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1. 发明授权

US06797783B1 Modified natural rubber 失效
标题翻译：改性天然橡胶
公开(公告)号：US06797783B1
公开(公告)日：2004-09-28
申请号：US08941132
申请日：1997-09-30
申请人： Yasuyuki Tanaka , Naoya Ichikawa , Toshiaki Sakaki , Yuichi Hioki , Masaharu Hayashi
发明人： Yasuyuki Tanaka , Naoya Ichikawa , Toshiaki Sakaki , Yuichi Hioki , Masaharu Hayashi
IPC分类号： C08F25506
CPC分类号： C08C19/06 , C08F253/00 , C08L51/04 , C08L2666/02
摘要： A modified natural rubber is disclosed, which is obtained by modifying a deproteinized natural rubber having a nitrogen content of less than 0.10% by weight. A process for improving the graft ratio and the graft efficiency of natural rubber and a process for improving the epoxidation ratio of natural rubber are also disclosed. The modified natural rubber of the present invention has a high modifying efficiency and thus shows an excellent modifying effect. It is also useful as a means for preventing allergy.
摘要翻译：公开了通过改性氮含量低于0.10重量％的脱蛋白天然橡胶而得到的改性天然橡胶。还公开了改善天然橡胶的接枝率和接枝效率的方法以及改善天然橡胶的环氧化比例的方法。本发明的改性天然橡胶具有高的改性效果，因此显示出优异的改性效果。它也可用作防止过敏的手段。

2. 发明授权

US5610212A Means for mechanically stabilizing deproteinized natural rubber latex 失效
标题翻译：用于机械稳定脱蛋白天然橡胶胶乳的方法
公开(公告)号：US5610212A
公开(公告)日：1997-03-11
申请号：US241989
申请日：1994-05-13
申请人： Yasuyuki Tanaka , Yuichi Hioki , Masaharu Hayashi , Naoya Ichikawa , Toshiaki Sakaki
发明人： Yasuyuki Tanaka , Yuichi Hioki , Masaharu Hayashi , Naoya Ichikawa , Toshiaki Sakaki
IPC分类号： C08C1/00 , C08C1/04 , C08C1/06 , C08K5/41
CPC分类号： C08C1/04 , C08C1/06
摘要： A means for stabilizing a deproteinized natural rubber latex is disclosed, comprising adding a stabilizer selected from the group consisting of (a) an anionic surfactant, (b) an amphoteric surfactant, (c) a nonionic surfactant, (d) a nonionic or amphoteric oligomer or polymer, and (e) an anionic oligomer or polymer. By adding the stabilizer, the mechanical stability of a deproteinized natural rubber latex can be markedly improved.
摘要翻译：公开了一种用于稳定脱蛋白天然橡胶胶乳的方法，包括加入选自（a）阴离子表面活性剂，（b）两性表面活性剂，（c）非离子表面活性剂，（d）非离子或两性低聚物或聚合物，和（e）阴离子低聚物或聚合物。通过添加稳定剂，可以显着提高脱蛋白天然橡胶胶乳的机械稳定性。

3. 发明授权

US5585459A Process for producing raw rubber 失效
标题翻译：生橡胶生产工艺
公开(公告)号：US5585459A
公开(公告)日：1996-12-17
申请号：US241714
申请日：1994-05-12
申请人： Yasuyuki Tanaka , Yuichi Hioki , Masaharu Hayashi , Naoya Ichikawa , Toshiaki Sakaki
发明人： Yasuyuki Tanaka , Yuichi Hioki , Masaharu Hayashi , Naoya Ichikawa , Toshiaki Sakaki
IPC分类号： C08C1/04 , C08C1/14 , C08C1/15
CPC分类号： C08C1/15 , C08C1/04 , C08C1/14
摘要： A process for producing raw rubber from a deproteinized natural rubber is disclosed, which comprises coagulating rubber particles in the deproteinized natural rubber latex by: (1) adding a nonionic surfactant having a cloud point of from 20.degree. to 100.degree. C. and a molecular weight of 300 or more to the deproteinized natural rubber latex and heating the latex to a temperature not lower than the cloud point of the nonionic surfactant; or (2) adding a coagulation assistant selected from the group consisting of: (a) an anionic surfactant, (b) an amphoteric surfactant, (c) a nonionic surfactant, (d) a nonionic or amphoteric oligomer or polymer, and (e) an anionic oligomer or polymer, to the deproteinized natural rubber latex; and then recovering the coagulated rubber particles. According to the process of the present invention, raw rubber containing substantially no metal ion can be produced with a high efficiency.
摘要翻译：公开了一种从脱蛋白天然橡胶生产生橡胶的方法，其包括：通过以下步骤将脱蛋白天然橡胶胶乳中的橡胶颗粒凝结：（1）加入浊点为20至100℃的非离子表面活性剂和分子重量为300以上的脱蛋白天然橡胶胶乳，并将胶乳加热至不低于非离子表面活性剂的浊点的温度; 或（2）加入选自以下的凝血助剂：（a）阴离子表面活性剂，（b）两性表面活性剂，（c）非离子表面活性剂，（d）非离子或两性低聚物或聚合物，和）阴离子低聚物或聚合物; 然后回收凝固的橡胶颗粒。根据本发明的方法，可以高效率地生产基本上不含金属离子的生橡胶。

4. 发明授权

US06335407B1 Deproteinized natural rubber and process for producing the same 失效
标题翻译：脱蛋白天然橡胶及其制备方法
公开(公告)号：US06335407B1
公开(公告)日：2002-01-01
申请号：US08799363
申请日：1997-02-14
申请人： Yasuyuki Tanaka , Yuichi Hioki , Naoya Ichikawa
发明人： Yasuyuki Tanaka , Yuichi Hioki , Naoya Ichikawa
IPC分类号： C08F500
CPC分类号： C08C1/04 , Y10S528/931 , Y10S528/932
摘要： A deproteinized natural rubber substantially free from any protein and a process for producing the same which comprises treating a latex with a protease and a specific surfactant or a combination of specific surfactants and separating rubber particles are disclosed. A method for elevating the green strength of a natural rubber and a method for lowering the green strength of a natural rubber are also disclosed. Furthermore, a means for preventing allergy induced by natural rubber is also disclosed.
摘要翻译：公开了一种基本上不含任何蛋白质的脱蛋白天然橡胶及其制备方法，其包括用蛋白酶和特定表面活性剂或特定表面活性剂和分离橡胶颗粒的组合处理胶乳。还公开了提高天然橡胶的生坯强度的方法和降低天然橡胶的生坯强度的方法。此外，还公开了一种防止由天然橡胶引起的变态反应的方法。

5. 发明授权

US06204358B1 Process for producing deproteinized natural rubber using protease and anionic surfactant 有权
标题翻译：使用蛋白酶和阴离子表面活性剂生产脱蛋白天然橡胶的方法
公开(公告)号：US06204358B1
公开(公告)日：2001-03-20
申请号：US09357077
申请日：1999-07-19
申请人： Yasuyuki Tanaka , Yuichi Hioki , Naoya Ichikawa
发明人： Yasuyuki Tanaka , Yuichi Hioki , Naoya Ichikawa
IPC分类号： C08C104
CPC分类号： C08C1/04 , Y10S528/932
摘要： A deproteinized natural rubber substantially free from any protein and a process for producing the same which comprises treating a latex with a protease and a specific surfactant or a combination of specific surfactants and separating rubber particles are disclosed. A method for elevating the green strength of a natural rubber and a method for lowering the green strength of a natural rubber are also disclosed. Furthermore, a means for preventing allergy induced by natural rubberis also disclosed.
摘要翻译：公开了一种基本上不含任何蛋白质的脱蛋白天然橡胶及其制备方法，其包括用蛋白酶和特定表面活性剂或特定表面活性剂和分离橡胶颗粒的组合处理胶乳。还公开了提高天然橡胶的生坯强度的方法和降低天然橡胶的生坯强度的方法。此外，还公开了一种预防由天然橡胶引起的变态反应的方法。

6. 发明授权

US06239253B1 Deproteinized natural rubber and process for producing the same 有权
标题翻译：脱蛋白天然橡胶及其制备方法
公开(公告)号：US06239253B1
公开(公告)日：2001-05-29
申请号：US09356523
申请日：1999-07-19
申请人： Yasuyuki Tanaka , Yuichi Hioki , Naoya Ichikawa
发明人： Yasuyuki Tanaka , Yuichi Hioki , Naoya Ichikawa
IPC分类号： C08C104
CPC分类号： C08C1/04 , Y10S528/932
摘要： A deproteinized natural rubber substantially free from any protein and a process for producing the same which comprises treating a latex with a protease and a specific surfactant or a combination of specific surfactants and separating rubber particles are disclosed. A method for elevating the green strength of a natural rubber and a method for lowering the green strength of a natural rubber are also disclosed. Furthermore, a means for preventing allergy induced by natural rubber is also disclosed.
摘要翻译：公开了一种基本上不含任何蛋白质的脱蛋白天然橡胶及其制备方法，其包括用蛋白酶和特定表面活性剂或特定表面活性剂和分离橡胶颗粒的组合处理胶乳。还公开了提高天然橡胶的生坯强度的方法和降低天然橡胶的生坯强度的方法。此外，还公开了一种防止由天然橡胶引起的变态反应的方法。

7. 发明授权

US06313074B1 Effect enhancer for agricultural chemical 有权
标题翻译：农药效果增强剂
公开(公告)号：US06313074B1
公开(公告)日：2001-11-06
申请号：US09462269
申请日：2000-04-03
申请人： Tadayuki Suzuki , Masaharu Hayashi , Kazuhiko Kurita , Yuichi Hioki
发明人： Tadayuki Suzuki , Masaharu Hayashi , Kazuhiko Kurita , Yuichi Hioki
IPC分类号： A01N2530
CPC分类号： A01N31/02 , A01N25/30 , Y10S514/975
摘要： There are provided an effect enhancer for an agricultural chemical and an a chemical formulation which is not pharmaceutically harmful to various crops and can be safely used and which has an excellent effect enhancing function to various agricultural chemicals. The effect enhancer for the agricultural chemical comprises, as an effective component, a compound represented by the following formula (I): R—O[(EO)x(PO)y](EO)z—H, wherein EO is an oxyethylene group; PO is an oxypropylene group; R is a straight-chin or branched alkyl group or alkenyl group having 6 to 30 carbon atoms; x is a value of 1 to 30 on the average; y is a value of 1 to 30 on the average, and z is a value of 1 to 30 on the average. The agricultural chemical formulation composes the above-mentioned surfactant and a technical grade of active ingredient or an active compound for an agricultural chemical.
摘要翻译：提供了一种农药的效果增强剂和对各种作物不具有药学上有害作用并且可以安全使用且对各种农药具有优异的增效作用的化学制剂。作为农药的效果增强剂，作为有效成分，含有由下式（I）表示的化合物：R-O [（EO）x（PO）y]（EO）z-H，其中EO为氧化乙烯基; PO是氧化丙烯基; R为碳原子数为6〜30的直链或支链烷基或烯基; x的平均值为1〜30; y平均为1〜30，平均为z为1〜30。农业化学制剂组成上述表面活性剂和农药的活性成分或活性化合物的工业级。

8. 发明授权

US5863909A Adjuvant composition for agricultural chemicals and method for enhancing the efficacy of agricultural chemical 失效
标题翻译：农药辅助成分及提高农化效能的方法
公开(公告)号：US5863909A
公开(公告)日：1999-01-26
申请号：US836719
申请日：1997-05-22
申请人： Kazuhiko Kurita , Keiko Hasebe , Katsuhiko Yamaguchi , Masaharu Hayashi , Yuichi Hioki
发明人： Kazuhiko Kurita , Keiko Hasebe , Katsuhiko Yamaguchi , Masaharu Hayashi , Yuichi Hioki
IPC分类号： A01N25/10 , A01N25/30 , A01N33/12 , A01N37/02 , A01N37/06 , A01N65/06 , A01P3/00 , A01N43/78 , A01N57/14 , B01J13/00
CPC分类号： A01N25/30 , Y10S514/941 , Y10S514/952 , Y10S514/975
摘要： An adjuvant composition for agricultural chemicals comprising at least one sorbitan/fatty acid ester surfactant (A) and at least one surfactant (B) selected from the group consisting of resin acid surfactants and anionic oligomer or polymer type quaternary ammonium salt surfactants can be used for various crops in safety without causing injury thereof to the crops, and can enhance the efficacies of various agricultural chemicals.
摘要翻译： PCT No.PCT / JP95 / 02382 Sec。 371日期：1997年5月22日 102（e）日期1997年5月22日PCT提交1995年11月22日PCT公布。公开号WO96 / 16539 日期1996年6月6日，包含至少一种脱水山梨醇/脂肪酸酯表面活性剂（A）和至少一种选自树脂酸性表面活性剂和阴离子低聚物或聚合物型季铵盐的表面活性剂（B）的农药用辅料组合物表面活性剂可以安全地用于各种作物，而不会对作物造成伤害，并且可以提高各种农药的有效性。

9. 发明授权

US5567606A Antifoaming agent for fermentation, L-amino acid-producing medium and production process of L-amino acids 失效
标题翻译：消泡剂用于发酵，L-氨基酸生产介质和L-氨基酸的生产过程
公开(公告)号：US5567606A
公开(公告)日：1996-10-22
申请号：US395656
申请日：1995-02-28
申请人： Masaharu Hayashi , Yuichi Hioki , Masafumi Shonaka , Tadashi Moriyama
发明人： Masaharu Hayashi , Yuichi Hioki , Masafumi Shonaka , Tadashi Moriyama
IPC分类号： B01D19/04 , C07C67/26 , C12M1/21 , C12N1/20 , C12N1/38 , C12P13/04 , C07C51/43 , C09K3/00
CPC分类号： B01D19/0404 , C07C67/26 , C12N1/38 , C12P13/04 , Y10S435/812 , Y10S516/01 , Y10S516/904
摘要： Disclosed herein are antifoaming agents for fermentation which include, as active ingredient at least one of (a) a reaction product obtained by adding at least one alkylene oxide to a mixture of a fat and/or oil with a trihydric or still higher polyhydric alcohol, or (b) a compound represented by the following general formula (1): ##STR1## wherein n stands for a number of 2-50, R.sup.1, R.sup.2 and R.sup.3 mean individually a hydrogen atom or an acyl group having 2-31 carbon atoms, x denotes an alkylene group having 2-4 carbon atoms, and m1, m2 and m3 are individually a number of 0-200, an L-amino acid-producing medium containing either one of these components, and a production process for L-amino acids making use of this medium. The use of this antifoaming agent permits the quick, sure and durable suppression of bubbling during incubation, and the overall production of the L-amino acid is significantly improved.
摘要翻译：本发明公开了用于发酵的消泡剂，其包括作为活性成分的至少一种（a）通过向脂肪和/或油的混合物中加入至少一种烯化氧与三元或更高级多元醇而获得的反应产物，或（b）由以下通式（1）表示的化合物：其中n表示2-50的数，R1，R2和R3分别表示氢原子或具有2- 31个碳原子，x表示具有2-4个碳原子的亚烷基，m1，m2和m3分别为0-200的数量，含有这些组分之一的L-氨基酸生产介质和制备方法对于使用该介质的L-氨基酸。这种消泡剂的使用允许在孵育期间快速，确定和持久地抑制起泡，并且L-氨基酸的总体生产显着改善。

10. 发明授权

US5462912A Agricultural chemical composition enhancer comprising quaternary di(polyoxyalkylene) ammonium alkyl sulfates 失效
标题翻译：包含季二（聚氧化烯）烷基硫酸铵的农药组合物增强剂
公开(公告)号：US5462912A
公开(公告)日：1995-10-31
申请号：US305731
申请日：1994-09-14
申请人： Yuichi Hioki , Kazuhiko Kurita , Keiko Kawabata , Toshikazu Azuma
发明人： Yuichi Hioki , Kazuhiko Kurita , Keiko Kawabata , Toshikazu Azuma
IPC分类号： A01N25/30 , A01N33/12
CPC分类号： A01N25/30 , A01N33/12 , Y10S514/975
摘要： An agricultural chemical composition which can be safely applied to crops without causing any chemical damage; comprising a mixture, which exerts excellent potentiating effects on various agricultural chemicals, of compounds represented by the following general formula (I) and having (n1+n2+n3) and (n4+n5+n6) each being a number of 0 to 100 on the average, and an agricultural chemical, wherein the weight ratio of the mixture to the agricultural chemical ranges from 0.1 to 50: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represent a straight-chain or branched alkyl, alkenyl or hydroxyalkyl group having from 1 to 30 carbon atoms.
摘要翻译：农药组合物，可以安全地施用于作物而不引起任何化学损害; 包括对各种农药具有优异的增效作用的混合物，由以下通式（I）表示的化合物和（n1 + n2 + n3）和（n4 + n5 + n6）各自为0至100的数平均而言，和农用化学品，其中混合物与农用化学品的重量比范围为0.1-50：（I）其中R1，R2和R3各自表示直链或支链烷基，链烯基或具有1至30个碳原子的羟烷基。

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