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    • 3. 发明授权
    • Dental materials based on dimer acid derivatives with ring opening polymerizable groups
    • 基于具有开环聚合基团的二聚酸衍生物的牙科材料
    • US08921450B2
    • 2014-12-30
    • US13175988
    • 2011-07-05
    • Norbert MosznerJörg AngermannUrs Karl FischerVolker Rheinberger
    • Norbert MosznerJörg AngermannUrs Karl FischerVolker Rheinberger
    • A61K6/08A61K6/083C07D339/00A61K6/00
    • C07D339/00A61K6/0023A61K6/083C08L33/08C08L33/10C08L65/00
    • The invention relates to a radically polymerizable monomer of formula (I) wherein W1 and W2 in each case independently represent H or X—R—Y—PG, wherein at least one of W1 and W2 represents X—R—Y—PG, X in each case independently is missing or represents an ether, ester, amide, urethane or urea group, Y in each case independently is missing or represents an ether, ester, amide, urethane or urea group, R in each case independently is missing or represents a C1-C16 alkylene radical which can be interrupted by one or more O atoms, wherein R can be missing only if X and/or Y is simultaneously also missing, and PG in each case independently represents a cyclic, ring-opening polymerizable group, a, b, c and d independently of each other can take the values 3 to 10. The invention also relates to polymerizable compositions which comprise the monomers according to the invention, as well as their use as dental materials and for the preparation of dental materials, in particular composites, cements, adhesives or coatings.
    • 本发明涉及式(I)的自由基聚合性单体,其中W1和W2各自独立地表示H或X-R-Y-PG,其中W1和W2中的至少一个表示X-R-Y-PG,X 在每种情况下都独立地缺失或表示醚,酯,酰胺,氨基甲酸酯或脲基,Y在每种情况下独立地缺失或表示醚,酯,酰胺,氨基甲酸酯或脲基,R各自独立地缺失或表示 可以被一个或多个O原子中断的C1-C16亚烷基,其中只有当X和/或Y同时缺失时,R只能缺失,并且每种情况下PG都独立地表示环状的开环聚合基团, a,b,c和d可以取值为3至10.本发明还涉及包含根据本发明的单体的可聚合组合物,以及它们作为牙科材料和用于制备牙科材料的用途 ,特别是composi 水泥,粘合剂或涂料。
    • 7. 发明授权
    • (Meth) acrylate-substituted iminooxidiazine dione derivatives
    • (甲基)丙烯酸酯取代的亚氨氧亚氨基二酮衍生物
    • US07078446B2
    • 2006-07-18
    • US10361961
    • 2003-02-10
    • Norbert MosznerThomas VölkelUrs Karl FischerVolker Rheinberger
    • Norbert MosznerThomas VölkelUrs Karl FischerVolker Rheinberger
    • A61K6/083A61C5/00C08G18/04
    • A61K6/083A61K6/0023C07D273/04C08L33/00
    • The invention relates to iminooxadiazine dione derivatives with the formula (I) in which X, Y and Z represent a (meth)acrylic acid radical of the formula (II) in which R1 is hydrogen, an aliphatic hydrocarbon radical with 1 to 14 carbon atoms, which can be interrupted by oxygen atoms, or an aromatic hydrocarbon radical with to 16 carbon atoms; R2 is hydrogen, an aliphatic hydrocarbon radical with 1 to 5 carbon atoms or an aromatic hydrocarbon radical with 6 carbon atoms, n is 1 or 2; where the (meth)acrylic acid radical of formula (II) is bound to the radical of formula (I) by R1 or R2 and the binding point remaining at R2 or R1 is saturated by hydrogen and X, Y and Z can be the same or different; the individual radicals R being able to be the same or different and selected from alicyclic or aromatic hydrocarbon radicals with 5 to 10 or aliphatic hydrocarbon radicals with 1 to 10 carbon atoms.
    • 本发明涉及式(I)的亚氨基恶二嗪二酮衍生物,其中X,Y和Z表示式(II)的(甲基)丙烯酸基,其中R 1是氢,脂族 可以被氧原子中断的具有1至14个碳原子的烃基或具有16个碳原子的芳族烃基; R 2是氢,具有1至5个碳原子的脂族烃基或具有6个碳原子的芳族烃基,n是1或2; 其中式(II)的(甲基)丙烯酸基团通过R 1或R 2 2与式(I)的基团结合,并且R H 2和R 1可以被氢饱和,X,Y和Z可以相同或不同; 各个基团R能够相同或不同,并且选自具有5-10个碳原子的脂族或芳族烃基或具有1-10个碳原子的脂族烃基。
    • 10. 发明授权
    • Hydrolyzable and polymerizable silanes based on methylene dithiepane
    • 基于亚甲基二硫杂环丁烷的可水解和可聚合硅烷
    • US06713555B2
    • 2004-03-30
    • US10260069
    • 2002-09-27
    • Norbert MosznerSabine SteinThomas VölkelVolker Rheinberger
    • Norbert MosznerSabine SteinThomas VölkelVolker Rheinberger
    • C08L8308
    • C07F7/1804
    • Methylene dithiepane silanes according to Formula I in which R1 is a saturated or unsaturated aliphatic or alicyclic hydrocarbon radical with 1 to 10 carbon atoms, which can be interrupted by one or more oxygen and/or sulphur atoms and can contain one or more ester, carbonyl, amide and/or urethane groups, or is an aromatic or heteroaromatic hydrocarbon radical with 6 to 18 carbon atoms, the hydrocarbon radicals being able to be substituted or unsubstituted; R2 has one of the meanings given for R1 or is absent; R3 has one of the meanings given for R1 or is absent; R4 is equal to —(CHR6)n—, —Y—CO—NH—(CHR6)n—, —Y—CO—NH—R5—, —(CHR6)n—S—R5—, —S—R5—, —CO—O—R5— or is absent, with n being equal to 1 to 4, R6 is hydrogen, C1 to C10 alkyl or C6 to C10 aryl, R5 has one of the meanings given for R1 and Y stands for an O or S atom or is absent; with R5 and R6 being able to be substituted or unsubstituted; X is a hydrolyzable group; a, b, c and x each independently of each other being 1, 2 or 3; and the sum of a+x=2 to 4. The silanes are particularly suitable for the preparation of dental materials.
    • 具有式Iin的亚甲基二噻吩烷硅烷,其中R 1是具有1至10个碳原子的饱和或不饱和脂族或脂环族烃基,其可被一个或多个氧和/或硫原子间隔并且可含有一个或多个酯 ,羰基,酰胺和/或氨基甲酸酯基团,或是具有6至18个碳原子的芳族或杂芳族烃基,所述烃基能够被取代或未取代; R 2具有R 1给出的含义之一或不存在; R 3具有R 1给出的含义之一或不存在; R 4等于 - (CHR 6)n - , - O-CO-NH-(CHR 6)n-,-Y-CO-NH-R 5 - , - (CHR < 6))nSR 5 - , - SR 5 - , - CO-OR 5 - 或不存在,n等于1至4,R 6是氢,C 1至C 10烷基或C 6 对于C 10芳基,R 5具有对R 1给出的含义之一,Y表示O或S原子或不存在; 其中R 5和R 6能够被取代或未取代; X是可水解基团; a,b,c和x各自独立地为1,2或3; 并且a + x = 2至4的总和。硅烷特别适用于制备牙科材料。