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1. 发明授权

US07750070B2 Process for production of clay nanocomposite 失效
标题翻译：粘土纳米复合材料生产工艺
公开(公告)号：US07750070B2
公开(公告)日：2010-07-06
申请号：US11641513
申请日：2006-12-19
申请人： Xiaoping Yang , Joseph John Kulig , Dane Kenton Parker
发明人： Xiaoping Yang , Joseph John Kulig , Dane Kenton Parker
IPC分类号： C08K3/00
CPC分类号： B60C1/0025 , B60C1/0008 , B60C1/0016 , C08K3/346 , C08L9/06
摘要： A process of preparing a nanocomposite comprised of an elastomer and at least partially exfoliated, intercalated water-swellable clay.
摘要翻译：制备由弹性体和至少部分剥离的插层的水溶胀性粘土组成的纳米复合材料的方法。

2. 发明申请

US20080146719A1 Process for production of clay nanocomposite 失效
标题翻译：粘土纳米复合材料生产工艺
公开(公告)号：US20080146719A1
公开(公告)日：2008-06-19
申请号：US11641513
申请日：2006-12-19
申请人： Xiaoping Yang , Joseph John Kulig , Dane Kenton Parker
发明人： Xiaoping Yang , Joseph John Kulig , Dane Kenton Parker
IPC分类号： C08K3/00
CPC分类号： B60C1/0025 , B60C1/0008 , B60C1/0016 , C08K3/346 , C08L9/06
摘要： A process of preparing a nanocomposite comprised of an elastomer and at least partially exfoliated, intercalated water-swellable clay, comprising the steps of (A) forming a first blend of water-swelled clay and anionic polymer particle emulsion by blending: (1) an aqueous mixture comprised of water and a multilayered water-swellable clay, exclusive of an intercalant for said clay, wherein said water-swellable clay is comprised of a plurality of stacked platelets with water-expanded galleries between said platelets, wherein said galleries contain naturally occurring cationic ion exchangeable ions therein, and (2) an emulsion of anionic synthetic vinylpyridine-styrene-butadiene terpolymer (VPSBR) elastomer particles as an aqueous pre-formed elastomer emulsion having a pH in a range of from about 6 to about 11, comprised of anionic elastomer particles (elastomer particles having anions on the surface derived from an anionic surfactant) prepared by aqueous free radical induced polymerization of monomers in the presence of a free radical generating polymerization initiator and non-polymerizable anionic surfactant, wherein said synthetic elastomer particles are derived from an aqueous polymerization of said monomers comprising from about 0.1 to about 40 weight percent of styrene, from about 60 to about 100 weight percent of 1,3-butadiene, and from about 0.1 to about 8 percent by weight of vinylpyridine monomers which have the structural formula: wherein R1 represents a hydrogen atom or a straight chain or branched alkyl group containing 1 to 4 carbon atoms; and (B) blending with said first blend an aqueous mixture comprised of water and inorganic acid having a pH in a range of about 1 to about 4.
摘要翻译：一种制备由弹性体和至少部分剥离的插层的水溶胀性粘土组成的纳米复合材料的方法，包括以下步骤：（A）通过以下步骤形成水溶胀粘土和阴离子聚合物颗粒乳液的第一共混物：（1）由水和多层水溶胀性粘土组成的水性混合物，不包括用于所述粘土的插入剂，其中所述水溶胀性粘土由在所述血小板之间的多个具有水膨胀图案的层叠血小板组成，其中所述画廊含有天然存在的阳离子可离子交换离子，和（2）阴离子合成乙烯基吡啶 - 苯乙烯 - 丁二烯三元共聚物（VPSBR）弹性体颗粒的乳液，其为具有约6至约11范围内的pH的水性预形成弹性体乳液，包含阴离子弹性体颗粒（由阴离子表面活性剂衍生的表面上具有阴离子的弹性体颗粒）通过自由基水溶液聚合制备在产生自由基的聚合引发剂和非可聚合阴离子表面活性剂的存在下，单体的聚合反应，其中所述合成弹性体颗粒衍生自所述单体的水聚合，所述单体包含约0.1至约40重量％的苯乙烯，约60至约100重量％的1,3-丁二烯和约0.1至约8重量％的具有以下结构式的乙烯基吡啶单体：其中R 1表示氢原子或直链或支链含有1至4个碳原子的烷基; 和（B）与所述第一共混物混合由水和无机酸组成的含水混合物，其pH在约1至约4的范围内。

3. 发明申请

US20080142131A1 Pneumatic tire 审中-公开
标题翻译：气动轮胎
公开(公告)号：US20080142131A1
公开(公告)日：2008-06-19
申请号：US11641335
申请日：2006-12-19
申请人： Xiaoping Yang , Joseph John Kulig , Dane Kenton Parker
发明人： Xiaoping Yang , Joseph John Kulig , Dane Kenton Parker
IPC分类号： C08K3/34 , B60C1/00
CPC分类号： B60C1/0016 , B60C1/0008 , B60C1/0025 , B60C17/0009 , C08K3/346 , C08L9/06
摘要： A pneumatic tire comprising at least one component, the at least one component comprising a rubber composition comprising:an vinylpyridine-styrene-butadiene (VPSBR) elastomer derived from monomers comprising vinylpyridine, styrene, and butadiene, wherein the VPSBR comprises from about 0.1 to about 8 percent by weight of vinylpyridine; andfrom about 5 to about 15 parts by weight, per 100 parts by weight of VPSBR, of an at least partially exfoliated clay.
摘要翻译：一种包含至少一种组分的充气轮胎，所述至少一种组分包含橡胶组合物，其包含：衍生自包含乙烯基吡啶，苯乙烯和丁二烯的单体的乙烯基吡啶 - 苯乙烯 - 丁二烯（VPSBR）弹性体，其中所述VPSBR包含约0.1至约 8重量％的乙烯基吡啶; 和约5至约15重量份，相对于100重量份的VPSBR为至少部分剥离的粘土。

4. 发明授权

US06369158B1 Dibenzyltrithiocarbonate molecular weight regulator for emulsion polymerization 失效
标题翻译：用于乳液聚合的二苄基二硫代碳酸酯分子量调节剂
公开(公告)号：US06369158B1
公开(公告)日：2002-04-09
申请号：US09470413
申请日：1999-12-22
申请人： Michael Leslie Senyek , Joseph John Kulig , Dane Kenton Parker
发明人： Michael Leslie Senyek , Joseph John Kulig , Dane Kenton Parker
IPC分类号： C08F240
CPC分类号： C08F212/08 , C08F236/10 , C08F2438/03 , C08F2/38
摘要： Mercaptans are normally used as chain transfer agents in emulsion polymerizations. The mercaptans used in commercial applications are typically complex mixtures of hundreds of similar compounds having boiling points within a narrow range. The chain transfer activity of different mercaptans with such mixtures can vary substantially. To further complicate the situation, the distribution of various mercaptans can also vary substantially between lots of material obtained from commercial sources. Thus, consistent molecular weight control is typically difficult to attain in free radical emulsion polymerizations. This invention is based upon the unexpected discovery that dibenzyltrithiocarbonate will act as a pure compound to effectively and consistently control molecular weight in free radical emulsion polymerizations. The polydispersity of polymers made using dibenzyltrithiocarbonate as a molecular weight regulator is similar to that obtained using conventional mercaptan systems. This invention more specifically discloses a process for controlling the molecular weight of a polymer synthesized by free radical emulsion polymerization that comprises polymerizing at least one monomer by free radical polymerization in an aqueous emulsion in the presence of dibenzyltrithiocarbonate. For instance, dibenzyltrithiocarbonate can be used as a molecular weight regulator in the synthesis of styrene-butadiene rubber by emulsion polymerization. Accordingly, this invention further discloses a process for synthesizing styrene-butadiene rubber (SBR) that comprises copolymerizing styrene monomer and 1,3-butadiene monomer by free radical polymerization in an aqueous emulsion in the presence of dibenzyltrithiocarbonate. The use of dibenzyltrithiocarbonate is inherently less odorous than the use of mercaptans.
摘要翻译：硫醇通常用作乳液聚合中的链转移剂。在商业应用中使用的硫醇通常是沸点在几个范围内的数百种类似化合物的复杂混合物。具有这种混合物的不同硫醇的链转移活性可以显着变化。为了进一步使情况复杂化，各种硫醇的分布也可以在从商业来源获得的许多材料之间显着变化。因此，在自由基乳液聚合中通常难以获得一致的分子量控制。本发明基于意想不到的发现，即二苄基三硫代碳酸酯将用作纯化合物以有效且一致地控制自由基乳液聚合中的分子量。使用二苄基三硫代碳酸酯作为分子量调节剂制备的聚合物的多分散性与使用常规硫醇体系获得的聚合物相似。本发明更具体地公开了一种控制通过自由基乳液聚合合成的聚合物的分子量的方法，该方法包括在二苄基三硫代碳酸酯的存在下，在水乳液中通过自由基聚合使至少一种单体聚合。例如，二苄基三硫代碳酸酯可以用作通过乳液聚合合成苯乙烯 - 丁二烯橡胶中的分子量调节剂。因此，本发明还公开了一种合成苯乙烯 - 丁二烯橡胶（SBR）的方法，其包括在二苄基三硫代碳酸酯存在下，在水性乳液中通过自由基聚合共聚苯乙烯单体和1,3-丁二烯单体。使用二苄基三硫代碳酸酯本身不如使用硫醇少。

5. 发明授权

US07671152B2 Surfactantless synthesis of amphiphilic cationic block copolymers 失效
标题翻译：两亲性阳离子嵌段共聚物的无表面活性合成
公开(公告)号：US07671152B2
公开(公告)日：2010-03-02
申请号：US11583424
申请日：2006-10-19
申请人： Dane Kenton Parker , Joseph John Kulig
发明人： Dane Kenton Parker , Joseph John Kulig
IPC分类号： C08F2/00 , C08F236/00
CPC分类号： C08F293/005 , C08F293/00 , C08F2438/03 , C08L53/00 , C08L53/02 , C08L2666/02
摘要： The present invention is directed to a method of producing an amphiphilic block copolymer, including the steps of: (1) preparing a first aqueous polymerization medium which is comprised of (a) 4-vinylpyridine, (b) a trithiocarbonate RAFT agent, and an emulsifier, wherein the emulsifier is prepared in-situ within the aqueous polymerization medium by the reaction of a latent surfactant with a surfactant activator; (2) polymerizing the 4-vinylpyridine within the first aqueous polymerization medium in the presence of a first free radical initiator to produce a poly(4-vinylpyridine); (3) protonating the poly(4-vinylpyridine) to form a protonated poly(4-vinylpyridine) RAFT macroinitiator; (4) preparing a second aqueous polymerization medium which is comprised of the protonated poly(4-vinylpyridine) RAFT macroinitiator and a monomer containing ethylenic unsaturation but is exclusive of a surfactant; and (5) polymerizing the protonated poly(4-vinylpyridine) RAFT macroinitiator and monomer containing ethylenic unsaturation within the second aqueous medium in the presence of a second free radical initiator and a temperature less than 100° C. to produce an amphiphilic block copolymer of the 4-vinylpyridine and monomer containing ethylenic unsaturation.
摘要翻译：本发明涉及一种制备两亲性嵌段共聚物的方法，包括以下步骤：（1）制备第一种水性聚合介质，其包含（a）4-乙烯基吡啶，（b）三硫代碳酸酯RAFT试剂和乳化剂，其中乳化剂通过潜在表面活性剂与表面活性剂活化剂的反应在水性聚合介质中原位制备; （2）在第一含水聚合介质中在第一自由基引发剂存在下聚合4-乙烯基吡啶以产生聚（4-乙烯基吡啶）; （3）使聚（4-乙烯基吡啶）质子化以形成质子化的聚（4-乙烯基吡啶）RAFT大分子引发剂; （4）制备由质子化的聚（4-乙烯基吡啶）RAFT大分子引发剂和含有烯属不饱和单体但不包括表面活性剂的单体组成的第二水性聚合介质; 和（5）在第二自由基引发剂和低于100℃的温度存在下，在第二水性介质中聚合质子化聚（4-乙烯基吡啶）RAFT大分子引发剂和含有烯属不饱和单体的单体，以产生两亲性嵌段共聚物 4-乙烯基吡啶和含有烯属不饱和单体的单体。

6. 发明申请

US20070149709A1 Surfactantless synthesis of amphiphilic cationic block copolymers 失效
标题翻译：两亲性阳离子嵌段共聚物的无表面活性合成
公开(公告)号：US20070149709A1
公开(公告)日：2007-06-28
申请号：US11583424
申请日：2006-10-19
申请人： Dane Kenton Parker , Joseph John Kulig
发明人： Dane Kenton Parker , Joseph John Kulig
IPC分类号： C08F297/02
CPC分类号： C08F293/005 , C08F293/00 , C08F2438/03 , C08L53/00 , C08L53/02 , C08L2666/02
摘要： The present invention is directed to a method of producing an amphiphilic block copolymer, including the steps of: (1) preparing a first aqueous polymerization medium which is comprised of (a) 4-vinylpyridine, (b) a trithiocarbonate RAFT agent, and an emulsifier, wherein the emulsifier is prepared in-situ within the aqueous polymerization medium by the reaction of a latent surfactant with a surfactant activator; (2) polymerizing the 4-vinylpyridine within the first aqueous polymerization medium in the presence of a first free radical initiator to produce a poly(4-vinylpyridine); (3) protonating the poly(4-vinylpyridine) to form a protonated poly(4-vinylpyridine) RAFT macroinitiator; (4) preparing a second aqueous polymerization medium which is comprised of the protonated poly(4-vinylpyridine) RAFT macroinitiator and a monomer containing ethylenic unsaturation but is exclusive of a surfactant; and (5) polymerizing the protonated poly(4-vinylpyridine) RAFT macroinitiator and monomer containing ethylenic unsaturation within the second aqueous medium in the presence of a second free radical initiator and a temperature less than 100° C. to produce an amphiphilic block copolymer of the 4-vinylpyridine and monomer containing ethylenic unsaturation.
摘要翻译：本发明涉及一种制备两亲性嵌段共聚物的方法，包括以下步骤：（1）制备第一种水性聚合介质，其包含（a）4-乙烯基吡啶，（b）三硫代碳酸酯RAFT试剂和乳化剂，其中乳化剂通过潜在表面活性剂与表面活性剂活化剂的反应在水性聚合介质中原位制备; （2）在第一含水聚合介质中在第一自由基引发剂存在下聚合4-乙烯基吡啶以产生聚（4-乙烯基吡啶）; （3）使聚（4-乙烯基吡啶）质子化以形成质子化的聚（4-乙烯基吡啶）RAFT大分子引发剂; （4）制备由质子化的聚（4-乙烯基吡啶）RAFT大分子引发剂和含有烯属不饱和单体但不包括表面活性剂的单体组成的第二水性聚合介质; 和（5）在第二自由基引发剂和低于100℃的温度存在下，在第二水性介质中聚合质子化聚（4-乙烯基吡啶）RAFT大分子引发剂和含有烯属不饱和单体的单体，以产生两亲性嵌段共聚物 4-乙烯基吡啶和含有烯属不饱和单体的单体。

7. 发明申请

US20100078110A1 PNEUMATIC TIRE 审中-公开
标题翻译：气动轮胎
公开(公告)号：US20100078110A1
公开(公告)日：2010-04-01
申请号：US12241472
申请日：2008-09-30
申请人： Paul Harry Sandstrom , Ping Zhang , Xiaoping Yang , Joseph John Kulig , Aaron Scott Puhala , Rebecca Lee Dando
发明人： Paul Harry Sandstrom , Ping Zhang , Xiaoping Yang , Joseph John Kulig , Aaron Scott Puhala , Rebecca Lee Dando
IPC分类号： B60C1/00 , C08K3/34
CPC分类号： B60C1/0016 , B60C1/00 , C08K3/346 , C08K5/548 , C08L9/06 , C08L23/18 , C08L65/00 , C08L91/06 , Y10T152/10846 , C08L2666/14
摘要： The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a rubber composition, the rubber composition comprising from about 50 to about 100 parts by weight, per 100 parts by weight of elastomer, of a vinylpyridine-styrene-butadiene (VPSBR) elastomer comprising units derived from monomers comprising styrene, 1,3-butadiene, and vinylpyridine monomers which have the structural formula: wherein R1 represents a hydrogen atom or a straight chain or branched alkyl group containing 1 to 4 carbon atoms, wherein the VPSBR comprises from about 0.1 to about 8 percent by weight of vinylpyridine monomer; from 0 to about 50 phr of at least one additional diene-based elastomer; from about 5 to about 15 phr of an at least partially exfoliated clay; and from about 1 to about 40 phr of a polyoctenamer.
摘要翻译：本发明涉及一种充气轮胎，其包括至少一种组分，所述至少一种组分包含橡胶组合物，所述橡胶组合物包含每100重量份弹性体约50至约100重量份的乙烯基吡啶（VPSBR）弹性体，其包含衍生自包含苯乙烯，1,3-丁二烯和乙烯基吡啶单体的单体的单元，其具有以下结构式：其中R 1表示氢原子或含有1至4个碳的直链或支链烷基原子，其中VPSBR包含约0.1至约8重量％的乙烯基吡啶单体; 0至约50phr的至少一种另外的二烯类弹性体; 约5至约15phr的至少部分脱落的粘土; 和约1至约40phr的聚辛烯。

8. 发明申请

US20100186868A1 PNEUMATIC TIRE 审中-公开
标题翻译：气动轮胎
公开(公告)号：US20100186868A1
公开(公告)日：2010-07-29
申请号：US12620921
申请日：2009-11-18
申请人： Paul Harry Sandstrom , Brad Stephen Gulas , David Mark Frantz , Steven Wayne Cronin , Michael Joseph Rachita , Joseph John Kulig , Robert Alan Woloszynek
发明人： Paul Harry Sandstrom , Brad Stephen Gulas , David Mark Frantz , Steven Wayne Cronin , Michael Joseph Rachita , Joseph John Kulig , Robert Alan Woloszynek
IPC分类号： B60C1/00
CPC分类号： B60C1/00 , B60C1/0016 , C08C19/44 , C08K3/36 , C08L9/00 , C08L15/00 , C08L2666/08
摘要： The present invention is directed to a pneumatic tire having a component comprising a vulcanizable rubber composition comprising, based on 100 parts by weight of elastomer (phr), (A) from about 60 to about 90 phr of a solution polymerized styrene-butadiene rubber functionalized with an alkoxysilane group and a primary amines; (B) from about 40 to about 10 phr of polybutadiene having a microstructure comprised of about 96 to about 99 percent cis 1,4-isomeric units, about 0.1 to about 1 percent trans 1,4-isomeric units and from about 1 to about 3 percent vinyl 1,2-isomeric units; a number average molecular weight (Mn) in a range of from about 75,000 to about 150,000 and a heterogeneity index (Mw/Mn) in a range of from about 3/1 to about 5/1; and (C) from about 50 to about 150 phr of silica.
摘要翻译：本发明涉及一种充气轮胎，其具有包括可硫化橡胶组合物的组分，该组合物包含基于100重量份的弹性体（phr），（A）约60至约90phr的功能化的聚合的丁苯橡胶具有烷氧基硅烷基和伯胺; （B）约40至约10phr的具有约96至约99％的顺式1,4-异构体单元，约0.1至约1％的反式1,4-异构体单元和约1至约1％的微结构的聚丁二烯 3％乙烯基1,2-异构体单元; 在约75,000至约150,000范围内的数均分子量（Mn）和约3/1至约5/1范围内的异质指数（Mw / Mn）; 和（C）约50至约150phr的二氧化硅。

9. 发明申请

US20150376343A1 COPOLYMERS OF CONJUGATED TRIENE MONOMERS FOR IMPROVED FILLER INTERACTION 有权
标题翻译：用于改进填料相互作用的共聚三烯单体共聚物
公开(公告)号：US20150376343A1
公开(公告)日：2015-12-31
申请号：US14797611
申请日：2015-07-13
申请人： Gabor Kaszas , Stephan Rodewald , Joseph John Kulig
发明人： Gabor Kaszas , Stephan Rodewald , Joseph John Kulig
IPC分类号： C08G77/00
CPC分类号： C08C19/28 , B60C1/0016 , C08C19/22 , C08C19/25 , C08F8/30 , C08F8/42 , C08F236/06 , C08F236/08 , C08F236/10 , C08F236/22 , C08G77/00 , C08K3/04 , C08K3/045 , C08K5/5419 , C08L19/006 , C08L21/00 , C08L9/00 , C08L2666/08 , C08F220/06 , C08F210/10 , C08F4/48
摘要： The present invention achieves increased filler interaction by incorporating a small amount (a few units per chain of rubbery polymer) of a conjugated triene monomer, such as alloocimene, randomly throughout the polymer chain of a rubbery polymer or at the chain ends of the rubbery polymer. The incorporation of the conjugated triene monomer leads to the formation of a polymer containing highly reactive conjugated diene units. These conjugated diene units can chemically react with carbon black leading to superior reinforcement. Alternatively, these conjugated diene units can be used for functionalization of the polymer with silica interactive/reactive groups using Diels Alder reactions. This functionalization of the rubbery polymer can conveniently be conducted in a mixer, such as a Banbury mixer, a mill mixer, or the like.
摘要翻译：本发明通过在橡胶状聚合物的整个聚合物链中或在橡胶状聚合物的链末端随机引入少量（每个链的橡胶状聚合物链）的共轭三烯单体如异环烯烃来实现增加的填料相互作用。共轭三烯单体的引入导致形成含高活性共轭二烯单元的聚合物。这些共轭二烯单元可以与炭黑发生化学反应，从而实现优异的增强。或者，这些共轭二烯单元可用于使用Diels Alder反应用二氧化硅相互作用/反应性基团对聚合物进行官能化。橡胶状聚合物的这种功能化可以方便地在混合器中进行，例如班伯里密炼机，研磨混合机等。

10. 发明申请

US20110136939A1 TIRE WITH COMPONENT CONTAINING CELLULOSE 审中-公开
标题翻译：轮胎与含有纤维素的组分
公开(公告)号：US20110136939A1
公开(公告)日：2011-06-09
申请号：US12632910
申请日：2009-12-08
申请人： Annette Lechtenboehmer , David Andrew Benko , Maurice Peter Klinkenberg , Joseph John Kulig , Klaus Unseld , Georges Marcel Victor Thielen , Claude Ernest Felix Boes , Hans-Bernd Fuchs
发明人： Annette Lechtenboehmer , David Andrew Benko , Maurice Peter Klinkenberg , Joseph John Kulig , Klaus Unseld , Georges Marcel Victor Thielen , Claude Ernest Felix Boes , Hans-Bernd Fuchs
IPC分类号： C08J3/22 , C08L1/00
CPC分类号： C08J3/22 , B60C1/00 , C08J5/045
摘要： The present invention is directed to a method of making a rubber composition, comprising the steps of mixing cellulose fibers and water to form a first mixture; mixing the first mixture with an aqueous diene-based elastomer latex to form a second mixture comprising cellulose fibers, elastomer, and water; and separating the cellulose fibers and elastomer from the water to form a elastomer/cellulose masterbatch.
摘要翻译：本发明涉及制备橡胶组合物的方法，包括以下步骤：将纤维素纤维和水混合以形成第一混合物; 将第一混合物与含水二烯基弹性体胶乳混合以形成包含纤维素纤维，弹性体和水的第二混合物; 并从水中分离纤维素纤维和弹性体以形成弹性体/纤维素母料。

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