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1. 发明授权

US5235099A Process for the preparation of ureidoperoxycarboxylic acids 失效
标题翻译：制备尿嘧啶羧酸的方法
公开(公告)号：US5235099A
公开(公告)日：1993-08-10
申请号：US793815
申请日：1991-11-18
申请人： Wolf-Dieter Muller , Frank Jaekel , Peter Naumann , Gerd Reinhardt
发明人： Wolf-Dieter Muller , Frank Jaekel , Peter Naumann , Gerd Reinhardt
IPC分类号： B01J27/02 , A01N47/28 , A01N47/30 , A01N47/32 , B01J31/02 , B01J31/08 , C07B61/00 , C07C407/00 , C07C409/40 , C11D3/39
CPC分类号： A01N47/28 , A01N47/30 , A01N47/32 , C07C407/00 , C11D3/3945 , C07C2101/14
摘要： A process for the preparation of ureidoperoxycarboxylic acids of the formula ##STR1## in which x is the number 1 or 2,A,if x is 1,is hydrogen, C.sub.1 -C.sub.20 -alkyl, aryl, preferably phenyl, or haloaryl, preferably chlorophenyl, orif x is 2,is C.sub.1 -C.sub.20 -alkylene or arylene, preferably phenylene,B is a group of the formula ##STR2## in which n is a number from 1 to 20,m is the number 0, 1 or 2,R.sup.1 is C.sub.1 -C.sub.20 -alkyl andR.sup.2 is in each case hydrogen or C.sub.1 -C.sub.20 -alkyl, which comprises dissolving carbamoyllactams of the formula ##STR3## in which x, A and B have the abovementioned meanings, in a one- to six-fold, preferably a one- to three-fold, amount by weight of a strong catalyst acid, by then adding water in a one- to ten-fold molar excess, relative to the carbamoyllactam, to the solution of the carbamoyllactam in the catalyst acid and by heating the reaction mixture to form the ureidocarboxylic acid, by then adding to the reaction mixture an aqueous hydrogen peroxide solution in a one- to ten-fold, preferably a two- to four fold, molar excess per oxidizable carboxyl group of the ureidocarboxylic acid formed in the preceding reaction step, and by then precipitating the resulting ureidoperoxycarboxylic acid from the reaction mixture.These compounds are suitable as bleaches, oxidants and disinfectants.
摘要翻译：制备式A [NHCONHBCOOOH] x的脲基过氧羧酸的方法，其中x为数1或2，如果x为1，则为A，为C 1 -C 20烷基，芳基，优选苯基或卤代芳基，优选氯苯基，或如果x为2，则为C 1 -C 20亚烷基或亚芳基，优选亚苯基，B为下式的基团：其中n为1至20的数，m为数 0,1或2，R 1是C 1 -C 20烷基，R 2在各自的情况下是氢或C 1 -C 20 - 烷基，其包括将式（ⅩⅧ）的氨基甲酰基内酰胺溶解在其中x，A和B具有上述含义，以强的催化剂酸的重量比为1至6倍，优选1至3倍，然后将相对于氨基甲酰基内酰胺的1至10倍摩尔过量的水加入到催化剂中的氨基甲酰基内酰胺，并加热反应混合物形成脲基羧酸，然后向反应混合物中加入过氧化氢水溶液在上述反应步骤中形成的脲基羧酸的每个可氧化羧基的摩尔过量为十倍，优选为二至四倍，然后从反应混合物中沉淀所得的脲基过氧羧酸。这些化合物适合作为漂白剂，氧化剂和消毒剂。

2. 发明授权

US5518650A Imidocarboxylic acid activators and sulfimidocarboxylic acid activators, processes for their preparation and their use 失效
标题翻译：二羧酸活化剂和亚磺酰基羧酸活化剂，其制备方法及其用途
公开(公告)号：US5518650A
公开(公告)日：1996-05-21
申请号：US455671
申请日：1995-05-31
申请人： Frank Jaekel , Gerd Reinhardt , Wolf-Dieter Muller
发明人： Frank Jaekel , Gerd Reinhardt , Wolf-Dieter Muller
IPC分类号： C07D207/452 , C07D207/40 , C07D209/48 , C07D211/88 , C07D223/10 , C07D275/02 , C07D275/06 , C07D279/02 , C07D281/02 , C07D401/06 , C07D401/10 , C07D403/06 , C07D403/10 , C07D417/06 , C07D417/10 , C11D3/39 , C11D3/395 , C11D3/48 , C11D7/54 , D06L3/02 , C09K3/00 , C01B15/00
CPC分类号： C07D207/40 , C07D209/48 , C11D3/392
摘要： This invention is directed to a process for bleaching textile objects and bleaching agent containing a persalt activators and salts thereof which are derived from imidocarboxylic acids and sulfimidocarboxylic acids of the formula I: ##STR1## in which A is a group of the formula ##STR2## n is the number 0, 1 or 2, R.sup.1 is hydrogen, chlorine, bromine, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, aryl, or alkylaryl,R.sup.2 is hydrogen, chlorine, bromine, --SO.sub.3 M, --CO.sub.2 M or --OSO.sub.3 M,X is C.sub.1 -C.sub.9 -alkylene or arylene,B is a group of the formula C.dbd.O or SO.sub.2,L is a leaving group.
摘要翻译：本发明涉及一种漂白纺织品和漂白剂的方法，所述漂白剂含有衍生自式I的亚氨基羧酸和亚磺酰亚氨基羧酸的式（I）的持久性活化剂及其盐：其中A是式 n是数字0,1或2，R1是氢，氯，溴，C1-C20-烷基，C2-C20-烯基，芳基或烷基芳基，R2是氢，氯，溴，-SO 3 M，-CO 2 M或-OSO 3 M，X为C 1 -C 9 - 亚烷基或亚芳基，B为式C = O或SO 2的基团，L为离去基团。

3. 发明授权

US4923996A Optically active rhodium complexes of 3,4-bis(diarylphosphino)pyrrolidines and their use for the preparation of phosphinothricin by asymmetric hydrogenation 失效
标题翻译： 3,4-双（二芳基膦基）吡咯烷的光学活性铑络合物及其用于通过不对称氢化制备膦丝菌素
公开(公告)号：US4923996A
公开(公告)日：1990-05-08
申请号：US312030
申请日：1989-02-17
申请人： Wolf-Dieter Muller , Hans-Jerg Kleiner
发明人： Wolf-Dieter Muller , Hans-Jerg Kleiner
IPC分类号： C07F9/30 , C07F9/572 , C07F15/00 , C08G18/10 , C08G18/28 , C08G18/83 , C08G65/32 , C08G65/329
CPC分类号： C08G65/329 , C07F15/008 , C07F9/301 , C07F9/5726 , C08G18/10 , C08G18/288
摘要： The invention relates to rhodium complexes of the formula[A--O--(CH.sub.2 CH.sub.2 O).sub.n --A].sup.2+ 2 X.sup.- Iaand[A--O--(CH.sub.2 CH.sub.2 O).sub.m --CH.sub.3 ].sup.+ X.sup.-Ibin whichn=5-1,000,m=5-250,X.sup.- denotes a tetrafluoroborate, hexafluorophosphate or per-chlorate anion,A denotes a radical of the formula ##STR1## (en).sub.2 denotes two molecules of a monoolefin or one molecule of a diolefinAr denotes phenyl or phenyl which is substituted by one or two alkyl groups having 1 or 2 carbon atoms andR.sup.1 denotes an arylene or alkylene bridge, and their use for the preparation of L-phosphinothricin and its derivatives by enantioselective catalytic hydrogenation of 2,3-dehydrophosphinothricin (derivatives).
摘要翻译：本发明涉及式[AO-（CH 2 CH 2 O）n A] 2+ 2 X-Ia和[AO-（CH 2 CH 2 O）m -CH 3] + X-Ib的铑络合物，其中n = 5-1,000，m = 250，X-表示四氟硼酸盐，六氟磷酸盐或全氯酸盐阴离子，A表示下式的基团II（en）2表示双分子的单烯烃或一分子的二烯烃Ar表示苯基或被取代的苯基通过一个或两个具有1或2个碳原子的烷基，并且R 1表示亚芳基或亚烷基桥，以及它们用于通过2,3-脱氢膦丝菌素（衍生物）的对映选择性催化氢化制备L-膦丝菌素及其衍生物的用途。

4. 发明授权

US4692322A Process for producing a product gas containing carbon oxides and hydrogen from methanol 失效
标题翻译：从甲醇生产含有碳氧化物和氢气的产品气体的方法
公开(公告)号：US4692322A
公开(公告)日：1987-09-08
申请号：US917997
申请日：1986-10-10
申请人： Friedrich-Wilhelm Moller , Walter Boll , Friedemann Marschner , Wolf-Dieter Muller
发明人： Friedrich-Wilhelm Moller , Walter Boll , Friedemann Marschner , Wolf-Dieter Muller
IPC分类号： C01B3/22 , B01J23/00 , C01B3/32 , C01B31/18 , C01B1/13
CPC分类号： C01B3/323 , Y02P20/52
摘要： The methanol vapor is mixed with a gas mixture which consists mainly of carbon dioxide and hydrogen and a high-methanol mixed feedstock is thus obtained. The mixed feedstock is fed to a first catalytic breakdown zone at an entrance temperature from 300.degree. to 400.degree. C., which contains a zinc-containing catalyst, which is indirectly heated. An intermediate having a methanol content not in excess of 1% by volume is withdrawn at a temperature in the range from 350.degree. to 600.degree. C. from the first breakdown zone and is cooled. Condensed water is removed at least in part from the intermediate, which is subsequently heated to a temperature in the range from 320.degree. to 420.degree. C. At least one-half of the heated intermediate product is supplied to a second catalytic breakdown zone, which also contains a zinc-containing catalyst, which is indirectly heated. A precursor product is withdrawn from the second breakdown zone at temperature from 350.degree. to 600.degree. C. and is cooled and aqueous condensate is withdrawn from the precursor. The product, which is subsequently supplied at an entrance temperature from 20.degree. to 80.degree. to and is passed through a separating zone, which contains a multiplicity of selectively permeable membranes. First and second gas streams are withdrawn from the separating zones. The first gas stream contains at least 90% by volume CO.sub.2 and H.sub.2. The second gas stream contains at least 30% by volume CO. The first gas stream is enriched with CO.sub.2 to provide a gas mixture, which is mixed with the methanol vapor.
摘要翻译：将甲醇蒸气与主要由二氧化碳和氢气组成的气体混合物混合，由此获得高 - 甲醇混合原料。混合原料在300℃至400℃的入口温度下进料到第一催化击穿区，其中含有间接加热的含锌催化剂。甲醇含量不超过1体积％的中间体在350℃至600℃的温度下从第一击穿区中取出并冷却。冷凝水至少部分地从中间体中除去，其随后被加热到320℃至420℃的温度。至少一半的加热的中间产物被供应到第二催化击穿区，其中还含有间接加热的含锌催化剂。在350℃至600℃的温度下将前体产物从第二击穿区域中取出并冷却，并从该前体中取出含水的冷凝物。该产品随后在20°至80°的入口温度下供给并通过分离区，该分离区含有多个选择性渗透膜。第一和第二气流从分离区域中排出。第一气流含有至少90体积％的二氧化碳和氢气。第二气流含有至少30体积％的CO。第一气流富含CO 2以提供与甲醇蒸气混合的气体混合物。

5. 发明授权

US4061475A Process for producing a gas which can be substituted for natural gas 失效
标题翻译：用于生产可代替天然气的气体的方法
公开(公告)号：US4061475A
公开(公告)日：1977-12-06
申请号：US773109
申请日：1977-02-28
申请人： Friedrich-Wilhelm Moller , Karl Bratzler , Wolf-Dieter Muller
发明人： Friedrich-Wilhelm Moller , Karl Bratzler , Wolf-Dieter Muller
IPC分类号： C10K3/04 , C10L3/08 , C10J3/00 , C10K3/02
CPC分类号： C10K3/04 , C10L3/08
摘要： A high methane gas which can be substituted for natural gas is produced from a primary gas made by the gasification of coal, tar, or heavy residual oil under superatmospheric pressures. The primary gas is purified to remove catalyst poisons and is scrubbed to remove carbon dioxide to a residual content below 2% by volume. The water vapor to carbon monoxide volume ratio of the scrubbed gas is adjusted to 0.55 : 1 to 1 : 1 and is then passed through a reaction zone containing a shift conversion catalyst and a methanation catalyst in a volume ratio of approximately 1 : 4 to 1 : 10. The scrubbed gas entering the reaction zone enters the reaction zone at a temperature of 300.degree.-500.degree. C.
摘要翻译：可以替代天然气的高甲烷气体是由在超大气压下煤，焦油或重残余油气化而成的主要气体产生的。纯化主要气体以除去催化剂毒素，并将其洗涤以除去二氧化碳至残留含量低于2体积％。将洗涤气体的水蒸气与一氧化碳体积比调节至0.55:1至1:1，然后通过含有换算转化催化剂和甲烷化催化剂的体积比为约1:4至1的反应区 10.进入反应区的洗涤气体在300-500℃的温度下进入反应区。

6. 发明授权

US4016189A Process for producing a gas which can be substituted for natural gas 失效
标题翻译：用于生产可代替天然气的气体的方法
公开(公告)号：US4016189A
公开(公告)日：1977-04-05
申请号：US598085
申请日：1975-07-22
申请人： Wolf-Dieter Muller , Friedrich-Wilhelm Moller , Heinz Jockel
发明人： Wolf-Dieter Muller , Friedrich-Wilhelm Moller , Heinz Jockel
IPC分类号： C07C1/02 , C07C1/00 , C07C9/04 , C07C67/00 , C10K3/02 , C10K3/04 , C10L3/08 , C07C1/04
CPC分类号： C10L3/08
摘要： A gas which can be substituted for natural gas is produced from a raw gas containing hydrogen and carbon oxides which is produced by the gasification of coal, tar or heavy residual oils under superatmospheric pressure. The raw gas is cooled, purified to remove catalyst poisons, particularly sulfur compounds, and then subjected to methanation and at least two stages in contact with nickel catalysts under pressures of 5-100 bars and at temperatures in the range of 200.degree.-500.degree. C. The product gas from the preceding methanation stage is reacted in the last methanation stage in contact with a catalyst which is indirectly cooled by a gas flowing in a countercurrent to the gas to be reacted.
摘要翻译：可以替代天然气的气体由含有氢气和碳氧化物的原料气体产生，该气体是在超大气压下通过煤，焦油或重质残油的气化生产的。原料气体被冷却，纯化以除去催化剂毒物，特别是硫化合物，然后在5-100巴的压力和200-500℃的温度范围内进行甲烷化和至少两个阶段与镍催化剂接触。 C.来自前一个甲烷化阶段的产物气体在最后的甲烷化阶段中与与被反应的气体逆流流动的气体间接冷却的催化剂接触而反应。

7. 发明授权

US5274048A Use of glycidyl phosphonates as crosslinkers in the preparation of hydrogels 失效
标题翻译：在制备水凝胶中使用缩水甘油基膦酸酯作为交联剂
公开(公告)号：US5274048A
公开(公告)日：1993-12-28
申请号：US772798
申请日：1991-10-08
申请人： Fritz Engelhardt , Ulrich Riegel , Hanss-Jerg Kleiner , Wolf-Dieter Muller
发明人： Fritz Engelhardt , Ulrich Riegel , Hanss-Jerg Kleiner , Wolf-Dieter Muller
IPC分类号： C08B15/10 , A61L15/60 , C08F8/00 , C08J3/24 , C08K5/53 , C08K5/5373 , C08L101/02 , C08F8/40
CPC分类号： A61L15/60 , C08K5/5373
摘要： The present invention relates to the use of compounds of the general formula I ##STR1## in which R denotes alkyl, alkenyl or aryl, which can be optionally substituted, as crosslinkers in the preparation of hydrogels, and to the hydrogels thus prepared and their use.
摘要翻译：本发明涉及通式I的化合物，其中R表示可任意取代的烷基，链烯基或芳基，作为制备水凝胶的交联剂，以及由此制备的水凝胶及其制备的水凝胶使用。

8. 发明授权

US5043474A Optically active rhodium complexes of 3,4-bis(diarylphosphino)pyrrolidines and their use for the preparation of phosphinothricin by asymmetric hydrogenation 失效
标题翻译： 3,4-双（二芳基膦基）吡咯烷的光学活性铑络合物及其用于通过不对称氢化制备膦丝菌素
公开(公告)号：US5043474A
公开(公告)日：1991-08-27
申请号：US466217
申请日：1990-01-17
申请人： Wolf-Dieter Muller , Hans-Jerg Kleiner
发明人： Wolf-Dieter Muller , Hans-Jerg Kleiner
IPC分类号： C07F9/30 , C07F9/572 , C07F15/00 , C08G18/10 , C08G18/28 , C08G18/83 , C08G65/32 , C08G65/329
CPC分类号： C08G65/329 , C07F15/008 , C07F9/301 , C07F9/5726 , C08G18/10 , C08G18/288
摘要： The invention relates to rhodium complexes of the formula[A--O--(CH.sub.2 CH.sub.2 O).sub.n --A].sup.2+ 2X.sup.- (Ia)and[A--O--(CH.sub.2 CH.sub.2 O).sub.m --CH.sub.3 ].sup.+ X.sup.-(Ib)in whichn=5-1,000,m=5-250,X.sup.- denotes a tetrafluoroborate, hexafluorophosphate or per-chlorate anion,A denotes a radical of the formula ##STR1## (en).sub.2 denotes two molecules of a monoolefin or one molecule of a diolefinAr denotes phenyl or phenyl which is substituted by one or two alkyl groups having 1 or 2 carbon atoms andR.sup.1 denotes an arylene or alkylene bridge,and their use for the preparation of L-phosphinothricin and its derivatives by enantioselective catalytic hydrogenation of 2,3-dehydrophosphinothricin (derivatives).

9. 发明授权

US4847013A Process for the preparation of N-phosphonomethylglycine 失效
标题翻译： N-膦酰基甲基甘氨酸的制备方法
公开(公告)号：US4847013A
公开(公告)日：1989-07-11
申请号：US210817
申请日：1988-06-24
申请人： Wolf-Dieter Muller
发明人： Wolf-Dieter Muller
IPC分类号： C07F9/38
CPC分类号： C07F9/3813
摘要： The invention relates to a process for the preparation of N-phosphonomethylglycine of the formula I ##STR1## wherein a compound of the formula II or salts and esters thereof ##STR2## in which R.sub.1 and R.sub.2 denote hydroxyl or a hydrolyzable group and R.sub.3 denotes aryl, is reacted in a closed reaction vessel in the presence of a dehydrogenation catalyst and a hydrogenation catalyst with an alkali metal hydroxide or alkaline earth metal hydroxide in water as the solvent and, when the reaction has ended, a mineral acid is added to liberate N-phosponomethylglycine from its salt.
摘要翻译：本发明涉及一种制备式I的N-膦酰基甲基甘氨酸的方法，其中式II化合物或其盐和酯（II）其中R 1和R 2表示羟基或可水解基团和R3表示芳基，在脱氢催化剂和氢化催化剂存在下，在封闭的反应容器中与碱金属氢氧化物或碱土金属氢氧化物在水中作为溶剂反应，当反应结束时，加入酸以从其盐中释放出N-膦酰基甲基甘氨酸。

10. 发明授权

US3996014A Methanation reactor 失效
标题翻译：甲烷反应器
公开(公告)号：US3996014A
公开(公告)日：1976-12-07
申请号：US583827
申请日：1975-06-04
申请人： Wolf-Dieter Muller , Friedrich-Wilhelm Moller , Karl Pirl
发明人： Wolf-Dieter Muller , Friedrich-Wilhelm Moller , Karl Pirl
IPC分类号： B01J8/02 , B01J8/04 , B01J23/00 , C07B61/00 , C07C1/00 , C07C1/02 , C07C9/04 , C07C67/00 , C10K3/04
CPC分类号： B01J8/048 , B01J8/0214 , B01J8/043 , C07C1/02
摘要： A reactor for catalytically converting gases containing carbon oxides, hydrogen and water vapor into methane under elevated temperatures and pressures. The reactor includes a substantially cylindrical outer shell which is provided at opposite end faces with a gas inlet and a gas outlet. An inner vessel contains part of the catalyst volume for the reactor which is impermeable to gas adjacent to the gas inlet. The inner vessel has a substantially cylindrical shell which defines a flow passage with the inner surface of the outer shell of the reactor and has openings for the radially inward passage of the gas mixture to be reacted. A perforated central gas-collecting tube containing no catalyst is positioned in the inner vessel and one or preferably two additional catalyst beds are positioned between the inner vessel and the gas outlet.
摘要翻译：用于在高温和高压下将含有碳氧化物，氢气和水蒸气的气体催化转化为甲烷的反应器。反应器包括基本上圆柱形的外壳，其在相对端面处设置有气体入口和气体出口。内部容器包含用于反应器的一部分催化剂体积，其对于与气体入口相邻的气体是不可渗透的。内部容器具有基本上圆柱形的壳体，其限定了具有反应器的外壳的内表面的流动通道，并且具有用于要反应的气体混合物的径向向内通道的开口。不含催化剂的穿孔的中央集气管被定位在内容器中，并且一个或优选两个另外的催化剂床位于内容器和气体出口之间。

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