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    • 9. 发明授权
    • Polycarbonate-polyolefin moulding compositions
    • 聚碳酸酯 - 聚烯烃模塑组合物
    • US4499237A
    • 1985-02-12
    • US180334
    • 1980-08-22
    • Peter TackeHelmut KorberJosef MertenDieter Neuray
    • Peter TackeHelmut KorberJosef MertenDieter Neuray
    • C08L7/00C08L21/00C08L23/00C08L33/00C08L33/02C08L51/00C08L51/02C08L69/00C08L101/00
    • C08L69/00
    • A mixture comprising 1. from 70 to 99% by weight of a predominantly aromatic polycarbonate; and 2. from 30 to 1% by weight of a polyolefin graft polymer of (a) 70 to 95% by weight of a graft base consisting of a homopolymer of aliphatic and/or aromatic monoolefins or of a copolymer of these olefins, and up to 50% by weight of other monoolefinically unsaturated, radially polymerizable compounds and/or up to 5% by weight of diolefins, and (b) 5 to 30% by weight of at least one graft-polymerizable vinyl compound, the olefin graft polymers having been obtained by contacting a melt of the graft base (a) with oxygen or an oxygen-containing gas for at most 10 min. with intensive mixing under a pressure of from 1 to 150 bars and at a temperature of from 80.degree. C. to 300.degree. C., adding the vinyl compounds (b) to be grafted on immediately afterwards with intensive mixing in the absence of oxygen or oxygen-containing gas and removing the residual monomers after the graft polymerization reaction.
    • 包含1.70至99重量%的主要是芳族聚碳酸酯的混合物; 和2.30至1重量%的(a)70至95重量%的由脂族和/或芳族单烯烃的均聚物或这些烯烃的共聚物组成的接枝基质的聚烯烃接枝聚合物和上述 至50重量%的其它单烯属不饱和的可径向聚合的化合物和/或至多5重量%的二烯烃,和(b)5至30重量%的至少一种可接枝聚合的乙烯基化合物,所述烯烃接枝聚合物具有 通过将接枝基质(a)的熔体与氧或含氧气体接触至多10分钟而获得。 在1至150巴的压力和80℃至300℃的温度下进行强烈混合,然后在不存在氧气的情况下立即将密封混合的乙烯基化合物(b)立即加入, 含氧气体,并在接枝聚合反应后除去残留的单体。