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1. 发明授权

US07893145B2 Oxygen-absorbing resin composition 有权
标题翻译：吸氧树脂组合物
公开(公告)号：US07893145B2
公开(公告)日：2011-02-22
申请号：US12298770
申请日：2007-04-27
申请人： Yasutaka Inubushi , Tatsuhiko Hayashibara , Hideharu Iwasaki , Kazuhiro Kurosaki , Emi Yatagai , Tomoyuki Watanabe , Mie Kanehara
发明人： Yasutaka Inubushi , Tatsuhiko Hayashibara , Hideharu Iwasaki , Kazuhiro Kurosaki , Emi Yatagai , Tomoyuki Watanabe , Mie Kanehara
IPC分类号： C08K5/04 , C08K5/09 , B32B27/00
CPC分类号： C08L29/04 , B32B1/08 , B32B27/18 , B32B27/304 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2307/7244 , B32B2439/00 , C08K5/098 , C08K2201/012 , C08L65/00 , Y10T428/31678 , Y10T428/31855 , C08L2666/02
摘要： The present invention provides an oxygen-absorbing resin composition containing a thermoplastic resin (A) having carbon-carbon double bonds substantially only in the main chain and a transition metal salt (B), and the oxygen absorption amount of 1 mol of carbon-carbon double bond of the thermoplastic resin (A) being 1.6 mols or more.
摘要翻译：本发明提供一种含有基本上仅在主链中具有碳 - 碳双键的热塑性树脂（A）和过渡金属盐（B）的氧吸收性树脂组合物，1摩尔碳 - 碳的氧吸收量热塑性树脂（A）的双键为1.6摩尔以上。

2. 发明申请

US20090169902A1 OXYGEN-ABSORBING RESIN COMPOSITION 有权
标题翻译：氧吸收树脂组合物
公开(公告)号：US20090169902A1
公开(公告)日：2009-07-02
申请号：US12298770
申请日：2007-04-27
申请人： Yasutaka Inubushi , Tatsuhiko Hayashibara , Hideharu Iwasaki , Kazuhiro Kurosaki , Emi Yatagai , Tomoyuki Watanabe , Mie Kanehara
发明人： Yasutaka Inubushi , Tatsuhiko Hayashibara , Hideharu Iwasaki , Kazuhiro Kurosaki , Emi Yatagai , Tomoyuki Watanabe , Mie Kanehara
IPC分类号： B32B27/32 , C08L29/04 , C08L27/06 , C08L33/20 , C08L77/00 , C08K5/098
CPC分类号： C08L29/04 , B32B1/08 , B32B27/18 , B32B27/304 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2307/7244 , B32B2439/00 , C08K5/098 , C08K2201/012 , C08L65/00 , Y10T428/31678 , Y10T428/31855 , C08L2666/02
摘要： The present invention provides an oxygen-absorbing resin composition containing a thermoplastic resin (A) having carbon-carbon double bonds substantially only in the main chain and a transition metal salt (B), and the oxygen absorption amount of 1 mol of carbon-carbon double bond of the thermoplastic resin (A) being 1.6 mols or more.
摘要翻译：本发明提供一种含有基本上仅在主链中具有碳 - 碳双键的热塑性树脂（A）和过渡金属盐（B）的氧吸收性树脂组合物，1摩尔碳 - 碳的氧吸收量热塑性树脂（A）的双键为1.6摩尔以上。

3. 发明申请

US20100051861A1 OXYGEN-ABSORBING RESIN COMPOSITION 审中-公开
标题翻译：氧吸收树脂组合物
公开(公告)号：US20100051861A1
公开(公告)日：2010-03-04
申请号：US12439844
申请日：2007-09-12
申请人： Yasutaka Inubushi , Mie Kanehara , Tatsuhiko Hayashibara , Tomoyuki Watanabe , Hideharu Iwasaki
发明人： Yasutaka Inubushi , Mie Kanehara , Tatsuhiko Hayashibara , Tomoyuki Watanabe , Hideharu Iwasaki
IPC分类号： C09K15/04
CPC分类号： C08L65/00 , B32B1/02 , B32B7/12 , B32B27/08 , B32B27/18 , B32B27/306 , B32B27/32 , B32B27/36 , B32B2307/31 , B32B2307/412 , B32B2307/516 , B32B2307/518 , B32B2307/702 , B32B2307/724 , B32B2307/7244 , B32B2439/00 , B32B2439/60 , B32B2439/70 , B65D65/40 , B65D81/266 , C08K5/098 , C08L9/00 , C08L45/00 , C08L51/003 , C08L53/02 , C08L2666/02 , C08L2666/24 , C08L2666/04
摘要： It is an object of the invention to provide an oxygen-absorbing resin composition that has excellent oxygen absorbency, in particular a high initial oxygen absorption rate, does not generate an unpleasant odor as a result of oxygen absorption and has high transparency. This objective is achieved by providing an oxygen-absorbing resin composition containing a thermoplastic resin (A) having the structural unit represented by formula (I) below, a transition metal salt (B) and, as necessary, a matrix resin (C): wherein R1 and R2 are as defined in the specification.
摘要翻译：本发明的目的是提供具有优异的氧吸收性，特别是高的初始氧吸收速率的氧吸收性树脂组合物，不会由于氧吸收而产生不愉快的气味并具有高透明度。该目的通过提供含有具有下述通式（I）所示结构单元的热塑性树脂（A），过渡金属盐（B）和根据需要的基体树脂（C）的氧吸收性树脂组合物来实现：其中R1和R2如说明书中所定义。

4. 发明申请

US20060281882A1 Oxygen absorption resin composition 有权
公开(公告)号：US20060281882A1
公开(公告)日：2006-12-14
申请号：US11442998
申请日：2006-05-31
申请人： Yoshihisa Tsuji , Yasutaka Inubushi , Mie Kodani , Tatsuhiko Hayashibara , Tomoyuki Watanabe , Hideharu Iwasaki
发明人： Yoshihisa Tsuji , Yasutaka Inubushi , Mie Kodani , Tatsuhiko Hayashibara , Tomoyuki Watanabe , Hideharu Iwasaki
IPC分类号： C08F30/04 , C08F230/04
CPC分类号： B32B27/08 , B32B27/32 , B32B27/36 , B32B2307/7244 , C08K3/10 , C08K2201/008 , C08L9/00 , C08L11/00 , C08L15/00 , C08L23/04 , C08L23/06 , C08L29/04 , Y10T428/1352 , Y10T428/31855 , Y10T428/31931 , C08L21/00 , C08L2666/08
摘要： An oxygen absorption resin composition is provided that comprises a thermoplastic resin (A) having carbon-carbon double bonds substantially in its main chain and a transition metal salt (B). If necessary, the composition further comprises a gas barrier resin (C), a compatibilizer (D) and the like. The composition has excellent oxygen absorption properties, and when the composition is employed, generation of odorous substances derived from the decomposition of resins as a result of oxygen absorption can be suppressed.

5. 发明授权

US07608341B2 Oxygen absorption resin composition 有权
公开(公告)号：US07608341B2
公开(公告)日：2009-10-27
申请号：US11442998
申请日：2006-05-31
申请人： Yoshihisa Tsuji , Yasutaka Inubushi , Mie Kodani , Tatsuhiko Hayashibara , Tomoyuki Watanabe , Hideharu Iwasaki
发明人： Yoshihisa Tsuji , Yasutaka Inubushi , Mie Kodani , Tatsuhiko Hayashibara , Tomoyuki Watanabe , Hideharu Iwasaki
IPC分类号： B32B27/00
CPC分类号： B32B27/08 , B32B27/32 , B32B27/36 , B32B2307/7244 , C08K3/10 , C08K2201/008 , C08L9/00 , C08L11/00 , C08L15/00 , C08L23/04 , C08L23/06 , C08L29/04 , Y10T428/1352 , Y10T428/31855 , Y10T428/31931 , C08L21/00 , C08L2666/08
摘要： An oxygen absorption resin composition is provided that comprises a thermoplastic resin (A) having carbon-carbon double bonds substantially in its main chain and a transition metal salt (B). If necessary, the composition further comprises a gas barrier resin (C), a compatibilizer (D) and the like. The composition has excellent oxygen absorption properties, and when the composition is employed, generation of odorous substances derived from the decomposition of resins as a result of oxygen absorption can be suppressed.

6. 发明授权

US07700698B2 Process for producing ring-opening metathesis polymer 有权
标题翻译：开环易位聚合物的制备方法
公开(公告)号：US07700698B2
公开(公告)日：2010-04-20
申请号：US11815803
申请日：2006-02-07
申请人： Hideharu Iwasaki , Yasutaka Inubushi
发明人： Hideharu Iwasaki , Yasutaka Inubushi
IPC分类号： C08F4/80 , C08G61/08 , C08F2/44
CPC分类号： C08G61/08 , C08K5/13 , C08K5/50 , C08K5/526
摘要： A process of producing a ring-opening metathesis polymer characterized in that a treatment to decrease the amount of oxygen and/or peroxide in at least one kind of polymerization starting material is performed prior to the ring-opening metathesis polymerization reaction of a cyclic olefin performed in the presence of a ruthenium carbene complex (catalyst). Treatments to decrease the amount of oxygen and/or peroxide include applying an adsorbent to a polymerization starting material to remove oxygen and/or peroxide by adsorption, applying an antioxidant to a polymerization starting material to decompose oxygen or peroxide, and the like.
摘要翻译：一种制备开环易位聚合物的方法，其特征在于在至少一种聚合原料中减少氧和/或过氧化物的量的处理在环烯烃的开环易位聚合反应之前进行在钌卡宾络合物（催化剂）的存在下。减少氧和/或过氧化物的量的处理包括将吸附剂施加到聚合起始材料上以通过吸附除去氧和/或过氧化物，将抗氧化剂施加到聚合起始材料上以分解氧气或过氧化物等。

7. 发明申请

US20090023874A1 PROCESS FOR PRODUCING RING-OPENING METATHESIS POLYMER 有权
标题翻译：生产开环元素聚合物的方法
公开(公告)号：US20090023874A1
公开(公告)日：2009-01-22
申请号：US11815803
申请日：2006-02-07
申请人： Hideharu Iwasaki , Yasutaka Inubushi
发明人： Hideharu Iwasaki , Yasutaka Inubushi
IPC分类号： C08F4/60 , C08F4/80
CPC分类号： C08G61/08 , C08K5/13 , C08K5/50 , C08K5/526
摘要： The process of producing a ring-opening metathesis polymer of the present invention is mainly characterized in that a treatment to decrease the amount of oxygen and/or peroxide in at least one kind of polymerization starting material is performed prior to the ring-opening metathesis polymerization reaction of a cyclic olefin performed in the presence of a ruthenium carbene complex (catalyst). As used herein, the “polymerization starting material” refers to various materials used for a ring-opening metathesis polymerization reaction and present in the reaction system, such as ruthenium carbene complex (catalyst) and cyclic olefin (monomer), as well as solvents, chain transfer agents and the like. In addition, the method for a treatment to decrease the amount of oxygen and/or peroxide include a method comprising applying an adsorbent to a polymerization starting material to remove oxygen and/or peroxide by adsorption, a method comprising applying an antioxidant to a polymerization starting material to decompose oxygen or peroxide and the like.According to the present invention, a ring-opening metathesis polymer can be produced at a higher reaction rate without degrading the high activity inherently possessed by a ruthenium carbene complex (catalyst). Because of being free of a decrease in the concentration of the catalyst maintaining the high activity during reaction, the thus-obtained polymer shows a small difference between polymerization lots and becomes homogeneous, and a polymer having a comparatively sharp molecular weight distribution can be produced.
摘要翻译：本发明的开环易位聚合物的制造方法的主要特征在于，在开环易位聚合之前进行至少一种聚合原料中的氧和/或过氧化物的量的减少处理在钌卡宾络合物（催化剂）的存在下进行的环状烯烃的反应。如本文所用，“聚合原料”是指用于开环易位聚合反应并存在于反应体系中的各种材料，例如钌卡宾络合物（催化剂）和环烯烃（单体），以及溶剂，链转移剂等。此外，减少氧和/或过氧化物的量的处理方法包括将吸附剂施加到聚合起始材料以通过吸附除去氧和/或过氧化物的方法，包括将抗氧化剂施加到聚合开始的方法用于分解氧气或过氧化物等的物质。根据本发明，可以以更高的反应速率制备开环易位聚合物，而不会降低钌卡宾配合物（催化剂）固有的高活性。由于在反应过程中催化剂的浓度降低而保持高的活性，所以由此获得的聚合物在聚合批间之间显示出很小的差异并且变得均匀，并且可以生产具有相当尖锐的分子量分布的聚合物。

8. 发明授权

US08044149B2 Process for production of hydrogenated polymers and hydrogenated polymers 有权
标题翻译：氢化聚合物和氢化聚合物的生产方法
公开(公告)号：US08044149B2
公开(公告)日：2011-10-25
申请号：US12442305
申请日：2007-09-20
申请人： Hideharu Iwasaki , Yasutaka Inubushi
发明人： Hideharu Iwasaki , Yasutaka Inubushi
IPC分类号： C08F8/42
CPC分类号： C08G61/08
摘要： Provision of, in a process of producing a hydrogenated polymer, which comprises steps of sequentially performing, in the presence of a ruthenium carbene complex, a ring-opening metathesis polymerization reaction of a cyclic olefin and a hydrogenation reaction of a ring-opening metathesis polymer produced by the polymerization reaction to give a hydrogenated polymer, a simple and economic process of obtaining a hydrogenated polymer having an extremely small content of residual ruthenium derived from the ruthenium carbene complex.A process of producing a hydrogenated polymer, which comprises, in the presence of a ruthenium carbene complex, subjecting a cyclic monoolefin and/or a cyclic diolefin to a ring-opening metathesis polymerization, hydrogenating the resulting ring-opening metathesis polymer to give a hydrogenated polymer, and bringing the hydrogenated polymer in contact with a poor solvent of the hydrogenated polymer in the presence of dissolved hydrogen to allow precipitation. As the poor solvent of the hydrogenated polymer, alcohol having 1 to 6 carbon atoms, ketone having 3 to 6 carbon atoms and the like are preferable.
摘要翻译：在生产氢化聚合物的方法中提供了包括以下步骤：在钌卡宾络合物的存在下，环烯烃的开环易位聚合反应和开环易位聚合物的氢化反应通过聚合反应生成氢化聚合物，获得氢化聚合物的简单且经济的方法，该氢化聚合物的钌卡宾络合物的残余钌含量极少。一种制备氢化聚合物的方法，其包括在钌卡宾络合物的存在下，使环状单烯烃和/或环状二烯烃进行开环易位聚合，将所得开环易位聚合物氢化，得到氢化聚合物，并使氢化聚合物与氢化聚合物的不良溶剂在溶解的氢气存在下接触以允许沉淀。作为氢化聚合物的不良溶剂，优选具有1〜6个碳原子的醇，具有3〜6个碳原子的酮等。

9. 发明申请

US20100029874A1 PROCESS FOR PRODUCTION OF HYDROGENATED POLYMERS AND HYDROGENATED POLYMERS 有权
标题翻译：生产氢化聚合物和加氢聚合物的方法
公开(公告)号：US20100029874A1
公开(公告)日：2010-02-04
申请号：US12442305
申请日：2007-09-20
申请人： Hideharu Iwasaki , Yasutaka Inubushi
发明人： Hideharu Iwasaki , Yasutaka Inubushi
IPC分类号： C08F4/80
CPC分类号： C08G61/08
摘要： Provision of, in a process of producing a hydrogenated polymer, which comprises steps of sequentially performing, in the presence of a ruthenium carbene complex, a ring-opening metathesis polymerization reaction of a cyclic olefin and a hydrogenation reaction of a ring-opening metathesis polymer produced by the polymerization reaction to give a hydrogenated polymer, a simple and economic process of obtaining a hydrogenated polymer having an extremely small content of residual ruthenium derived from the ruthenium carbene complex.A process of producing a hydrogenated polymer, which comprises, in the presence of a ruthenium carbene complex, subjecting a cyclic monoolefin and/or a cyclic diolefin to a ring-opening metathesis polymerization, hydrogenating the resulting ring-opening metathesis polymer to give a hydrogenated polymer, and bringing the hydrogenated polymer in contact with a poor solvent of the hydrogenated polymer in the presence of dissolved hydrogen to allow precipitation. As the poor solvent of the hydrogenated polymer, alcohol having 1 to 6 carbon atoms, ketone having 3 to 6 carbon atoms and the like are preferable.
摘要翻译：在生产氢化聚合物的方法中提供了包括以下步骤：在钌卡宾络合物的存在下，环烯烃的开环易位聚合反应和开环易位聚合物的氢化反应通过聚合反应生成氢化聚合物，获得氢化聚合物的简单且经济的方法，该氢化聚合物的钌卡宾络合物的残余钌含量极少。一种制备氢化聚合物的方法，其包括在钌卡宾络合物的存在下，使环状单烯烃和/或环状二烯烃进行开环易位聚合，将所得开环易位聚合物氢化，得到氢化聚合物，并使氢化聚合物与氢化聚合物的不良溶剂在溶解的氢气存在下接触以允许沉淀。作为氢化聚合物的不良溶剂，优选具有1〜6个碳原子的醇，具有3〜6个碳原子的酮等。

10. 发明申请

US20140224120A1 ADSORBENT 有权
标题翻译：吸引力
公开(公告)号：US20140224120A1
公开(公告)日：2014-08-14
申请号：US14342641
申请日：2012-09-04
申请人： Yasutaka Inubushi , Takashi Hori , Toyoaki Kurihara , Hiroyuki Ogi
发明人： Yasutaka Inubushi , Takashi Hori , Toyoaki Kurihara , Hiroyuki Ogi
IPC分类号： B01J20/26 , B01D53/047 , B01D53/04 , F17C1/00
CPC分类号： B01J20/26 , B01D53/02 , B01D53/0462 , B01D53/047 , B01D2253/112 , B01D2253/202 , B01D2253/204 , B01D2253/25 , B01D2257/504 , B01D2257/7025 , B01D2259/4525 , B01J20/223 , B01J20/261 , B01J20/262 , B01J20/264 , B01J2220/44 , C01B3/508 , C01B13/0281 , C01B17/167 , C01B17/60 , C01B21/0455 , C01B21/20 , C01B23/0057 , C01C1/006 , C07C7/12 , F17C1/00 , F17C11/00 , F17C11/005 , F17C11/007 , Y02C10/08 , Y02C20/20 , Y02P20/152 , Y02P20/156 , C07C9/04 , C07C9/06
摘要： An object of the present invention is to provide an adsorbent material having excellent gas storage performance and gas separation performance.This object can be achieved by an adsorbent material comprising a composition comprising a metal complex (A) and an elastomer (B), the metal complex (A) containing an anionic ligand and at least one metal ion selected from ions of metals belonging to Groups 1 to 13 of the periodic table, the metal complex (A) being capable of undergoing a volume change upon adsorption, and the mass ratio of the metal complex (A) and the elastomer (B) being within the range of 1:99 to 99:1.
摘要翻译：本发明的目的是提供一种具有优异的气体储存性能和气体分离性能的吸附材料。该目的可以通过包含含有金属络合物（A）和弹性体（B），含有阴离子配体的金属络合物（A）和选自属于基团的金属离子的至少一种金属离子的组合物的吸附材料来实现 1〜13，金属络合物（A）能够在吸附时发生体积变化，金属络合物（A）和弹性体（B）的质量比在1:99〜 99：1。

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