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1. 发明授权

US08637600B2 Processing of rubber compositions including siliceous fillers 有权
标题翻译：包括硅质填料的橡胶组合物的加工
公开(公告)号：US08637600B2
公开(公告)日：2014-01-28
申请号：US13207694
申请日：2011-08-11
申请人： Xiao-Dong Pan , Zengquan Qin , Yuan-Yong Yan , Jessica Kurasch
发明人： Xiao-Dong Pan , Zengquan Qin , Yuan-Yong Yan , Jessica Kurasch
IPC分类号： C08K3/34 , C08L9/00
CPC分类号： C08K5/134 , C08L7/00 , C08L9/06 , C08L15/00
摘要： Vulcanizates with desirable properties can be obtained from compositions incorporating polymers that include hydroxyl group-containing aryl functionalities, silica or other particulate filler(s) that contain or include oxides of silicon and a compound that includes multiple hydroxyl groups. The compound can act to disrupt the interactivity of the functionalities and the particulate filler particles during processing of the composition, thereby facilitating processing of the composition.
摘要翻译：具有期望性质的硫化橡胶可以从包含含羟基芳基官能团的聚合物的组合物，二氧化硅或其中包含或包括硅的氧化物和包括多个羟基的化合物的其它颗粒填料获得。该组合物可以在组合物加工期间起作用以破坏功能性和颗粒填料颗粒的相互作用，从而有助于组合物的加工。

2. 发明申请

US20120059113A1 PROCESSING OF RUBBER COMPOSITIONS INCLUDING SILICEOUS FILLERS 有权
标题翻译：橡胶组合物的加工，包括硅胶填料
公开(公告)号：US20120059113A1
公开(公告)日：2012-03-08
申请号：US13207694
申请日：2011-08-11
申请人： Xiao-Dong Pan , Zengquan Qin , Yuan-Yong Yan , Jessica Kurasch
发明人： Xiao-Dong Pan , Zengquan Qin , Yuan-Yong Yan , Jessica Kurasch
IPC分类号： C08J3/20 , C08K3/36 , C08J3/24 , C08L9/06
CPC分类号： C08K5/134 , C08L7/00 , C08L9/06 , C08L15/00
摘要： Vulcanizates with desirable properties can be obtained from compositions incorporating polymers that include hydroxyl group-containing aryl functionalities, silica or other particulate filler(s) that contain or include oxides of silicon and a compound that includes multiple hydroxyl groups. The compound can act to disrupt the interactivity of the functionalities and the particulate filler particles during processing of the composition, thereby facilitating processing of the composition.
摘要翻译：具有期望性质的硫化橡胶可以从包含含羟基芳基官能团的聚合物的组合物，二氧化硅或其中包含或包括硅的氧化物和包括多个羟基的化合物的其它颗粒填料获得。该组合物可以在组合物加工期间起作用以破坏功能性和颗粒填料颗粒的相互作用，从而有助于组合物的加工。

3. 发明授权

US09365660B2 Anionic polymerization initiators and processes 有权
标题翻译：阴离子聚合引发剂和方法
公开(公告)号：US09365660B2
公开(公告)日：2016-06-14
申请号：US13381311
申请日：2010-06-28
申请人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan , David M. Roggeman
发明人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan , David M. Roggeman
IPC分类号： C08F4/48 , C07F1/02 , C08F36/04 , C08F136/04 , C08F236/04 , C08F12/08
CPC分类号： C08F4/48 , C07F1/02 , C08F4/484 , C08F12/08 , C08F36/04 , C08F136/04 , C08F236/04 , C08F2810/40 , C08F236/10
摘要： A group of compounds defined by the general formula (I) can be used to anionically initiate polymerization of unsaturated monomers. In the formula, M is an alkali metal atom, R1 is an aryl group having at least one OR2 substituent group where each R2 is a group that is nonreactive toward M, and R is a hydrocarbyl group. The subject initiators can be used in semi-batch and continuous polymerization processes, even those which are performed at elevated temperatures.
摘要翻译：由通式（I）定义的一组化合物可以用于阴离子引发不饱和单体的聚合。在该式中，M为碱金属原子，R1为具有至少一个OR 2取代基的芳基，其中每个R 2为不对M反应的基团，R为烃基。本发明的引发剂可以用于半间歇和连续聚合过程中，甚至可以在高温下进行。

4. 发明授权

US08946355B2 Hydroxyaryl functionalized polymers 有权
标题翻译：羟基芳基官能化聚合物
公开(公告)号：US08946355B2
公开(公告)日：2015-02-03
申请号：US13381331
申请日：2010-06-30
申请人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan
发明人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan
IPC分类号： C08F236/10 , C08L15/00 , C08L7/00 , C08F2/38 , C08C19/44
CPC分类号： C08F2/38 , C08C19/44 , C08F236/10 , C08L7/00 , C08L15/00 , C08F4/545 , C08L2666/08
摘要： A functionalized polymer includes the reaction product of a reactive polymer and a compound that includes an aryl group having at least one directly bonded OGp substituent, where Gp is a protecting group, and a substituent (Q) which is free of active hydrogen atoms and which is, or connects to the aryl group through, a moiety that includes a carbon-to-nitrogen multiple bond. The polymer can be provided from a solution that includes one or more types of ethylenically unsaturated monomers which include at least one type of polyene, particularly one or more conjugated dienes in certain embodiments. An active terminus of the resulting reactive polymer can react with the Q substituent of the compound so as to provide a polymer having as a terminal functionality the radical of a compound that includes an aryl group having at least one directly bonded OGp substituent.
摘要翻译：官能化聚合物包括反应性聚合物和包括具有至少一个直接键合的OGp取代基的芳基的化合物的反应产物，其中Gp是保护基，和不含活性氢原子的取代基（Q），其中是或通过包含碳 - 氮多键的部分连接到芳基。聚合物可以由包括一种或多种类型的烯键式不饱和单体的溶液提供，所述烯属不饱和单体在某些实施方案中包括至少一种类型的多烯，特别是一种或多种共轭二烯。所得反应性聚合物的活性末端可与化合物的Q取代基反应，从而提供具有包含具有至少一个直接键合的OGp取代基的芳基的化合物基团作为末端官能团的聚合物。

5. 发明申请

US20110028632A1 Method of Making Hydroxyaryl-Functionalized Interpolymer 有权
标题翻译：制备羟基芳基官能化的共聚物的方法
公开(公告)号：US20110028632A1
公开(公告)日：2011-02-03
申请号：US12828494
申请日：2010-07-01
申请人： Zengquan Qin , Yuan-Yong Yan , Xiao-Dong Pan
发明人： Zengquan Qin , Yuan-Yong Yan , Xiao-Dong Pan
IPC分类号： C08K3/22 , C08L39/04 , C08L9/00 , C08K3/34
CPC分类号： C08F297/00 , B60C1/0016 , C08C19/44 , C08F8/12 , C08F212/14 , C08F236/10 , C08F2/38 , C08F4/28
摘要： Cationic techniques can be used to polymerize monomers that include a class of hydroxyaryl compounds so as to provide polymers that exhibit desirable properties including, but not limited to, reduced hysteresis. Compositions such as vulcanizates in which such polymers can be utilized and products such as tire components that incorporate and/or are manufactured from such compositions also are provided.
摘要翻译：阳离子技术可以用于聚合包含一类羟基芳基化合物的单体，以便提供显示所需性质的聚合物，包括但不限于减少滞后。还可以提供组合物，例如其中可以使用这种聚合物的硫化橡胶以及并入和/或由这些组合物制造的产品如轮胎组分。

6. 发明授权

US09868850B2 Rubber compositions including siliceous fillers 有权
公开(公告)号：US09868850B2
公开(公告)日：2018-01-16
申请号：US14623424
申请日：2015-02-16
申请人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan
发明人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan
IPC分类号： C08K5/544 , C08K3/36 , C08K5/5419 , C08C19/44 , C08F36/04 , C08L15/00 , C08K5/548 , C08L7/00 , C08K5/549
CPC分类号： C08K5/544 , C08C19/44 , C08F36/04 , C08K3/36 , C08K5/5419 , C08K5/548 , C08K5/549 , C08L7/00 , C08L15/00 , C08F4/48
摘要： Vulcanizates with desirable properties can be obtained from compositions incorporating polymers that include hydroxyl group-containing aryl functionalities, silica or other particulate filler(s) that contain or include oxides of silicon and a group or compound that can act to covalently bond the filler particles and the polymer. The group can be provided as a substituent of the filler particle, or a discreet compound can be provided in the composition.

7. 发明授权

US09738733B2 Polymers incorporating hydroxyl group-containing methylstyrene 有权
公开(公告)号：US09738733B2
公开(公告)日：2017-08-22
申请号：US15265532
申请日：2016-09-14
申请人： Zengquan Qin , Yuan-Yong Yan , Xiao-Dong Pan
发明人： Zengquan Qin , Yuan-Yong Yan , Xiao-Dong Pan
IPC分类号： C08F12/14 , C08K3/04 , C08K3/36 , C08L19/00 , C08C19/44 , C07F7/18 , C08F36/04 , C08F236/10 , C08L15/00 , C08L9/06 , B60C1/00 , C08F212/14 , C08L7/00
CPC分类号： C08C19/44 , B60C1/0016 , C07F7/1804 , C08F12/14 , C08F36/04 , C08F212/14 , C08F236/10 , C08K3/04 , C08K3/045 , C08K3/36 , C08L7/00 , C08L9/06 , C08L15/00 , C08L19/006 , C08L2310/00 , Y02P20/55 , C08F4/48 , C08L2666/08
摘要： Vulcanizates with desirable properties can be obtained from compounds incorporating polymers that include hydroxyl group-containing α-methylstyrene functionalities. The functionalities can be incorporated by using any or all of appropriate initiators, monomers and optional terminating compounds. Such polymers exhibit excellent interactivity with both conventional and non-conventional fillers.

8. 发明授权

US08871871B2 Hydroxyaryl functionalized polymers 有权
标题翻译：羟基芳基官能化聚合物
公开(公告)号：US08871871B2
公开(公告)日：2014-10-28
申请号：US12810846
申请日：2008-12-28
申请人： Xiao-Dong Pan , Zengquan Qin , Yuan-Yong Yan , Dennis R. Brumbaugh , Jason T. Poulton
发明人： Xiao-Dong Pan , Zengquan Qin , Yuan-Yong Yan , Dennis R. Brumbaugh , Jason T. Poulton
IPC分类号： C08F212/14 , C08F236/10 , C08C19/44 , C08F297/04 , C08F36/04 , C08L53/02 , C08K3/00 , C08F290/06 , C08F290/14 , C08F297/02
CPC分类号： C08F36/06 , C07D339/08 , C08C19/44 , C08F36/04 , C08F212/14 , C08F290/06 , C08F290/14 , C08F297/02 , C08F297/04 , C08K3/013 , C08L53/02 , Y02P20/55 , C08F4/48 , C08L2666/02 , C08L15/00
摘要： Vulcanizates with desirable properties can be obtained from compounds incorporating polymers that include hydroxyl group-containing aryl functionalities. The functionalities can be incorporated by using any or all of appropriate initiators, monomers and optional terminating compounds. Such polymers exhibit excellent interactivity with both conventional and non-conventional fillers.
摘要翻译：具有所需性能的硫化橡胶可以从包含含羟基芳基官能团的聚合物的化合物中获得。可以通过使用任何或所有合适的引发剂，单体和任选的终止化合物来掺入官能团。这些聚合物与常规和非常规填料都具有优异的相互作用。

9. 发明授权

US09926400B2 Method of making hydroxyaryl-functionalized interpolymer by free radical initiated polymerization 有权
公开(公告)号：US09926400B2
公开(公告)日：2018-03-27
申请号：US13381564
申请日：2010-07-01
申请人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan
发明人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan
IPC分类号： C08F297/00 , C08F236/10 , B60C1/00 , C08F212/14
CPC分类号： C08F297/00 , B60C1/0016 , C08C19/44 , C08F8/12 , C08F212/14 , C08F236/10 , C08F2/38 , C08F4/28
摘要： Radical polymerization techniques can be used to polymerize monomers that include a class of hydroxyaryl compounds so as to provide polymers that exhibit desirable properties including, but not limited to, reduced hysteresis. Compositions such as vulcanizates in which such polymers can be utilized and products such as tire components that incorporate and/or are manufactured from such compositions also are provided.

10. 发明授权

US09371434B2 Elastomeric compounds having increased cold flow resistance and methods producing the same 有权
标题翻译：具有增加的耐冷流阻力的弹性体化合物及其制备方法
公开(公告)号：US09371434B2
公开(公告)日：2016-06-21
申请号：US13174934
申请日：2011-07-01
申请人： Xiao-Dong Pan , Zengquan Qin , Yuan-Yong Yan
发明人： Xiao-Dong Pan , Zengquan Qin , Yuan-Yong Yan
IPC分类号： C08K5/098 , C08K5/00 , C08L15/00 , C08L21/00
CPC分类号： C08F236/10 , C08F136/06 , C08K3/04 , C08K3/22 , C08K5/0091 , C08K5/098 , C08K2003/2296 , C08L15/00 , C08L21/00 , C08L91/00 , C08L91/06
摘要： Elastomeric compounds having increased cold flow resistance may be obtained by utilizing from 10-100 phr of a functionalized rubbery polymer containing specified types of functionalizing units, at least 0.01 phr of a multivalent metal organic salt and 0-90 phr of at least one additional rubbery polymer.
摘要翻译：具有增加的耐冷流阻性的弹性体化合物可以通过利用10-100phr的含有特定类型的官能化单元的官能化橡胶状聚合物，至少0.01phr的多价金属有机盐和0-90phr的至少一种另外的橡胶质聚合物。

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