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1. 发明授权

US4113762A Method of making carbonic acid esters 失效
标题翻译：制造碳酸酯的方法
公开(公告)号：US4113762A
公开(公告)日：1978-09-12
申请号：US827771
申请日：1977-08-25
申请人： Wolfgang Gaenzler , Klaus Kabs , Guenter Schroeder
发明人： Wolfgang Gaenzler , Klaus Kabs , Guenter Schroeder
IPC分类号： C07C68/00
CPC分类号： C07C68/005
摘要： A method for making a carbonic acid ester of the formula ##STR1## wherein R is --CH.sub.3, --C.sub.2 H.sub.5, or --C.sub.3 H.sub.7, which comprises reacting the corresponding alcohol, ROH, with carbon monoxide and oxygen, under pressure and at elevated temperature, in the presence of a copper-containing catalyst, said catalyst being a complex formed between copper-I-chloride and vanadium trichloride, chromium trichloride, iron trichloride, cobalt-II-chloride, aluminum trichloride, or silicon tetrachloride.
摘要翻译：制备式“IMAGE”的碳酸酯的方法，其中R是-CH 3，-C 2 H 5或-C 3 H 7，其包括使相应的醇ROH与一氧化碳和氧在压力和升高的温度下，在含铜催化剂的存在，所述催化剂是在氯化-1-氯和三氯化钒，三氯化铬，三氯化铁，氯化钴 - 氯化物，三氯化铝或四氯化硅之间形成的络合物。

2. 发明授权

US3952045A Method for preparing carbonic acid esters 失效
标题翻译：制备碳酸酯的方法
公开(公告)号：US3952045A
公开(公告)日：1976-04-20
申请号：US485630
申请日：1974-07-03
申请人： Wolfgang Gaenzler , Guenter Schroeder , Klaus Kabs
发明人： Wolfgang Gaenzler , Guenter Schroeder , Klaus Kabs
IPC分类号： C07C69/96 , B01J23/00 , B01J31/16 , B01J31/18 , B01J31/24 , C07B61/00 , C07C68/00
CPC分类号： B01J31/1875 , B01J31/1845 , B01J31/185 , C07C68/005 , B01J2531/16
摘要： A method for preparing carbonic acid esters, ##EQU1## by reacting an alcohol, ROH, with carbon monoxide and oxygen in the presence of a catalyst comprising a copper salt, chloride or bromide, and an organic phosphorus compound such as a phosphine oxide, phosphite, phosphate, or phosphonate.
摘要翻译：在包含铜盐，氯化物或溴化物的催化剂以及有机磷化合物如氧化膦的存在下，使醇ROH与一氧化碳和氧反应，制备碳酸酯O PARALLEL ROCOR的方法，亚磷酸盐，磷酸盐或膦酸盐。

3. 发明授权

US4147718A Method for making methacrylic acid, its nitrile and its esters 失效
标题翻译：制备甲基丙烯酸及其腈及其酯的方法
公开(公告)号：US4147718A
公开(公告)日：1979-04-03
申请号：US869605
申请日：1978-01-16
申请人： Wolfgang Gaenzler , Klaus Kabs , Guenter Schroeder
发明人： Wolfgang Gaenzler , Klaus Kabs , Guenter Schroeder
IPC分类号： C07C69/54 , B01J21/00 , B01J23/02 , C07B61/00 , C07C51/00 , C07C51/353 , C07C57/04 , C07C67/00 , C07C67/30 , C07C121/32
CPC分类号： C07C253/30 , B01J23/02 , C07C51/353 , Y02P20/52
摘要： In the method of making a compound of the formula ##STR1## wherein X is carboxyl, a carboxylic acid ester group --COOR.sub.2, or cyano, by reaction of a compound of the formula CH.sub.3 CH.sub.2 X with methylal in the presence of a catalyst, the improvement wherein said catalyst is a catalyst system which consists essentially of (1) silicon dioxide dosed with a basic component and (2) a member selected from the group consisting of aluminum oxide and titanium dioxide.
摘要翻译：在制备其中X是羧基的式“IMAGE”的化合物的方法中，羧酸酯基-COOR 2或氰基通过式CH3CH2X的化合物与甲缩醛在催化剂的存在下反应，其改进在于所述催化剂是一种催化剂体系，其基本上由（1）配有碱性组分的二氧化硅和（2）选自氧化铝和二氧化钛的组分组成。

4. 发明授权

US4069381A Method for preparing glycol esters 失效
标题翻译：制备甘油酯的方法
公开(公告)号：US4069381A
公开(公告)日：1978-01-17
申请号：US415453
申请日：1973-11-12
申请人： Wolfgang Gaenzler , Klaus Kabs , Guenter Schroeder
发明人： Wolfgang Gaenzler , Klaus Kabs , Guenter Schroeder
IPC分类号： C07C67/00 , C07C67/05 , C07C69/16
CPC分类号： C07C67/05
摘要： An improved method for making glycol monoesters and diesters of carboxylic acid by the reaction of an olefin and oxygen in the presence of a carboxylic acid and a catalyst, wherein said catalyst includes a compound of a metal of groups IVB - VIIB having an atomic number between 40 and 42 inclusive or between 72 and 75 inclusive, i.e. zirconium, niobium, molybdenum, hafnium, tantalum, tungsten, or rhenium.

5. 发明授权

US3960934A Method for the oxycarbonylation of ethylene and propylene 失效
标题翻译：乙烯和丙烯氧羰基化的方法
公开(公告)号：US3960934A
公开(公告)日：1976-06-01
申请号：US561633
申请日：1975-03-24
申请人： Wolfgang Gaenzler , Klaus Kabs , Guenter Schroeder
发明人： Wolfgang Gaenzler , Klaus Kabs , Guenter Schroeder
IPC分类号： C07C67/38 , B01J23/00 , B01J31/00 , C07B61/00 , C07C69/54 , C07C69/66
CPC分类号： C07C69/54
摘要： A process for the catalytic oxycarbonylation of ethylene and propylene by reaction with carbon monoxide and oxygen in a methanolic or ethanolic reaction medium employing a catalyst which contains a compound of vanadium, chromium, iron, cobalt, nickel or copper and chloride, bromide, or iodide ions.
摘要翻译：通过使用含有钒，铬，铁，钴，镍或铜的化合物和氯化物，溴化物或碘化物的催化剂在甲醇或乙醇反应介质中与一氧化碳和氧气反应来进行乙烯和丙烯的催化氧羰基化的方法离子。

6. 发明授权

US4647696A Method for making isobutyric acid 失效
标题翻译：制备异丁酸的方法
公开(公告)号：US4647696A
公开(公告)日：1987-03-03
申请号：US474799
申请日：1983-03-14
申请人： Siegmund Besecke , Guenter Schroeder , Hermann-Josef Siegert , Wolfgang Gaenzler
发明人： Siegmund Besecke , Guenter Schroeder , Hermann-Josef Siegert , Wolfgang Gaenzler
IPC分类号： C07C51/14 , C07C67/38 , C07B53/00 , C07C53/124
CPC分类号： C07C51/14 , C07C67/38
摘要： What is disclosed is a continuous one-step method for the preparation of isobutyric acid or a lower alkyl ester thereof by the Koch synthesis, which method comprises reacting propylene, carbon monoxide, and water or a lower alcohol, in the gaseous and liquid phases, in the presence of hydrogen fluoride as a Koch catalyst, at a temperature between 80.degree. C. and 160.degree. C., at a dwell time of the liquid phase of less than 20 minutes, and with a high degree of backmixing, while maintaining the content of propylene in the reaction mixture at less than one percent by weight of the liquid phase, wherein all or part of the propylene, carbon monoxide, and water or lower alcohol can be replaced by binary addition compounds formed pairwise between these materials. In the alternative, isopropylformiate can be continuously rearranged in the presence of hydrogen fluoride to produce isobutyric acid.
摘要翻译：所公开的是通过Koch合成制备异丁酸或其低级烷基酯的连续一步法，该方法包括在气相和液相中使丙烯，一氧化碳和水或低级醇反应，在作为Koch催化剂的氟化氢的存在下，在80℃至160℃的温度下，在液相的停留时间小于20分钟，并具有高度的回混，同时保持反应混合物中丙烯的含量小于液相的1重量％，其中全部或部分丙烯，一氧化碳和水或低级醇可以由这些材料成对形成的二元加成化合物代替。在替代方案中，异丙基甲酸酯可以在氟化氢的存在下连续重排以产生异丁酸。

7. 发明授权

US4228102A Preparation of carboxylic acid amides 失效
标题翻译：羧酸酰胺的制备
公开(公告)号：US4228102A
公开(公告)日：1980-10-14
申请号：US14361
申请日：1979-02-23
申请人： Siegmund Besecke , Wolfgang Gaenzler , Guenter Schroeder
发明人： Siegmund Besecke , Wolfgang Gaenzler , Guenter Schroeder
IPC分类号： C07C67/00 , C07C231/00 , C07C231/02 , C07C233/09 , C07C102/06
CPC分类号： C07C231/02
摘要： What is disclosed is a method for making amides of the formula ##STR1## wherein R.sub.1 is hydrogen or methyl,R.sub.3 is straight-chain or branched alkyl or unsubstituted or substituted aryl, andR.sub.4 is hydrogen or straight-chain or branched unsubstituted or substituted alkyl, which comprises reacting an ester of the formula ##STR2## wherein R.sub.2 is alkyl having 1 to 6 carbon atoms, with heating and under autogenous pressure, in a homogeneous phase, with an amine of the formula ##STR3## said amine being present in an amount which is stoichiometrically deficient up to an amount which is in small stoichiometric excess with respect to said ester.
摘要翻译：所公开的是制备式IMA的酰胺的方法，其中R1是氢或甲基，R3是直链或支链烷基或未取代或取代的芳基，R4是氢或直链或支链的未取代或取代的烷基该方法包括使下式的化合物（其中R 2为具有1至6个碳原子的烷基）在加热和自生压力下在均相中与下式的胺反应：所述胺存在于化学计量不足量至相对于所述酯具有小的化学计量过量的量。

8. 发明授权

US4452999A Method for making isobutyric acid 失效
标题翻译：制备异丁酸的方法
公开(公告)号：US4452999A
公开(公告)日：1984-06-05
申请号：US380609
申请日：1982-05-21
申请人： Siegmund Besecke , Guenter Schroeder , Hermann-Josef Siegert , Wolfgang Gaenzler
发明人： Siegmund Besecke , Guenter Schroeder , Hermann-Josef Siegert , Wolfgang Gaenzler
IPC分类号： C07C51/14 , C07C67/38
CPC分类号： C07C51/14 , C07C67/38
摘要： What is disclosed is a continuous one-step method for the preparation of isobutyric acid or a lower alkyl ester thereof by the Koch synthesis, which method comprises reacting propylene, carbon monoxide, and water or a lower alcohol, in the gaseous and liquid phases, in the presence of hydrogen fluoride as a Koch catalyst, at a temperature between 80.degree. C. and 160.degree. C., at a dwell time of the liquid phase of less than 20 minutes, and with a high degree of backmixing, while maintaining the content of propylene in the reaction mixture at less than one percent by weight of the liquid phase, wherein all or part of the propylene, carbon monoxide, and water or lower alcohol can be replaced by binary addition compounds formed pairwise between these materials. In the alternative, isopropylformiate can be continuously rearranged in the presence of hydrogen fluoride to produce isobutyric acid.
摘要翻译：所公开的是通过Koch合成制备异丁酸或其低级烷基酯的连续一步法，该方法包括在气相和液相中使丙烯，一氧化碳和水或低级醇反应，在作为Koch催化剂的氟化氢的存在下，在80℃至160℃的温度下，在液相的停留时间小于20分钟，并具有高度的回混，同时保持反应混合物中丙烯的含量小于液相的1重量％，其中全部或部分丙烯，一氧化碳和水或低级醇可以由在这些材料之间成对形成的二元加成化合物代替。在替代方案中，异丙基甲酸酯可以在氟化氢的存在下连续重排以产生异丁酸。

9. 发明授权

US4576971A Flame-retarded polyacrylamide or polymethacrylimide synthetic resin foam 失效
标题翻译：阻燃聚丙烯酰胺或聚甲基丙烯酰亚胺合成树脂泡沫
公开(公告)号：US4576971A
公开(公告)日：1986-03-18
申请号：US683042
申请日：1984-12-18
申请人： Ehrenfried Baumgartner , Siegmund Besecke , Wolfgang Gaenzler
发明人： Ehrenfried Baumgartner , Siegmund Besecke , Wolfgang Gaenzler
IPC分类号： C08F2/44 , C08J9/04 , C08K5/5333 , C08J9/06
CPC分类号： C08J9/04 , C08K5/5333 , C08J2333/26
摘要： Flame retarded polyacrylimide or polymethacrylimide resin foams containing at least 70 percent by weight of cyclic acrylimide or methacrylimide units and incorporating at least 1 percent by weight of phosphorus, present at least partially in the form of a phosphorus compound, XCH.sub.2 --PO(OR).sub.2, wherein R is methyl, ethyl, or chloromethyl, and X is hydrogen, halogen, hydroxyl, or RO--CO--.
摘要翻译：含有至少70重量％的环状丙烯酰亚胺或甲基丙烯酰亚胺单元的阻燃聚丙烯酰亚胺或聚甲基丙烯酰胺树脂泡沫，并且至少部分以磷化合物XCH 2 PO（OR）2的形式并入至少1重量％的磷其中R是甲基，乙基或氯甲基，X是氢，卤素，羟基或RO-CO-。

10. 发明授权

US4656119A Method of manufacturing X-ray resist 失效
标题翻译：制造X射线抗蚀剂的方法
公开(公告)号：US4656119A
公开(公告)日：1987-04-07
申请号：US802450
申请日：1985-11-27
申请人： Frithjof Asmussen , Wolfgang Gaenzler , Winfried Wunderlich
发明人： Frithjof Asmussen , Wolfgang Gaenzler , Winfried Wunderlich
IPC分类号： G03C5/00 , G03F7/039 , G03F7/16 , G03F7/26 , G03F7/32 , G03F7/38 , H01L21/027
CPC分类号： G03F7/168 , G03F7/039 , G03F7/325 , Y10S430/168
摘要： A method of producing X-ray resist with etching patterns, using known supports which are coated with a film comprised of copolymers of methacrylonitrile and methacrylic acid is disclosed. This method uses the following protocol.(a) A copolymer of methacrylonitrile and methacrylic acid with molecular weight
摘要翻译：公开了一种用蚀刻图形制造X射线抗蚀剂的方法，该方法使用由包含甲基丙烯腈和甲基丙烯酸共聚物的膜涂覆的已知载体。此方法使用以下协议。（a）使用分子量小于700,000的甲基丙烯腈和甲基丙烯酸的共聚物来涂覆载体。（b）在X射线照射之前，将膜在低于150℃的温度下进行热处理，直至获得无溶剂的未交联的膜。（c）X射线照射后，在140〜170℃的温度下对膜进行回火15-30分钟。（d）然后用由水和/ 或含有羟基和/或醚基和/或酯基形式的氧的有机溶剂。

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