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1. 发明授权

US4008280A Process for production of acrolein 失效
标题翻译：丙烯醛生产工艺
公开(公告)号：US4008280A
公开(公告)日：1977-02-15
申请号：US511473
申请日：1974-10-01
申请人： Yoshihisa Watanabe , Toshiyuki Sugihara , Kenji Takagi , Makoto Imanari , Naohiro Nojiri
发明人： Yoshihisa Watanabe , Toshiyuki Sugihara , Kenji Takagi , Makoto Imanari , Naohiro Nojiri
IPC分类号： B01J23/887 , C07C45/35 , C07C45/04
CPC分类号： B01J23/8876 , C07C45/35 , B01J2523/00
摘要： For production of acrolein by gas-phase catalytic oxidation of propylene with molecular oxygen, there is used a catalyst containing molybdenum, bismuth, cobalt, nickel, iron, tin, silicon, and a particular borate in a prescribed proportion. Sodium or manganese is employed for formation of the desired borate. For preparation of the catalyst, the borate of each of the metals is preferably supplied in the combined form of a sodium or manganese salt of various boric acids, such as borax, although it may be supplied separately as a boric acid and a decomposable compound of each metal.
摘要翻译：为了通过用分子氧气对丙烯进行气相催化氧化生产丙烯醛，使用含有钼，铋，钴，镍，铁，锡，硅和特定硼酸盐的催化剂。使用钠或锰来形成所需的硼酸盐。为了制备催化剂，每种金属的硼酸盐优选以各种硼酸如硼砂的钠盐或锰盐的组合形式提供，尽管它可以单独供应为硼酸和可分解化合物每个金属。

2. 发明授权

US3965162A Process for production of acrylic acid 失效
标题翻译：丙烯酸生产工艺
公开(公告)号：US3965162A
公开(公告)日：1976-06-22
申请号：US408291
申请日：1973-10-23
申请人： Yoshihisa Watanabe , Makoto Imanari , Naohiro Nojiri , Nobuhiko Fuga , Masato Nakajima
发明人： Yoshihisa Watanabe , Makoto Imanari , Naohiro Nojiri , Nobuhiko Fuga , Masato Nakajima
IPC分类号： B01J23/00 , B01J23/28 , C07B61/00 , C07C51/00 , C07C57/055 , C07C67/00 , C07C51/32
CPC分类号： B01J23/28
摘要： A process for production of acrylic acid by vapor phase catalytic oxidation of acrolein comprising effecting the catalytic oxidation in the presence of a catalyst comprising1. oxides of molybdenum2. oxides of niobium3. oxides of silicon, and4. oxides of elements selected from the group consisting of copper, zinc, titanium, manganese, tungsten, iron, cobalt, nickel, cadmium, gallium, mercury, thorium and boron.
摘要翻译：一种通过气相催化氧化丙烯醛生产丙烯酸的方法，包括在催化剂存在下进行催化氧化，所述催化剂包含1.氧化钼2.氧化铌3.氧化物，氧化物，以及4.选自元素的氧化物铜，锌，钛，锰，钨，铁，钴，镍，镉，镓，汞，钍和硼的集团。

3. 发明授权

US4014766A Electrolytic treatment of waste water 失效
标题翻译：废水电解处理
公开(公告)号：US4014766A
公开(公告)日：1977-03-29
申请号：US625099
申请日：1975-10-23
申请人： Yoshihisa Watanabe , Naohiro Nojiri
发明人： Yoshihisa Watanabe , Naohiro Nojiri
IPC分类号： C02F1/461 , C02F1/463 , C02F1/48 , C02F1/72 , C02C5/12 , C25C1/10
CPC分类号： C02F1/488 , C02F1/46114 , C02F1/463 , C02F1/72 , C02F2101/22
摘要： Waste water is subjected to electrolysis in an electrolytic cell having an anode comprising an insoluble central electrode and a body of particulate iron pieces disposed therearound and in electrical contact therewith, whereby impurities in the waste water become occluded within a floc of iron hydroxide formed by electrolytic dissolution of the iron pieces, and the floc containing the impurities is subjected to oxidation processing and is thereafter separated. A magnetic field can be applied to the waste water thus treated thereby to promote sedimentation of the floc.
摘要翻译：废水在具有阳极的电解槽中进行电解，该阳极包含不溶性中心电极和设置在其周围并与其电接触的颗粒状铁屑体，由此废水中的杂质被吸收在由电解质形成的氢氧化铁絮凝物中将铁片和含有杂质的絮状体的溶解进行氧化处理，然后分离。可以对这样处理的废水施加磁场，从而促进絮凝物的沉降。

4. 发明授权

US4812437A Silver-deposited catalyst for production of ethylene oxide 失效
标题翻译：用于生产环氧乙烷的银沉积催化剂
公开(公告)号：US4812437A
公开(公告)日：1989-03-14
申请号：US46177
申请日：1987-05-05
申请人： Naohiro Nojiri , Yukio Sakai , Tomoatsu Iwakura
发明人： Naohiro Nojiri , Yukio Sakai , Tomoatsu Iwakura
IPC分类号： C07D301/10 , B01J23/66 , B01J27/10 , B01J21/12 , B01J23/02 , B01J23/04 , B01J23/50
CPC分类号： C07D301/10 , B01J23/66 , Y02P20/52
摘要： A silver-deposited catalyst for production of ethylene oxide by oxidizing ethylene, having high selectivity and long life, is provided by this invention. The catalyst is characterized by a combination of (a) catalyst ingredients comprising silver and a cation component selected at least from sodium, potassium, rubidium and cesium, and (b) a carrier composed mainly of alpha-alumina, said carrier having a surface area of 0.6 to 2 m.sup.2 /g, a water absorption of 20 to 50%, a silica content of 0.5 to 12% by weight, a silica content, per m.sup.2 /g of surface area, of 0.5 to 12, preferably 1 to 8, and a sodium content of 0.08 to 2% by weight.
摘要翻译：通过本发明提供了通过氧化乙烯生产环氧乙烷的银沉积催化剂，具有高选择性和长寿命。催化剂的特征在于（a）包含银和至少选自钠，钾，铷和铯的阳离子组分的催化剂成分和（b）主要由α-氧化铝组成的载体的组合，所述载体具有表面积为0.6〜2m 2 / g，吸水率为20〜50％，二氧化硅含量为0.5〜12重量％，二氧化硅含量/ m 2 / g表面积为0.5〜12，优选为1〜8，钠含量为0.08〜2重量％。

5. 发明授权

US4642360A Method for producing ethylene oxide 失效
标题翻译：生产环氧乙烷的方法
公开(公告)号：US4642360A
公开(公告)日：1987-02-10
申请号：US782178
申请日：1985-10-01
申请人： Naohiro Nojiri , Yukio Sakai
发明人： Naohiro Nojiri , Yukio Sakai
IPC分类号： C07D301/10 , B01J8/00 , B01J8/02 , C04B35/18 , C07D301/08
CPC分类号： B01J8/008 , C04B35/18 , C07D301/08
摘要： A packing material for a reactor for producing ethylene oxide by the catalytic oxidation of ethylene in the presence of molecular oxygen, wherein the packing material is used at the inlet side of a catalyst layer of the reactor, is silica-alumina containing 10 to 8 wt. % of silica, and is produced by sintering the silica-alumina at 1200.degree. to 1500.degree. C.
摘要翻译：用于在分子氧存在下通过乙烯的催化氧化生产环氧乙烷的反应器的包装材料，其中包装材料在反应器的催化剂层的入口侧使用，是包含10至8重量％的二氧化硅 - 氧化铝。的二氧化硅，并且通过在1200℃至1500℃下烧结二氧化硅 - 氧化铝来制备。

6. 发明授权

US4786624A Silver catalyst for production of ethylene oxide from ethylene 失效
标题翻译：用于从乙烯生产环氧乙烷的银催化剂
公开(公告)号：US4786624A
公开(公告)日：1988-11-22
申请号：US17686
申请日：1987-02-24
申请人： Naohiro Nojiri , Yukio Sakai
发明人： Naohiro Nojiri , Yukio Sakai
IPC分类号： B01J23/50 , B01J23/66 , B01J23/68 , C07D301/10 , B01J23/04 , B01J27/06
CPC分类号： C07D301/10 , B01J23/50 , B01J23/66 , B01J23/68 , B01J23/681 , Y02P20/52
摘要： A catalyst for the production of ethylene oxide from ethylene, said catalyst comprising a porous carrier composed of a molded article of a refractory material and at least silver grains deposited on the carrier, wherein(A) silver is distributed on the outside surface of the carrier and on the inner surfaces of the pores of the carrier,(B) silver grains distributed on the inner surfaces of the pores of the carrier have an average diameter of 0.05 to 0.4 micron, and(C) the loading (S) of silver on the outside surface layer of the catalyst and the loading (I) of silver on the innermost layer of the catalyst satisfy the following expressionI.gtoreq.0.65S; and a process for producing a catalyst for the production of ethylene oxide from ethylene, which comprises impregnating an aqueous solution containing a silver salt and an amine as a complex forming agent in a porous carrier composed of a molded article of a refractory material, and heating the carrier with superheated steam to deposit silver on the carrier.

7. 发明授权

US4746749A Process for producing silver oxalate 失效
标题翻译：生产草酸银的方法
公开(公告)号：US4746749A
公开(公告)日：1988-05-24
申请号：US70805
申请日：1987-07-07
申请人： Naohiro Nojiri , Yukio Sakai , Tomoatsu Iwakura
发明人： Naohiro Nojiri , Yukio Sakai , Tomoatsu Iwakura
IPC分类号： C07C55/07 , C07C51/00 , C07C51/41 , C07C55/06 , C07C67/00 , C07F1/10
CPC分类号： C07C51/412
摘要： A process for producing silver oxalate, which comprises reacting(a) one member selected from the group consisting of oxalic acid and oxalic acid salts as one reactant, with(b) a silver salt as the other reactant, at a pH of not more than 5 in an aqueous medium thereby to precipitate silver oxalate.

8. 发明授权

US4415476A Silver-based catalyst containing chlorine as an anionic component for the production of ethylene oxide 失效
标题翻译：含有氯作为阴离子成分的银基催化剂用于生产环氧乙烷
公开(公告)号：US4415476A
公开(公告)日：1983-11-15
申请号：US349978
申请日：1982-02-18
申请人： Akimi Ayame , Naohiro Nojiri , Yukio Sakai
发明人： Akimi Ayame , Naohiro Nojiri , Yukio Sakai
IPC分类号： B01J23/66 , B01J27/10 , C07B61/00 , C07D301/10
CPC分类号： B01J23/66 , C07D301/10 , Y02P20/52
摘要： A catalyst comprises sodium and cesium as a cationic component and chlorine as an anionic component in addition to silver which is a typical conventional catalyst component for the production of ethylene oxide by oxidation of ethylene. Use of the catalyst of the invention gives ethylene oxide at an improved selectivity.
摘要翻译：作为阳离子成分的钠和铯，除了作为阴离子成分的氯以外，作为用于通过乙烯氧化生产环氧乙烷的典型的常规催化剂组分，催化剂包括。使用本发明的催化剂以改善的选择性给出环氧乙烷。

9. 发明授权

US4939114A Silver-deposited catalyst for production of ethylene oxide 失效
标题翻译：用于生产环氧乙烷的银沉积催化剂
公开(公告)号：US4939114A
公开(公告)日：1990-07-03
申请号：US268546
申请日：1988-11-07
申请人： Naohiro Nojiri , Yukio Sakai , Yoshiaki Saotome , Tomoatsu Iwakura
发明人： Naohiro Nojiri , Yukio Sakai , Yoshiaki Saotome , Tomoatsu Iwakura
IPC分类号： B01J21/04 , B01J23/54 , B01J23/66 , B01J35/00 , C07D301/10 , C07D303/04
CPC分类号： B01J23/66 , C07D301/10 , B01J21/04 , B01J35/002 , Y02P20/52
摘要： A silver-deposited catalyst for the production of ethylene oxide by the oxidation of ethylene, said catalyst comprising(1) a carrier composed mainly of alpha-alumina, which carrier does not show acidity in a visual color change method in a toluene solvent using a dimethyl yellow indicator having a pKa of +3.3, and does not show basicity in a color reaction in a toluene solvent using a bromothymol blue having a pKa of +7.1, and(2) as catalyst components, silver and at least one cationic component selected from sodium, potassium, rubidium and cesium.

10. 发明授权

US4690913A Silver catalyst for production of ethylene oxide from ethylene and process for producing the catalyst 失效
标题翻译：用于从乙烯生产环氧乙烷的银催化剂和用于生产催化剂的方法
公开(公告)号：US4690913A
公开(公告)日：1987-09-01
申请号：US767831
申请日：1985-08-20
申请人： Naohiro Nojiri , Yukio Sakai
发明人： Naohiro Nojiri , Yukio Sakai
IPC分类号： B01J23/50 , B01J23/66 , B01J23/68 , C07D301/10 , B01J23/02 , B01J23/04
CPC分类号： C07D301/10 , B01J23/50 , B01J23/66 , B01J23/68 , B01J23/681 , Y02P20/52
摘要： A catalyst for the production of ethylene oxide from ethylene, said catalyst comprising a porous carrier composed of a molded article of a refractory material and at least silver grains deposited on the carrier, wherein(A) silver is distributed on the outside surface of the carrier and on the inner surfaces of the pores of the carrier,(B) silver grains distributed on the inner surfaces of the pores of the carrier have an average diameter of 0.05 to 0.4 micron, and(C) the loading (S) of silver on the outside surface layer of the catalyst and the loading (I) of silver on the innermost layer of the catalyst satisfy the following expressionI.gtoreq.0.65S; and a process for producing a catalyst for the production of ethylene oxide from ethylene, which comprises impregnating an aqueous solution containing a silver salt and an amine as a complex forming agent in a porous carrier composed of a molded article of a refractory material, and heating the carrier with superheated steam to deposit silver on the carrier.
摘要翻译：一种用于从乙烯生产环氧乙烷的催化剂，所述催化剂包括由耐火材料的模制品和沉积在载体上的至少银颗粒构成的多孔载体，其中（A）银分布在载体的外表面上并且在载体的孔的内表面上，（B）分布在载体孔的内表面上的银颗粒的平均直径为0.05至0.4微米，（C）银的负载量（S）催化剂的外表面层和催化剂最内层上的银负载量（I）满足下式I> = 0.65S; 以及由乙烯制造环氧乙烷的催化剂的制造方法，其特征在于，在由耐火材料成形体构成的多孔载体中浸渍含有银盐和胺作为络合物形成剂的水溶液，加热具有过热蒸汽的载体在载体上沉积银。

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