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    • 3. 发明申请
    • Bio-based Polyethylene Terephthalate Polymer and Method of Making Same
    • 生物基聚对苯二甲酸乙二醇酯聚合物及其制备方法
    • US20110262669A1
    • 2011-10-27
    • US13169562
    • 2011-06-27
    • Robert M. KriegelXiaoyan HuangMikell W. Schultheis
    • Robert M. KriegelXiaoyan HuangMikell W. Schultheis
    • B32B1/08
    • C08G63/183C08G63/199C08G63/78Y10T428/1352Y10T428/1379
    • A bio-based polyethylene terephthalate polymer comprising from about 25 to about 75 weight percent of a terephthalate component and from about 20 to about 50 weight percent of a diol component, wherein at least about one weight percent of at least one of the terephthalate and/or the diol component is derived from at least one bio-based material. A method of producing a bio-based polyethylene terephthalate polymer comprising obtaining a diol component comprising ethylene glycol, obtaining a terephthalate component comprising terephthalic acid, wherein at least one of the diol component and/or the diol component is derived from at least one bio-based material, and reacting the diol component and the terephthalate component to form a bio-based polyethylene terephthalate polymer comprising from about 25 to about 75 weight percent of the terephthalate component and from about 20 to about 50 weight percent of the diol component.
    • 一种基于生物的聚对苯二甲酸乙二醇酯聚合物,其包含约25至约75重量%的对苯二甲酸酯组分和约20至约50重量%的二醇组分,其中至少约1重量%的至少一种对苯二甲酸酯和/ 或二醇组分衍生自至少一种基于生物的材料。 一种制备生物基聚对苯二甲酸乙二醇酯聚合物的方法,包括获得包含乙二醇的二醇组分,得到包含对苯二甲酸的对苯二甲酸酯组分,其中至少一种二醇组分和/或二醇组分衍生自至少一种生物基聚对苯二甲酸乙二醇酯, 并使二元醇组分和对苯二甲酸酯组分反应形成一种生物基聚对苯二甲酸乙二醇酯聚合物,其包含约25至约75重量%的对苯二甲酸酯组分和约20至约50重量%的二醇组分。
    • 9. 发明授权
    • Method to reduce regenerated acetaldehyde in pet resin
    • 减少宠物树脂中再生乙醛的方法
    • US5874517A
    • 1999-02-23
    • US997402
    • 1997-12-23
    • Xiaoyan HuangLigia Dominguez
    • Xiaoyan HuangLigia Dominguez
    • C08G63/183C08G63/78C08G63/85C08G63/86C08K5/00C08G63/02
    • C08G63/78C08K5/005C08G63/183C08G63/85C08G63/86
    • There is disclosed a process for reducing the amount of acetaldehyde generated when polyethylene terephthalate (PET) chip is subjected to high temperatures in order to render the PET chip suitable for making food containers, particularly beverage bottles. This process comprises the addition of primary and secondary antioxidants either prior to or after the PET polycondensation reaction in order to reduce the amount of regenerated acetaldehyde produced by the polymer. The polyethylene terephthalate produced by this process reduces regenerated acetaldehyde by at least 25% in comparison to control resin produced without antioxidants, while maintaining suitable color for use as clear glass replacement. There is also disclosed a process for molding a PET preform wherein the polymer prepared as described above is melted, formed into the desired preform shape, and solidified by cooling. This preform can then be reheated above its glass transition temperature and molded into the desired container shape.
    • 公开了当聚对苯二甲酸乙二醇酯(PET)芯片经受高温时产生的乙醛量减少以使PET芯片适合于制造食品容器,特别是饮料瓶的方法。 该方法包括在PET缩聚反应之前或之后添加一级和二级抗氧化剂,以减少聚合物产生的再生乙醛的量。 通过该方法制备的聚对苯二甲酸乙二醇酯与没有抗氧化剂的对照树脂相比,将再生乙醛减少至少25%,同时保持合适的颜色用作透明玻璃替代物。 还公开了一种用于模塑PET预成型件的方法,其中将如上所述制备的聚合物熔化,形成所需的预制件形状,并通过冷却固化。 然后可以将该预成型件重新加热到其玻璃化转变温度以上并模制成所需的容器形状。