翻译：包含颗粒的树脂组合物
公开(公告)号：US06818678B2
公开(公告)日：2004-11-16
申请号：US10073075
申请日：2002-02-12
申请人： Yoshikazu Yamaguchi , Takao Yashiro , Isao Nishiwaki , Takashi Ukachi
发明人： Yoshikazu Yamaguchi , Takao Yashiro , Isao Nishiwaki , Takashi Ukachi
IPC分类号： C08F246
CPC分类号： C08F290/068 , C08F2/44 , C08F283/12 , C08F292/00 , C08L51/08
摘要： A resin composition comprising: (A) particles prepared by bonding at least one oxide of an element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium, and an organic compound which includes a polymerizable unsaturated group, (B) an oligomer-type radiation polymerization initiator having a site which generates photo-radicals by irradiation of radioactive rays, and (C) a compound having at least two polymerizable unsaturated groups in the molecule.
摘要翻译：一种树脂组合物，其包含：（A）通过将选自硅，铝，锆，钛，锌，锗，铟，锡，锑和铈中的至少一种元素的氧化物与有机化合物其包含聚合性不饱和基团，（B）具有通过放射线照射产生光自由基的位点的低聚物型放射线聚合引发剂，（C）分子中具有至少2个聚合性不饱和基团的化合物。

6. 发明授权

US06521677B2 Radiation-curable metal particles and curable resin compositions comprising these particles 失效
标题翻译：包含这些颗粒的可辐射固化金属颗粒和可固化树脂组合物
公开(公告)号：US06521677B2
公开(公告)日：2003-02-18
申请号：US09849619
申请日：2001-05-07
申请人： Takao Yashiro , Yuichi Eriyama , Isao Nishikawi , Takashi Ukachi
发明人： Takao Yashiro , Yuichi Eriyama , Isao Nishikawi , Takashi Ukachi
IPC分类号： C08K906
CPC分类号： G02B1/111 , B82Y30/00 , C01P2002/02 , C01P2004/20 , C01P2004/32 , C01P2004/34 , C01P2004/61 , C01P2004/64 , C01P2006/12 , C01P2006/21 , C01P2006/22 , C01P2006/44 , C01P2006/60 , C01P2006/90 , C09C1/62 , C09C3/12 , G02B1/105 , G02B1/11 , G02B1/14
摘要： Provided is a liquid curable resin composition which can produce transparent cured products with a high refractive index, high hardness, and superior abrasion resistance, and which can be suitably used as a coating material. The liquid curable resin composition comprises: (A) a poly-functional (meth)acrylic compound having at least three (meth) acryloyl groups in the molecule; (B) a reaction product obtained by the reaction of a compound having a polymerizable unsaturated group and alkoxysilyl group in the molecule and particles metal oxide, the metals being preferably selected from the group consisting of zirconium, antimony, zinc, tin, cerium, and titanium; and (C) a radiation polymerization initiator.
摘要翻译：本发明提供一种能够生产具有高折射率，高硬度，优异的耐磨性的透明固化物的液体固化性树脂组合物，可以适合用作涂料。液固性树脂组合物包含：（A）在分子中具有至少三个（甲基）丙烯酰基的多官能（甲基）丙烯酸化合物; （B）通过在分子中具有聚合性不饱和基团和烷氧基甲硅烷基的化合物与颗粒金属氧化物反应获得的反应产物，所述金属优选选自锆，锑，锌，锡，铈和钛; 和（C）辐射聚合引发剂。

7. 发明授权

US6013749A Liquid curable resin composition 失效
标题翻译：液体固化树脂组合物
公开(公告)号：US6013749A
公开(公告)日：2000-01-11
申请号：US48978
申请日：1998-03-27
申请人： Atsushi Baba , Yuichi Eriyama , Takashi Ukachi
发明人： Atsushi Baba , Yuichi Eriyama , Takashi Ukachi
IPC分类号： G03F7/028 , C08F2/46 , C08F220/10 , C08F230/08 , C08F283/12 , C08F290/06 , C08K9/04 , C08L33/04 , C08L43/04 , C08L55/00 , C08L83/07 , C08L83/10 , C09C1/30 , C09C3/10 , C09D5/16 , G02B1/10 , G02B1/14 , G02B1/18 , G03F7/075 , C08F30/08
CPC分类号： C08F283/12
摘要： A liquid curable resin composition containing:(A) a polyfunctional (meth)acrylic compound having at least three (meth)acryloyl groups in a molecule;(B) a reaction product obtained by the reacting (i) an alkoxysilane compound having a polymerizable unsaturated group, a urethane bonding group and an organic group represented by the formula (1), ##STR1## and (ii) silica particles; (C) a silicone polymer; and(D) an irradiation sensitive initiator.The composition when coated on surfaces of plastic molded articles and other materials provides for superior slip characteristics and resistance to abrasions, stains, weather, solvents and alkali environments. The composition of the instant invention is particularly suitable as a hard coat material for plastic optical components, touch panels, film-type liquid crystal elements, molded plastic articles or as a stain-proof or scratch-proof coating for wall and flooring materials which are used as architectural interior finishings.
摘要翻译：一种液体固化树脂组合物，其含有：（A）分子中具有至少三个（甲基）丙烯酰基的多官能（甲基）丙烯酸化合物; （B）通过使（i）具有聚合性不饱和基团的烷氧基硅烷化合物，氨基甲酸酯键合基和由式（1）表示的有机基团反应得到的反应产物和（ii）二氧化硅颗粒; （C）硅氧烷聚合物; 和（D）照射敏感引发剂。当涂覆在塑料模制品和其它材料的表面上时的组合物提供优异的滑动特性和耐擦伤，污渍，天气，溶剂和碱性环境的耐受性。本发明的组合物特别适合用作塑料光学部件，触摸屏，薄膜型液晶元件，模制塑料制品或作为用于墙壁和地板材料的防污或防刮涂层的硬涂层材料，其为用作建筑内饰。

8. 发明授权

US06355703B1 Liquid curable resin composition, coating, and cured coating therefrom 失效
标题翻译：液固固化树脂组合物，涂层和固化涂层
公开(公告)号：US06355703B1
公开(公告)日：2002-03-12
申请号：US09592615
申请日：2000-06-12
申请人： Atsushi Baba , Yuichi Eriyama , Takashi Ukachi
发明人： Atsushi Baba , Yuichi Eriyama , Takashi Ukachi
IPC分类号： C08F248
CPC分类号： C09D183/10 , C08F265/04 , C08F292/00 , C08F222/1006
摘要： The invention relates to a liquid curable resin composition comprising: (A) a polyfunctional (meth)acrylic compound containing at least three (meth)acryloyl groups in the molecule, (B) a reaction product of an alkoxy silane compound having a polymerizable unsaturated group, an urethane bond group, and an organic group represented by the following formula (1), wherein X is NH—, —O—, or —S— and Y is an oxygen atom or a sulfur atom, and when X is —O—, Y is a sulfur atom, with silica particles, (C) a radiation curable acrylic resin comprising a carboxyl group in its molecule, of which the Tg is 50 or higher, (D) a radiation polymerization initiator, and (E) a non reactive solvent. The invention further relates to the coating obtained after evaporation of the solvent, and to the cured coating after irradiation.
摘要翻译：本发明涉及一种液体可固化树脂组合物，其包含：（A）分子中含有至少三个（甲基）丙烯酰基的多官能（甲基）丙烯酸化合物，（B）具有可聚合不饱和基团的烷氧基硅烷化合物，氨基甲酸酯键基和由下式（1）表示的有机基，其中X是NH-，-O-或-S-，Y是氧原子或硫原子，当X是-O - ，Y是硫原子，二氧化硅颗粒，（C）在其分子中包含羧基的辐射固化丙烯酸树脂，其Tg为50或更高，（D）辐射聚合引发剂，和（E）非反应性溶剂。本发明还涉及在溶剂蒸发之后获得的涂层以及照射后的固化涂层。

9. 发明授权

US6160067A Reactive silica particles, process for manufacturing the same, use of the same 失效
标题翻译：活性二氧化硅颗粒，制造方法相同，使用相同
公开(公告)号：US6160067A
公开(公告)日：2000-12-12
申请号：US53625
申请日：1998-04-02
申请人： Yuichi Eriyama , Atsushi Baba , Takashi Ukachi
发明人： Yuichi Eriyama , Atsushi Baba , Takashi Ukachi
IPC分类号： C07F7/18 , C08F283/12 , C08F290/14 , C08F292/00 , C08L51/08 , C08L51/10 , C09C1/30 , C09D4/00 , C09D4/06 , C09D151/10 , C08F30/08
CPC分类号： B82Y30/00 , C01P2002/82 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2004/80 , C07F7/1804 , C08F283/12 , C08F290/147 , C08F290/148 , C08F292/00 , C08L51/08 , C08L51/10 , C09C1/3081 , C09C1/309 , C09D4/00 , C09D4/06 , C09D151/10 , C08F222/1006
摘要： Reactive silica particles capable of producing coatings exhibiting excellent scratch resistance, weather resistance, adhesiveness, and curability, while satisfying a wide spectrum of performances from transparency to semi-transparency and providing a glossy surface as well as a frosty surface. Reactive silica particles comprises silica particles and an organic compound chemically bonded to the silica particles via a silyloxy group, wherein the organic compound has a polymerizable unsaturated group, a group represented by the following formula (1), ##STR1## (wherein X is a group selected from --NH--, --O--, and --S-- and Y is a group selected from oxygen and sulfur, provided that when X is --O--, Y is a sulfur atom), and a group represented by the following formula (2), ##STR2## (wherein Z is a group selected from oxygen and sulfur)
摘要翻译：能够产生耐刮擦性，耐候性，粘合性和固化性优异的涂层的活性二氧化硅颗粒，同时满足从透明度到半透明度的广泛性能，并提供光泽表面以及霜面。活性二氧化硅颗粒包括二氧化硅颗粒和通过甲硅烷氧基化学键合到二氧化硅颗粒上的有机化合物，其中有机化合物具有可聚合不饱和基团，由下式（1）表示的基团（其中X是选自 -NH-，-O-和-S-，Y是选自氧和硫的基团，条件是当X是-O-，Y是硫原子）和由下式（2）表示的基团时，，（其中Z是选自氧和硫的基团）

10. 发明授权

US06265133B1 Radiation curable resin composition 有权
标题翻译：辐射固化树脂组合物
公开(公告)号：US06265133B1
公开(公告)日：2001-07-24
申请号：US09209418
申请日：1998-12-11
申请人： Toshihiko Takahashi , Keiko Kato , Tsuyoshi Watanabe , Yuichi Eriyama , Takashi Ukachi
发明人： Toshihiko Takahashi , Keiko Kato , Tsuyoshi Watanabe , Yuichi Eriyama , Takashi Ukachi
IPC分类号： G03F7027
CPC分类号： C09D163/10 , C08F290/062 , C08L2666/54
摘要： A radiation curable resin composition comprising (A) a first linear (meth)acryloyl and aromatic group-containing compound, (B) a second branched (meth)acryloyl group-containing compound, (C) a radiation polymerization initiator, and (D) silica particles having a secondary average particle diameter of 0.5 to 5 &mgr;m. The composition is suitable for use as a printable heat-resistant protective coat which is used for information recording media such as thermosensible recording cards and thermosensible photographic printing paper.
摘要翻译：一种辐射固化树脂组合物，其包含（A）第一直链（甲基）丙烯酰基和含芳基的化合物，（B）第二支链（甲基）丙烯酰基化合物，（C）辐射聚合引发剂和（D）二次平均粒径为0.5〜5μm的二氧化硅粒子。该组合物适合用作可印刷的耐热保护涂层，其用于信息记录介质如热敏记录卡和热敏照相印刷纸。

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