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1. 发明授权

US08405958B2 Conductive polymer suspension and method for producing the same, conductive polymer material, and solid electrolytic capacitor and method for producing the same 有权
标题翻译：导电聚合物悬浮体及其制造方法，导电聚合物材料和固体电解电容器及其制造方法
公开(公告)号：US08405958B2
公开(公告)日：2013-03-26
申请号：US13013361
申请日：2011-01-25
申请人： Naoki Takahashi , Tomoki Nobuta , Yasuhisa Sugawara , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
发明人： Naoki Takahashi , Tomoki Nobuta , Yasuhisa Sugawara , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
IPC分类号： H01G9/025
CPC分类号： H01G9/0036 , C08G2261/3223 , C08G2261/794 , C08K5/24 , C08L25/18 , C08L65/00 , H01G9/028 , H01G9/15 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： The present invention provides a conductive polymer suspension for providing a conductive polymer material having high conductivity and a method for producing the same, and particularly provides a solid electrolytic capacitor having low ESR and a method for producing the same. In an emulsion comprising a dopant of a low molecular organic acid or a salt thereof, obtained by emulsifying a monomer providing a conductive polymer, using a nonionic surfactant, in a water, the monomer is subjected to chemical oxidative polymerization, using an oxidant, to synthesize a conductive polymer. The obtained conductive polymer is purified, and then, the purified conductive polymer and an oxidant are mixed in an aqueous solvent containing a polyacid component to produce a conductive polymer suspension.
摘要翻译：本发明提供一种用于提供具有高导电性的导电聚合物材料的导电聚合物悬浮体及其制造方法，特别是提供一种具有低ESR的固体电解电容器及其制造方法。在包含低分子有机酸或其盐的掺杂剂的乳液中，通过使用非离子表面活性剂在水中乳化提供导电聚合物的单体获得，使用氧化剂对单体进行化学氧化聚合合成导电聚合物。纯化得到的导电性聚合物，然后将纯化的导电性聚合物和氧化剂混合在含有多元酸成分的水性溶剂中，制成导电性高分子悬浮液。

2. 发明申请

US20120256117A1 CONDUCTIVE POLYMER SUSPENSION AND METHOD FOR PRODUCING THE SAME, CONDUCTIVE ORGANIC MATERIAL, AND ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：导电聚合物悬浮体及其制造方法，导电有机材料和电解电容器及其制造方法
公开(公告)号：US20120256117A1
公开(公告)日：2012-10-11
申请号：US13083001
申请日：2011-04-08
申请人： Yasuhisa SUGAWARA , Tomoki Nobuta , Naoki Takahashi , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
发明人： Yasuhisa SUGAWARA , Tomoki Nobuta , Naoki Takahashi , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
IPC分类号： H01B1/12 , B05D5/12 , H01G9/025
CPC分类号： H01G9/028 , H01B1/127
摘要： Provided are an electroconductive polymer suspension solution and a method for producing the same, which has excellent adhesion to a substrate and excellent liquid resistance and which can provide an organic material having high electroconductivity. An electroconductive polymer suspension solution of an exemplary embodiment of the invention contains an electroconductive polymer, at least one kind of a water-soluble polyhydric alcohol, and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol. The electroconductive polymer suspension solution can be produced by collecting an electroconductive polymer which is obtained by chemical oxidative polymerization of a monomer giving the electroconductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant, by contacting the electroconductive polymer with an oxidant in an aqueous solvent containing a polyacid, and further by mixing at least one kind of a water-soluble polyhydric alcohol and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol.
摘要翻译：提供一种导电聚合物悬浮液及其制造方法，其具有优异的对基材的粘附性和优异的耐液性，并且可以提供具有高导电性的有机材料。本发明的一个示例性实施方案的导电聚合物悬浮液包含导电聚合物，至少一种水溶性多元醇和至少一种具有两个或更多个官能团的水溶性有机物质，其可以是与水溶性多元醇缩合。导电聚合物悬浮液可以通过收集导电聚合物来制备，导电聚合物通过使含氧有机酸或其盐作为掺杂剂的溶剂中的氧化剂通过化学氧化聚合得到导电聚合物而获得，聚合物与含有多酸的水性溶剂中的氧化剂反应，进一步通过混合至少一种水溶性多元醇和至少一种具有两个或更多个官能团的水溶性有机物质，所述官能团可以与水溶性多元醇。

3. 发明授权

US09087640B2 Conductive polymer suspension and method for producing the same, conductive organic material, and electrolytic capacitor and method for producing the same 有权
标题翻译：导电聚合物悬浮体及其制造方法，导电有机材料和电解电容器及其制造方法
公开(公告)号：US09087640B2
公开(公告)日：2015-07-21
申请号：US13083001
申请日：2011-04-08
申请人： Yasuhisa Sugawara , Tomoki Nobuta , Naoki Takahashi , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
发明人： Yasuhisa Sugawara , Tomoki Nobuta , Naoki Takahashi , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
IPC分类号： H01B1/00 , E04B1/74 , B05D5/12 , H01G9/028 , H01B1/12
CPC分类号： H01G9/028 , H01B1/127
摘要： Provided are an electroconductive polymer suspension solution and a method for producing the same, which has excellent adhesion to a substrate and excellent liquid resistance and which can provide an organic material having high electroconductivity. An electroconductive polymer suspension solution of an exemplary embodiment of the invention contains an electroconductive polymer, at least one kind of a water-soluble polyhydric alcohol, and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol. The electroconductive polymer suspension solution can be produced by collecting an electroconductive polymer which is obtained by chemical oxidative polymerization of a monomer giving the electroconductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant, by contacting the electroconductive polymer with an oxidant in an aqueous solvent containing a polyacid, and further by mixing at least one kind of a water-soluble polyhydric alcohol and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol.
摘要翻译：提供一种导电聚合物悬浮液及其制造方法，其具有优异的对基材的粘附性和优异的耐液性，并且可以提供具有高导电性的有机材料。本发明的一个示例性实施方案的导电聚合物悬浮液包含导电聚合物，至少一种水溶性多元醇和至少一种具有两个或更多个官能团的水溶性有机物质，其可以是与水溶性多元醇缩合。导电聚合物悬浮液可以通过收集导电聚合物来制备，导电聚合物通过使含氧有机酸或其盐作为掺杂剂的溶剂中的氧化剂通过化学氧化聚合得到导电聚合物而获得，聚合物与含有多酸的水性溶剂中的氧化剂反应，进一步通过混合至少一种水溶性多元醇和至少一种具有两个或更多个官能团的水溶性有机物质，所述官能团可以与水溶性多元醇。

4. 发明申请

US20140022705A1 ELECTROCONDUCTIVE POLYMER SOLUTION, ELECTROCONDUCTIVE POLYMER MATERIAL AND METHOD FOR PRODUCING SAME, AND SOLID ELECTROLYTIC CAPACITOR 审中-公开
标题翻译：电极聚合物溶液，电极聚合物材料及其制造方法和固体电解电容器
公开(公告)号：US20140022705A1
公开(公告)日：2014-01-23
申请号：US14110351
申请日：2012-04-09
申请人： Yasuhiro Tomioka , Tomoki Nobuta , Yasuhisa Sugawara , Yuji Yoshida , Satoshi Suzuki
发明人： Yasuhiro Tomioka , Tomoki Nobuta , Yasuhisa Sugawara , Yuji Yoshida , Satoshi Suzuki
IPC分类号： H01G9/028
CPC分类号： H01G9/028 , C08G2261/1424 , C08G2261/3223 , C08G2261/51 , C08G2261/794 , C08G2261/90 , C08K3/24 , C08K5/053 , C08L25/18 , C08L29/04 , C08L65/00 , H01B1/127 , H01G9/0036 , H01G9/15
摘要： This is to provide an electroconductive polymer material which has excellent adhesion to a base and excellent water resistance. Also, this is to provide a solid electrolytic capacitor which has excellent water resistance by using the same. An electroconductive polymer solution according to the present invention contains an electroconductive polymer, at least one water-soluble multivalent alcohol, and at least one oxoacid having two or more hydroxy groups. Since a resin obtained by carrying out a polycondensation reaction of the water-soluble multivalent alcohol and the oxoacid has a cross-linked structure, an electroconductive polymer having lower water-absorbing property and more excellent water resistance in comparison with a resin having a linear structure can be obtained.
摘要翻译：这是提供一种导电聚合物材料，其具有优异的与基材的粘附性和优异的耐水性。此外，这是提供一种通过使用它的耐水性优异的固体电解电容器。根据本发明的导电聚合物溶液含有导电聚合物，至少一种水溶性多价醇和至少一个具有两个或多个羟基的含氧酸。由于通过进行水溶性多价醇和含氧酸的缩聚反应获得的树脂具有交联结构，与具有线性结构的树脂相比，具有较低吸水性和更优异耐水性的导电聚合物可以获得。

5. 发明申请

US20140022706A1 ELECTRIC CONDUCTIVE POLYMER AQUEOUS SUSPENSION AND METHOD FOR PRODUCING THE SAME, ELECTRIC CONDUCTIVE ORGANIC MATERIAL, AND SOLID ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME 审中-公开
标题翻译：导电聚合物水性悬浮体及其制造方法，导电有机材料和固体电解电容器及其制造方法
公开(公告)号：US20140022706A1
公开(公告)日：2014-01-23
申请号：US14110085
申请日：2012-04-09
申请人： Yasuhisa Sugawara , Tomoki Nobuta , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
发明人： Yasuhisa Sugawara , Tomoki Nobuta , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
IPC分类号： H01G9/028 , H01G9/00
CPC分类号： H01G9/028 , C08G73/0266 , C08G2261/3223 , C08G2261/794 , C08J3/05 , C08J2365/00 , C08L65/00 , C08L79/02 , H01B1/122 , H01B1/18 , H01G9/0036 , H01G9/15 , H01G11/48 , Y02E60/13 , C08L25/18
摘要： An electric conductive polymer aqueous suspension is prepared by dispersing an electric conductive polymer powder whose surface is doped with a polyacid in which the number of anion groups is 50% or more and 99% or less with respect to the number of repeating units of the polyacid. By using the electric conductive polymer aqueous suspension, an organic material excellent in adhesiveness to a substrate and humidity resistance, and high in conductivity, as well as a solid electrolytic capacitor low in ESR and excellent in reliability in a high humidity atmosphere, and a method for producing the same can be provided.
摘要翻译：导电性聚合物水性悬浮液是通过将表面掺杂有多酸的导电性聚合物粉末，其中阴离子基数为多酸的重复单元数为50％以上且99％以下。通过使用导电性聚合物水性悬浮液，具有优异的基材粘合性和耐高湿性，导电性高的有机材料以及ESR低，高湿度环境下的可靠性优异的固体电解电容器，可以提供其制造方法。

6. 发明申请

US20140098467A1 ELECTROCONDUCTIVE POLYMER, ELECTROCONDUCTIVE POLYMER AQUEOUS SOLUTION, ELECTROCONDUCTIVE POLYMER FILM, SOLID ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME 审中-公开
标题翻译：电极聚合物，电极聚合物水溶液，电极聚合物膜，固体电解电容器及其制造方法
公开(公告)号：US20140098467A1
公开(公告)日：2014-04-10
申请号：US14119848
申请日：2012-05-30
申请人： Yasuhisa Sugawara , Tomoki Nobuta , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
发明人： Yasuhisa Sugawara , Tomoki Nobuta , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
IPC分类号： H01G9/025 , H01G9/00
CPC分类号： H01G9/025 , C08G2261/3221 , C08G2261/3223 , C08K5/42 , H01G9/0029 , H01G9/028 , C08L65/00 , C08L101/12
摘要： An electroconductive polymer having high electroconductivity, an electroconductive polymer aqueous solution, and an electroconductive polymer film are provided. Further, a solid electrolytic capacitor having a reduced ESR and a method for producing the same are provided. An electroconductive polymer according to an exemplary embodiment of the invention contains a monomolecular organic acid having one anion group and one or more hydrophilic group.
摘要翻译：提供具有高导电性的导电聚合物，导电聚合物水溶液和导电聚合物膜。此外，提供了具有降低的ESR的固体电解电容器及其制造方法。根据本发明的示例性实施方案的导电聚合物包含具有一个阴离子基团和一个或多个亲水基团的单分子有机酸。

7. 发明申请

US20140092529A1 ELECTROCONDUCTIVE POLYMER SOLUTION AND METHOD FOR PRODUCING THE SAME, ELECTROCONDUCTIVE POLYMER MATERIAL, AND SOLID ELECTROLYTIC CAPACITOR USING THE SAME AND METHOD FOR PRODUCING THE SAME 审中-公开
标题翻译：电介质聚合物溶液及其制造方法，电极聚合物材料和使用其的固体电解电容器及其制造方法
公开(公告)号：US20140092529A1
公开(公告)日：2014-04-03
申请号：US14001034
申请日：2012-02-27
申请人： Tomoki Nobuta , Yasuhisa Sugawara , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
发明人： Tomoki Nobuta , Yasuhisa Sugawara , Yuji Yoshida , Satoshi Suzuki , Yasuhiro Tomioka
IPC分类号： H01G9/028 , H01G9/00
CPC分类号： H01G9/028 , C08G2261/3223 , C08K3/04 , C08L25/18 , C08L65/00 , H01B1/127 , H01G9/0036 , H01G9/15 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： Provided are an electroconductive polymer solution in which the carbon material has excellent dispersibility, an electroconductive polymer material which has a high electroconductivity and which can be produced by a simple method, and a solid electrolytic capacitor and a method for producing the same which has a low ESR without increasing a leakage current. An electroconductive polymer solution according to an exemplary embodiment of the invention contains an electroconductive polymer, a polysulfonic acid or a salt thereof which functions as a dopant to the electroconductive polymer, a mixture of a polyacid and a carbon material, and a solvent.
摘要翻译：提供一种其中碳材料具有优异分散性的导电聚合物溶液，具有高导电性并且可以通过简单方法制备的导电聚合物材料，以及固体电解电容器及其制造方法 ESR不增加泄漏电流。根据本发明示例性实施方案的导电聚合物溶液含有导电聚合物，多磺酸或其盐，其用作导电聚合物的掺杂剂，多酸和碳材料的混合物以及溶剂。

8. 发明授权

US09455092B2 Electric conductive polymer suspension and method for producing the same, electric conductive polymer material, and electrolytic capacitor and method for producing the same 有权
标题翻译：导电聚合物悬浮体及其制造方法，导电聚合物材料和电解电容器及其制造方法
公开(公告)号：US09455092B2
公开(公告)日：2016-09-27
申请号：US14118100
申请日：2012-05-17
申请人： Yasuhisa Sugawara , Tomoki Nobuta , Satoshi Suzuki , Yasuhiro Tomioka
发明人： Yasuhisa Sugawara , Tomoki Nobuta , Satoshi Suzuki , Yasuhiro Tomioka
IPC分类号： H01G9/15 , H01G9/028 , H01B1/12 , C08G73/02 , C08L77/00 , C08L65/00 , C09D125/18 , H01G11/48 , H01G11/56 , H01B1/20
CPC分类号： H01G9/15 , C08G73/0266 , C08G2261/3221 , C08G2261/3223 , C08G2261/794 , C08K5/053 , C08L25/18 , C08L65/00 , C08L67/00 , C08L77/00 , C08L101/12 , C09D125/18 , H01B1/127 , H01B1/20 , H01G9/028 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： An electric conductive polymer suspension is produced by performing chemical oxidative polymerization of a monomer for providing an electric conductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant to form an electric conductive polymer, recovering the electric conductive polymer, allowing an oxidant to act on the electric conductive polymer in an aqueous solvent containing a polyacid, and further mixing a dispersant with a branched structure and then pulverizing the electric conductive polymer. According to the electric conductive polymer suspension, an organic material high in conductivity, and excellent in adhesiveness to a substrate and water resistance, and a method for producing the material, as well as an electrolytic capacitor and a method for producing the capacitor can be provided.
摘要翻译：通过在含有有机酸或其盐的溶剂中使用氧化剂作为掺杂剂进行用于提供导电聚合物的单体的化学氧化聚合来制备导电聚合物悬浮液，以形成导电聚合物，回收导电聚合物聚合物，允许氧化剂在含有多酸的水性溶剂中作用于导电聚合物，并进一步混合具有支化结构的分散剂，然后粉碎导电聚合物。根据导电性聚合物悬浮液，可以提供高导电性，对基材的粘附性和耐水性优异的有机材料及其制造方法，以及电解电容器及其制造方法。。

9. 发明申请

US20140211372A1 ELECTRIC CONDUCTIVE POLYMER SUSPENSION AND METHOD FOR PRODUCING THE SAME, ELECTRIC CONDUCTIVE POLYMER MATERIAL, AND ELECTROLYTIC CAPACITOR AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：导电聚合物悬浮体及其制造方法，导电聚合物材料和电解电容器及其制造方法
公开(公告)号：US20140211372A1
公开(公告)日：2014-07-31
申请号：US14118100
申请日：2012-05-17
申请人： Yasuhisa Sugawara , Tomoki Nobuta , Satoshi Suzuki , Yasuhiro Tomioka
发明人： Yasuhisa Sugawara , Tomoki Nobuta , Satoshi Suzuki , Yasuhiro Tomioka
IPC分类号： H01G9/028 , H01G9/15
CPC分类号： H01G9/15 , C08G73/0266 , C08G2261/3221 , C08G2261/3223 , C08G2261/794 , C08K5/053 , C08L25/18 , C08L65/00 , C08L67/00 , C08L77/00 , C08L101/12 , C09D125/18 , H01B1/127 , H01B1/20 , H01G9/028 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： An electric conductive polymer suspension is produced by performing chemical oxidative polymerization of a monomer for providing an electric conductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant to form an electric conductive polymer, recovering the electric conductive polymer, allowing an oxidant to act on the electric conductive polymer in an aqueous solvent containing a polyacid, and further mixing a dispersant with a branched structure and then pulverizing the electric conductive polymer. According to the electric conductive polymer suspension, an organic material high in conductivity, and excellent in adhesiveness to a substrate and water resistance, and a method for producing the material, as well as an electrolytic capacitor and a method for producing the capacitor can be provided.
摘要翻译：通过在含有有机酸或其盐的溶剂中使用氧化剂作为掺杂剂进行用于提供导电聚合物的单体的化学氧化聚合来制备导电聚合物悬浮液，以形成导电聚合物，回收导电聚合物聚合物，允许氧化剂在含有多酸的水性溶剂中作用于导电聚合物，并进一步混合具有支化结构的分散剂，然后粉碎导电聚合物。根据导电性聚合物悬浮液，可以提供高导电性，对基材的粘附性和耐水性优异的有机材料及其制造方法，以及电解电容器及其制造方法。。

10. 发明申请

US20110129241A1 IMAGE FORMING APPARATUS USING PLURALITY OF ROTATION MEMBERS, AND CONTROL METHOD THEREOF 有权
标题翻译：使用旋转成员的多样性的图像形成装置及其控制方法
公开(公告)号：US20110129241A1
公开(公告)日：2011-06-02
申请号：US12953712
申请日：2010-11-24
申请人： Yasuhiro Tomioka , Yasuhiro Sendoda , Yoshimichi Ikeda
发明人： Yasuhiro Tomioka , Yasuhiro Sendoda , Yoshimichi Ikeda
IPC分类号： G03G15/00
CPC分类号： G03G15/5008 , G03G15/1615 , G03G15/757
摘要： An image forming apparatus includes first and second rotation members which are a plurality of rotation members for performing image formation and rotate in contact with each other. A first driving motor drives the first rotation member. A second driving motor drives the second rotation member. The obtaining unit obtains pieces of motor driving information about driving states of the first or second driving motor at respective relative driving speeds when the relative driving speed of the second driving motor with respect to the driving speed of the first driving motor is changed to a plurality of relative driving speeds. The control unit controls the driving speed of at least either the first or second driving motor in image formation to reduce the relative speed difference between the circumferential velocities of the first and second rotation members based on the pieces of motor driving information obtained by the obtaining unit.
摘要翻译：图像形成装置包括第一和第二旋转构件，其是用于进行图像形成并彼此旋转的多个旋转构件。第一驱动马达驱动第一旋转构件。第二驱动马达驱动第二旋转构件。当第二驱动电动机相对于第一驱动电动机的驱动速度的相对驱动速度改变为多个时，获取单元以相应的驱动速度获得关于第一或第二驱动电动机的驱动状态的电动机驱动信息的相对行驶速度。控制单元基于由获取单元获得的电动机驱动信息来控制图像形成中的第一或第二驱动电动机中的至少一个的驱动速度，以减小第一和第二旋转构件的圆周速度之间的相对速度差。

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