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1. 发明申请

WO2014139679A2 METATHESIS CATALYSTS AND REACTIONS USING THE CATALYSTS 审中-公开
标题翻译：甲烷催化剂及其催化剂的反应
公开(公告)号：WO2014139679A2
公开(公告)日：2014-09-18
申请号：PCT/EP2014/000671
申请日：2014-03-13
申请人： XIMO AG
发明人： ONDI, Levente , VARGA, Jeno , BUCSAI, Agota , TOTH, Florian , LORINCZ, Krisztian , HEGEDUS, Csaba , ROBBE, Emmanuel , FRATER, Geog
IPC分类号： B01J31/22
CPC分类号： B01J31/2265 , B01J31/143 , B01J31/1608 , B01J31/1805 , B01J31/181 , B01J31/2208 , B01J31/2226 , B01J31/223 , B01J2231/543 , B01J2531/0266 , B01J2531/0288 , B01J2531/64 , B01J2531/66 , B01J2540/20 , B01J2540/22 , B01J2540/225 , C07C6/04 , C07C67/293 , C07C67/347 , C07C2531/12 , C07C2531/22 , C07C2601/10 , C07F11/00 , C08G61/08 , C08G2261/418 , C07C11/02
摘要： The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1 : 500 or less, and the conversion of the first or the second olefin to said olefin is at least 50 %, characterized in that as compound that catalyzes said metathesis reaction a compound of formula (A) is used: wherein M is Mo or W; R 1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R 2 and R 3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R 5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R 4 is a residue R 6 -X-, wherein X = O and R 6 is aryl, optionally substituted; or X = S and R 6 is aryl, optionally substituted; or X = O and R 6 is (R 7 , R 8 , R 9 )Si; wherein R 7 , R 8 , R 9 are alkyl or phenyl, optionally substituted; or X = O and R 6 is (R 10 , R 11 , R 12 )C, wherein R 10 , R 11 , R 12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.
摘要翻译：本发明涉及在易位反应中由第一烯烃和第二烯烃形成烯烃的方法，其包括步骤（i）：（i）使第一烯烃与第二烯烃在存在催化所述复分解反应的化合物，使得所述化合物与第一或第二烯烃的摩尔比为1：500或更小，并且第一或第二烯烃向所述烯烃的转化率为至少50％其特征在于作为催化所述复分解反应的化合物，使用式（A）的化合物：其中M是Mo或W; R 1是芳基，杂芳基，烷基或杂烷基; 任选取代的; R 2和R 3可以相同或不同，并且是氢，烷基，烯基，杂烷基，杂烯基，芳基或杂芳基; 任选取代的; R 5是任选取代的烷基，烷氧基，杂烷基，芳基，杂芳基，甲硅烷基烷基，甲硅烷基氧基; 和R 4是残基R 6 -X-，其中X = O和R 6是任选被取代的芳基; 或X = S且R 6为任选取代的芳基; 或X = O且R 6是（R 7，R 8，R 9）Si; 其中R 7，R 8，R 9是烷基或苯基，其任选地被取代; 或X = O且R 6是（R 10，R 11，R 12）C，其中R R 11，R 12独立地选自苯基，烷基; 任选取代的; 以及该方法中使用的催化剂。

2. 发明公开

EP2969204A2 MOLYBDENUM AND TUNGSTEN COMPLEXES AS OLEFIN METATHESIS CATALYSTS AND REACTIONS USING THE CATALYSTS 无效转让
标题翻译：钼或钨复杂得多的烯烃复分解催化剂和反应使用本催化剂
公开(公告)号：EP2969204A2
公开(公告)日：2016-01-20
申请号：EP14710501.9
申请日：2014-03-13
申请人： XiMo AG
发明人： ONDI, Levente , VARGA, Jeno , BUCSAI, Agota , TOTH, Florian , LORINCZ, Krisztian , HEGEDUS, Csaba , ROBBE, Emmanuel , FRÁTER, Georg
IPC分类号： B01J31/22 , B01J31/18 , B01J31/14 , C07C6/04 , C08G61/08
CPC分类号： B01J31/2265 , B01J31/143 , B01J31/1608 , B01J31/1805 , B01J31/181 , B01J31/2208 , B01J31/2226 , B01J31/223 , B01J2231/543 , B01J2531/0266 , B01J2531/0288 , B01J2531/64 , B01J2531/66 , B01J2540/20 , B01J2540/22 , B01J2540/225 , C07C6/04 , C07C67/293 , C07C67/347 , C07C2531/12 , C07C2531/22 , C07C2601/10 , C07F11/00 , C08G61/08 , C08G2261/418 , C07C11/02
摘要： The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1:500 or less, and the conversion of the first or the second olefin to said olefin is at least 50%, characterized in that as compound that catalyzes said metathesis reaction a compound of the following formula is used: wherein M is Mo or W; R1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R2 and R3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R4 is a residue R6—X—, wherein X═O and R6 is aryl, optionally substituted; or X═S and R6 is aryl, optionally substituted; or X═O and R6 is (R7, R8, R9)Si; wherein R7, R8, R9 are alkyl or phenyl, optionally substituted; or X═O and R6 is (R10, R11, R12)C, wherein R10, R11, R12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.
摘要翻译：本发明涉及从第一烯烃与在复分解反应的第二烯烃的烯烃形成，其包括步骤（i）的方法：（i）使用的化合物的存在下第二烯烃的第一烯烃没有催化说复分解检查反应做了所述化合物的第一或第二种烯烃的摩尔比为1：500或更小，并且所述第一或第二烯烃所述的烯烃的转化率至少为50％，其特征在于照化合物没有催化所述复分解反应中使用下述式的化合物：worin M为Mo或W; R1为芳基，杂芳基，烷基或杂烷基; OPTIONALLY substituiertem; R2和R3可以是相同的或不同的并且是氢，烷基，链烯基，杂烷基，杂烯基，芳基或杂芳基; OPTIONALLY substituiertem; R 5是烷基，烷氧基，杂烷基，芳基，杂芳基，甲硅烷基，甲硅烷氧基，任选substituiertem; 并且R 4是一个残基R6-X，X = O worin和R 6是芳基，任选substituiertem; 或X = S，R 6是芳基，任选substituiertem; 或X = O和R 6为（R7，R8，R9）的Si; worin R7，R8，R9是烷基或苯基，其任选substituiertem; 或X = O和R 6是（R10，R11，R12）C，worin R10，R11，R12独立地选自苯基，烷基; OPTIONALLY substituiertem; 并在该方法中使用的催化剂。

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