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    • 1. 发明授权
    • Photocatalyst material producing method and photocatalyst material producing apparatus
    • 光催化剂材料的制造方法和光催化剂材料的制造装置
    • US07771797B2
    • 2010-08-10
    • US10588735
    • 2005-07-15
    • Yoichiro TabataTetsuya SaitsuYujiro OkiharaRyohei Ueda
    • Yoichiro TabataTetsuya SaitsuYujiro OkiharaRyohei Ueda
    • H05H1/32
    • C01B13/11B01J23/02B01J23/06B01J23/08B01J23/14B01J23/16B01J23/72B01J23/745B01J35/004B01J37/0238B01J37/349C01B2201/64
    • This invention provides a new photocatalyst material producing apparatus and photocatalyst material producing method that can produce a large quantity of photocatalyst material of high quality by a chemical reaction in light high-field plasma in a highly oxidative high-concentration ozone medium state, instead of systems to produce a photocatalyst material by PVD and CVD, which are conventional dry deposition methods.In a photocatalyst material producing method and photocatalyst material producing apparatus according to this invention, a pair of facing electrodes are provided via a dielectric material in a discharge gap where gas mainly containing oxygen gas is supplied, and an AC voltage is applied between the electrodes to generate dielectric barrier discharge (silent discharge or creeping discharge) in the discharge gap. Thus, oxygen gas containing ozone gas is created and a metal or metal compound is modified to a photocatalyst material by the dielectric barrier discharge.
    • 本发明提供了一种新的光催化剂材料生产装置和光催化剂材料的制备方法,其可以通过高氧化高浓度臭氧介质状态下的轻高等离子体中的化学反应生成大量高质量的光催化剂材料,而不是系统 通过PVD和CVD制备光催化剂材料,这是常规的干法沉积方法。 在根据本发明的光催化剂材料的制造方法和光催化剂材料制造装置中,在供给主要含有氧气的气体的放电间隙中,经由电介质材料设置一对面对电极,并且在电极之间施加交流电压 在放电间隙中产生电介质阻挡放电(无声放电或爬电放电)。 因此,产生含有臭氧气体的氧气,并且通过介电阻挡放电将金属或金属化合物改性为光催化剂材料。
    • 4. 发明授权
    • Ozone concentrator
    • 臭氧浓缩器
    • US08409520B2
    • 2013-04-02
    • US12743984
    • 2008-11-28
    • Koji OtaYasuhiro TanimuraYoichiro TabataYujiro OkiharaTetsuya SaitsuNoriyuki NakamuraRyohei Ueda
    • Koji OtaYasuhiro TanimuraYoichiro TabataYujiro OkiharaTetsuya SaitsuNoriyuki NakamuraRyohei Ueda
    • B01J19/08
    • C01B13/10B01D53/047B01D2253/106B01D2256/14B01D2259/403Y02P20/123Y02P20/124
    • Provided is an ozone concentrator including an ozone generator (3), adsorption/desorption columns (4) in which silica gel (6) cooled with a certain-temperature refrigerant (25) for concentrating ozone generated by the ozone generator (3) is packed, a refrigerating machine (23) for cooling the refrigerant (25), a vacuum pump (20) for enhancing a concentration of the ozone in one of the adsorption/desorption columns (4) by discharging mainly oxygen from the silica gel (6) adsorbing the ozone, a plurality of valves (8) to (13) for air pressure operations, for switching passages of gas that is allowed to flow in or flow out with respect to the adsorption/desorption columns (4), and ozone concentration meters (28, 29) for measuring the concentration of the ozone enhanced by the vacuum pump (20), in which a discharge line of the vacuum pump (20) is connected to another one of the adsorption/desorption columns (4), whereby the ozone is allowed to pass through another one of the adsorption/desorption columns again. Therefore, stable ozone of high concentration can be generated at a satisfactory energy efficiency without any temperature difference between upper and lower positions of adsorption/desorption columns.
    • 提供一种臭氧浓缩器,其包括臭氧发生器(3),吸收/解吸塔(4),其中用用于浓缩臭氧发生器(3)产生的臭氧的一定温度制冷剂(25)冷却的硅胶(6)被包装 ,用于冷却制冷剂(25)的制冷机(23),用于通过主要从硅胶(6)中排出氧气来提高其中一个吸附/解吸塔(4)中的臭氧浓度的真空泵(20) 吸附臭氧,多个用于空气压力操作的阀(8)至(13),用于切换相对于吸附/解吸塔(4)流入或流出的气体的通道,以及臭氧浓度计 (28,29),用于测量真空泵(20)增强的臭氧浓度,其中真空泵(20)的排放管线连接到另一个吸附/解吸塔(4),由此, 允许臭氧通过另一个吸附/ des orption列。 因此,可以以令人满意的能量效率产生高浓度的稳定的臭氧,而在吸附/解吸塔的上部和下部位置之间没有任何温差。
    • 5. 发明申请
    • OZONE CONCENTRATOR
    • 臭氧浓缩器
    • US20100266463A1
    • 2010-10-21
    • US12743984
    • 2008-11-28
    • Koji OtaYasuhiro TanimuraYoichiro TabataYujiro OkiharaTetsuya SaitsuNoriyuki NakamuraRyohei Ueda
    • Koji OtaYasuhiro TanimuraYoichiro TabataYujiro OkiharaTetsuya SaitsuNoriyuki NakamuraRyohei Ueda
    • B01J19/08
    • C01B13/10B01D53/047B01D2253/106B01D2256/14B01D2259/403Y02P20/123Y02P20/124
    • Provided is an ozone concentrator including an ozone generator (3), adsorption/desorption columns (4) in which silica gel (6) cooled with a certain-temperature refrigerant (25) for concentrating ozone generated by the ozone generator (3) is packed, a refrigerating machine (23) for cooling the refrigerant (25), a vacuum pump (20) for enhancing a concentration of the ozone in one of the adsorption/desorption columns (4) by discharging mainly oxygen from the silica gel (6) adsorbing the ozone, a plurality of valves (8) to (13) for air pressure operations, for switching passages of gas that is allowed to flow in or flow out with respect to the adsorption/desorption columns (4), and ozone concentration meters (28, 29) for measuring the concentration of the ozone enhanced by the vacuum pump (20), in which a discharge line of the vacuum pump (20) is connected to another one of the adsorption/desorption columns (4), whereby the ozone is allowed to pass through another one of the adsorption/desorption columns again. Therefore, stable ozone of high concentration can be generated at a satisfactory energy efficiency without any temperature difference between upper and lower positions of adsorption/desorption columns.
    • 提供一种臭氧浓缩器,其包括臭氧发生器(3),吸收/解吸塔(4),其中用用于浓缩臭氧发生器(3)产生的臭氧的一定温度制冷剂(25)冷却的硅胶(6)被包装 ,用于冷却制冷剂(25)的制冷机(23),用于通过主要从硅胶(6)中排出氧气来提高其中一个吸附/解吸塔(4)中的臭氧浓度的真空泵(20) 吸附臭氧,多个用于空气压力操作的阀(8)至(13),用于切换相对于吸附/解吸塔(4)流入或流出的气体的通道,以及臭氧浓度计 (28,29),用于测量真空泵(20)增强的臭氧浓度,其中真空泵(20)的排放管线连接到另一个吸附/解吸塔(4),由此, 允许臭氧通过另一个吸附/ des orption列。 因此,可以以令人满意的能量效率产生高浓度的稳定的臭氧,而在吸附/解吸塔的上部和下部位置之间没有任何温差。
    • 7. 发明申请
    • APPARATUS FOR PRODUCING HIGH-CONCENTRATION OZONE GAS AND METHOD OF PRODUCING HIGH-CONCENTRATION OZONE GAS
    • 生产高浓度臭氧气体的方法及生产高浓度臭氧气体的方法
    • US20110052483A1
    • 2011-03-03
    • US12745595
    • 2008-11-28
    • Yoichiro TabataYujiro OkiharaTetsuya SaitsuNoriyuki NakamuraRyohei UedaKoji OtaYasuhiro Tanimura
    • Yoichiro TabataYujiro OkiharaTetsuya SaitsuNoriyuki NakamuraRyohei UedaKoji OtaYasuhiro Tanimura
    • C01B13/10B01J19/08
    • C01B13/10B01D53/04B01D53/047B01D2253/106B01D2256/14B01D2259/403B01D2259/404B01D2259/41C01B13/0203
    • An ozonized gas having a pressure exceeding atmospheric pressure and having a predetermined concentration is supplied to adsorption/desorption columns (4) at a low temperature state of 0° C. or less and a high pressure and packed with silica gel (6) serving as an adsorbent. The adsorption/desorption columns (4) have been constituted so that at least three of a plurality of adsorption/desorption columns (4), i.e., adsorption/desorption columns (4-1, 4-2, and 4-3), are disposed in a serial cycle arrangement to constitute a main adsorption/desorption column group (99), and that an adsorption/desorption column (4-4) is disposed in parallel with the main adsorption/desorption column group (99) to constitute an auxiliary adsorption/desorption column (999). In a period in which none of the three columns of the main adsorption/desorption column group (99) is performing desorption processing, the auxiliary adsorption/desorption column (999) performs desorption processing. Therefore, the apparatus can continuously output high-concentration ozone at a high flow rate. By thus efficiently producing a high-concentration ozonized gas, the amount of the ozone capable of being output can be increased and the amount of discharge gas which is not permitted to be output can be reduced. That efficient production enables the apparatus for producing high-concentration ozone gas to be compact, satisfactorily operable, and inexpensive.
    • 将压力超过大气压并具有预定浓度的臭氧化气体在0℃或更低和高压的低温状态下供给至吸附/解吸塔(4),并填充硅酸(6)作为 吸附剂。 吸附/解吸塔(4)已被构成使得多个吸附/解吸塔(4)中的至少三个,即吸附/解吸塔(4-1,4-2和4-3)是 以串联循环装置排列以构成主吸附/解吸塔组(99),并且吸附/解吸塔(4-4)与主吸附/解吸塔组(99)平行设置以构成辅助 吸附/解吸柱(999)。 在主吸附/解吸塔组(99)的三个塔中没有一个进行解吸处理的时间段内,辅助吸附/解吸塔(999)进行解吸处理。 因此,该装置能够以高流量连续输出高浓度臭氧。 由此,能够高效率地生成高浓度的臭氧化气体,能够提高能输出的臭氧的量,能够减少不允许输出的排出气体的量。 这种有效的生产使得高浓度臭氧气体的制造装置致密,令人满意地可操作并且便宜。
    • 10. 发明授权
    • N-phase ozone generator
    • N相臭氧发生器
    • US07744825B2
    • 2010-06-29
    • US10581044
    • 2004-09-29
    • Yoichiro TabataYujiro OkiharaMasayuki IshikawaTetsuya Saitsu
    • Yoichiro TabataYujiro OkiharaMasayuki IshikawaTetsuya Saitsu
    • B01J19/08
    • H02M7/48C01B13/115C01B2201/12C01B2201/40C01B2201/76C01B2201/84C01B2201/90
    • A compact, inexpensive, large-capacity ozone generator with increased ease of apparatus maintenance. An ozone power supply includes an n-phase inverter for obtaining an AC voltage having a predetermined frequency and outputting an n-phase AC voltage waveform; n reactors and an n-phase transformer for converting an n-phase AC voltage to a high AC voltage; n high-voltage terminals for outputting the n-phase high AC voltage; and a low-voltage terminal having a common potential. Ozone generator units are electrically divided into n pieces within a discharge chamber. Each ozone generator unit includes n high-voltage electrode terminals and one low-voltage electrode terminal, common to all ozone generator units. Each ozone generator unit supports an n-phase AC discharge to generate ozone.
    • 一种紧凑,便宜,大容量的臭氧发生器,提高了设备​​维护的便利性。 臭氧电源包括用于获得具有预定频率的AC电压并输出n相交流电压波形的n相逆变器; n个电抗器和用于将n相交流电压转换成高交流电压的n相变压器; n个高压端子,用于输出n相高交流电压; 以及具有共同电位的低电压端子。 臭氧发生器单元在放电室内电分为n个片。 每个臭氧发生器单元包括n个高压电极端子和一个低压电极端子,它们与所有臭氧发生器单元共用。 每个臭氧发生器单元支持n相AC放电以产生臭氧。