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    • 9. 发明授权
    • Pyrone-3-carboxamide compounds and herbicidal composition thereof
    • 吡喃-3-甲酰胺化合物及其除草组合物
    • US4886546A
    • 1989-12-12
    • US24348
    • 1987-03-11
    • Hiroshi YagiharaYukihisa GotoKazuhisa MasamotoYasuo MorishimaHirokazu Osabe
    • Hiroshi YagiharaYukihisa GotoKazuhisa MasamotoYasuo MorishimaHirokazu Osabe
    • A01N43/16A01N43/40C07D309/38C07D311/74C07D311/94C07D401/04C07D405/04
    • C07D401/04A01N43/16A01N43/40C07D309/38C07D311/74C07D311/94
    • A compound of the formula (I) ##STR1## wherein (1) when R.sub.1 is a C.sub.2-11 alkyl, a lower alkenyl, a lower alkynyl, a cycloalkyl, a lower alkoxyalkyl, an aralkyl which may be substituted, a lower haloalkyl or a 5 or 6 membered heterocycle;R.sub.2, R.sub.3 and R.sub.4 are the same or different, hydrogen, a halogen, cyano, nitro, amino, a lower alkyl, a lower haloalkyl, hydroxy, a lower alkoxy, an aryloxy, carboxy, or a lower alkoxycarbonyl;R.sub.5 is hydrogen, a halogen, a C.sub.1-11 alkyl, an aryl which may be substituted, an aralkyl which may be substituted;R.sub.6 is a C.sub.1-11 alkyl, a lower alkenyl, a lower alkynyl, a cycloalkyl, a lower alkoxyalkyl, an aryl which may be substituted, an aralkyl which may be substituted, a lower haloalkyl, or a 5 or 6 membered heterocycle; or R.sub.5 and R.sub.6 may be combined to form a group of --(CH.sub.2).sub.m -- (m is 3 or 4);(2) when R.sub.1 is an aryl which may be substituted;R.sub.2, R.sub.3, R.sub.4 and R.sub.5 have the same meanings as defined above; R.sub.6 is a C.sub.1-11 alkyl, a lower alkenyl, a lower alkynyl, a cycloalkyl, a lower alkoxyalkyl, an aralkyl which may be substituted, a haloalkyl or a 5 or 6 membered heterocycle, or R.sub.5 and R.sub.6 may be combined to form a group of --(CH.sub.2).sub.m -- (m is 3 or 4);(3) when R.sub.1 is methyl;R.sub.2, R.sub.3, R.sub.4 and R.sub.5 have the same meanings as defined above; R.sub.6 is a C.sub.2-12 alkyl, a lower alkenyl, a lower alkynyl, a cycloalkyl, a lower alkoxyalkyl, an aryl which may be substituted, an aralkyl which may be substituted, a lower haloalkyl or a 5 or 6 membered heterocycle or R.sub.5 and R.sub.6 may be combined to form a group of --(CH.sub.2).sub.m -- (m is 3 or 4); or(4) when R.sub.1 and R.sub.6 are methyl;R.sub.2, R.sub.3 and R.sub.4 have the same meanings as defined above; R.sub.5 is a halogen, a C.sub.1-11 alkyl, an aryl which may be substituted or an aralkyl which may be substituted, which is useful as herbicide.
    • 式(I)化合物其中(1)当R 1为C 2-11烷基时,低级链烯基,低级炔基,环烷基,低级烷氧基烷基,可被取代的芳烷基, 低级卤代烷基或5或6元杂环; R2,R3和R4相同或不同,氢,卤素,氰基,硝基,氨基,低级烷基,低级卤代烷基,羟基,低级烷氧基,芳氧基,羧基或低级烷氧基羰基。 R5是氢,卤素,C1-11烷基,可被取代的芳基,可被取代的芳烷基; R6是C1-11烷基,低级烯基,低级炔基,环烷基,低级烷氧基烷基,可被取代的芳基,可被取代的芳烷基,低级卤代烷基或5或6元杂环; 或者R 5和R 6可以组合形成 - (CH 2)m - (m为3或4)的基团。 (2)当R1是可被取代的芳基时; R2,R3,R4和R5具有与上述相同的含义; R6是C1-11烷基,低级烯基,低级炔基,环烷基,低级烷氧基烷基,可被取代的芳烷基,卤代烷基或5或6元杂环,或者R5和R6可以组合形成 - (CH 2)m - (m为3或4); (3)当R1为甲基时; R2,R3,R4和R5具有与上述相同的含义; R6是C2-12烷基,低级链烯基,低级炔基,环烷基,低级烷氧基烷基,可被取代的芳基,可被取代的芳烷基,低级卤代烷基或5或6元杂环或R5和 R6可以组合形成 - (CH 2)m - (m为3或4)的基团。 或(4)当R 1和R 6为甲基时; R2,R3和R4具有与上述相同的含义; R5是卤素,C1-11烷基,可被取代的芳基或可被取代的芳烷基,其可用作除草剂。
    • 10. 发明授权
    • Pyridine-3-carboxamide derivatives
    • 吡啶-3-甲酰胺衍生物
    • US4844732A
    • 1989-07-04
    • US922038
    • 1986-10-20
    • Yukihisa GotoKazuhisa MasamotoHiroshi YagiharaYasuo MorishimaHirokazu Osabe
    • Yukihisa GotoKazuhisa MasamotoHiroshi YagiharaYasuo MorishimaHirokazu Osabe
    • A61K31/44A01N43/40A01N43/42A61K31/4402A61K31/4418A61K31/4425A61K31/443A61K31/455A61K31/47A61P29/00C07D213/22C07D213/82C07D213/89C07D215/56C07D401/04C07D405/04C07D405/06
    • C07D213/82A01N43/40C07D401/04C07D405/04
    • A compound of the formula (I) ##STR1## or a salt thereof, wherein R is hydrogen atom, phenyl group which may be substituted freely or a group of --(CH.sub.2).sub.n --R.sub.1 wherein n is an interger from 1 to 3 and R.sub.1 is hydrogen atom, hydroxy group, lower alkoxy group, mercapto group, lower alkylthio group, amino group, di-lower alkylamino group, C.sub.3-11 alkyl group, lower alkenyl group, lower alkynyl group, cycloalkyl group, 5- or 6-membered heterocyclic group, or phenyl group which may be substituted by one or two substituents of halogen, lower alkyl or lower alkoxy; R.sub.2 and R.sub.7 are different, hydrogen atom, C.sub.1-11 alkyl group, lower alkenyl group, lower alkynyl group, cycloalkyl group, lower alkoxyalkyl group, lower alkylthioalkyl group, phenyl group whch may be substiuted freely, aralkyl group whose nucleus may be substituted by one or two substituents of halogen, lower alkyl or lower alkoxy or haloalkyl gorup or 5- or 6-membered heterocyclic group; R.sub.3, R.sub.4 and R.sub.5 are, the same or different, hydrogen atom, halogen atom, cyano group, nitro group, amino group, lower alkyl group, lower haloalkyl group, hydroxy group, lower alkoxygroup, aryloxy group, carboxy group or lower alkoxycarbonyl group; R.sub.6 is hydrogen atom, halogen atom, lower alkyl group, phenyl group which may be substituted freely or aralkyl group which may be substituted freely; or R.sub.6 and R.sub.7 may be combined to form a group of --(CH.sub.2).sub.m --(m is 3 or 4), which is useful e.g., a plant growth inhibitor.
    • 式(I)的化合物或其盐,其中R是氢原子,可以被取代的苯基或 - (CH 2)n -R 1的基团,其中n是1的整数 3,R1为氢原子,羟基,低级烷氧基,巯基,低级烷硫基,氨基,二低级烷基氨基,C3-11烷基,低级烯基,低级炔基,环烷基, 或6元杂环基,或可被卤素,低级烷基或低级烷氧基的一个或两个取代基取代的苯基; R2和R7不同,氢原子,C1-11烷基,低级烯基,低级炔基,环烷基,低级烷氧基烷基,低级烷基硫代烷基,苯基可以自由取代,其核可以被其取代的芳烷基 一个或两个卤素,低级烷基或低级烷氧基或卤代烷基取代基或5-或6-元杂环基; R3,R4和R5是相同或不同的氢原子,卤原子,氰基,硝基,氨基,低级烷基,低级卤代烷基,羟基,低级烷氧基,芳氧基,羧基或低级烷氧基羰基 ; R6是氢原子,卤素原子,低级烷基,可被取代的苯基或可以被取代的芳烷基; 或者R 6和R 7可以组合形成 - (CH 2)m - (m为3或4)的基团,其可用于例如植物生长抑制剂。