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1. 发明申请

US20110300040A1 METHOD FOR PRODUCING SODIUM TUNGSTATE, METHOD FOR COLLECTING TUNGSTEN, APPARATUS FOR PRODUCING SODIUM TUNGSTATE, AND METHOD FOR PRODUCING SODIUM TUNGSTATE AQUEOUS SOLUTION 有权
标题翻译：用于生产钨酸钠的方法，用于收集钨酸盐的方法，用于生产黄铁矿的方法，以及用于生产黄铁矿水溶液的方法
公开(公告)号：US20110300040A1
公开(公告)日：2011-12-08
申请号：US13140767
申请日：2010-03-05
申请人： Yoshiharu Yamamoto , Kazuo Sasaya , Takayuki Fudo , Akira Nakano , Syunsuke Yamanaka , Takahisa Iguchi , Fumiatsu Sato , Akihiko Ikegaya
发明人： Yoshiharu Yamamoto , Kazuo Sasaya , Takayuki Fudo , Akira Nakano , Syunsuke Yamanaka , Takahisa Iguchi , Fumiatsu Sato , Akihiko Ikegaya
IPC分类号： C01G41/00 , B01J19/00
CPC分类号： C22B34/36 , B01J8/10 , B01J19/28 , B01J2219/0004 , B01J2219/00132 , B01J2219/00157 , C01G23/005 , C01G35/00 , C01G37/02 , C01G37/14 , C01G41/00 , C01G41/003 , C01G41/02 , C01G51/42 , C01G53/42 , C01P2002/72 , C22B7/001 , C22B7/006 , Y02P10/214 , Y02P10/234 , Y02W30/54
摘要： Provided are a method for producing sodium tungstate by supplying an oxidant made of sodium nitrate or sodium nitrite to bring a tungsten containing material and the oxidant into contact with each other in an atmosphere containing oxygen to thereby continuously produce a reaction product; a method for collecting tungsten using the method; and an apparatus for producing sodium tungstate. Also provided are a method for producing a sodium tungstate aqueous solution in which a reductant is introduced into a melt containing the above-described reaction product which is then dissolved in water; and a method for collecting tungsten using the method.
摘要翻译：提供一种通过供给由硝酸钠或亚硝酸钠制成的氧化剂以使含钨材料和氧化剂在含氧气氛中相互接触从而连续产生反应产物来生产钨酸钠的方法; 采用该方法收集钨的方法; 以及生产钨酸钠的装置。还提供了一种生产钨酸钠水溶液的方法，其中将还原剂引入含有上述反应产物的熔体中，然后溶解在水中; 以及使用该方法收集钨的方法。

2. 发明授权

US08632747B2 Method for producing sodium tungstate, method for collecting tungsten, apparatus for producing sodium tungstate, and method for producing sodium tungstate aqueous solution 有权
标题翻译：钨酸钠的制造方法，钨的收集方法，钨酸钠的制造装置以及钨酸钠水溶液的制造方法
公开(公告)号：US08632747B2
公开(公告)日：2014-01-21
申请号：US13140767
申请日：2010-03-05
申请人： Yoshiharu Yamamoto , Kazuo Sasaya , Takayuki Fudo , Akira Nakano , Syunsuke Yamanaka , Takahisa Iguchi , Fumiatsu Sato , Akihiko Ikegaya
发明人： Yoshiharu Yamamoto , Kazuo Sasaya , Takayuki Fudo , Akira Nakano , Syunsuke Yamanaka , Takahisa Iguchi , Fumiatsu Sato , Akihiko Ikegaya
IPC分类号： C01G41/02
CPC分类号： C22B34/36 , B01J8/10 , B01J19/28 , B01J2219/0004 , B01J2219/00132 , B01J2219/00157 , C01G23/005 , C01G35/00 , C01G37/02 , C01G37/14 , C01G41/00 , C01G41/003 , C01G41/02 , C01G51/42 , C01G53/42 , C01P2002/72 , C22B7/001 , C22B7/006 , Y02P10/214 , Y02P10/234 , Y02W30/54
摘要： Provided are a method for producing sodium tungstate by supplying an oxidant made of sodium nitrate or sodium nitrite to bring a tungsten containing material and the oxidant into contact with each other in an atmosphere containing oxygen to thereby continuously produce a reaction product; a method for collecting tungsten using the method; and an apparatus for producing sodium tungstate. Also provided are a method for producing a sodium tungstate aqueous solution in which a reductant is introduced into a melt containing the above-described reaction product which is then dissolved in water; and a method for collecting tungsten using the method.
摘要翻译：提供一种通过供给由硝酸钠或亚硝酸钠制成的氧化剂以使含钨材料和氧化剂在含氧气氛中相互接触从而连续产生反应产物来生产钨酸钠的方法; 采用该方法收集钨的方法; 以及生产钨酸钠的装置。还提供了一种生产钨酸钠水溶液的方法，其中将还原剂引入含有上述反应产物的熔体中，然后溶解在水中; 以及使用该方法收集钨的方法。

3. 发明授权

US08974674B2 Method for producing ammonium tungstate aqueous solution 有权
标题翻译：钨酸铵水溶液的制备方法
公开(公告)号：US08974674B2
公开(公告)日：2015-03-10
申请号：US13582644
申请日：2010-03-05
申请人： Hideaki Ito , Takeshi Itakura , Yoshiharu Yamamoto , Kazuo Sasaya , Takuya Okuno , Fumiatsu Sato , Syunsuke Yamanaka , Akihiko Ikegaya
发明人： Hideaki Ito , Takeshi Itakura , Yoshiharu Yamamoto , Kazuo Sasaya , Takuya Okuno , Fumiatsu Sato , Syunsuke Yamanaka , Akihiko Ikegaya
IPC分类号： C01G41/00 , B01J49/00 , C02F1/42
CPC分类号： C01G41/00 , C01P2006/80 , G10L13/08 , G10L15/06 , G10L15/187
摘要： A method for producing an ammonium tungstate aqueous solution includes the steps of: adding sulfuric acid to a solution containing tungstate ions; bringing the solution having the sulfuric acid added therein, into contact with an anion exchange resin; and bringing the anion exchange resin into contact with an aqueous solution containing ammonium ions.
摘要翻译：制备钨酸铵水溶液的方法包括以下步骤：向含钨酸盐离子的溶液中加入硫酸; 将其中加入硫酸的溶液与阴离子交换树脂接触; 并使阴离子交换树脂与含有铵离子的水溶液接触。

4. 发明申请

US20120328506A1 METHOD FOR PRODUCING AMMONIUM TUNGSTATE AQUEOUS SOLUTION 有权
标题翻译：生产黄铁矿水溶液的方法
公开(公告)号：US20120328506A1
公开(公告)日：2012-12-27
申请号：US13582644
申请日：2010-03-05
申请人： Hideaki Ito , Takeshi Itakura , Yoshiharu Yamamoto , Kazuo Sasaya , Takuya Okuno , Fumiatsu Sato , Syunsuke Yamanaka , Akihiko Ikegaya
发明人： Hideaki Ito , Takeshi Itakura , Yoshiharu Yamamoto , Kazuo Sasaya , Takuya Okuno , Fumiatsu Sato , Syunsuke Yamanaka , Akihiko Ikegaya
IPC分类号： C01G41/02
CPC分类号： C01G41/00 , C01P2006/80 , G10L13/08 , G10L15/06 , G10L15/187
摘要： A method for producing an ammonium tungstate aqueous solution includes the steps of: adding sulfuric acid to a solution containing tungstate ions; bringing the solution having the sulfuric acid added therein, into contact with an anion exchange resin; and bringing the anion exchange resin into contact with an aqueous solution containing ammonium ions.
摘要翻译：制备钨酸铵水溶液的方法包括以下步骤：向含钨酸盐离子的溶液中加入硫酸; 将其中加入硫酸的溶液与阴离子交换树脂接触; 并使阴离子交换树脂与含有铵离子的水溶液接触。

5. 发明申请

US20120144753A1 CEMENTED CARBIDE AND CUTTING TOOL USING SAME 有权
标题翻译：使用相同的碳化物和切割工具
公开(公告)号：US20120144753A1
公开(公告)日：2012-06-14
申请号：US13390841
申请日：2010-08-11
申请人： Takuya Okuno , Kazuhiro Hirose , Hideki Moriguchi , Akihiko Ikegaya , Kazuo Sasaya , Yoshiharu Yamamoto
发明人： Takuya Okuno , Kazuhiro Hirose , Hideki Moriguchi , Akihiko Ikegaya , Kazuo Sasaya , Yoshiharu Yamamoto
IPC分类号： B24D3/04 , B24D3/08
CPC分类号： C22C29/08 , C22C14/00
摘要： There are provided a cemented carbide high in thermal diffusivity and excellent in wear resistance, and a cutting tool including a base material formed of this cemented carbide. The cemented carbide is a WC based cemented carbide in which a hard phase mainly constituted of WC grains is bound by a binder phase mainly constituted of Co, and is used for a cutting tool. The binder phase is substantially constituted of Co, or Co and Ni. A total content of Co and Ni is not less than 4.5 mass % and not more than 15 mass %. In this cemented carbide, the WC grains have an average diameter of not less than 0.4 μm and not more than 4 μm.
摘要翻译：提供了热扩散性高且耐磨性优异的硬质合金，以及包括由该硬质合金形成的基材的切削工具。硬质合金是WC基硬质合金，其中主要由WC颗粒构成的硬质相主要由Co组成的粘合剂相结合，并用于切削工具。粘结相基本上由Co或Co和Ni构成。 Co和Ni的总含量不小于4.5质量％且不大于15质量％。在这种硬质合金中，WC颗粒的平均直径不小于0.4μm且不大于4μm。

6. 发明授权

US08801816B2 Cemented carbide and cutting tool using same 有权
标题翻译：硬质合金和切削刀具使用相同
公开(公告)号：US08801816B2
公开(公告)日：2014-08-12
申请号：US13390841
申请日：2010-08-11
申请人： Takuya Okuno , Kazuhiro Hirose , Hideki Moriguchi , Akihiko Ikegaya , Kazuo Sasaya , Yoshiharu Yamamoto
发明人： Takuya Okuno , Kazuhiro Hirose , Hideki Moriguchi , Akihiko Ikegaya , Kazuo Sasaya , Yoshiharu Yamamoto
IPC分类号： B24B1/00 , B24D11/00
CPC分类号： C22C29/08 , C22C14/00
摘要： There are provided a cemented carbide high in thermal diffusivity and excellent in wear resistance, and a cutting tool including a base material formed of this cemented carbide. The cemented carbide is a WC based cemented carbide in which a hard phase mainly constituted of WC grains is bound by a binder phase mainly constituted of Co, and is used for a cutting tool. The binder phase is substantially constituted of Co, or Co and Ni. A total content of Co and Ni is not less than 4.5 mass % and not more than 15 mass %. In this cemented carbide, the WC grains have an average diameter of not less than 0.4 μm and not more than 4 μm.
摘要翻译：提供了热扩散性高且耐磨性优异的硬质合金，以及包括由该硬质合金形成的基材的切削工具。硬质合金是WC基硬质合金，其中主要由WC颗粒构成的硬质相主要由Co组成的粘合剂相结合，并用于切削工具。粘结相基本上由Co或Co和Ni构成。 Co和Ni的总含量不小于4.5质量％且不大于15质量％。在这种硬质合金中，WC颗粒的平均直径不小于0.4μm且不大于4μm。

7. 发明授权

US06881475B2 Amorphous carbon coated tool and fabrication method thereof 有权
标题翻译：无定形碳涂层工具及其制造方法
公开(公告)号：US06881475B2
公开(公告)日：2005-04-19
申请号：US10167770
申请日：2002-06-11
申请人： Satoshi Ohtani , Naoto Okazaki , Kiyoshi Ogata , Haruyo Fukui , Miki Irie , Yoshiharu Utsumi , Hisanori Ohara , Hideki Moriguchi , Akihiko Ikegaya , Keiichi Tsuda , Makoto Setoyama
发明人： Satoshi Ohtani , Naoto Okazaki , Kiyoshi Ogata , Haruyo Fukui , Miki Irie , Yoshiharu Utsumi , Hisanori Ohara , Hideki Moriguchi , Akihiko Ikegaya , Keiichi Tsuda , Makoto Setoyama
IPC分类号： C23C16/26 , C23C14/02 , C23C14/06 , C23C30/00 , B23B27/14
CPC分类号： C23C14/022 , C23C14/0605 , C23C30/005 , Y10T407/27 , Y10T408/78 , Y10T428/24479 , Y10T428/24628 , Y10T428/24942 , Y10T428/24975 , Y10T428/265 , Y10T428/30
摘要： An amorphous carbon coated tool includes a base material of WC base cemented carbide, and an amorphous carbon film formed on this base material. The cobalt content in the base material is at least 12% by mass. The maximum thickness of the amorphous carbon film is at least 0.05 μm and not more than 0.5 μm at the cutting edge. The amorphous carbon film is deposited with graphite as the source material by physical vapor deposition in an atmosphere substantially absent of hydrogen. The amorphous carbon film coated tool superior in wear resistance and adhesion resistance is preferably applicable to rotating tools such as drills, end mills and reamers, indexable inserts used for milling cutters and turning tools, and cutting-off tools such as cutters, knives, or slitters.
摘要翻译：无定形碳涂覆工具包括WC基底硬质合金的基材和在该基材上形成的无定形碳膜。基材中的钴含量为12质量％以上。无定形碳膜的最大厚度在切割边缘处为至少0.05μm和不大于0.5μm。无定形碳膜通过物理气相沉积在基本上不含氢的气氛中作为源材料沉积。优异的耐磨性和耐粘附性的无定形碳膜涂布工具优选适用于诸如钻头，立铣刀和铰刀的旋转工具，用于铣刀和车刀的可转位刀片，以及切割工具，例如刀具，刀具或切割机。

8. 发明授权

US06293739B1 Coated cemented carbide cutting tool 有权
标题翻译：涂层硬质合金刀具
公开(公告)号：US06293739B1
公开(公告)日：2001-09-25
申请号：US09423353
申请日：1999-11-23
申请人： Katsuya Uchino , Akihiko Ikegaya
发明人： Katsuya Uchino , Akihiko Ikegaya
IPC分类号： B23B2714
CPC分类号： C23C30/005 , Y10T407/26 , Y10T407/27 , Y10T428/24975
摘要： The invention is to prolong the life time of tools dramatically by (1) considerably improving the flaking resistance of the coating layer at the time of cutting, (2) increasing the wear resistance and crater resistance of the coating layer itself, and (3) enhancing the breakage strength of the coating layer in comparison with the conventional coating cutting tools. In order to achieve the object, the coated cemented carbide of the invention has the following structure in the coating layer on the surface of the cemented carbides: The outer layer has an Al2O3 layer practically having an &agr;-type crystal structure. The Al2O3 layer has a region where &agr;-type and &kgr;-type crystal grains coexist in the first row of the crystal grains that grow on the inner layer. In addition to that, the crystal grains of &agr;-Al2O3 in the region include no pores.
摘要翻译：本发明是通过（1）大大提高切割时涂层的耐剥落性，（2）提高涂层本身的耐磨性和耐火蚀性，从而显着延长刀具的使用寿命;（3）与常规的涂层切割工具相比，增强了涂层的断裂强度。为了实现该目的，本发明的涂覆硬质合金在硬质合金表面的涂层中具有以下结构：外层具有实际上具有α型晶体结构的Al 2 O 3层。 Al 2 O 3层具有在内层上生长的第一排晶粒中的α型和κ型晶粒共存的区域。除此之外，该区域中的α-Al 2 O 3的晶粒不包括孔。

9. 发明授权

US6082936A Coated hard metal tool 失效
标题翻译：涂硬质工具
公开(公告)号：US6082936A
公开(公告)日：2000-07-04
申请号：US871367
申请日：1997-06-09
申请人： Hideki Moriguchi , Akihiko Ikegaya
发明人： Hideki Moriguchi , Akihiko Ikegaya
IPC分类号： B23B27/14 , B23P15/28 , C23C30/00
CPC分类号： B23B27/145 , B23P15/28 , C23C30/005 , B23B2200/242 , B23B2200/245 , Y10T407/26 , Y10T407/27 , Y10T407/28
摘要： A coated hard metal tool includes a hard metal base material having an edged part on an insert ridge portion defining a connecting portion between a flank and a rake face, and a coating film applied to a surface of the hard metal base material. The coating film has a surface-treated part on the insert ridge portion. The coating film is so formed that Rc1/(Rs1+d) 1.0, wherein Rs1 represents the radius of curvature of a convex curved surface formed on the boundary between the flank and the edged part on the surface of the hard metal base material, Rc1 represents the radius of curvature of a convex curved surface formed on the boundary between the flank and the surface-treated part, Rs2 represents the radius of curvature of a convex curved surface formed on the boundary between the rake face and the edged part on the surface of the hard metal base material, Rc2 represents the radius of curvature of a convex curved surface formed on the boundary between the rake face and the surface-treated part, and d represents the average thickness of the coating film in a region other than the edged part. According to this structure, a coated hard metal tool having a long life which is improved in wear resistance with no damage on its breakage resistance can be provided.
摘要翻译：涂覆的硬金属工具包括硬质金属基材，其具有限定在侧面和前刀面之间的连接部分的插入脊部分上的边缘部分，以及施加到硬质金属基材的表面的涂膜。涂膜在插入脊部分上具有表面处理部分。该涂膜形成为Rc1 /（Rs1 + d）<1.0和Rc2 /（Rs2 + d）> 1.0，其中Rs1表示形成在侧面和边缘部分之间的边界上的凸曲面的曲率半径在硬质金属基材的表面上，Rc1表示形成在侧面和表面处理部分之间的边界上的凸曲面的曲率半径，Rs2表示形成在边界上的凸曲面的曲率半径在硬质金属基材的表面上的前刀面和边缘部分之间，Rc2表示形成在前刀面和表面处理部之间的边界上的凸曲面的曲率半径，d表示平均厚度在除了边缘部分之外的区域中的涂膜。根据该结构，可以提供寿命长的涂层硬质金属工具，其耐磨性提高，其耐破坏性不受损害。

10. 发明授权

US5597272A Coated hard alloy tool 失效
标题翻译：涂层硬质合金工具
公开(公告)号：US5597272A
公开(公告)日：1997-01-28
申请号：US427601
申请日：1995-04-24
申请人： Hideki Moriguchi , Daisuke Murakami , Akihiko Ikegaya , Toshio Nomura
发明人： Hideki Moriguchi , Daisuke Murakami , Akihiko Ikegaya , Toshio Nomura
IPC分类号： B23B27/14 , B23C5/20 , C23C16/40 , C23C16/56 , C23C30/00
CPC分类号： C23C16/56 , B23B27/145 , B23C5/207 , C23C16/403 , C23C30/005 , B23B2200/202 , B23B2224/04 , B23B2224/32 , B23B2224/36 , B23C2200/201 , B23C2200/203 , B23C2200/243 , B23C2224/04 , B23C2224/32 , B23C2224/36 , Y10T407/27 , Y10T407/28 , Y10T408/78 , Y10T408/81 , Y10T428/24355 , Y10T428/24413 , Y10T428/24802 , Y10T428/24926
摘要： An improved coated hard alloy tool having a substrate made of a hard alloy, and a multi-layer ceramic coating film provided on the surface of the substrate, the coating film including at least one oxide layer. The top several layers of the coating film are missing partially or completely in an area where the tool is brought into frictional contact with a workpiece. At least one oxide layer (such as Al.sub.2 O.sub.3 layer) is included in the missing layers. This increases wear resistance of the coated hard alloy tool.
摘要翻译：一种改进的涂覆硬质合金工具，其具有由硬质合金制成的基底，以及设置在该基底表面上的多层陶瓷涂膜，所述涂膜包括至少一层氧化物层。在工件与工件摩擦接触的区域中，涂层的顶部几层部分或完全缺失。缺失层中包含至少一层氧化物层（如Al2O3层）。这增加了涂层硬质合金工具的耐磨性。

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