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    • 2. 发明授权
    • Glass material suitable for a waveguide of an optical amplifier
    • 适用于光放大器波导的玻璃材料
    • US06413891B1
    • 2002-07-02
    • US09689394
    • 2000-10-11
    • Doo-Hee ChoYong-Gyu ChoiKyong-Hon Kim
    • Doo-Hee ChoYong-Gyu ChoiKyong-Hon Kim
    • C03C312
    • C03C13/048C03C3/122C03C3/253H01S3/177
    • Glasses of the present invention are tellurite and oxyhalide glasses doped with rare-earth ion, which can be applied to highly efficient optical amplifiers and lasers for optical communication. They are thermally and chemically stable during and after the fabrication processes of the optical fiber. The glass material includes 20˜70 mole % of TeO2, a heavy metal oxide, 0.001˜10 mole % of a rare earth ion dopant, 5˜30 mole % of MO, M being selected from a group consisting of Mg, Ca, Sr, Ba, Zn and Pb, and optionally 1˜20 mole % of R2O, R being selected from a group consisting of Li, Na, K, Rb and Cs. In the composition of the glass, 3˜18 mole % of MO and R2O may be substituted by the metal halides. The glasses of the present invention are similar in phonon energy to the conventional tellurite glasses not to increase the non-radiative transition rate. Further, the fluorescence lifetime is additionally increased in case of partial substitution of oxide to halide.
    • 本发明的玻璃是掺杂有稀土离子的碲酸盐和卤氧化物玻璃,其可以应用于用于光通信的高效光放大器和激光器。 它们在光纤的制造过程中和之后是热和化学稳定的。 玻璃材料包括20〜70摩尔%的TeO 2,重金属氧化物,0.001〜10摩尔%的稀土离子掺杂剂,5〜30摩尔%的MO,M选自Mg,Ca,Sr ,Ba,Zn和Pb,以及任选的1-20摩尔%的R 20,R选自Li,Na,K,Rb和Cs。 在玻璃的组成中,3〜18摩尔%的MO和R2O可以被金属卤化物取代。 本发明的玻璃在声子能量方面与常规的碲化物玻璃类似,不增加非辐射跃迁速率。 此外,在将氧化物部分置换为卤化物的情况下,荧光寿命另外增加。