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    • 7. 发明授权
    • Tungsten-modified platinum NOx traps for automotive emission reduction
    • 用于汽车减排的钨改性铂NO x阱
    • US5950421A
    • 1999-09-14
    • US993927
    • 1997-12-18
    • Mohinder S. ChatthaRobert J. KudlaClifford Norman Montreuil
    • Mohinder S. ChatthaRobert J. KudlaClifford Norman Montreuil
    • B01D53/94F01N3/08F01N3/00
    • F01N3/0842B01D53/9422F01N3/0814F01N3/0871B01D2255/1021B01D2255/1025B01D2255/20776Y02T10/22Y02T10/24
    • The invention is a method of treating exhaust gases generated by an internal combustion engine using a NOx trap in the exhaust gas system. The method comprises locating an essentially alkaline earth-free nitrogen oxide trap in the exhaust gas passage and cycling the air/fuel ratio of the exhaust gases entering the trap between lean and rich, such that the trap absorbs nitrogen oxides during the lean cycle and desorbs the nitrogen oxides when the concentration of the oxygen in the exhaust gas is lowered as during a rich cycle. The trap comprises: (a) a porous support material comprising mostly .gamma.-alumina and (b) metals consisting essentially of 0.1 to 2 wt. % tungsten oxide and precious metal comprising 0.5 to 4 wt. % platinum deposited on the support, the amount of said metals being individually based on the weight of said support material. The desorbed nitrogen oxides may be converted over the precious metal to N.sub.2 and O.sub.2 by reductants like hydrocarbons present in the exhaust gas.
    • 本发明是一种利用排气系统中的NOx捕集器来处理由内燃机产生的废气的方法。 该方法包括将排气通道中基本上不含碱性的无土氮氧化物捕集器定位,并且循环在贫和富之间进入捕集阱的排气的空气/燃料比,使得阱在贫循环期间吸收氮氧化物并解吸 当在富循环期间排气中的氧浓度降低时,氮氧化物。 捕集器包括:(a)主要包含γ-氧化铝的多孔支撑材料和(b)基本上由0.1至2重量% %的氧化钨和贵重金属,其含有0.5〜4wt。 %铂沉积在载体上,所述金属的量分别基于所述载体材料的重量。 解吸的氮氧化物可以通过诸如排放气体中存在的烃之类的还原剂在贵金属上转化为N 2和O 2。