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1. 发明授权

US07691483B2 Resin-coated metal sheet 失效
标题翻译：树脂涂层金属板
公开(公告)号：US07691483B2
公开(公告)日：2010-04-06
申请号：US10594533
申请日：2005-03-30
申请人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinsuke Watanabe , Mitsunori Ota
发明人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinsuke Watanabe , Mitsunori Ota
IPC分类号： B32B15/09 , B32B27/08
CPC分类号： C23C28/00 , B32B15/08 , B32B27/08 , B32B27/36 , B32B2307/4026 , B32B2307/518 , B32B2307/704 , B32B2307/728 , B32B2439/66 , B32B2439/70 , C09D167/02 , Y10T428/24942 , Y10T428/26 , Y10T428/265 , Y10T428/31678 , Y10T428/31681
摘要： The resin-coated metal sheet is composed of: a metal sheet; a lower resin layer containing a hydrophilic copolyester, formed on at least one side of the metal sheet; and an upper resin layer containing a polyester containing a diol component composed of a diol derivative of 1 to 10% by mole of alicyclic compound and 99 to 90% by mole of ethylene glycol, and a dicarboxylic acid component consisting of terephthalic acid, formed on the lower resin layer. The sum of cyclic trimer of alkylene terephthalate existing in the upper resin layer and the lower resin layer is 0.9% or less by mass. Since the manufacture of food cans using the resin-coated metal sheet does not induce white haze phenomenon and retort blushing phenomenon on outer surface of the can even after retorting, the decorative appearance on outer surface of the can is not deteriorated.
摘要翻译：树脂被覆金属片由金属片构成，在所述金属板的至少一侧形成含有亲水性共聚酯的下层树脂层; 和含有由二醇衍生物构成的二醇成分的聚酯的上层树脂层，所述二醇成分由脂环族化合物为1〜10摩尔％的二醇衍生物和99〜90摩尔％的乙二醇构成，以及由对苯二甲酸组成的二羧酸成分，下层树脂层。存在于上树脂层和下树脂层中的对苯二甲酸亚烷基酯的环状三聚体的总和为0.9质量％以下。由于使用树脂涂覆金属片的食品罐的制造即使在蒸煮后也不会引起罐外表面的白霾现象和蒸煮发白现象，所以罐外表面的装饰外观不会变差。

2. 发明申请

US20080261063A1 Resin-Coated Metal Sheet 审中-公开
标题翻译：树脂涂层金属板
公开(公告)号：US20080261063A1
公开(公告)日：2008-10-23
申请号：US11579795
申请日：2005-05-18
申请人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Katsunori Nakai , Mitsunori Ota
发明人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Katsunori Nakai , Mitsunori Ota
IPC分类号： B32B27/36
CPC分类号： B32B15/09 , B32B1/02 , B32B15/08 , B32B27/08 , B32B27/18 , B32B27/36 , B32B2309/105 , B32B2439/66 , B65D65/42 , Y10T428/31797
摘要： The resin-coated metal sheet has: a metal sheet; a lower polyester resin layer having 0.03 or smaller plane orientation factor and 5 to 20 μm of thickness, being formed on at least one side of the metal sheet; and an upper polyester resin layer containing 0.1 to 5% by mass of olefin wax, having larger than 0.06 and not larger than 0.15 of plane orientation factor and 0.5 to 10 μm of thickness, being formed on the lower polyester resin layer. The metal sheet assures excellent taking-out performance of the contents also those of low fat and high protein foods, and provides formability and adhesion requested for the container working.
摘要翻译：树脂涂覆的金属片具有：金属片; 在金属片的至少一面上形成具有0.03或更小的平面取向因子和5至20μm的厚度的下聚酯树脂层; 并且在下聚酯树脂层上形成含有0.1〜5质量％以上的具有大于0.06且不大于0.15的面取向因子和0.5至10微米厚度的烯烃蜡的上聚酯树脂层。金属片材确保了低脂肪和高蛋白食品的内容物的良好的取出性能，并提供了容器加工所需的成形性和粘合性。

3. 发明申请

US20070202309A1 Resin-Coated Metal Sheet 失效
标题翻译：树脂涂层金属板
公开(公告)号：US20070202309A1
公开(公告)日：2007-08-30
申请号：US10594533
申请日：2005-03-30
申请人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinuke Watanabe , Mitsunori Ota
发明人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinuke Watanabe , Mitsunori Ota
IPC分类号： B32B7/02
CPC分类号： C23C28/00 , B32B15/08 , B32B27/08 , B32B27/36 , B32B2307/4026 , B32B2307/518 , B32B2307/704 , B32B2307/728 , B32B2439/66 , B32B2439/70 , C09D167/02 , Y10T428/24942 , Y10T428/26 , Y10T428/265 , Y10T428/31678 , Y10T428/31681
摘要： The resin-coated metal sheet is composed of: a metal sheet; a lower resin layer containing a hydrophilic copolyester, formed on at least one side of the metal sheet; and an upper resin layer containing a polyester containing a diol component composed of a diol derivative of 1 to 10% by mole of alicyclic compound and 99 to 90% by mole of ethylene glycol, and a dicarboxylic acid component consisting of terephthalic acid, formed on the lower resin layer. The sum of cyclic trimer of alkylene terephthalate existing in the upper resin layer and the lower resin layer is 0.9% or less by mass. Since the manufacture of food cans using the resin-coated metal sheet does not induce white haze phenomenon and retort blushing phenomenon on outer surface of the can even after retorting, the decorative appearance on outer surface of the can is not deteriorated.
摘要翻译：树脂被覆金属片由金属片构成，在所述金属板的至少一侧形成含有亲水性共聚酯的下层树脂层; 和含有由二醇衍生物构成的二醇成分的聚酯的上层树脂层，所述二醇成分由脂环族化合物为1〜10摩尔％的二醇衍生物和99〜90摩尔％的乙二醇构成，以及由对苯二甲酸组成的二羧酸成分，下层树脂层。存在于上树脂层和下树脂层中的对苯二甲酸亚烷基酯的环状三聚体的总和为0.9质量％以下。由于使用树脂涂覆金属片的食品罐的制造即使在蒸煮后也不会引起罐外表面的白霾现象和蒸煮发白现象，所以罐外表面的装饰外观不会变差。

4. 发明授权

US5391290A Method for continuously tin-electroplating metal strip 失效
标题翻译：连续锡电镀金属条的方法
公开(公告)号：US5391290A
公开(公告)日：1995-02-21
申请号：US38529
申请日：1993-03-29
申请人： Mikiyuki Ichiba , Hiroki Iwasa , Toyofumi Watanabe , Masaaki Yamashita , Katsumi Kojima
发明人： Mikiyuki Ichiba , Hiroki Iwasa , Toyofumi Watanabe , Masaaki Yamashita , Katsumi Kojima
IPC分类号： C25D3/32 , C25D5/20
CPC分类号： C25D5/20 , C25D3/32
摘要： A method for continuously tin-electroplating a metal strip, which comprises the steps of: causing a DC electric current to flow between a metal strip and an anode arranged adjacent to the metal strip while passing the metal strip at a travelling speed of at least 1 m/minute through an acidic tin-electroplating solution containing tin ions and an organic acid within a range of from 4.8 to 98 g/l as converted into sulfuric acid, to form a tin-electroplating layer on at least one surface of the metal strip; and applying an ultrasonic vibration, emitted from at least one ultrasonic vibrator and having an intensity within a range of from 0.01 to 1,000 W/100 cm.sup.2 and a frequency within a range of from 25 to 55 kHz, to the acidic tin-electroplating solution between the metal strip and the anode, thereby removing a diffusion layer of tin ions existing in the acidic tin-electroplating solution adjacent to the surface of the metal strip.
摘要翻译：一种用于连续锡电镀金属带的方法，其特征在于包括以下步骤：使金属带与邻近金属带布置的阳极之间的直流电流流动，同时使金属带以至少1的行进速度通过 m /分钟，通过含有锡离子和有机酸的酸性锡 - 电镀溶液，其转化为硫酸在4.8至98g / l的范围内，以在金属带的至少一个表面上形成锡 - 电镀层 ; 将从至少一个超声波振子发射的强度为0.01〜1000W / 100cm 2，频率范围为25〜55kHz的超声波振动施加到酸性锡 - 电镀液金属带和阳极，从而除去存在于与金属带的表面相邻的酸性锡 - 电镀溶液中的锡离子的扩散层。

5. 发明授权

US5275716A Method for manufacturing tin-electroplated cold-rolled steel strip 失效
标题翻译：镀锡冷轧钢带的制造方法
公开(公告)号：US5275716A
公开(公告)日：1994-01-04
申请号：US029781
申请日：1993-03-11
申请人： Katsumi Kojima , Mikiyuki Ichiba , Hiroki Iwasa , Toyofumi Watanabe
发明人： Katsumi Kojima , Mikiyuki Ichiba , Hiroki Iwasa , Toyofumi Watanabe
IPC分类号： C25D5/48 , C25D7/06
CPC分类号： C25D5/48
摘要： A method for manufacturing a tin-electroplated cold-rolled steel strip, which comprises the steps of: continuously annealing a degreased cold-rolled steel strip; then, subjecting, following the continuous annealing treatment, the continuously annealed cold-rolled steel strip to a continuous tin-electroplating treatment in a tin-electroplating bath to form, on at least one surface of the cold-rolled steel strip, a tin-electroplating layer having a plating weight within a range of from 0.1 to 2.8 g/m.sup.2 per surface of the cold-rolled steel strip; and then, temper-rolling, following the continuous tin-electroplating treatment, the cold-rolled steel strip having the tin-electroplating layer on at least one surface thereof, at a reduction ratio within a range of from 1 to 5%.
摘要翻译：一种用于制造镀锡冷轧钢带的方法，包括以下步骤：连续退火脱脂冷轧钢带; 然后，在连续退火处理之后，使连续退火的冷轧钢带在锡 - 电镀浴中进行连续锡电镀处理，以在冷轧钢带的至少一个表面上形成锡 - 电镀层，其镀层重量在冷轧钢带表面0.1〜2.8g / m2的范围内; 然后在连续锡电镀处理之后，在其至少一个表面上具有锡 - 电镀层的冷轧钢带以1％至5％的范围内的压缩比进行回火。

6. 发明授权

US4875984A Method for manufacturing electrolytically chromated steel sheet 失效
标题翻译：电解铬酸盐钢板的制造方法
公开(公告)号：US4875984A
公开(公告)日：1989-10-24
申请号：US309683
申请日：1989-02-10
申请人： Hiroki Iwasa , Toyofumi Watanabe , Hirohide Furuya
发明人： Hiroki Iwasa , Toyofumi Watanabe , Hirohide Furuya
IPC分类号： C25D11/38
CPC分类号： C25D11/38
摘要： A method for manufacturing an electrolytically chromated steel sheet, comprising the steps of: subjecting a steel sheet to an anodic electrolytic treatment with a quantity of electricity of from 0.3 to 30 coulomb/dm.sup.2 in an acidic electrolyte containing at least one of chromic anhydride, chromate and bichromate, to form a hydrated chromium oxide film having numerous holes and numerous thin portions over the entire area of at least one surface of the steel sheet; and then subjecting the anodically treated steel sheet to a cathodic electrolytic chromate treatment in an acidic electrolytic chromating solution to form on the at least one surface of the steel sheet a chromate film comprising a metallic chromium layer as a lower layer having thereon numerous granular projections, and a hydrated chromium oxide layer as an upper layer. The electrolytically chromated steel sheet manufactured in accordance with the method of the present invention has excellent secondary paint adhesion and weldability, and has a satisfactory surface hue.

7. 发明授权

US4898649A Method for manufacturing electrolytically chromated steel sheet 失效
标题翻译：电解铬酸盐钢板的制造方法
公开(公告)号：US4898649A
公开(公告)日：1990-02-06
申请号：US309774
申请日：1989-02-10
申请人： Hiroki Iwasa , Toyofumi Watanabe , Hirohide Furuya
发明人： Hiroki Iwasa , Toyofumi Watanabe , Hirohide Furuya
IPC分类号： C25D11/38
CPC分类号： C25D11/38 , C25D9/06 , C25D9/10
摘要： A method for manufacturing an electrolytically chromated steel sheet, comprising the steps of: subjecting a steel sheet intermittently to a plurality of runs of cathodic electrolytic chromate treatment in an acidic electrolytic chromating solution. At least one of these plurality of runs of cathodic electrolytic chromate treatment is carried out at a high electric current density within the range of from 90 to 200 A/dm.sup.2, to form on at least one surface of the steel sheet a chromating film comprising a metallic chromium layer as a lower layer having numerous granular projections over the entire surface thereof, and a hydrated chromium oxide layer as an upper layer. The electrolytically chromated steel sheet manufactured in accordance with the method of the present invention is excellent in a secondary paint adhesion and a weldability, and has a satisfactory surface hue.

8. 发明授权

US5500290A Surface treated steel sheet 失效
标题翻译：表面处理钢板
公开(公告)号：US5500290A
公开(公告)日：1996-03-19
申请号：US265239
申请日：1994-06-24
申请人： Satoru Udagawa , Masaki Abe , Satoru Ando , Yasuhiro Matsuki , Toyofumi Watanabe , Yukimitsu Shiohara , Masaya Morita , Akimasa Kido
发明人： Satoru Udagawa , Masaki Abe , Satoru Ando , Yasuhiro Matsuki , Toyofumi Watanabe , Yukimitsu Shiohara , Masaya Morita , Akimasa Kido
IPC分类号： C21D8/04 , C23C2/02 , B32B15/18
CPC分类号： C21D8/0426 , C23C2/02 , C21D8/0436 , C21D8/0478 , Y10S428/941 , Y10T428/12458 , Y10T428/12792 , Y10T428/12799 , Y10T428/12937
摘要： A surface treated steel sheet comprises: a steel sheet containing C, Si, Mn, P, S, Ni, Ti, Cu and B; a diffused alloy layer containing Fe, Ni, and P; and a zinc coating layer formed on the diffused alloy layer.A method for producing a surface treated steel sheet comprises the steps of: preparing a steel sheet; coating the steel sheet with a Ni-P coating layer; heat-treating the steel sheet coated with the Ni-P coating layer; and forming a zinc coating layer on the diffused alloy layer.
摘要翻译：表面处理钢板包括：含有C，Si，Mn，P，S，Ni，Ti，Cu和B的钢板; 含Fe，Ni和P的扩散合金层; 以及形成在扩散合金层上的锌涂层。一种表面处理钢板的制造方法，其特征在于，包括以下工序：制造钢板; 用Ni-P涂层涂覆钢板; 对涂覆有Ni-P涂层的钢板进行热处理; 并在扩散合金层上形成锌涂层。

9. 发明授权

US5494706A Method for producing zinc coated steel sheet 失效
标题翻译：镀锌钢板的制造方法
公开(公告)号：US5494706A
公开(公告)日：1996-02-27
申请号：US263088
申请日：1994-06-21
申请人： Masaki Abe , Satoru Ando , Toyofumi Watanabe , Yukimitsu Shiohara
发明人： Masaki Abe , Satoru Ando , Toyofumi Watanabe , Yukimitsu Shiohara
IPC分类号： C23C2/02 , C25D15/02
CPC分类号： C23C2/02
摘要： A method for producing zinc coated steel sheet comprises the steps of: forming a Ni--P alloy coating layer containing P of 8 to 15 wt. % on at least one surface of a steel sheet; heat-treating the steel sheet coated with the alloy layer in a non-oxidizing atmosphere to form an Fe--Ni--P diffused alloy layer at an interface of the steel sheet and the alloy coating layer; and zinc coating the steel sheet coated with the diffused alloy layer to form a zinc coating layer.
摘要翻译：制造镀锌钢板的方法包括以下步骤：形成含有8〜15重量％的P的Ni-P合金涂层。％在钢板的至少一个表面上; 在非氧化性气氛中对涂有合金层的钢板进行热处理，在钢板和合金涂层的界面形成Fe-Ni-P扩散合金层; 并涂覆涂有扩散合金层的钢板以形成锌涂层。

10. 发明授权

US5458764A Method of manufacturing plated steel sheet with zn-cr alloy plating 失效
标题翻译：用zn-cr合金电镀制造电镀钢板的方法
公开(公告)号：US5458764A
公开(公告)日：1995-10-17
申请号：US188212
申请日：1994-01-27
申请人： Takayuki Urakawa , Satoru Ando , Toyofumi Watanabe
发明人： Takayuki Urakawa , Satoru Ando , Toyofumi Watanabe
IPC分类号： C25D3/56 , C25D3/22 , C25D3/06 , C25D3/10
CPC分类号： C25D3/565
摘要： There is disclosed a method of manufacturing a plated steel sheet with a Zn--Cr alloy plating, including the steps of preparing a plating bath having a pH of 1 to 3 by adding 50 to 250 g/l of ammonium sulfate to a sulfuric acid plating bath and forming a Zn--Cr alloy plating film on a steel sheet using the resultant plating bath.
摘要翻译：公开了一种用Zn-Cr合金电镀制造镀覆钢板的方法，包括以下步骤：通过向硫酸镀层中加入50至250g / l的硫酸铵来制备pH为1至3的镀浴使用所得的电镀浴在钢板上形成Zn-Cr合金镀膜。

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