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1. 发明授权

US4251639A Manufacture of flexible foams 失效
标题翻译：制造柔性泡沫
公开(公告)号：US4251639A
公开(公告)日：1981-02-17
申请号：US28313
申请日：1979-04-09
申请人： Wolfgang Jarre , Herbert Stutz , Ernst Schoen
发明人： Wolfgang Jarre , Herbert Stutz , Ernst Schoen
IPC分类号： C08G18/00 , C08G18/72 , C08G18/76 , C08G18/80 , C08G18/14
CPC分类号： C08G18/8035 , C08G18/8041
摘要： This invention concerns a process for the manufacture of flexible polyurethane foams from urethane-modified aromatic polyisocyanates having an NCO content of 15 to 30 percent by weight and a viscosity of 100 to 2000 centipoises at 20.degree. C., which are obtained by reaction of a mixture of diphenylmethane diisocyanates and polyphenylene polymethylene polyisocyanates containing 55 to 85 percent by weight of diphenylmethane diisocyanate based on the total weight of the polyisocyanate mixture and a hydroxyl compound with 2 to 4 Zerewitinoff active hydrogen atoms and a molecular weight of 60 to 1500, in an equivalency ratio of NCO groups to active hydrogen atoms of the hydroxyl compound of 2:1 to 60:1, polyols, catalysts, blowing agents, and optionally, chain extenders, auxiliaries, and additives.
摘要翻译：本发明涉及一种由氨基甲酸酯改性的芳族聚异氰酸酯制备柔性聚氨酯泡沫体的方法，该聚氨酯改性芳族聚异氰酸酯在20℃下的NCO含量为15-30％（重量），粘度为100-2000厘泊，这是通过基于多异氰酸酯混合物的总重量含有55-85重量％的二苯基甲烷二异氰酸酯和具有2-4个Zerewitinoff活性氢原子并且分子量为60至1500的羟基化合物的二苯基甲烷二异氰酸酯和聚亚苯基多亚甲基多异氰酸酯的混合物， NCO基团与羟基化合物的活性氢原子的当量比为2:1至60:1，多元醇，催化剂，发泡剂和任选的增链剂，助剂和添加剂。

2. 发明授权

US4293657A Stable melamine polyol dispersions, a process for their manufacture and for the preparation of foamed polyurethane plastics 失效
标题翻译：稳定的三聚氰胺多元醇分散体，其制造方法和泡沫聚氨酯塑料的制备
公开(公告)号：US4293657A
公开(公告)日：1981-10-06
申请号：US166636
申请日：1980-07-07
申请人： Dietmar Nissen , Matthias Marx , Wolfgang Jarre , Ernst Schoen , Walter Decker
发明人： Dietmar Nissen , Matthias Marx , Wolfgang Jarre , Ernst Schoen , Walter Decker
IPC分类号： C08J9/00 , C08K5/3492 , C08G18/14
CPC分类号： C08J9/0028 , C08K3/34 , C08K5/34 , C08K5/34922 , C08J2375/04
摘要： Stable melamine-polyoxyalkylene polyether polyol dispersions are prepared by the in situ reduction of melamine particles wherein 90 percent of the melamine particles have a particle size of less than 10 microns. Stabilizers for the melamine-polyol dispersion are selected from the group consisting of(a) silicic acids and silicates,(b) salts of perfluorinated alkyl carboxylic acids having 4 to 20 carbon atoms, salts of alkyl sulfonic acids and perfluorinated alkylsulfonic acids having 4 to 20 carbon atoms and polyperfluoroether polyols having molecular weights of 300 to 6000, and(c) salts of fatty alcohol sulfates having 6 to 30 carbon atoms.These dispersions are useful for the preparation of polyurethane foams.
摘要翻译：通过原位还原三聚氰胺颗粒制备稳定的三聚氰胺 - 聚氧化烯聚醚多元醇分散体，其中90％的三聚氰胺颗粒具有小于10微米的粒度。三聚氰胺 - 多元醇分散体的稳定剂选自（a）硅酸和硅酸盐，（b）具有4至20个碳原子的全氟化烷基羧酸盐，烷基磺酸盐和全氟烷基磺酸的盐，其具有4至 20个碳原子和分子量为300〜6000的聚全氟醚多元醇，（c）碳原子数为6〜30的脂肪醇硫酸盐。这些分散体可用于制备聚氨酯泡沫体。

3. 发明授权

US4243755A Process for the manufacture of reinforced polyurethane foams 失效
标题翻译：制造增强聚氨酯泡沫的方法
公开(公告)号：US4243755A
公开(公告)日：1981-01-06
申请号：US93375
申请日：1979-11-13
申请人： Matthias Marx , Dietmar Nissen , Wolfgang Jarre
发明人： Matthias Marx , Dietmar Nissen , Wolfgang Jarre
IPC分类号： C08J9/00 , C08G18/14
CPC分类号： C08J9/0066 , C08J9/0061 , C08J2375/04
摘要： The invention relates to a process for the manufacture of reinforced polyurethane foams based on the reaction of organic polyisocyanates and polyols in the presence of filler dispersions. These dispersions are prepared by in situ crushing of the filler in the polyisocyanate or polyol to a particle size of less than 7 microns.
摘要翻译：本发明涉及一种基于有机多异氰酸酯和多元醇在填料分散体存在下的反应来制造增强聚氨酯泡沫体的方法。这些分散体通过将多异氰酸酯或多元醇中的填料原位粉碎至小于7微米的粒度来制备。

4. 发明授权

US4668708A Process for the preparation of elastic polyurethane flexible foams usable in cold-mold techniques to produce molded articles 失效
标题翻译：用于制备可用于冷模技术的弹性聚氨酯软质泡沫塑料的制备方法来生产模塑制品
公开(公告)号：US4668708A
公开(公告)日：1987-05-26
申请号：US869199
申请日：1986-05-30
申请人： Gerhard Mueller , Matthias Marx , Wolfgang Jarre , Edwin Baumann , Ingolf Buethe
发明人： Gerhard Mueller , Matthias Marx , Wolfgang Jarre , Edwin Baumann , Ingolf Buethe
IPC分类号： C08G18/10 , C08G18/14
CPC分类号： C08G18/10 , Y10S521/914
摘要： The invention is a process for the preparation of elastic polyurethane flexible foams having densities from approximately 25 to 60 kg/m.sup.3, and producing molded articles in closed molds at temperatures from 25.degree. to 80.degree. C., comprising reacting(A) an organic polyisocyanate prepolymer having an isocyanate content from 6 to 20 percent by weight prepared by reacting a toluene diisocyanate and/or a diphenylmethane diisocyanate with a di- to tetrafunctional polyether polyol having a hydroxyl number from 20 to 50 and oxyethylene terminal group content of at least 10 to 30 percent by weight(B) a mixture of compounds containing reactive hydrogen atoms, comprising a mixture of(a) from 55 to 89.5 parts by weight of at least one di- to tetrafunctional polyether polyol having a hydroxyl number of from 20 to 80 and less than 10 percent by weight terminal oxyethylene groups,(b) from 0.5 to 20 parts by weight of at least one alkanolamine, and(c) from 10 to 25 parts by weight water, in the presence of(C) a blowing agent,(D) a catalyst, and optionally(E) auxiliaries and/or additives.
摘要翻译：本发明是制备密度为约25至60kg / m 3的弹性聚氨酯柔性泡沫体的方法，并且在封闭模具中在25℃至80℃的温度下生产模制品，其包括使（A）有机多异氰酸酯预聚物的异氰酸酯含量为6〜20重量％，其通过使甲苯二异氰酸酯和/或二苯基甲烷二异氰酸酯与羟基数为20至50的二至四官能团聚醚多元醇反应制备，氧乙烯基端基含量为至少10至 30重量％（B）含有反应性氢原子的化合物的混合物，其包含（a）55至89.5重量份的至少一种羟基数为20至80的二官能或四官能团聚醚多元醇的混合物，以及末端氧乙烯基少于10重量％，（b）0.5至20重量份的至少一种链烷醇胺，和（c）10至25重量份的水，（C）发泡剂，（D）催化剂和任选的（E）助剂和/或添加剂。

5. 发明授权

US4237237A Hydrophobic polyurethane foams, their manufacture and use 失效
标题翻译：疏水性聚氨酯泡沫，其制造和使用
公开(公告)号：US4237237A
公开(公告)日：1980-12-02
申请号：US34541
申请日：1979-04-30
申请人： Wolfgang Jarre , Rolf Wurmb
发明人： Wolfgang Jarre , Rolf Wurmb
IPC分类号： C08G18/00 , B01J20/26 , C02F1/68 , C08G18/28 , C08G18/36 , C08G18/38 , C08J9/00 , C08G18/14
CPC分类号： C08J9/0028 , C02F1/681 , C08G18/281 , C08G18/36 , C08G18/3825 , C08J9/0023 , C08K5/09 , C08K5/10 , C08K5/20 , C08G2101/005 , C08G2101/0083 , C08J2375/04 , Y10S521/905
摘要： Hydrophobic polyurethane foams which have densities of from 4 to 15 g/liter and in which the number of closed cells is from 2 to 30%, and the number of open cells from 98 to 70%, based on the total number of cells, are obtained from polyisocyanates, polyhydroxy compounds, catalysts and water, with or without lipophilic compounds, the components being reacted in such amounts that the ratio of hydrogen atoms capable of undergoing a Zerewitinoff reaction to NCO groups is from 1.3 to 10:1. The foams are suitable for the absorption of oil and/or by hydrophobic solvents, which may or may not contain halogen, from water.
摘要翻译：密度为4〜15g / l，封闭细胞数为2〜30％的疏水性聚氨酯泡沫，基于细胞总数的98〜70％的开放细胞数为由具有或不具有亲脂性化合物的多异氰酸酯，多羟基化合物，催化剂和水得到的组分以使得能够进行Zerewitinoff反应的氢原子与NCO基团的比例为1.3至10:1的量反应。泡沫适合于从水中吸收油和/或吸收可能含有或不含有卤素的疏水性溶剂。

6. 发明授权

US4279757A Process for separating hydrophobic organic liquids from water 失效
标题翻译：疏水性有机液体与水分离的方法
公开(公告)号：US4279757A
公开(公告)日：1981-07-21
申请号：US108424
申请日：1979-12-31
申请人： Gerard DeBeuckelaer , Wolfgang Jarre , Rolf Wurmb , Matthias Marx
发明人： Gerard DeBeuckelaer , Wolfgang Jarre , Rolf Wurmb , Matthias Marx
IPC分类号： B01D17/02 , B01D17/022 , C02F1/68 , C08G18/36 , C08G18/38 , C08G18/69 , C02F1/28
CPC分类号： C08G18/69 , B01D17/0202 , C08G18/36 , C08G18/3825 , C02F1/681 , C08G2101/0008 , C08G2101/0041 , C08G2101/0083
摘要： A process for separating hydrophobic organic liquids from water comprising passing a mixture of water and hydrophobic organic liquids through a column-like vessel which is filled with a hydrophobic, preferably open-celled, polyurethane foam, said foam having a high absorption capacity, permits high flow-through velocities even as the foam becomes covered and saturated with the hydrophobic organic liquids, is reversibly deformable, and can be reused.
摘要翻译：一种从水中分离疏水性有机液体的方法，包括使水和疏水性有机液体的混合物通过填充有疏水性，优选开孔聚氨酯泡沫的柱状容器，所述泡沫具有高吸收能力，允许高甚至当泡沫被疏水性有机液体覆盖并饱和时，流通速度是可逆变形的，并且可以重复使用。

7. 发明授权

US4237240A Process for the manufacture of flexible polyurethane foams with high load-bearing and high energy-absorption capacity 失效
标题翻译：制造具有高承载能力和高能量吸收能力的柔性聚氨酯泡沫的方法
公开(公告)号：US4237240A
公开(公告)日：1980-12-02
申请号：US28311
申请日：1979-04-09
申请人： Wolfgang Jarre , Peter Weyland , Gerhard Mueller
发明人： Wolfgang Jarre , Peter Weyland , Gerhard Mueller
IPC分类号： C08G18/40 , C08G18/42 , C08G18/76 , C08G18/14
CPC分类号： C08G18/42 , C08G18/4018 , C08G18/4236 , C08G18/7664 , C08G2101/0008 , C08G2101/005 , C08G2101/0058 , C08G2101/0083
摘要： The invention concerns a process for the manufacture of flexible polyurethane foams by reaction of a mixture consisting of diphenylmethane diisocyanates and polyphenylene polymethylene polyisocyanates having a functionality greater than 2 containing 55 to 85 percent by weight diphenylmethane diisocyanate based on the total weight of the isocyanate mixture with polyester polyols or mixtures of polyester polyols and polyether polyols having a polyester polyol content of more than 60 percent by weight based on the weight of the polyol mixture, and optionally chain extenders, auxiliaries, and additives, in the presence of catalysts and, in particular, water as a blowing agent. The special selection of starting compounds results in the production of flexible polyurethane foams having a high resistance to hydrolysis, high load-bearing capacity, and high energy absorption upon impact.
摘要翻译：本发明涉及通过由二苯基甲烷二异氰酸酯和功能性大于2的聚亚苯基多亚甲基多异氰酸酯组成的混合物制造柔性聚氨酯泡沫的方法，所述多异氰酸酯含有55至85重量％的二苯基甲烷二异氰酸酯，基于异氰酸酯混合物的总重量，聚酯多元醇或聚酯多元醇和聚醚多元醇的混合物，其聚酯多元醇含量基于多元醇混合物的重量大于60重量％，以及任选的增链剂，助剂和添加剂，在催化剂存在下，特别是，水作为发泡剂。起始化合物的特殊选择导致生产具有高抗水解性，高承载能力和高冲击能量吸收的柔性聚氨酯泡沫。

8. 发明授权

US6013692A Cellular polyurethane elastomers 有权
标题翻译：蜂窝状聚氨酯弹性体
公开(公告)号：US6013692A
公开(公告)日：2000-01-11
申请号：US91108
申请日：1998-12-17
申请人： Ulrich Daum , Arno Feeken , Wolfgang Jarre , Andreas Schmidt , Reinhard Sklenarz
发明人： Ulrich Daum , Arno Feeken , Wolfgang Jarre , Andreas Schmidt , Reinhard Sklenarz
IPC分类号： C08G18/32 , C08G18/10 , C08G18/38 , C08G101/00 , C08G18/04
CPC分类号： C08G18/3814 , C08G18/10 , C08G2101/0008 , C08G2101/0083
摘要： Cellular Polyurethane elastomer which is produced by reacting:(a) an isocyanate component which includes methylenebis(phenyl isocyanate) (MDI) and/or tolylene diisocyante (TDI), in monomeric form or as liquefied prepolymer with(b) compounds which at least two isocyanate-reactive hydrogen atoms and(c) 4,4'-methylenebis(3-chloro-2,6-dialylaniline) or a mixture of 4,4'-methylenebis-(3-chloro-2,6-dialyaniline) with one or more aromatic, aliphatic or cycloaliphatic diamines as chain extending agent, if desired with further polyol, and(d) a blowing agent in the presence of the usual catalysts and, if desired, other additives.
摘要翻译： PCT No.PCT / EP96 / 05542 Sec。 371日期1998年12月17日第 102（e）日期1998年12月17日PCT 1996年12月11日PCT公布。出版物WO97 / 21749 日本1996年6月19日通过使（a）异氰酸酯组分（包括亚甲基双（苯基异氰酸酯）（MDI））和/或甲苯二异氰酸酯（TDI），单体形式或液化预聚物与（b）至少两个异氰酸酯反应性氢原子和（c）4,4'-亚甲基双（3-氯-2,6-二苯基苯胺）或4,4'-亚甲基双（3-氯-2,6 二亚氨基苯胺）与一种或多种芳族，脂族或脂环族二胺作为扩链剂，如果需要，另外的多元醇，和（d）发泡剂在通常的催化剂和如果需要的情况下，其它添加剂。

9. 发明授权

US4258141A Process for manufacture of flexible polyurethane foams with cyanic acid derivatives 失效
标题翻译：用氰酸衍生物制造柔性聚氨酯泡沫的方法
公开(公告)号：US4258141A
公开(公告)日：1981-03-24
申请号：US028663
申请日：1979-04-10
申请人： Wolfgang Jarre , Gerhard Mueller , Otmar Zipp , Eckhard Ropte
发明人： Wolfgang Jarre , Gerhard Mueller , Otmar Zipp , Eckhard Ropte
IPC分类号： C08G18/00 , C08G18/38 , C08G18/72 , C08G18/76 , C08J9/00 , C08G18/14
CPC分类号： C08J9/0028 , C08G18/3838 , C08G18/3851 , C08G18/7664 , C08K5/29 , C08K5/34 , C08J2375/04
摘要： The invention concerns a process for the manufacture of flame resistant flexible polyurethane foams by reacting a mixture of diphenylmethane diisocyanates and polyphenylene polymethylene polyisocyanates having a functionality greater than 2 containing 40 to 90 percent by weight diphenylmethane diisocyanate based on the total weight of said mixture; polyols, cyanic acid derivatives such as cyanamide, dicyandiamide, guanidine, biguanidine, melamine, cyanuric alkyl esterhydrazides and -amides as flame inhibitors, and blowing agents; as well as, possibly, chain extenders and other additives. The flexible polyurethane foams are suited for the familiar areas of applications, but especially as sound-insulation material for the construction industry.
摘要翻译：本发明涉及通过使二苯基甲烷二异氰酸酯和具有大于2的官能度的聚亚苯基多亚甲基多异氰酸酯的混合物与基于所述混合物的总重量的40至90重量％的二苯基甲烷二异氰酸酯反应制备阻燃软质聚氨酯泡沫体的方法; 多元醇，氰酸衍生物如氰胺，双氰胺，胍，双胍胺，三聚氰胺，氰尿烷基酯酰肼和作为阻燃剂的酰胺;和发泡剂; 以及可能的扩链剂和其它添加剂。柔性聚氨酯泡沫适用于熟悉的应用领域，特别适用于建筑行业的隔音材料。

10. 发明授权

US4251411A Process for the manufacture of organic polymer polyol 失效
标题翻译：制备有机聚合物多元醇的方法
公开(公告)号：US4251411A
公开(公告)日：1981-02-17
申请号：US941285
申请日：1978-09-11
申请人： Gerhard Heinz , Hermann Dikow , Wolfgang Jarre , Dietmar Nissen , Klaus Matthias , Hanshelmut Kaeppel
发明人： Gerhard Heinz , Hermann Dikow , Wolfgang Jarre , Dietmar Nissen , Klaus Matthias , Hanshelmut Kaeppel
IPC分类号： C08G18/08 , C08G18/62 , C08G18/63 , C08J3/09 , C08J9/00 , C08K5/05
CPC分类号： C08J3/09 , C08G18/14 , C08G18/62 , C08G18/635 , C08J9/0061
摘要： A process for the manufacture of partially dehydrated organic polymer polyol dispersions from the reaction of polyhydroxyl compounds and aqueous polymer dispersions wherein the problem of excessive viscosity is overcome by mixing the reactants with a recycled partially dehydrated polyol polymer dispersion, removing water from the reaction mixture, removing a portion of the partially dehydrated polyol polymer dispersion, and recycling the remainder.
摘要翻译：从多羟基化合物和聚合物水分散体的反应制备部分脱水的有机聚合物多元醇分散体的方法，其中通过将反应物与循环的部分脱水多元醇聚合物分散体混合来克服过度粘度的问题，从反应混合物中除去水，除去部分脱水的多元醇聚合物分散体的一部分，并循环剩余部分。

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