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    • 7. 发明授权
    • Fibrous apatite and method for producing the same
    • 纤维磷灰石及其制造方法
    • US4659617A
    • 1987-04-21
    • US773482
    • 1985-09-06
    • Shigeo FujiiShoichi MoriJyoichi Tabuchi
    • Shigeo FujiiShoichi MoriJyoichi Tabuchi
    • A61F2/00A61L27/12C12N1/00D01F9/08B32B7/02C01B15/16A61C8/00B29C33/40
    • C12N1/00A61L27/12D01F9/08A61F2310/00293Y10T428/249921
    • The present invention provides a fibrous product of apatite comprising one or more apatites selected from a group of apatites represented by the general formula:M.sub.10 (ZO.sub.4).sub.6 X.sub.2wherein M represents Ca, Ba, Mg, Sr, Pb, Cd, Fe and the like, ZO.sub.4 represents PO.sub.4, AsO.sub.4, VO.sub.4, CO.sub.3 and the like, and X represents F, Cl, OH and the like. This fibrous product of apatite has many applications such as uses for medical treatment, large scale microorganism cultivating media and others, and particularly it is useful as apatite implant materials having a good compatibility with living organism and superior workability.A fibrous apatite product of this invention may be produced by a method comprising the steps of:(a) preparing a dispersion of apatite by dispersing fine apatite particles uniformly in a solution of binder in water, said apatite being one or more apatites selected from a group of apatites represented by the general formula:M.sub.10 (ZO.sub.4).sub.6 X.sub.2 wherein M represents Ca, Ba, Mg, Sr, Pb, Cd, Fe and the like, ZO.sub.4 represents PO.sub.4, AsO.sub.4, VO.sub.4, CO.sub.3 and the like, and X represents F, Cl, OH and the like;(b) continuously exctruding the thus prepared dispersion through a plurality of spinning orifices in a spinning apparatus while simultaneously stretching the dispersion into a fibrous state with the aid of a high speed air flow to form a stream of fine fibers;(c) heating said fiber stream to evaporate the water in the fibers;(d) blowing said dewatered fiber stream upon a collector means to form a cotton-like product of apatite bonded together by the binder; and(e) if desired, calcining said cotton-like product.
    • 本发明提供一种磷灰石的纤维制品,其包含一种或多种选自以下通式代表的磷灰石的磷灰石:M10(ZO4)6X2,其中M表示Ca,Ba,Mg,Sr,Pb,Cd,Fe等 ,ZO4表示PO4,AsO4,VO4,CO3等,X表示F,Cl,OH等。 磷灰石的这种纤维状产品具有许多用途,例如医疗用途,大规模微生物培养基等,特别适用于与活体相容性好,加工性好的磷灰石植入材料。 本发明的纤维状磷灰石产品可以通过包括以下步骤的方法制备:(a)通过将细磷灰石颗粒均匀地分散在粘合剂的水溶液中来制备磷灰石的分散体,所述磷灰石是一种或多种磷灰石,其选自 由通式M10(ZO4)6X2表示的磷灰石组,其中M表示Ca,Ba,Mg,Sr,Pb,Cd,Fe等,ZO4表示PO4,AsO4,VO4,CO3等,X表示 F,Cl,OH等; (b)通过纺丝设备中的多个纺丝孔连续地将这样制备的分散体除去,同时借助高速空气流将分散体拉伸成纤维状态,形成细纤维流; (c)加热所述纤维流以蒸发纤维中的水; (d)将所述脱水纤维流吹送到收集器装置上以形成通过粘合剂粘合在一起的磷灰石的棉状产品; 和(e)如果需要,煅烧所述棉状产品。