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1. 发明授权

US06552153B1 Thermoplastic resins having incorporated mold release agents 有权
标题翻译：具有并入脱模剂的热塑性树脂
公开(公告)号：US06552153B1
公开(公告)日：2003-04-22
申请号：US09357272
申请日：1999-07-20
申请人： Wolfgang Kaufhold , Friedemann Müller , Wolfgang Bräuer , Hans-Georg Hoppe , Hans-Georg Wussow
发明人： Wolfgang Kaufhold , Friedemann Müller , Wolfgang Bräuer , Hans-Georg Hoppe , Hans-Georg Wussow
IPC分类号： C08G1862
CPC分类号： B29C33/62 , C08G18/2815 , C08G18/4063 , C08G18/6208 , C08G18/698 , C08G2125/00
摘要： A mixture of hydroxy-terminated hydrocarbons useful as a mold release agent for polymers is disclosed. The polymers suitable in the present context are the ones prepared by polyaddition or polycondensation, in particular, thermoplastic polyurethane and polyurethane urea.
摘要翻译：公开了可用作聚合物脱模剂的羟基封端的烃的混合物。在本文中适用的聚合物是通过加聚或缩聚制备的聚合物，特别是热塑性聚氨酯和聚氨酯脲。

2. 发明授权

US06624278B2 Process for producing thermally stable thermoplastic polyurethanes 有权
公开(公告)号：US06624278B2
公开(公告)日：2003-09-23
申请号：US10008164
申请日：2001-12-03
申请人： Friedemann Müller , Wolfgang Bräuer , Hans-Georg Hoppe , Hans-Georg Wussow , Hans Wagner
发明人： Friedemann Müller , Wolfgang Bräuer , Hans-Georg Hoppe , Hans-Georg Wussow , Hans Wagner
IPC分类号： C08G1830
CPC分类号： C08G18/3206 , C08G18/0895 , C08G18/2825 , C08G18/4238
摘要： A continuous process for the production of thermoplastically processable polyurethane elastomer is disclosed. The process comprise adding acid H compounds in an amount calculated to control and render constant the melt viscosity of the product. The inventive elastomer has constant melt flow behavior and high thermal stability.

3. 发明授权

US06527995B1 Process for preparing soft, elastic polyurethane 有权
标题翻译：制备柔软，弹性聚氨酯的方法
公开(公告)号：US06527995B1
公开(公告)日：2003-03-04
申请号：US09610832
申请日：2000-07-06
申请人： Wolfgang Kaufhold , Hans-Georg Hoppe , Wolfgang Bräuer , Jürgen Winkler , Hans-Georg Wussow
发明人： Wolfgang Kaufhold , Hans-Georg Hoppe , Wolfgang Bräuer , Jürgen Winkler , Hans-Georg Wussow
IPC分类号： D04H154
CPC分类号： C08G18/721 , C08G18/0895 , C08G18/6607 , C08G18/664 , C08G2140/00
摘要： A process for producing a thermoplastic polyurethane film by means of sintering a particulate thermoplastic polyurethane in a heated mold, is described. The thermoplastic polyurethane has: (i) a melt index of 20 to 100, measured at 190° C. and under an applied force of 21.2 N; (ii) a relative solution viscosity of 1.15 to 1.45, the relative solution viscosity being determined by, measuring the viscosity (a) of a solution of 0.4 grams of the thermoplastic polyurethane in 99.7 grams N-methyl-2-pyrrolidone containing 0.1% dibutylamine at 25° C., measuring the viscosity (b) of N-methyl-2-pyrrolidone containing 0.1% dibutylamine at 25° C., and dividing viscosity (a) by viscosity (b); and (iii) a Shore hardness of 80 to 98.
摘要翻译：描述了通过在加热的模具中烧结颗粒状热塑性聚氨酯来制造热塑性聚氨酯膜的方法。热塑性聚氨酯具有：（i）在190℃和21.2N的施加力下测量的20至100的熔体指数; （ii）相对溶液粘度为1.15至1.45，相对溶液粘度通过测量在含有0.1％二丁胺的99.7克N-甲基-2-吡咯烷酮中的0.4克热塑性聚氨酯溶液的粘度（a）在25℃下测量在25℃下含有0.1％二丁胺的N-甲基-2-吡咯烷酮的粘度（b），并将粘度（a）除以粘度（b）。和（iii）肖氏硬度为80-98。

4. 发明授权

US06486243B2 Thermoplastically processable polyurethane elastomers having an improved intrinsic color 失效
标题翻译：具有改进的固有颜色的热塑性可加工聚氨酯弹性体
公开(公告)号：US06486243B2
公开(公告)日：2002-11-26
申请号：US09969344
申请日：2001-10-01
申请人： Wolfgang Bräuer , Wolfgang Kaufhold , Hans-Georg Hoppe , Hans-Georg Wussow
发明人： Wolfgang Bräuer , Wolfgang Kaufhold , Hans-Georg Hoppe , Hans-Georg Wussow
IPC分类号： C08K549
CPC分类号： C08G18/10 , C08G18/4854 , C08G18/6674 , C08K5/527 , C08G18/3206 , C08L75/04
摘要： A light-colored thermoplastic molding composition comprising a polyurethane elastomer is disclosed. The polyurethane which is the reaction product of at least one polyol, at least one organic diisocyanate and at least one polyol chain extender contains one or more pentaerythritol diphosphites color stabilizers conforming to a specific formula exhibits improved color stability and improved processability. The process for preparation entails introducing the stabilizer before the reaction has been completed.
摘要翻译：公开了一种包含聚氨酯弹性体的浅色热塑性模塑组合物。作为至少一种多元醇，至少一种有机二异氰酸酯和至少一种多元醇增链剂的反应产物的聚氨酯包含一种或多种符合特定配方的季戊四醇二亚磷酸酯颜色稳定剂，其显示出改进的颜色稳定性和改善的加工性能。制备方法需要在反应完成之前引入稳定剂。

5. 发明授权

US07160974B2 Thermoplastically processable polyurethanes (TPU) with self-extinguishing properties, a process for their preparation and their use 失效
标题翻译：具有自熄性能的热塑性可加工聚氨酯（TPU），其制备方法及其用途
公开(公告)号：US07160974B2
公开(公告)日：2007-01-09
申请号：US10642984
申请日：2003-08-18
申请人： Henricus Peerlings , Wolfgang Bräuer , Hans-Georg Wussow , Juergen Winkler , Hans-Georg Hoppe
发明人： Henricus Peerlings , Wolfgang Bräuer , Hans-Georg Wussow , Juergen Winkler , Hans-Georg Hoppe
IPC分类号： C08G18/10 , C08G18/38 , C08G18/48 , C08G18/50 , C08G18/76
CPC分类号： C08G18/12 , C08G18/10 , C08G18/3878 , C08K5/521 , C08L75/04
摘要： The present invention relates to thermoplastically processable polyurethane elastomers (TPU) with tensile strengths of >35 MPa (measured in accordance with EN ISO 527-3), with shrinkages of
摘要翻译：本发明涉及拉伸强度> 35MPa（根据EN ISO 527-3测量）的热塑性可加工聚氨酯弹性体（TPU），其收缩率小于3％，并且基于至少使用自熄性一种可以内置的防火剂，其制备方法及其用途。

6. 发明授权

US06790916B2 Process for the preparation of soft, low-shrinkage, thermoplastic polyurethane elastomers which can be easily released from the mold 有权
标题翻译：用于制备柔软，低收缩，热塑性聚氨酯弹性体的方法，其可以容易地从模具中释放
公开(公告)号：US06790916B2
公开(公告)日：2004-09-14
申请号：US10368708
申请日：2003-02-19
申请人： Wolfgang Bräuer , Herbert Heidingsfeld , Hans-Georg Hoppe , Hans-Georg Wussow , Eva Brigitte Eggeling , Wolfgang Röhrig
发明人： Wolfgang Bräuer , Herbert Heidingsfeld , Hans-Georg Hoppe , Hans-Georg Wussow , Eva Brigitte Eggeling , Wolfgang Röhrig
IPC分类号： C08G1810
CPC分类号： C08G18/4854 , C08G18/10 , C08G18/4238 , C08G2410/00 , C08G18/3206 , C08G18/7671
摘要： The present invention relates to a process for the production of molding compositions, which can easily be released from the mold. These molding compositions comprise thermoplastic polyurethanes with a hardness of 45 to 65 Shore A, with good mechanical properties, with low shrinkage and good low temperature properties.
摘要翻译：本发明涉及可以容易地从模具中释放的用于生产模塑组合物的方法。这些模塑组合物包含硬度为45至65肖氏A的热塑性聚氨酯，具有良好的机械性能，低收缩率和良好的低温性能。

7. 发明授权

US06218479B1 Nonrigid, thermoplastic moulding compositions 失效
标题翻译：非刚性的热塑性模塑组合物
公开(公告)号：US06218479B1
公开(公告)日：2001-04-17
申请号：US09503628
申请日：2000-02-14
申请人： Jürgen Winkler , Hans-Georg Hoppe , Wolfgang Bräuer , Hans-Georg Wussow
发明人： Jürgen Winkler , Hans-Georg Hoppe , Wolfgang Bräuer , Hans-Georg Wussow
IPC分类号： C08L7504
CPC分类号： C08G18/664 , C08G18/08 , C08G18/0895 , C08G18/10 , C08L75/06 , C08G18/3206 , C08L75/04
摘要： This invention relates to thermoplastically processable, readily demouldable moulding compositions with low shrinkage and with a hardness of 65 to 85 Shore A, consisting of a mixture of A) a thermoplastic polyurethane of hardness 60 to 75 Shore A and B) a thermoplastic polyurethane of hardness 76 to 90 Shore A, which is produced continuously by a special multi-stage process.
摘要翻译：本发明涉及具有低收缩率和硬度为65至85肖氏A的热塑性可加工的，易脱模的模塑组合物，由以下组成的混合物组成：A）硬度为60至75肖氏A的热塑性聚氨酯和B）硬度为76至 90 Shore A，通过特殊的多阶段过程连续生产。

8. 发明授权

US06559266B2 Aliphatic thermoplastic polyurethanes, a process for producing them and the use thereof 有权
标题翻译：脂肪族热塑性聚氨酯，其制造方法及其用途
公开(公告)号：US06559266B2
公开(公告)日：2003-05-06
申请号：US09447025
申请日：1999-11-22
申请人： Wolfgang Kaufhold , Wolfgang Braeuer , Hans-Georg Wussow , Hans-Georg Hoppe , Steven C. Manning
发明人： Wolfgang Kaufhold , Wolfgang Braeuer , Hans-Georg Wussow , Hans-Georg Hoppe , Steven C. Manning
IPC分类号： C08G1842
CPC分类号： C08G18/73 , C08G18/6607 , C08G18/758
摘要： A molding composition comprising thermoplastic polyurethane is disclosed. The polyurethane is characterized in having ultimate tensile strength (UTS) and elongation at break (EAB) values after hot storage which are, each, at least 60% of the corresponding value before hot storage, glass transition temperature equal to or lower than −50° C., UTS and EAB values after hydrolytic storage which are, each, at least 80% of the corresponding value before hydrolytic storage, and Shore A hardness of 70 to 95. The polyurethane is a product of a reaction comprising an aliphatic diisocyanate, a mixture of polyols and a chain extender and contains a UV stabilizer, an antioxidant and an optional anti-hydrolysis agent.
摘要翻译：公开了一种包含热塑性聚氨酯的模制组合物。聚氨酯的特征在于在热存储之后具有极限拉伸强度（UTS）和断裂伸长率（EAB）值，它们各自在热存储之前的相应值的至少60％，玻璃化转变温度等于或低于-50 水解储存后的UTS和EAB值各自为水解储存前相应值的至少80％，肖氏A硬度为70至95.聚氨酯是包含脂族二异氰酸酯，多元醇和扩链剂的混合物，并含有UV稳定剂，抗氧化剂和任选的抗水解剂。

9. 发明授权

US5981655A Process for preparing TPU molding compositions 失效
标题翻译：制备TPU模塑组合物的方法
公开(公告)号：US5981655A
公开(公告)日：1999-11-09
申请号：US006064
申请日：1998-01-12
申请人： Herbert Heidingsfeld , Willi Meister , Bernhard Schulte , Wolfgang Brauer , Friedemann Muller , Hans-Georg Hoppe , Hans-Georg Wussow , Jurgen Winkler
发明人： Herbert Heidingsfeld , Willi Meister , Bernhard Schulte , Wolfgang Brauer , Friedemann Muller , Hans-Georg Hoppe , Hans-Georg Wussow , Jurgen Winkler
IPC分类号： C08L55/02 , C08G18/00 , C08G18/08 , C08G18/65 , C08L55/00 , C08L75/00 , C08L75/04 , C08L101/00
CPC分类号： C08L75/04 , C08G18/0895
摘要： A process for the continuous production of a thermoplastic molding composition containing a mixture of a TPU and a thermoplastic (co)polymer is disclosed. The process comprises(i) introducing into an extruder via a first feed point component I) with at least 3% by weight, with respect to component I), of at least one member selected from the group consisting of components A), B) and C), and(ii) metering in the balance of said A), B) and C) into said extruder via one or more subsequent feed points,(iii) extruding components I) and II) under conditions sufficient to cause A), B) and C) reaction to form TPU, and(iv) upon the completion of said reaction, removing the resulting mixture of TPU and (co)polymer from the extruder,wherein component I) comprises 1 to 60% by weight, with respect to the total mixture, of a thermoplastic (co)polymer, and wherein component II) comprises 99 to 40% by weight, with respect to the total mixture, of the polyurethane-forming components including A) an organic diisocyanate, B) a linear polyol having terminal hydroxyl groups and a number average molecular weight of 500 to 5000, and C) a chain extender having a molecular weight of 60 to 500, and wherein the molar ratio of NCO groups in A) to the groups which react with NCO in B) and C) is in the range of 0.9 to 1.2.
摘要翻译：公开了一种用于连续生产含有TPU和热塑性（共）聚合物的混合物的热塑性模塑组合物的方法。该方法包括（i）通过第一进料点组分I）向至少一种选自组分A），B）中的至少一种成分引入至少3重量％的挤出机，相对于组分I）和（ii）在所述A），B）和C）的余量中通过一个或多个后续进料点将所述A），B）和C）的余量计量加入到所述挤出机中，（iii）在足以导致A）和，B）和C）反应形成TPU，和（iv）在完成所述反应后，从挤出机中除去所得TPU和（共）聚合物的混合物，其中组分I）包含1至60重量％相对于总混合物，热塑性（共）聚合物，并且其中组分II）包含相对于总混合物的99至40重量％的形成聚氨酯的组分，包括A）有机二异氰酸酯，B）具有末端羟基，数均分子量为500〜5000的直链状多元醇，C）扩链剂分子量为60至500，并且其中A）中的NCO基团与在B）和C）中与NCO反应的基团的摩尔比在0.9至1.2的范围内。

10. 发明授权

US5760133A Process for preparing TPU molding compositions 失效
公开(公告)号：US5760133A
公开(公告)日：1998-06-02
申请号：US633939
申请日：1996-04-17
申请人： Herbert Heidingsfeld , Willi Meister , Bernhard Schulte , Wolfgang Brauer , Friedemann Muller , Hans-Georg Hoppe , Hans-Georg Wussow , Jurgen Winkler
发明人： Herbert Heidingsfeld , Willi Meister , Bernhard Schulte , Wolfgang Brauer , Friedemann Muller , Hans-Georg Hoppe , Hans-Georg Wussow , Jurgen Winkler
IPC分类号： C08L55/02 , C08G18/00 , C08G18/08 , C08G18/65 , C08L55/00 , C08L75/00 , C08L75/04 , C08L101/00 , D01F1/02
CPC分类号： C08L75/04 , C08G18/0895
摘要： A process for the continuous production of a thermoplastic molding composition containing a mixture of a TPU and a thermoplastic (co)polymer is disclosed. The process comprises (i) introducing into an extruder via a first feed point component I) with at least 3% by weight, with respect to component I), of at least one member selected from the group consisting of components A), B) and C), and(ii) metering in the balance of said A), B) and C) into said extruder via one or more subsequent feed points, (iii) extruding components I) and II) under conditions sufficient to cause A), B) and C) reaction to form TPU, and (iv) upon the completion of said reaction, removing the resulting mixture of TPU and (co)polymer from the extruder, wherein component I) comprises 1 to 60% by weight, with respect to the total mixture, of a thermoplastic (co)polymer, and wherein component II) comprises 99 to 40% by weight, with respect to the total mixture, of the polyurethane-forming components including A) an organic diisocyanate, B) a linear polyol having terminal hydroxyl groups and a number average molecular weight of 500 to 5000, and C) a chain extender having a molecular weight of 60 to 500, and wherein the molar ratio of NCO groups in A) to the groups which react with NCO in B) and C) is in the range of 0.9 to 1.2.

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