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    • 1. 发明申请
    • Light oil composition
    • 轻油组成
    • US20120011920A1
    • 2012-01-19
    • US13200350
    • 2011-09-23
    • Yasutoshi IguchiHideaki SuganoOsamu Tamura
    • Yasutoshi IguchiHideaki SuganoOsamu Tamura
    • G01N30/72
    • C10L1/08
    • The invention provides a gas oil composition wherein the molar ratio of isoparaffins with carbon number of m and two or more branches to isoparaffins with carbon number of m and one branch within the range of C10-21 is 0.05-3.5, wherein m is an integer of 10-21, and the molar ratio of isoparaffins with carbon number of n and two or more branches to isoparaffins with carbon number of n and one branch within the range of C22-25 is 0.1-10.0, wherein n is an integer of 22-25. The invention also provides a gas oil composition wherein the molar ratio of isoparaffins with carbon number of m and two or more branches to isoparaffins with carbon number of m and one branch within the range of C10-23 is 0.05-4.0, wherein m is an integer of 10-23, and the distillate volume at a distillation temperature of 250° C. (E250) is 15-65%.
    • 本发明提供一种瓦斯油组合物,其中碳原子数为m和两个或多个分支的异链烷烃与碳数为m的异链烷烃与一个分支在C10-21的范围内的摩尔比为0.05-3.5,其中m为整数 为10-21,碳原子数n和两个或多个分支的异链烷烃与碳数为n的异链烷烃和C22-25的一个分支的摩尔比为0.1-10.0,其中n为22的整数 -25。 本发明还提供了一种瓦斯油组合物,其中碳数为m和两个或更多个分支的异链烷烃与碳数为m和一个分支在C10-23范围内的异链烷烃的摩尔比为0.05-4.0,其中m为 蒸馏温度为250℃的馏出物体积(E250)为15-65%。
    • 2. 发明申请
    • LIGHT OIL COMPOSITIONS
    • US20090101541A1
    • 2009-04-23
    • US12293310
    • 2007-03-07
    • Yasutoshi IguchiHideaki SuganoOsamu Tamura
    • Yasutoshi IguchiHideaki SuganoOsamu Tamura
    • C10L1/04
    • C10L1/08
    • The invention provides a gas oil composition having a C10-24 paraffin composition that satisfies the condition represented by inequality (1-1) below, a slow-cooling cloud point of no higher than −6.0° C. and a pour point of no higher than −7.5° C. The invention further provides a gas oil composition having a C10-24 paraffin composition that satisfies the condition represented by inequality (1-2) below, a distillate volume at a distillation temperature of 250° C. (E250) of 5-45% and a slow-cooling cloud point of higher than −6.0° C. In inequalities (1-1) and (1-2), n is the carbon number of the paraffin and f(n) is the paraffin composition parameter for the carbon number of n represented by formula (2) below. In formula (2), n represents an integer of 10-24, and a, b and c respectively represent the proportion (in terms of molar value) of normal paraffins with carbon number of n, of isoparaffins with carbon number of n and one branch and of isoparaffins with carbon number of n and two or more branches, with respect to the total amount of paraffins with carbon number of n. [ Mathematical   Formula   1 ] 340.0 ≤ ∑ n = 10 24   f  ( n ) ≤ 400.0 ( 1  -  1 ) [ Mathematical   Formula   2 ] f  ( n ) = 27.45 - 3.55  ( b / a ) - 0.65  ( c / a ) ( 2 ) [ Mathematical   Formula   3 ] 370.0 ≤ ∑ n = 10 24   f  ( n ) ≤ 430.0 ( 1  -  2 )
    • 3. 发明授权
    • Light oil compositions
    • 轻油组合物
    • US08080068B2
    • 2011-12-20
    • US12293310
    • 2007-03-07
    • Yasutoshi IguchiHideaki SuganoOsamu Tamura
    • Yasutoshi IguchiHideaki SuganoOsamu Tamura
    • C10L1/08
    • C10L1/08
    • The invention provides a gas oil composition having a C10-24 paraffin composition that satisfies the condition represented by inequality (1-1) below, a slow-cooling cloud point of no higher than −6.0° C. and a pour point of no higher than −7.5° C. The invention further provides a gas oil composition having a C10-24 paraffin composition that satisfies the condition represented by inequality (1-2) below, a distillate volume at a distillation temperature of 250° C. (E250) of 5-45% and a slow-cooling cloud point of higher than −6.0° C. In inequalities (1-1) and (1-2), n is the carbon number of the paraffin and f(n) is the paraffin composition parameter for the carbon number of n represented by formula (2) below. In formula (2), n represents an integer of 10-24, and a, b and c respectively represent the proportion (in terms of molar value) of normal paraffins with carbon number of n, of isoparaffins with carbon number of n and one branch and of isoparaffins with carbon number of n and two or more branches, with respect to the total amount of paraffins with carbon number of n. [ Mathematical ⁢ ⁢ Formula ⁢ ⁢ 1 ] 340.0 ≤ ∑ n = 10 24 ⁢ ⁢ f ⁡ ( n ) ≤ 400.0 ( 1 ⁢ - ⁢ 1 ) [ Mathematical ⁢ ⁢ Formula ⁢ ⁢ 2 ] f ⁡ ( n ) = 27.45 - 3.55 ⁢ ( b / a ) - 0.65 ⁢ ( c / a ) ( 2 ) [ Mathematical ⁢ ⁢ Formula ⁢ ⁢ 3 ] 370.0 ≤ ∑ n = 10 24 ⁢ ⁢ f ⁡ ( n ) ≤ 430.0 ( 1 ⁢ - ⁢ 2 )
    • 本发明提供了一种具有满足以下不等式(1-1)所示条件的C10-24链烷烃组合物,不高于-6.0℃的缓冷浊点和不高于 本发明还提供了一种具有满足下述不等式(1-2)所示条件的C10-24链烷烃组合物的蒸汽油组合物,蒸馏温度为250℃的馏出物体积(E250) 为5-45%,缓冷浊点高于-6.0℃。在不等式(1-1)和(1-2)中,n为石蜡的碳数,f(n)为石蜡 由下式(2)表示的碳数n的组成参数。 在式(2)中,n表示10-24的整数,a,b和c分别表示碳数为n的异链烷烃的碳数为n的正构链烷烃的比例(以摩尔数计) 分支和碳数为n和两个或更多个分支的异链烷烃,相对于碳数为n的链烷烃的总量。 [数学式·公式1]340.0≤Σn = 10 24·塞特·⁡(n)≤400.0(1·1)[数学式公式2] f⁡(n)= 27.45〜3.55 (b / a)-0.65(c / a)(2)[数学式公式3]370.0≤Σn = 10 24通过f(n)≤430.0(1-2)
    • 4. 发明申请
    • Light Oil Composition
    • 轻油组合物
    • US20090165362A1
    • 2009-07-02
    • US12295191
    • 2007-03-07
    • Yasutoshi IguchiHideaki SuganoOsamu Tamura
    • Yasutoshi IguchiHideaki SuganoOsamu Tamura
    • C10L1/08
    • C10L1/08
    • The invention provides a gas oil composition wherein the molar ratio of isoparaffins with carbon number of m and two or more branches to isoparaffins with carbon number of m and one branch within the range of C10-21 is 0.05-3.5, wherein m is an integer of 10-21, and the molar ratio of isoparaffins with carbon number of n and two or more branches to isoparaffins with carbon number of n and one branch within the range of C22-25 is 0.1-10.0, wherein n is an integer of 22-25. The invention also provides a gas oil composition wherein the molar ratio of isoparaffins with carbon number of m and two or more branches to isoparaffins with carbon number of m and one branch within the range of C10-23 is 0.05-4.0, wherein m is an integer of 10-23, and the distillate volume at a distillation temperature of 250° C. (E250) is 15-65%.
    • 本发明提供一种瓦斯油组合物,其中碳原子数为m和两个或多个分支的异链烷烃与碳数为m的异链烷烃与一个分支在C10-21的范围内的摩尔比为0.05-3.5,其中m为整数 为10-21,碳原子数n和两个或多个分支的异链烷烃与碳数为n的异链烷烃和C22-25的一个分支的摩尔比为0.1-10.0,其中n为22的整数 -25。 本发明还提供了一种瓦斯油组合物,其中碳数为m和两个或更多个分支的异链烷烃与碳数为m和一个分支在C10-23范围内的异链烷烃的摩尔比为0.05-4.0,其中m为 蒸馏温度为250℃的馏出物体积(E250)为15-65%。
    • 6. 发明申请
    • PROCESS FOR PRODUCING HYDROCARBON OIL
    • 生产油料油的工艺
    • US20110218376A1
    • 2011-09-08
    • US13119333
    • 2009-09-16
    • Yasutoshi IguchiTatsuo HamamatsuHideki OnoAkira KoyamaHideshi Iki
    • Yasutoshi IguchiTatsuo HamamatsuHideki OnoAkira KoyamaHideshi Iki
    • C07C1/207
    • C10G3/46C10G3/49C10G3/50C10G45/04C10G45/06C10G45/08C10G2300/1014C10G2300/1018C10G2300/202C10G2300/207C10G2300/4006C10G2300/4012C10G2300/4081C10G2300/70C10G2400/02C10G2400/04C10G2400/08Y02P30/20
    • The method for manufacturing a hydrocarbon oil of the present invention comprises a first step wherein a plurality of reaction zones filled with a specific catalyst is disposed in series and a feedstock oil containing an oxygen-containing hydrocarbon compound derived from an animal or vegetable oil is supplied and hydrotreated under the conditions of a hydrogen pressure of 1 MPa or more and 10 MPa or less in each of the reaction zones; and a second step wherein hydrogen, hydrogen sulfide, carbon dioxide and water are removed from a product to be treated obtained in the first step to obtain a hydrocarbon oil. Among the plurality of reaction zones, the inlet temperature of the reaction zone disposed on the most upstream side is 150° C. or more and 250° C. or less, the inlet temperature of the second most upstream reaction zone or below is equal to or higher than the condensation temperature of water, and the outlet temperature of the reaction zone disposed on the most downstream side is 260° C. or more and 360° C. or less. The feedstock oil comprises a recycled oil containing a specific amount of a part of the hydrocarbon oil obtained in the second step and a specific amount of a sulfur-containing hydrocarbon compound.
    • 本发明的烃油的制造方法包括第一步骤,其中填充有特定催化剂的多个反应区域串联设置,并且供给含有源自动物或植物油的含氧烃化合物的原料油 并在每个反应区中在氢气压力为1MPa以上且10MPa以下的条件下进行加氢处理; 第二步骤,从第一步骤中得到的待处理产物中除去氢,硫化氢,二氧化碳和水,得到烃油。 在多个反应区域中,设置在最上游侧的反应区域的入口温度为150℃以上且250℃以下,第二上游反应区域以下的入口温度等于 或高于水的冷凝温度,并且设置在最下游侧的反应区的出口温度为260℃以上且360℃以下。 原料油包含含有特定量的第二步获得的一部分烃油的再循环油和特定量的含硫烃化合物。
    • 8. 发明申请
    • PROCESS FOR PRODUCING HYDROCARBON OIL
    • 生产油料油的工艺
    • US20110237853A1
    • 2011-09-29
    • US13119310
    • 2009-09-16
    • Tatsuo HamamatsuHideki OnoYasutoshi IguchiHideshi IkiYoshihiko Kinoshita
    • Tatsuo HamamatsuHideki OnoYasutoshi IguchiHideshi IkiYoshihiko Kinoshita
    • C10G1/00
    • C10G45/02C10G3/46C10G3/49C10G3/50C10G2300/1014C10G2300/1018C10G2300/202C10G2300/4018Y02P30/20
    • A method for manufacturing a hydrocarbon oil, comprising: a first step wherein a feedstock oil containing an oxygen-containing organic compound and a water-insoluble chlorine-containing compound is brought into contact with a hydrogenation catalyst comprising a support containing a porous inorganic oxide and one or more metals selected from Group VIA and Group VIII of the periodic table supported on the support in the presence of hydrogen to generate a hydrocarbon oil and water in a vapor state by the hydrodeoxygenation of an oxygen-containing organic compound and convert the water-insoluble chlorine-containing compound into a water-soluble chlorine-containing compound; a second step wherein the water in the reaction product of the first step is maintained in a vapor state and the reaction product of the first step is brought into contact with a nitrogen-containing Brønsted base compound which has a boiling point at normal pressure of 100° C. or less and is water-soluble to obtain a product to be treated; and a third step wherein the product to be treated is cooled to a temperature not higher than the temperature at which water in a vapor state is liquefied to form an aqueous phase containing a water-soluble chlorine-containing compound and a nitrogen-containing Brønsted base compound and then separate the aqueous phase from an oil to be treated to obtain a product oil containing a hydrocarbon oil.
    • 一种烃油的制造方法,包括:第一工序,其中含有含氧有机化合物的原料油和不溶于水的含氯化合物与含有多孔无机氧化物的载体的氢化催化剂接触, 选自元素周期表第VIA族和第VIII族的一种或多种金属在氢气存在下负载在载体上以通过含氧有机化合物的加氢脱氧产生烃油和蒸气状态的水, 不溶性含氯化合物变成水溶性含氯化合物; 第二步骤,其中第一步骤的反应产物中的水保持蒸气状态,并使第一步的反应产物与常压下的沸点为100的含氮布朗斯台德碱化合物接触 ℃或更低,并且是水溶性的,以获得待处理的产品; 以及第三步骤,其中待处理的产品被冷却到不高于蒸汽状态的水液化的温度的温度,以形成含有水溶性含氯化合物和含氮布朗斯台德碱的水相 化合物,然后将水相与待处理的油分离,得到含有烃油的产物油。