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    • 6. 发明授权
    • Continuous process for the production of polyacrylonitrile filaments and
fibers
    • 连续生产聚丙烯腈长丝和纤维的方法
    • US4622195A
    • 1986-11-11
    • US586578
    • 1984-03-06
    • Michael BuebDieter PauliniEdgar MuschelknautzWolfram WagnerHerbert Groschel
    • Michael BuebDieter PauliniEdgar MuschelknautzWolfram WagnerHerbert Groschel
    • D01D5/04D01F6/18D01F6/38D02G1/12D02G1/16D02J1/00
    • D01F6/18D02G1/122
    • Polyacrylonitrile filaments and fibers may be obtained without interruption by spinning the spinning solution into a hot-air spinning duct, washing, drawing, crimping, preparing, steaming, drying cooling and, optionally, cutting at a take-off rate kept at 150 to 400 m/minute and for a tow weight of from 10 to 100 g/m when(a) the washing process is carried out in several stages on the countercurrent principle and a vibrating duct is used for transporting the spun tow through the washing process,(b) drawing is carried out before and/or after washing in a steam atmosphere at 100.degree. to 120.degree. C.,(c) crimping is carried out in an aerodynamic crimping unit using a hot, gaseous medium under a pressure of from 5 to 16 bars and at a temperature in the range from 50.degree. to 210.degree. C.,(d) the preparation is continuously applied to the tow before, during or after crimping,(e) for steaming, the tow is transported through a steaming apparatus in folded form and in the absence of tension on a vibrating duct and, at the same time, treated with steam at 100.degree. to 120.degree. C.,(f) finally, the tow is dried in folded form on a belt dryer using hot air at 60.degree. to 180.degree. C., subsequently cooled with cold air to temperatures below 50.degree. C. and, optionally, delivered to a cutting machine.
    • 可以通过将纺丝溶液旋转成热风纺丝管,洗涤,拉伸,卷曲,制备,蒸煮,干燥冷却和任选地以保持在150至400的起飞速率进行切割而获得聚丙烯腈长丝和纤维 (a)按照逆流原理在数个阶段进行洗涤过程,并且使用振动管道通过洗涤过程输送纺丝丝束(m / min,丝束重量为10-100g / m 2) b)在100-120℃的蒸汽气氛中洗涤之前和/或之后进行拉伸,(c)在空气动力学压接单元中使用热气体介质在5〜 16巴,温度范围为50至210℃,(d)在卷曲之前,期间或之后将制品连续施加到丝束上,(e)蒸汽时,丝束通过蒸汽装置 以折叠的形式和在没有紧张的情况下 振动管道,同时用100-120℃的蒸汽处理,(f)最后,使用60℃至180℃的热空气将丝束以折叠形式在带式干燥机上干燥,随后 用冷空气冷却到低于50℃的温度,并且任选地被输送到切割机。
    • 8. 发明授权
    • Production of very fine polymer fibres
    • 生产非常细的聚合物纤维
    • US4937020A
    • 1990-06-26
    • US292696
    • 1989-01-03
    • Wolfram WagnerPeter R. NyssenDirk BerkenhausHans-Theo van Pey
    • Wolfram WagnerPeter R. NyssenDirk BerkenhausHans-Theo van Pey
    • D01F6/06D01D5/08D01D5/18D01F6/60
    • D04H3/02D01D5/18D04H3/009D04H3/011D04H3/16
    • The polymer granular melt (1) is whirled out of a rotating nozzle head (6) through a plurality of exit holes (24) with fibre formation (32) and the fibres formed (9) are deposited on a collecting surface (12) in web form (15). This polymer melt is introduced into the nozzle head (6) under a preliminary pressure of 1 bar to 200 bar, preferably 1 bar to 50 bar. Furthermore, the fibres (32) are deflected by a high-speed gas stream (7, 8) in a radial direction at a radial distance of 10 mm to 200 mm from the exit holes (24) and, in the course of being deflected, are simultaneously drawn and stretched. The melt streams (32) exiting from the exit holes (24) can be additionally drawn by gas streams (26, 34) exiting in the vicinity of the exit holes (24) at the nozzle head (6) with a predominantly radial component before coming under the influence of the axial deflecting gas stream (7, 8).
    • 聚合物颗粒状熔体(1)通过具有纤维形成(32)的多个出口孔(24)从旋转喷嘴头(6)旋转出来并且形成的纤维(9)沉积在收集表面(12)上 网络形式(15)。 该聚合物熔体在1巴至200巴,优选1巴至50巴的预备压力下引入喷嘴头(6)。 此外,纤维(32)在离开孔(24)的径向距离为10mm至200mm的径向方向上被高速气流(7,8)偏转,并且在被偏转的过程中 ,同时拉伸和拉伸。 从出口孔(24)排出的熔体流(32)可以另外由在喷嘴头(6)处的出口孔(24)附近出口的气流(26,34)以主要的径向分量吸引 在轴向偏转气流(7,8)的影响下。
    • 10. 发明授权
    • Apparatus for the production of fine mineral fibres
    • 用于生产细矿物纤维的设备
    • US4676815A
    • 1987-06-30
    • US847797
    • 1986-04-03
    • Wolfram WagnerPeter R. NyssenGunter EspanionDirk BerkenhausGunter HaladudaHans-Theo van PeyKarl-Heinz Schott
    • Wolfram WagnerPeter R. NyssenGunter EspanionDirk BerkenhausGunter HaladudaHans-Theo van PeyKarl-Heinz Schott
    • C03B37/022C03B37/06D01D5/14
    • C03B37/06D01D5/14
    • Filaments of a molten material issue from a plurality of openings in a heated melt crucible and are further fiberized in a draw nozzle by means of a blowing medium. The diameter of the outlet openings (3) at the base of the melt crucible (1) is very small and is 0.2 to 1.5 mm, so that very fine primary filaments (12) are already formed at this point. These primary filaments are grasped by a very turbulent current at the entrance of the draw nozzle (5). The transverse component of the current decreasing in favor of the longitudinal component as the axial distance from the outlet openings (3) increases. The draw nozzle also has an inlet portion, which has a sharp outer edge and widens in the direction of flow, so that air blows against the primary filaments at a high speed and they are exposed to a strong pressure gradient in the longitudinal direction before entering the inlet portion. In the draw nozzle the primary filaments which are themselves already very thin are drawn out further until they have the required final diameter. For this purpose a zone is provided in the interior of the nozzle, following the inlet portion, in which zone the rate of flow of the blowing medium is 400 m/s to 600 m/s at a pressure of between 0.1 and 0.4 bar. By means of this device very fine mineral fibres with a substantially uniform fibre diameter of between 0.1 .mu.m and 5 .mu.m can be produced.
    • 熔融材料的长丝从加热熔融坩埚中的多个开口出现,并通过吹塑介质进一步在牵引喷嘴中纤维化。 在熔融坩埚(1)底部的出口开口(3)的直径非常小,为0.2-1.5mm,从而在这一点上已经形成非常细的一次丝(12)。 这些初级细丝在拉伸喷嘴(5)的入口处被非常湍流的电流所夹持。 随着与出口(3)的轴向距离的增加,电流的横向分量有利于纵向分量。 牵引喷嘴还具有入口部分,其具有尖锐的外边缘并且在流动方向上变宽,使得空气以高速吹向初级细丝,并且在进入之前暴露于纵向方向上的强压力梯度 入口部分。 在拉丝喷嘴中,本身已经非常薄的主丝被进一步拉出,直到它们具有所需的最终直径。 为此,在喷嘴的内部设有一区域,在入口部分之后,在0.1-4.0巴的压力下,吹送介质的流速为400m / s至600m / s。 通过该装置,可以生产出具有0.1μm至5μm之间的基本上均匀的纤维直径的非常细的矿物纤维。