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    • 7. 发明授权
    • Denitration catalyst, process for preparing the same, and exhaust gas
purification method
    • 脱硝催化剂,其制备方法和废气净化方法
    • US6143687A
    • 2000-11-07
    • US254376
    • 1999-04-02
    • Naomi ImadaYasuyoshi Kato
    • Naomi ImadaYasuyoshi Kato
    • B01D53/86B01J21/06B01J23/22B01J23/24B01J33/00B01J37/02B01J31/00B01J23/00C01B21/00
    • B01J33/00B01D53/8628B01J37/0219B01J37/0244B01J21/063B01J23/22B01J23/24Y10S502/507
    • A denitration catalyst for use in the reduction of nitrogen oxides contained in an exhaust gas containing highly deliquescent salts as dust with ammonia, which bears thereon a porous coating of a water-repellent organic resin, a porous coating of a mixture of a water-repellent organic resin with inorganic oxide particles, or a porous coating of a mixture of a water-repellent organic resin with catalyst component particles. The denitration catalyst can be prepared, for example, by coating the surface of a denitration catalyst with an aqueous dispersion containing a water-repellent organic resin having a lower concentration, drying the coating, further coating the dried coating with an aqueous dispersion containing a water-repellent organic resin having a higher concentration, and then drying the coating to form a porous coating of a water-repellent organic resin. This denitration catalyst, even when used in the treatment of an exhaust gas containing ash containing highly deliquescent salts, enables the water-repellent porous coating formed on the surface to prevent the salts that have deliquesced from entering the catalyst. This can prevent the deterioration of the catalyst and enables a high catalytic activity to be maintained for a long period of time.
    • PCT No.PCT / JP98 / 03083 Sec。 一九九九年四月二日 102(e)1999年4月2日PCT PCT 1998年7月9日PCT公布。 出版物WO99 /​​ 02262 日期1999年1月21日用于还原包含在含有高度潮解性盐的废气中的氮氧化物的脱硝催化剂,其中所述废气含有氨,作为防尘有机树脂的多孔涂层,混合物的多孔涂层 具有无机氧化物颗粒的防水有机树脂,或防水有机树脂与催化剂组分颗粒的混合物的多孔涂层。 脱硝催化剂可以例如通过用含有较低浓度的拒水性有机树脂的水性分散体涂覆脱硝催化剂的表面来制备,干燥涂层,进一步用含有水的水分散体涂覆干燥的涂层 - 具有较高浓度的有机有机树脂,然后干燥该涂层以形成防水有机树脂的多孔涂层。 该脱硝催化剂即使用于处理含有高度潮解盐的灰分的废气,也能够使表面上形成的防水多孔涂层防止已经潮解的盐进入催化剂。 这可以防止催化剂的劣化,并且能够长期保持高的催化活性。